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By P. den Hoed, R. I. Rambiyana

"Four sulphide minerals - pyrite (FeS2), pyrrhotite (Fe1-xS), pentlandite ([Ni,Fe]9S8), and chalcopyrite (CuFeS2) - contain the base metals and most of the iron in concentrates of platinum group metals (PGMs). In the pyrometallurgical processing of PGM concentrates these sulphides form a matte during smelting, and iron and sulphur are removed from the matte during the converting process. This paper discusses the roasting of Merensky concentrate in air before smelting, with the purpose of reducing the matte load to the converter.Roasting tests were conducted in a bench-scale rotary kiln at temperatures from 350°C to 700°C. The concentrate tested contained 17.4% sulphur and consisted of 23% pyrrhotite, 16% pentlandite, 11% chalcopyrite, and 2% pyrite. The particles were fine (d50 = 22 µm), and all the sulphide particles were liberated. Roasting in air at 550°C and 650°C for 20 minutes removed respectively 60% and 70% of the sulphur. The iron in the sulphides was oxidized to Fe3O4 (magnetite) at temperatures below 500°C and to Fe2O3 (haematite) at temperatures above 550°C. At 700°C the bed sintered and copper oxides formed. At temperatures below 450°C oxidation was incomplete: pyrrhotite remained and only 30% of the sulphur was removed. Smelting tests were conducted to assess matte fall and the deportment of copper and nickel to matte. It was evident that roasting resulted in lower matte falls (a drop of approximately 60%) compared with matte falls from unroasted concentrate. The iron and sulphur levels in the matte were reduced to below 3.5% and 22% respectively.This paper also briefly describes the mechanisms by which pyrrhotite, chalcopyrite, and pentlandite are oxidized during roasting. For chalcopyrite, the mechanism proceeds through an intermediate solid solution phase, which extends from Cu1.02Fe1.04S2 to Cu2.04Fe0.72S2 to a copper-rich solid solution of bornite (Cu4Fe1.4S4-Cu2S). The oxidation of pentlandite proceeds through a monosulphide solid solution (Ni0.39Fe0.53S-Ni0.74Fe0.15S) to a solid solution of heazlewoodite ([Ni,Fe]3}xS2). These mechanisms are explored in relation to chemical thermodynamics and microstructures."

Jan 1, 2015

By Jose a. Sanchidrian, Ramon G. Eguren, Javier L. Amigo

On December 2013 a MEMU exploded at a blasting site in Norway, after burning for more than two hours. This paper describes the analyses made to determine the actual yield of the explosion, the lessons learned from the event and the actions taken as a consequence. The conclusions of the analysis were the following: - The yield of the explosion was 650-1450 kg TNT. In terms of AN and ANE they correspond to 1300 – 3700 kg AN, or 950 – 2450 kg ANE or ANE/AN blend. These quantities are 8 to 31 % of the explosive precursors in the truck. The burning of the truck and its load for two and a half hours had consumed more than two thirds (perhaps up to 90 %) of the explosive precursor material.

Jan 1, 2016

By C MacDonald

There are many technologies available today in terms of fire and life safety in road tunnels. So many in fact that it is becoming more and more difficult for clients and contractors alike to determine what they want and what they need. From a clientÆs perspective, fire and life safety is about protection to its infrastructure and to the public at large. Conversely, the contractor is looking to meet its æfit for purposeÆ or ædeem to complyÆ requirements in the most economic and practicable way. Practices regarding fire and life safety in road tunnels have undergone a degree of transformation during the last decade or more throughout the world. This transformation has largely been driven by a series of catastrophic accidents such as the major fires in Europe including the Mont Blanc Tunnel, Tauern Tunnel, Saint-Gothard Tunnel, and now most recently in the CityLink Tunnels in Melbourne. International guidelines produced by organisations such as the Permanent International Association of Road Congresses (PIARC), the European Union, the International Tunnelling Association (ITA) and the US National Fire Protection Authority (NFPA) now provide clients, owners and designers with the tools required to define and specify the required fire and life safety systems in road tunnels. The majority of these tools are based on risk assessment and risk management. Recent road tunnel projects within Australia, however, have not referred solely to such guidelines. Clients have opted to prescribe different or additional fire and life safety requirements within the projectÆs technical specification documentation (project requirements), leaving designers and contractors with little room to implement alternatives or substitutions. Further, these project requirements are largely dictated by practice established on previous road tunnel projects within Australia. This paper looks at the current international guidelines and practices and undertakes a comparison with the EastLink tunnels in Melbourne and other road tunnels within Australia and makes assessment on whether Australian methods are the most appropriate for clients and contractors alike. Focus is directed to the key elements of fire and life safety such as:traffic envelope, barrier arrangements and emergency walkway provisions;deluge systems;drainage systems;fire rating requirements;tunnel ventilation systems;cross passage provisions;fire safety assessment;critical intelligence systems including help phones, CCTV, incident detection, tunnel signage, etc; andexternal tunnel control systems.

