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By F. Göktepe

Flotation gases and conditioning of the pulp with them are one of the important parameters of flotation and should be taken into account especially in the flotation of sulphide ores. In this study, flotation of pure chalcopyrite and pyrite samples were investigated with air, oxygen and nitrogen as flotation gas and the effect of conditioning with these three gases also were performed. Flotation gas was introduced for 5min, 10min, 15min and 20 min. For chalcopyrite flotation there was no drastic change in recovery when air, oxygen and nitrogen were used as flotation gas but conditioning the pulp with oxygen for 10 minutes increased the recovery about 8% where pulp potential has been approximately 25 mV with chalcopyrite and 150 mV with platinum electrodes. Conditioning with all three gases decreased the pyrite recovery by about 20% with 20 minutes conditioning. Pulp potential decreased in the presence of nitrogen while conditioning with air and oxygen increased the pulp potential for both electrodes. Generally potential increased for both minerals with oxygenation and aeration time but it was stable or slightly decreased with nitrogenation. Comparison of the gases showed that the different flotation gases do not effect flotation recovery but conditioning the pulp with these gases at pre-flotation effects chalcopyrite and pyrite flotation recovery, most dramatically pyrite.

Jan 1, 2014

By K. C. Corin, Z. G. Song, J. G. Wiese

In the present investigation flotation was used as a diagnostic to understand the effects of changes to the media during the grinding stage. The observations from flotation for different media are discussed in terms of particle size distribution, water recovery, solid recovery and valuable mineral recovery. The chemical parameters; pH, redox potential (Eh) and dissolved oxygen (DO) levels were measured. A Base Metal Sulphide (BMS) ore was ground under media of different shapes and compositions to determine the effect of different rod/ball material on the flotation performance of the ore. For a given grind (D80 = 75 µm), media shape had no effect on flotation performance of a BMS ore. Different grinding media had significant effect on slurry chemical properties and flotation performance. Mild steel rods (RMMS) produced the highest solids recovery, nickel and pyrrhotite (Po) recovery, with the highest ethylenediaminetetraacetic acid (EDTA) extractable iron and the lowest DO level. Chrome steel balls and stainless steel rods produced the lowest metal recovery, EDTA extractable iron and the highest DO level. A complementary study was conducted to investigate the effect of using different grinding media compositions, viz, ceramic, forged steel, 15% chrome steel, stainless steel and a mixture of stainless steel and 15% chrome steel (50:50) balls were investigated using a Platinum Group Mineral (PGM), UG2 ore. Grinding products of five different media produced the same solids and water recovery, but the grades and recoveries of Platinum Group Elements (PGE) and chromite were different. Grinding products of ceramic media showed the best flotation performance, with the highest PGE recovery and the lowest Cr2O3 recovery. While grinding products of stainless steel balls (SS) produced the lowest PGE recovery and highest Cr2O3 grade and recovery in the concentrates.

Jan 1, 2016

By K. C. Corin, Z. G. Song, J. G. Wiese

In the present study the effect of using different grinding media, viz, ceramic balls, forged steel balls, 15% Cr steel balls, stainless steel and mixture of stainless steel and 15% Cr steel balls (50:50) on the flotation performance of a Platinum Group Mineral (PGM) UG2 ore was investigated. Test work was conducted using a laboratory scale horizontal tumbling mill and a batch flotation cell. Power draw to achieve a specific P80 was determined for each media type. Changes in flotation behaviour were evaluated in terms of particle size distribution, water recovery, solid recovery and valuable mineral recovery. pH, Eh and DO levels were also measured. Grinding products of five different media produced similar solids and water recovery, which is indicative of the froth characteristics, but the grades and recoveries of PGE and chromite were different. The product obtained when using ceramic media showed the best flotation performance, producing the highest PGE recovery and the lowest Cr2O3 recovery. The products obtained when using stainless steel balls (SS) produced the lowest PGE recovery and highest Cr2O3 grade and recovery. The paper proposes possible reasons to explain these observations which may have significant importance for the operation of a PGM concentrator.

