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By Xin-liang Gao, Qing Li, Gui-qin Fu, Duo Jin, Miao-yong Zhu

"Optical microscope together with alternative wet-dry cyclic accelerated corrosion tests and XRD, SEM were employed on bridge weathering steel samples with different Mn and Ni contents which were vacuum induction melted and rolled to study their effects on the microstructure and rust layer evolution in er' containing condition. The results show that the microstructure is mainly ferrite and pearlite when Mn and Ni contents are 0.75 %, 0.42 %, respectively. Both the increase of Mn and Ni contents will make pearlite disappear while granular bainite appear, meanwhile the grain size decreases. With the increase of Mn content, the corrosion rate decreases in the initial stage, but the effect becomes little in the later stage. The increase of Ni not only improves the corrosion resistance of steel base at the initial stage but also hinders the tendency of further corrosion. As Mn content increases, a-FeOOH contents in rust layer decreases. With increase of Ni content, the content of a-FeOOH in the rust increases while that ofy-FeOOH decreases.IntroductionWeathering steels had been ~radually applied in manufacture of bridges owing to reducing the corrosion rate remarkably [I- l .Good weldability was needed for high performance bridge weathering steels. Since carbon was thought to be bad for weldability, low carbon content steel was adopted and Mn was added to amend the mechanical strength loss. Some scholars[6, 7l believed that Mn was beneficial for increasing corrosion resistance performance of the steel in marine atmospheric environment. Some scholars [S, 9l thought that Mn had little effect on corrosion resistance in marine atmospheric environment. Presently, the effect of Mn on bridge weathering steel in marine atmospheric environment still remained poorly understood. Ni was considered to be beneficial for increasing corrosion resistance performance in marine atmospheric environment [JO-l4l However, the high cost limited its application range. What would bring to the rust and corrosion by decreasing Ni content needed further research.Most researchers assumed that microstructures only affected the corrosion behavior of bare steel. But the study of Guo et al. P5l showed that the homogenous microstructures were beneficial for the corrosion resistance of steels. The effect of Mn, Ni content change on microstructure and microstructure on corrosion still remained poorly understood. In the present work, the effect of Mn and Ni on the microstructures of steel matrix, as well as the microstructures on the rust and corrosion was investigated."

Jan 1, 2014

By Mei-le He, Min Chen, Xiang Shen, Lei Xu, Lei Liu, Nan Wang, Xue-liang Yin

In the current study, Al2O3-MgO-CaO refractories were prepared at 1400-1600 by the addition of MnO micro-powders, and the effect of MnO addition on densification behavior of the refractory was discussed. The results showed that the doped MnO dissolved to MgAl2O4 phase, and promoted the growth of MgAl2O4 grains by the formation of MgAl2O4 solid solution. As a result, the dense microstructure was obtained, with the apparent porosity decreased from 19.2% to 5.4% and the bulk density increased from 2.78g/cm3 to 3.15g/cm3 after firing at 1600 for 2h by the addition of 4% MnO. In addition, a texture microstructure was observed, which is considered to be favorable to improve mechanical properties and the service life of Al2O3-MgO-CaO system refractories.

Jan 1, 2016

By George Breyer

DURING the past 25 years the steelmaker has experienced some difficulty in producing steel to meet the standards established by the metallurgist. In contrast to the past, when a chemical specification of broad limits was the only requirement, he now has to employ such tests as microscopic, macroscopic, tensile, impact, Magnaflux and even X-ray and supersonic. The development of these tests has more than set the pace for a manufacturing process of which the exactness still hinges to an important degree on the ability of the furnace operator. In our efforts to produce steel, and especially alloy steel, to meet the exactness of modern engineering specification, many factors must be taken into account. It is not sufficient to make a good heat of steel in the furnace and then be satisfied that the job is done, since there are many pitfalls between the furnace and the finished product. The literature abounds with information on melting practices, deoxidation methods and slag control, but the lack of positive information about what happens when the steel is teemed into molds is quite evident. Such questions as what is the proper mold size, shape and thickness; which is the best mold coating; what is the best rate of pour for any given steel, and what is the effect of cooling rates on quality, are still answered by opinions. It is acknowledged that a poor heat of steel cannot be improved in the pouring pit. On the other hand, a good heat can be ruined by improper handling after it leaves the furnace.