Jan 1, 2008

By F. Habashi

The first documentary evidence for the use of fire to extract a metal was furnished by the wall paintings of the ancient Egyptians showing workers using the blowpipe and bellows to increase the temperature to melt gold in a crucible. Furnaces grew in size and complexity, coke replaced charcoal in the blast furnace, and the Industrial Revolution took place in England that gradually spread worldwide. More metals became known and new techniques were introduced for their extraction. Among these, metallothermic reactions became prominent in the nineteenth century immediately after the discovery of the electric current and its use to liberate the alkali metals from their salts. Once these metals became available, they were used to produce aluminium from alumina that resisted all other methods of attack. Aluminium, now available on a large scale, was used to decompose the most stable compounds and liberate more metals that became the basis of modern civilization.

Jan 1, 2004

By J. -M. Lopez-Cuesta, C. Petter, B. Otazaghine, M. Batistella, R. Sonnier

"Kaolinite is a dioctahedral aluminosilicate widely used as paper filler and coating pigment. At the best of our knowledge, kaolinite is not widely used in polymer industry. Therefore, in this study, the flame retardant effect of kaolinite in ethylene vinyl acetate copolymer (EVA) and polypropylene (PP) were studied and compared with an alumina trihydrate (ATH) and Talc. Cone calorimeter results shows that the weight percentage of ATH in EVA/ATH composites must be at least 50 wt. % in order to reach an improvement in fire retardancy in terms of pHRR. In the case of EVA/kaolinite, even with 35 wt. % the pHRR is largely reduced. Comparing PP/Talc and PP/kaolinite composites at 30 wt. %, both fillers leads to same reduction in pHRR with a slightly better performance for PP/kaolinite composites. In both cases an intumescent behavior of kaolinite composites was observed that could slow the rate of the rising degradation products, allowing radical recombination reactions. Also, it was observed that kaolinite forms a protective layer on the surface of the samples, which could insulate the material. These behaviors (intumescence and formation of a protective barrier) could reduce the transfer of the degradation products to the flame and explain the better performance of kaolinite composites. INTRODUCTION The use of mineral fillers as fire retardants in polymer matrix are well known and widely studied [1]–[10]. Aluminum and magnesium hydroxides (respectively ATH and MDH) are the most widely used inorganic fire retardants. To achieve fire retardancy with these mineral fillers, about 50-60% loading is required which decrease the physical properties of the composites. The fire behavior of composite EVA has been the subject of many studies [4], [7], [9]–[15]. EVA copolymers are commonly used in the cable industry, due to their high ductility, even at high loading rates. In such applications, the flame retardant systems should be introduced into the polymer to improve the fire reaction. Many flame retardant systems have been tested but the most used industrially relates to formulations based on hydrated mineral fillers (aluminum hydroxide and magnesium hydroxide). Their low cost and reduced fumes generation explains their success. However, to obtain good performance with this type of flame retardants, it is necessary to incorporate high levels (up to 65 wt %), which severely impact other properties such as processability and mechanical behavior. The main modes of action of these flame retardants are the dilution of the gas phase, the endothermic decomposition and a barrier effect created by the inorganic oxide residue which may be improved by the incorporation of other components such as montmorillonites, silicas or talcs."