Jan 1, 2015

Toxic gases, mostly carbon monoxide (CO) and nitrous oxides (NOx), are invariably generated by commercial explosives under practical conditions of usage because of oxygen unbalance and non-ideal chemical reaction. Permitted explosives are statutorily required to meet the criteria stipulated by regulatory authority for their toxic fume quality for their safe use in underground coalmines. Solid blasting using P5 explosives contribute around 60% production from Indian underground coal mines. Low pull and yield per blast in solid blasting has been identified as a reason for low production and productivity of Indian underground coal mines. In an effort to improve performance of solid blasting, it was envisaged to apply air decking between suitable P5 explosives using high density polyethylene (HDPE) spacers under a Ministry of Coal, Government of India funded project. A non-deflagrating slurry explosive composition having high air gap sensitivity was specially developed for this purpose, so that air decked cartridges get detonated sympathetically with single priming. However, statutory authority in India apprehended that the use of oxygen negative HDPE spacers can influence the generation of toxic gases. The effect of using HDPE spacers on the generation of toxic gases was studied under simulated laboratory conditions with newly developed as well as with three commercial P5 explosives. The results of studies presented in this paper revealed that the level of carbon monoxide increases linearly and there is no significant effect on the level of oxides of nitrogen due to the use of HDPE spacers with selected explosives. Studies also revealed that this newly developed slurry explosive can be used for air decking up to 15 cm using HDPE spacers of weight not more than 21 g without exceeding the permissible limits for toxic gases.

Jan 1, 2008

By Yang Xiao, Zhang Yimin, Bao Shenxu, Liu Chun

Stone coal is a unique vanadium-bearing resource in China. Many techniques, such as salt roasting-water leaching, blank roasting-acid leaching, direct acid leaching etc. have been developed for vanadium extraction from stone coal. The vanadium leaching rate can reach 74.9% for stone coal from Jiangxi, but only about 27% of vanadium is leached for Hubei ore by applying salt roasting-water leaching technique. This paper investigats the vanadium occurrence in stone coal by microscope observation and electron probe, and compares the minerals components of stone coal from Jiangxi and Hubei. Although most vanadium exist as an isomorphism by replacing Al(III) from dioctahedral structure in mica group minerals in stone coal from two regions, the free vanadium is remarkably abundant in Jiangxi stone coal than in Hubei stone coal, which results the fact that vandium is relatively readily extracted from former. Moreover, the content of calcite in Hubei stone coal is much higher than that in Jiangxi stone coal. Calcium can react with V2O5 to form water insoluble calcium vanadates during roasting and this may be the reasone why the water leaching rate of vanadium is low for Hubei ore. Acid leaching is more beneficial to the vanadium leaching but other extra methods, such as adding aid-leaching agent and/or increasing acid concentration is need for the ore where vanadium is embeded firmly. This study can effectively guide the selection of vanadium extraction techniques for stone coal from different regions.

Jan 1, 2014

At times the phosphate industry, in Florida, encounters phosphate rock that gives lower than expected P2O5 recovery in the rougher plant section. The drop in recovery is typically 10% and as much as 30% or more. Variations in feed quality from day to day, shift to shift and even from drag-line to drag line, represent a challenge to the beneficiation plant operators and reagents? suppliers. Therefore, this characterization study has been initiated to identify the reasons for the differences in flotation behavior of such feeds. The study involves many samples to cover such variations. The characterization work includes: ? Mineralogical and chemical analysis; ? Size, shape, surface roughness and porosity analysis; ? Surface charge and surface contamination with other phases (minerals); ? Clay content and its relationship to phosphate and silica particles. The results correlated with flotation data and adsorption density measurements clearly establish the statistically significant variability in characteristic features that influence flotation response. This article discusses results from the above listed studies. On the basis of the obtained data, recommendations of practical approaches to overcome the problem of feed variability in phosphate flotation plants are delineated.

Jan 1, 2014

By A. Mitrašinovic, A. Wolf

"The aim of this investigation was to determine the most suitable additive for recovering metals from converter slags generated during Ni extraction. Fluxes analyzed were silica and lime and reductants included pig iron, ferrosilicon and copper-silicon compound. Slag was settled at 1300°C for one hour to simulate the smelting environment. The newly formed matte and slag were characterized by chemical composition and morphology. Microstructural studies showed that slag formed after adding reductants consisted of primarily fayalite, with traces of magnetite. Entrained matte was present in the slag mostly as prills of Ni3S2-FeS matrix and a Cu2S-FeS secondary phase below 10µm in diameter. Kinetic parameters of matte formation, valuable metal recovery rates and partition coefficients were deduced. Silica additions generated higher partition coefficients for copper and nickel than the addition of lime. Additives used as reducing agents had higher valuable metal recovery rates and partition coefficients. Silica additions favoured the formation a higher grade matte while lime additions will hinder metal recovery. Pig iron, ferrosilicon and Cu30Si were the most effective reductants for valuable metals recovery. Cu10Si and coke additions had little to no effect on valuable metals recovery."

Jan 1, 2015

By I. Milton LeBaron

OPERATION of the phosphate flotation plant at the Peace Valley mine of the International Minerals and Chemical Corporation, Florida, began in the summer of [ ] 1942. Since that time several changes have been made in the flowsheet, with resultant increases in metallurgical results. Three flowsheets, together with the comparative plant results, are given in this paper, together with a discussion of the desliming circuit used for preliminary washing of the flotation feed. FIRST FLOWSHEET CHANGES Fig. I lists the essential units in the original flowsheet at the Peace Valley plant. The figures for tonnage and grade are average for a period of two months. Mineral Separation Airflow cells are used for both the fatty acid and the amine float. Three immediate difficulties presented themselves in the use of this flow sheet: I. Floating a maximum amount of phosphate in the rougher section to give good recovery sent a low-grade concentrate to the silica float, resulting in high costs for amine reagent in that section.

Jan 1, 1946

By G. Sachs, E. J. Ripling, J. J. Lynch

INTRODUCTION General IT is general practice to evaluate the strength properties of a particular metal from its stress-strain [(S1 - E1]) curve obtained by means of a conventional tension test. Such a stress-strain curve, Fig I, illustrates two important properties of a metal, its ability to strain harden, and its ability to withstand a certain limiting stress, the "fracture stress,"[ (s'r)], and a certain limiting strain, the "ductility" [(e1)], before it fails by separation. These two fracturing characteristics are the coordinates of the point of fracture in Fig I. In the case of a metal which necks in a tension test, both the fracture stress and the ductility (measured in a tension test) are dependent upon (a) the shape of the neck and (b) average values of the stresses and strains over the cross section at the moment of fracture. However, for the purpose of this investigation, these average quantities, rather than the actual values, may be considered for reasons of simplicity. It appears that the conclusions also hold true if the analysis were carried out for actual values of fracture stress and ductility at the locus of failure. In this paper, the effects of straining (at room temperature) by various methods on [ ] the above metal characteristics, which were determined by subsequent tension tests will be discussed. According to our present knowledge, any such prestraining results in a stress-strain curve (in subsequent testing by tension), Fig 2, the general shape, or flow characteristics, of which can be derived from the original stress-strain curve of the unstrained metal minus a certain portion exhausted by the initial straining. This phenomenon is called strain hardening, and may be measured by the magnitude of the cut-off, or the "effective strain," from which the new curve must start in order to coincide in its plastic branch with the original stress-strain curve.