Jan 1, 2015

By A Sturgess, P McKenna, P D. Erskine, D Doley, V C. Glenn

For more than four decades, rehabilitated lands in the Bowen Basin have been planted with buffel grass (Cenchrus Ciliaris), which is often used to provide rapid, stabilising and erosion reducing cover to reshaped landforms (Erskine and Fletcher, 2013; Harwood, Hacker and Mott, 1999; Grigg, Shelton and Mullen, 2000; Naidu et al, 1997). Historically introduced to Central Queensland and encouraged by pastoralists in the early 1900s (Humphreys, 1967), the species has been extensively used by mine managers in seeding mixes (Coaldrake and Russell, 1970; Edye, 1975), and the invasive nature of the grass has led to the monodominance in rehabilitated areas of semi-arid Central Queensland. With 40 open cut coalmines in Central Queensland (Department of Natural Resources and Mines, 2015), a considerable amount of land is either disturbed mine footprint (156 200 ha) or rehabilitated (29 200 ha) (Dale, 2015), and the bulk of rehabilitation consists of relatively young (<30-year-old) developing ecosystems, with demonstrated biomass fuel loads up to 20 t/ha (Grigg, Shelton and Mullen, 2000).Uncontrolled fire poses a significant risk to rehabilitated landforms that are located in close proximity to mining infrastructure, neighbouring communities, open pits with exposed flammable coal seams and flammable stockpiled coal resource. Mine lease holders in Queensland have the added responsibility of managing and protecting any endangered regional ecosystem communities, and flora and fauna listed federally under the Environment Protection Biodiversity and Conservation Act 1999 or the State Vegetation Management Act 1999; as well as, any culturally significant sites such as scar trees or middens that are found on-site. Additionally, uncontrolled fire in rehabilitated landscapes poses a significant risk to mine site closure goals, with the potential to create altered states and stalled ecological trajectories (Grant, 2006). CITATION:McKenna, P, Glenn, V, Erskine, P D, Doley, D and Sturgess, A, 2016. Fire behaviour in buffel grass dominated mine site rehabilitation in Central Queensland, Australia, in Proceedings Life-of-Mine 2016 Conference , pp 158–162 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 28, 2016

By Negar Elhami Khorasani, Anthony Tessari, Nan Hua

Fire hazards can cause severe and irrecoverable damage to reinforced concrete (RC) tunnel linings, threatening the serviceability and resilience of transportation networks. This paper first examines the existing methodologies that are used to classify damage to tunnel linings from fire. These approaches are then supplemented with the results of advanced modeling and inputs from industry experts to propose new fire damage/ repair classifications with the associated thresholds. The results of the presented research can be used to guide fire risk assessment as well as the performance-based design of tunnel fire protection.

Jun 13, 2023

"A fire design innovation of the concrete lining of the Ohio River Bridges East End Crossing Tunnel has been developed. As a result from a fire suppression and tunnel ventilation system, the project design Heat Release Rate (HRR) was able to be constrained from 300 MW to about 50 MW. With this reduced HRR, concrete lining without passive fire protection may be acceptable, if the tunnel concrete lining will not result in explosive spalling during the designed fire event. Concrete explosive spalling test was proposed to verify this assumption. Since no standard concrete fire explosive spalling testing procedure exists, a project specific testing procedure was developed and fire tests conducted. From fire test results, it is concluded that the proposed tunnel concrete lining, in conjunction with the proposed fire suppressing and ventilation system, will not experience explosive spalling and does not require a passive fire protection system. INTRODUCTION The Ohio River Bridge East End Crossing Tunnel is part of a Public Private Partnership project, which connects transportation network between Louisville, Kentucky and southern Indiana. Located in Louisville, Kentucky, the twin-tube highway tunnel provides northbound and southbound lanes of the Kentucky approach to a new bridge across the Ohio River. Tunnel lengths are approximately 1,675-ft and 1,685 for the northbound tube and the southbound tube, respectively. Connected by two cross-passages, both tubes have a roadway width of 40-ft, for 3-lane traffic, and a vertical clearance of 26.5-ft.The Tunnel was constructed by drill and blast method with shotcrete and rock dowels as initial ground supports. The final tunnel lining consists of 16 inches cast-in-place concrete lining and 20 inches invert slab, with a waterproofing system around the tunnel perimeter. Two (2) tunnel side drains and one (1) invert drain were provided for each tube. This paper describes the rational in assessing fire design requirements of the tunnel final concrete lining, to answer the question whether a passive fire protection system is needed or not."