Jan 1, 1948

By M. A. Reyes, J. Bickson, J. R. Srednicki

Federal laws mandate the presence of refuge alternatives (RAs) in underground coal mines and provide guidelines for harmful gas removal. After an explosion, harmful gases can follow survivors into an RA and can reach a deadly concentration. Investigators from the National Institute for Occupational Safety and Health (NIOSH) tested 12 ventilation system configurations (VSCs) to purge sulfur hexafluoride (SF6) tracer gas from a built-in-place (BIP) RA in the Experimental Mine in Bruceton, PA. Using a borehole air supply, tests were conducted with airflows of 750 and 1,000 standard cubic feet per minute (SCFM). Excluding a VSC where the air inlet was 1.98 m (78 in) from the air outlet, the results show that the time to purge the SF6 concentration from 1,000 parts per million (ppm) to 25 ppm ranged from 26 to 29 minutes for an airflow of 750 SCFM and ranged from 18 to 23 minutes for an airflow 1,000 SCFM. Mines can use this information to reduce purge time in case of a mine disaster and determine which VSC to avoid. INTRODUCTION After a fire or an explosion in an underground mine, the concentration of carbon monoxide can reach a fatal level. In a mine disaster, the main goal is to escape. However, if miners cannot escape, they have to migrate to a location to find refuge and, if possible, communication, and a borehole source for a fresh air supply. To ensure survival of the miners, Federal laws mandate the presence of a refuge alternative (RA) within 304.5 m (1,000 ft) of the nearest mining face. In addition, Code of Federal Regulations Title 30 CFR Section 7 sets the guidelines for personnel tracking, RAs, and the removal of noxious gases in underground coal mines (Mineral Resources, 30 CFR, 2014). Federal regulations define an RA as a protected, secure space with an isolated atmosphere and integrated components (Mineral Resources, 30 CFR, 2014). There are three types of RAs: portable metal RAs, portable tent-type RAs, and built-in-place (BIP) RAs. A BIP RA is constructed using masonry or other stoppings to create an isolated space in a mined-out area. Blast doors are installed in one or both of the stoppings for the miners to enter the RA. Furthermore, RAs must provide the following components: breathable air, food, water, air monitoring, and harmful gas removal. Federal regulations have emphasized the mandate for breathable air and harmful gas removal in the following words: “Purging or other effective procedures shall be provided for the airlock to dilute the carbon monoxide concentration to 25 ppm” (Mineral Resources, 30 CFR, 2014). The purpose of the mine ventilation system is to provide a sufficient quantity of air to the underground mine workings, to dilute methane and other contaminants, to maintain a suitable working environment, and to prevent accidents from happening (Cheng and Wei, 2014). In addition, the organic nature of coal amplifies risks from poisonous gases, explosions, and fires (Engström et al., 2018). If an underground coal mine ventilation system fails after an explosion, the concentration of toxic gases, most notably carbon monoxide, will increase. Carbon monoxide is dangerous because it creates tissue hypoxia by binding to hemoglobin (Özmen and Aksoy, 2015).

Jan 1, 2019

By Li Yang, Andre Cezar Zingano, Alberto Fronza

"Immediate roof control is very important to the security and stability of entries in coal mining. It is also the highest cost in the coal mining operation, and roof spalling is directly responsible for coal contamination. The immediate roof in the coal mines in the State of Santa Catarina varies in lithology and in the presence of structures, such as bedding planes, vertical fractures that cut lamination, sandstone, and siltstone boulders. The presence and crossing of these structures should influence the decision of the specification of the roof support. Furthermore, the variation of rock layer and quality of the roof must be immediately followed by the variation of support specification. This work aims to study the behavior of the immediate roof under different geological and structural conditions during the excavation of entries, including the changing of the geometry of the entry as a function of time. This includes the effect of vertical fractures that cross the bedding planes of the roof and the position of those fractures on the roof. The effect of time between excavation and installing support to stabilize the roof is also examined. This study uses empirical methodologies for support design and numerical methods to study the behavior of the roof when anchored to the different scenarios proposed. The results of this work show the importance of quality characterization of the roof in terms of the type of rock and its thickness and the presence of vertical fractures that cut the bedding planes of the roof immediately.INTRODUCTION The immediate roof in a coal mine can varies in terms of typology and structural features, like bedding plane spacing and vertical joints. The roof support must be specified based on the features of the roof layer and its classification. Unal (1983) and Mark, Molinda, and Dolinar (2001) suggest that the roof support design should be based on the rock mass rating (RMR) and coal mining roof rating (CMRR), which look at rock mass classifications. These methods are based on the beam-building approach, and the bedding planes are tied together using fully grouted bolt. The bolt can be pre-tensioned or not depending the time of the curing of the resin."