Jan 1, 2016

Provide reliable, early-warning fire detection instruments, telemetry, and control systems for noncoal underground mines. Approach Industrial-grade fire detection instruments and signal telemetry equipment were modified for long-term exposure to harsh underground mine conditions, then were installed in four mines to evaluate long-term performance and reliability. How It Works The elapsed time between the onset of a fire and its detection is critical because fires tend to grow in size and intensity with time. Early fire detection and warning permit the initiation of a mine's emergency plan (evacuation, fire fighting, etc.) while the fire is still small, or ideally, while it is still in the incipient stage. Fire detection and warning systems, utilizing sensitive heat, flame, smoke, and gas analyzers, provide the most rapid and reliable indication of a developing fire.

Jan 1, 1987

By Wood P. D, Pettifer G. R

In the upper coal surface in the Latrobe Valley, craters known locally as fireholes have developed due to prehistoric coal fires. They can be several hundred metres across and up to fifty metres deep, and are now filled with overburden materials varying from hard baked clays to very soft lacustrine clays. In addition to reducing coal reserves, continuous mining operations are seriously affected by fireholes. Large undulations in the upper coal surface result in a mixture of coal and overburden on the upper mining levels. The very soft lacustrine clays are unstable in the mine batters and the overburden dump, are difficult to handle on the bucket wheel excavator/conveyer system, and have insufficient bearing capacity for the large bucket wheel excavators. Early identification is essen- tial and both drilling and dynamic core penetrometer have been exten- sively used. However, this has not proved adequate in locating and defining the extent of all fireholes, due largely to their irregular shape. To overcome this a range of geophysical techniques has been trialled with very promising results. A trial area has been covered on a twenty metre grid using gravity and Geonics EM34 conductivity measurements and the same area has been covered at a closer spacing with high resolution magnetics. Image processing of contoured magnetic, EM34 conductivity and residual gravity data has resulted in very good correlation with drilling data.

Jan 1, 1989

By Louis Frost

"A FIRE which forced the sealing -of the east side of Dominion No. 16 Colliery in the Town of New Waterford, Nova Scotia, occurred on October 6th, 1952 (Figure 1).So far as can be ascertained, the fire was first noticed in the roof of No. 7 East Lateral, after a brushing shot had been fired in the pavement. There appears to .be no doubt that this shot •blew out, igniting a small feeder in the roof.Regular air measurements and air samples, taken over a long period prior to the fire, indicated that the ventilation was adequate, for at no time had the percentage of CH4 in the general air current exceeded one per cent in this location. The last regular monthly samples and air measurements, taken at the end of September, showed the condition of the ventilation to be:Return at the Top of No. 8 East WallQuantity .... 27,700 cu. ft. per min.CH4 .......................... 0.32 per centC02 ................................ 0.10 per centHowever, in the week preceding the fire the mine examiner on four occasions had reported small feeders of gas at the face of the brushing in No. 7 East Lateral.Figure 2 is a diagram of the working place where the shots were fired. The face brushing had been shot down at 3 :45 p.m. and cleaned up. Two 'hurdle screens' had also been erected, one close to the face brushing and the other fifteen feet from the face."

Jan 1, 1953

By W. Leblanc, J. Phalen

This paper tells the story of a serious mine fire on a mechanized longwall face in a submarine coal mine at Glace Bay, Nova Scotia. The story gives, in chronological order, a technical account of the steps taken to investigate, fight and contain the fire. The time during which the events took place spans from June 19 to November 7, 1975.