Jan 1, 2017

By Amaneh E. Kenarsari

Among the different sources of uncertainty in pile bearing capacity prediction including inherent heterogeneity, measurement and model uncertainties, the inherent heterogeneity of soil properties is of particular interest and is considered in this study. Cone tip resistance data are utilized to calculate pile bearing capacity by considering vertical soil variability. In this regard, cone tip resistance component of CPT data is assumed as a random parameter. Realizations of this parameter are achieved with the aid of local average subdivisions and random field theories. Monte Carlo simulation is used to generate different realizations of CPT or CPT-u data. Pile bearing capacity was then calculated by the use of direct method. Pile bearing capacity are predicted for a project in south of Iran using this method and probability density function for the total bearing capacity of pile is plotted. Coefficient of variation of 33% for ultimate bearing capacity shows the variability of bearing capacity due to variation of soil strength in depth. Cumulative probability chart for the ultimate bearing capacity are plotted as an efficient tool for estimating ultimate bearing capacity of piles with different desired confidence levels for vertically variable soil strength properties. Significant difference between mean value of pile bearing capacity (18 MN) and limit with 95% confidence level (8 MN) emphasizes the importance of considering soil variability.

Jan 1, 2011

By R Castedo, P Segarra, I del Castillo, L M. López, J A. Sanchidrián

This work investigates some suggested methods for blast vibration monitoring on a hard surface based on 53 tests on a vibration exciter. Errors in the measurement attributable to coupling have been described as function of frequency by the rock-to-mount (or coupling) transmissibility, ie ratio of the velocity of the vibration sensor mount to the velocity of the rock motion. Transmissibility has been measured from 2 to 200 Hz, at two vibration levels (5 and 20 mm/s), in four seismographs. Attachment methods with an anchor, thermal adhesive and gypsum plaster allow stiff rock-to-mount coupling. They ensure accurate measurements (errors below 0.3 dB) for frequencies commonly found in blasting (below 100 Hz) irrespective of the mount characteristics and the vibration level. Free laid mounts and sandbagged vibration sensors lead generally to a poor, weak coupling. Errors are non-linear errors with the input velocity, ie the operating frequency window narrows as the velocity of the ground increases. Free mounts follow ground motion acceptably well (error up to 0.4 dB) at both vibration levels and frequencies below 15 Hz. At higher frequencies, free mounts lead to the largest distortions with expected errors ranging from 0.8 to 6.6 dB. Sandbagging limits the expected errors below 1.3 dB, but it does not prevent large errors that can be up to 4.5 dB. Both frequency and velocity should be considered together to assess the measurement errors instead of the expected accelerations, as it is currently made.CITATION:Segarra, P, Sanchidrián, J A, Castedo, R, López, L M and del Castillo, I, 2015. Effect of vibration sensor mounting method on the quality of vibration measurements, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 545–552 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By A. A. el-Geassy, A. A. el-Tawil, Hesham M. Ahmed, Bo Bjorkman

The Iron and steel industry is one of the most intensive energy consuming processes. The majority of iron making processes is now directed towards the uses of fossil-based energy sources like coke, coal and oil. Recently, emphasis has been paid to replace part of fossil- based energy sources with renewable biomass-derived reducing agents. In the present work, the possibility of the effective use of woody biomass in carbon-iron oxide composites was investigated. Wood powder was carbonized in N2 atmosphere at 300 up to 450oC. The carbon content in the produced bio-char increased with temperature. The porosity of the char arises from maintaining the cellular structure inherent in wood biomass increases with temperature. The reduction behavior of four iron oxide-bio char composites having different fixed carbon content were carried out non-isothermally up to 1200oC in Ar atmosphere using thermogravimetric anlyser (TGA). Quadruple mass spectroscopy (QMS) was also adopted to measure the CO, CO2 concentrations in the off gases resulted during reduction process. The effect of volatile matter on the reduction of iron oxide was intensively studied. The different phases developed in the reduced product were identified by X-ray diffraction (XRD). The reduction of composites was found to proceed in a stepwise manner (Fe2O3?Fe3O4?FexO?Fe).

Jan 1, 2015

By James Ransford Dankwah

This work investigates the effect of waste plastics addition on the reduction of iron oxide by sawdust. Composite pellets of iron oxide containing sawdust (SD), high density polyethylene (HDPE) and blends of SD/HDPE were fired under argon in a horizontal tube furnace at temperatures between 1300 and 1500 °C. Reduced samples were weighed after 10 minutes of reduction and the extent of reduction was calculated from the measured oxygen contents of the compact. The results showed improved extent of reduction when SD was blended with HDPE. The highest extent of reduction was achieved at SD:HDPE ratio of 2:3.

Jan 1, 2014

By B. J. Arnold, F. F. Aplan

Prior laboratory work has demonstrated that much of the fine ash forming minerals entering a flotation froth are there as a result of water carryover- from the bulk contents of the flotation cell (Arnold and Aplan, 1986a). Using a bank of four 8.5 m3 (300 cu ft) Wemco flotation cells cleaning a well-liberated Lower Kittanning seam coal, test results show that the sulfur and ash content of the froth is directly related to the water content of the froth (or inversely related to the percent solids in the froth). Reagent changes that result in a watery froth produce a higher ash content in the froth. A direct comparison of laboratory and plant results show that the standard laboratory flotation test produces a product higher in sulfur and ash than that produced in the plant. Caution should be exercised when extrapolating laboratory test results to the plant situation. A method of estimating coal flotation product quality in the plant based on laboratory tests is given.

Jan 1, 1991

By G. Wang, L. R. Moore, Y. Xiong, A. Gorken

"Mining is a very water intensive industry. As such, the industry has become dependent on applying alternate sources in efforts to minimize the impact on the locally available fresh water. Sources such as recycled water, sea water, and even acid mine drainage have been applied at some limited applications, while other mines may not even have the option of fresh water available in their region. However, the different sources of water will have varying concentrations and types of soluble salts and suspended solids, which can lead to dramatic differences in mineral processing when comparing these types of waters. Water quality is known to affect bubble generation and strength, mineral surface charge, and even reagent coordination properties. This paper focuses on the exploration of how water quality and soluble salts affect the flotation of iron and titanium containing minerals from feldspar, and the design of flotation collectors for optimal performance in this water.INTRODUCTIONFeldspar is defined as a tectosilicate mineral with the generic structure of MAlxSixO8, where M represents the cation (Celik, 2001). Feldspar is most often found naturally occurring with quartz, iron containing minerals (i.e mica), and titanium containing minerals (i.e. rutile). The alumina component of feldspar is of interest to glass making, while the alkali metal component is of interest to ceramics (Vidyadhar, 2002). In glass making, the alumina is known to improve product hardness, durability, and resistance to chemical corrosion. In ceramics, the alkalis act as a flux; a flux lowers the melting temperature of the mineral mixture, and assists in connecting the other components present in ceramics. Quartz is stated as having a negative effect on the melting point of the feldspar. Although quartz is typically not removed during the feldspar applications in the glass industry, it needs to be reduced for the ceramics industry. Iron and titanium based minerals are known to have negative effects on color and quality of the products in both glass and ceramics. Thus, these “contaminants” must be reduced to a certain product specification via feldspar beneficiation (Table 1)."

Jan 1, 2016

By Stuart Brashear, Lee Schettler

The effect of water on several ANFO/emulsion blend ratios are documented by both physical observations and analytical testing to demonstrate the effect even small quantities of water can have on water resistant blends.