Jan 1, 1976

By D J. Brake

The risk from fire remains one of the most serious of underground mine disaster scenarios. The impacts of mine fires on the underground ventilation system and the production of toxic gases have been difficult to model and therefore assessments have relied largely on empirical data, historical precedent and subjective opinions. Underground fire modelling software has had limited availability and been technically challenging and time consuming to use especially for routine mine investigations. There has also been no well-accepted set of assumptions for fire modelling in mines, which has resulted in a lack of confidence in adopting its use more widely. This paper describes modelling of three critical fire scenarios in underground hard rock mines: a fire (LHD) in an underground diesel refuelling facility, a fire in an underground explosives magazine and a fire on an underground ore transport conveyor. Modelling was undertaken using VentsimÆs VentFIREÖ fire simulation module. It describes the basis of design, the key assumptions, the methodology used and provides examples of the outputs, conclusions and recommendations. It reviews the impacts of these fires on egress and entrapment strategies in the mine. Some general principles regarding improvements to ventilation circuit design based on this analysis are also recommended. Whilst the fire scenarios were based on actual case studies, they have been disguised for this paper.CITATION:Brake, D J, 2013. Fire modelling in underground mines using Ventsim Visual VentFIRE software, in Proceedings The Australian Mine Ventilation Conference , pp 265-276 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 1, 2013

By L. D. Savage

Several experiments were conducted using a large crib fire adjacent to a Kennedy Metal Products steel stopping in a simulated cross cut to evaluate the proposed mechanisms by which a mine fire would breach the stopping. Temperatures in the convective air paths on both sides of the stopping, at the surface of the roof and 16mm within the roof were measured to evaluate the effects of heat transfer. The results indicate that roof failure is the prime method of breaching this design of stopping.

Jan 1, 1996

By T. Glenn Pobanz

For more than fifty years Walter Kidde & Company, Inc. has engaged in the development and manufacturing of both fire suppression and detection equipment. Our initial work for the mining industry centered around dry chemical extinguish-ing equipment for mine haulage cars. To fulfill this need, Kidde engineered and developed a manually activated dry chemical system to provide protection for the wheel wells, cable reels, and motor compartments on various pieces of underground mining equipment. The next phase of mining operation fire protection for Kidde was the area of detection and automatic fire suppression for conveyor belt heads. Early in 1970, a field evaluation program and belt head demonstration unit was taken to 10 areas throughout West Virginia, Kentucky, Pennsylvania, and Ohio. This extensive field program was a joint effort with National Mine Service Company of Pittsburgh, Pennsylvania. The objectives of this program were to study mine hazard problems and to determine further requirements of mine operators. The resulting belt head detection system centered around our Continuous Strip Thermistor Core heat detector in conjunction with a Kidde stored pressure dry chemical extinguishing system. Continuous Strip detection has been in use for a number of years in aerospace applications. It has proven flexible and reliable for the rapid detection of overheat conditions and fires in engines of over half the aircraft flying today. The use of Continuous Strip gave us flexibility to protect surface areas over and around the actual conveyor belt head equipment. The nature of Continuous Strip allows us to bend, wrap, and attach the 20 foot long thermistor element over the desired protected points of the belt head. An integral part of the conveyor belt head protection system is the control panel utilizing our comprehensive knowledge of fire alarm control logic. This panel contains supervision circuits which sound trouble signals upon detecting a break in the Continuous Strip; breaks in the wiring to the remote electrical extinguishing activators or to the alarm bell; or loss of primary power. A separate control module provides the adjustable alarm temperature setting of the

Jan 1, 1971

Provide reasonably priced, reliable fire protection for front-end loaders. Approach Automatic fire sensing and suppression systems were developed and ruggedized for use on front-end loaders operating in harsh mine environments. How It Works Temperature sensors mounted in the loader's engine, transmission, and articulation areas detect the heat from a fire while it is still small and controllable. This triggers the release of the ABC class dry chemical extinguishing agent through a fixed piping system onto the fire. The system can also be manually activated from either the cab or ground level. Locations of the principal components of the system are shown in the drawing. Two control subsystems were designed to respond to varying fire protection needs and mine conditions. One subsystem only initiates discharge of the extinguishing agent. The other subsystem initiates visual and audible operator alarms if there is a fire sensed or if there is a fault in the control circuit.

Jan 1, 1979

By T. G. Carter

"During the early part of the 1980s, four new surface coal mines commenced operation in the Province of British Columbia. Each represented a major investment in both persons and materials in order to protect this investment in one significant area-the fixed portion of the surface coal handling system-a substantial amount of work was undertaken to ensure that the system was well protected from an outbreak of fire. A great deal of effort in this field had already been made by those coal mines which had been in operation for a number of years and experience gained at these operations was utilized in determining the level and extent of fire protection for the new mines.This paper summarizes the major problems, and suggests some of the methods of solution, in providing an adequate degree of fire protection for surface coal handling systems. It will also discuss the potential for gas and dust explosions together with ways to minimize this potential.The Fixed Coal Handling SystemNote: The word ""fixed"" has been used in its present context to denote that part of the coal handling system where the coal is moved via fixed installations such as a conveyor. It differentiates from that part of the system where coal is moved by mobile equipment.The raw coal delivered to the truck dump will undergo two major processes on its way to the rail load out. The first will be at the coal preparation plant where coal of specified quality will be extracted from the raw feed to the plant. If this coal is of metallurgical quality, and sometimes if it is of thermal quality, it will pass through a thermal dryer where part of the moisture acquired during coal preparation will be removed, i.e. the second process. As the complexity of both the coal preparation plant and the thermal dryer is such as to warrant separate considerations they will not form part of this paper. Each of the processes, however, is generally, housed in its own building, thus, containment of any hazards is usually more attainable than those existing or caused in the rest of the system."

Jan 1, 1988

By U .. C. Rojas, J .. C. Gomez

"Fire Refined Copper (EI Teniente Three Stars) has been produced at Caletones Smelter of Codelco Chile since almost the beginning of its operations.Due to changing features of the copper market, together with the targets on technical efficiency and productivity, it has become more and more relevant for copper industry to reach both, good final product quality and a proper environmental control.At present, copper refining process at Caletones Smelter takes place in two cylindrical tilting furnaces, where solid fluxes are injected through horizontal tuyeres into the molten bath. (Fig. N2 1)Solid reagents are pneumatically conveyed and injected into the liquid copper bath attaining excellent solid - liquid contact, so the impurities removal efficiencies are found to be high. Same injection tuyeres are used to introduce both oxidising agent (normal air) and reducing agent (reformed gas) into the molten bath. Air or nitrogen is used as conveying gas for solid reagents, depending on the process stage.This pap~r gives a fundamental description of the process and industrial results related to the injection of blend of sodium and calcium carbonates to remove arsenic and antimony, silica and granulated reverberatory slag to remove lead and a mixture of calcium carbonate and mineral coal to reduce the selenium content of the fire refined copper."

Jan 1, 1996

By Linda L. Chasko, Charles P. Lazzara, Ronald S. (deceased) Conti, William J. Wiehagen

Fire has long been a concern for underground mine workers. A mine fire can occur at any time and can result in a partial or total evacuation of mine personnel and the loss of lives. Fires can grow rapidly. Time is the critical element. Prompt detection, timely and accurate warnings to those potentially affected, and a proficient response by underground miners can have a tremendous impact on the social and economic consequence of a small underground fire. Fire preparedness and response have components of technology and people. These components can work synergistically to reduce the time it takes to bring the system back in balance. This report deals with the preparedness of miners to respond to underground mine fires. It is intended to aid the mining industry in understanding the various roles of emergency responders and the training techniques used to increase their skill levels. The report also presents a technology overview to assist in effective response to mine fires.

Jan 12, 2005

By Linda L. Chasko, Charles P. Lazzara, Ronald S. Conti, William J. Wiehagen

Fire has long been a concern for underground mine workers. A mine fire can occur at any time and can result in a partial or total evacuation of mine personnel and the loss of lives. Fires can grow rapidly. Time is the critical element. Prompt detection, timely and accurate warnings to those potentially affected, and a proficient response by underground miners can have a tremendous impact on the social and economic consequence of a small underground fire. Fire preparedness and response have components of technology and people. These components can work synergistically to reduce the time it takes to bring the system back in balance. This report deals with the preparedness of miners to respond to underground mine fires. It is intended to aid the mining industry in understanding the various roles of emergency responders and the training techniques used to increase their skill levels. The report also presents a technology overview to assist in effective response to mine fires.