Jan 1, 1996

By Xiaochun Xiao, Xin Ding, Yishan Pan, DI WU, Xiangfeng Lv

Rockburst is a sudden disastrous instability of coal mass that poses a serious threat to underground exploitation of coal resources; therefore, approaches of prediction and control methods are valuable for improving mining environments. The mechanical properties and bursting liability of coal with drying, under-saturated, and saturated moisture content under uniaxial compression are investigated, and the charge induction signal during coal deformation both in the laboratory and on-site is recorded in this study. The presence of water reduces the cohesion and increases the internal stress caused by non-uniform deformation of minerals, resulting in the strength, elastic modulus, and bursting liability being weakened. The charge induction precursor main frequency band is 1–100 Hz and belongs to the very-low-frequency signal regime, and it indeed varies with the loading stage, leading to specimen failure owing to changes in amplitude and continuity of the charge pulse in both the time and frequency domains. Water inhibits the richness of charge induction and reduces the bursting liability, and the earlier the precursor appears, the more total charge emerges. Moreover, measurement results indicate that the amplitude and continuity of the charge pulse decrease over a longer time, as recorded in a coal seam with water injection, further verifying the weakening of the coal dynamic characteristics. Charge induction can be a valuable tool with which to obtain the precursors for rockburst and to aid the evaluation of water injection.

Dec 26, 2022

By H. Y. Sohn, M. Y. Mohassab-Ahmed

"As part of research to develop a novel flash ironmaking process using reduction of iron ore concentrate by natural gas or hydrogen, sulfur and phosphorus distribution ratios between MgOsaturated slag and iron were determined in the temperature range 1550-1650°C under three different gas atmospheres: H2/H2O, H2/H2O/CO/CO2, and CO/CO2. The distribution coefficients of sulfur (Ls) were 4.0, 2.0, and 0.8, respectively, under these atmospheres. The distribution coefficients of phosphorus (Lp) were, respectively, 8, 17, and 20 under these atmospheres. In the flash process over -25 wt% P and S volatilize during ore concentrate downward flight in the reactor shaft in addition to avoiding coke. Therefore, iron produced by the flash ironmaking process would have much lower sulfur contents than the typical hot metal produced by the BF.IntroductionGiven the issues related to large carbon dioxide emissions and energy consumption in the existing ironmaking technologies, a novel flash ironmaking technology was conceived by Sohn [1-3] at the University of Utah. This technology is the first ironmaking process that will convert iron ore concentrate directly to metallic iron in-flight. This process will produce iron directly from concentrate without requiring pelletization or sintering and avoid the need for coke. In addition, this process concept takes full advantage of the fine particle size of concentrate with a large surface area, which permits rapid reduction by a gas. In this novel ironmaking process, potential reductants and fuels are H2, natural gas, and coal gas. Therefore, an iron-slag bath is expected to be at equilibrium with gas atmospheres of mainly H2/H2O or CO/CO2/H2/H2O, respectively, corresponding to the use of H2 or natural gas/coal gas. Since the effects of an H2O- containing atmosphere on slag properties have not been studied before, it is critical for the development of the novel flash process to determine these effects. In H2-H2O-CO-CO2 gas mixtures under ironmaking conditions, H20 was found to have the most pronounced effect on the slag chemistry [ 4, 5]. In addition, it was found in this laboratory that water in the gas atmosphere affected the distribution of Mn between slag and molten iron [6]. Most previous work used CO/CO2 gas mixture to control oxygen partial pressure (p02) [7, 8]. Others used only inert atmospheres [9], although Kor and Richardson [10] used a mixture of C02/H2 to control p02. For phosphorus, previous research focused on Ar [11], Ar-CO mixture [12], CO [13], CO/CO2 [14] or N2/CO [15]. Therefore, it was necessary to investigate the effect of water vapor content in H2-H2O-CO-CO2 mixtures on the equilibrium distribution of sulfur and phosphorus between CaO-MgOsatSiO2-Al2O3-FeO- MnO (0.2-0.8 wt%)-P2O5 (0.1-0.9 wt%) slag and molten iron as part of the development of the novel flash ironmaking technology."

Jan 1, 2014