Jan 1, 1947

By Juan Hernández Ávila

This work studies the Molybdenum effect on the microestructure, mechanical properties of an as-cast ductile iron. For this study five ductile irons with different amounts of Molybdenum each were made in an induction furnace. In this material nodule count and nodularity is affected by the Molybdenum additions; The iron´s matrix, nodules and the phase were analyzed using scanning electron microscopy detecting Molybdenum only in the matrix. Mechanical properties such as hardness, microhardness, tensile strength and yield strength show increments as the Molybdenum amount is increased. In the same way, ferrite and pearlite phases display a variation in their percentage as the contents of the alloy element increase. This element has a marked influence on the pearlite interlaminar spacing. From the obtained results we conclude that Molybdenum in these quantities dissolves in solid ferrite solution during the solidification process, improving the material´s mechanical properties.

Jan 1, 2009

By R. Venugopal, V. K. Saxena, Veerendra Singh

"Ore morphology plays a vital role during the milling and liberation of minerals. This study was carried out to understand the role of mineral crystallography and mineral interfaces on the milling and liberation processes. Data related to mineral crystallography, Vickers Hardness Number and beneficiation processes were collected from literature, and detailed statistical analysis was conducted to relate these parameters. Review of the crystallographic information of minerals present in ores indicates that molecular weight and cell parameters significantly affect milling and liberation characteristics. Mineral interfaces were classified into the three categories of coherent crystals, semi-coherent and incoherent crystals, and breakage behaviors were studied. The studied cases revealed that these material interfaces control the micropore properties that play a vital role in the initiation of intergranular and intercrystalline fractures which occur in siliceous manganese ores and dolomite as a result of thermal treatment. In contrast, banded hematite jasper and coal exhibited a much more complex fracture pattern due to their coherent interfaces and finer physical associations. This study explains the effect of the various types of interfaces on milling, and the approach can be helpful in developing a methodology to enhance mineral liberation with minimum energy consumption.IntroductionComminution is a vital unit operation in the mineralprocessing, cement-making, power-generation and pharmaceutical industries. Its importance in mineral beneficiation operations is increasing every year as a result of the growing need to exploit lower-grade ore bodies and process reject materials (Blazy et al., 1994; DOE, 2005). Low-grade ores require significant energy during grinding to liberate the valuable minerals, which are further separated from the gangues by various beneficiation methods. Various attempts have been made to enhance mineral liberation during grinding to minimize energy consumption. Most of these studies focused on the analyses of the compression mechanism, chemical additives, thermal treatment, microwave treatment and electric disintegration (Klimpel and Austin, 1982; Norgate and Weller, 1994; Bearman et al., 1997; Kumar et al., 2010; Wang et al., 2011; Singh et al., 2012). However, many of these efforts had limited success, and there is a need to see the problem from a fresh perspective."

Jan 1, 2015

By Jingyuan Wang, Hengyi Zhang, Peng Lan, Ruitian Zhang, Jiaquan Zhang, Yang Li

"For the determination of mould taper and wall thickness, a 3-D numerical model of ingot-mould-hot top system has been made to evaluate the related ingot solidification process and the final soundness. The effect of mould wall thickness and the taper of its hot faces on the thermal history and the as cast structure of steel ingot has been revealed through the numerical simulation. It is shown that the ingot soundness can be improved remarkably by increasing the mould wall thickness, which is possibly beneficial to the mould life as well owning to an improved mould thermal state. The mould taper is vital to the ingot soundness but much less coherent to the mould temperature profiles. Under given casting situations, a larger mould taper can lead to a less intensity of the shrinkage porosities at the top part of ingot.IntroductionIngot casting is still one of important processes for steel production, which is adopted especially for the supply of large-sized semi-products of high quality special steels. The understanding to the solidification process is vital to both the yield improvement of casting production and the quality control of steel ingots, such as their soundness and homogeneity.The ingot processing and service performance are closely related to its defects, such as porosities and pipes[1,2], which are the most common but serious defects during ingots casting. In the late 1960s, Mahadevan and Murthy et al.[3], Irani and Kondic[4] began to analyze criteria for the prediction of shrinkage porosities in light metal casting. In 1980s, Niyama and Uchida[5], Hansen and Sahm[6,7] et al have successfully presented some related porosities and pipes criteria for steel casting. At the same time, numerical solidification simulation was well developed and applied to ingot quality studies[8-10]. However, due to the quick development of continuous casting, less emphasis has been given to the further study on ingot casting process. There leaves much work to be made for the comprehensive understanding to ingot quality improvement and the mould design by the aid of modern solidification technology[11, 12]. In this paper, the effects of mould taper and wall thickness on its thermal history, ingot solidification and the final soundness are numerically studied through solidification simulation, which has been adopted in mould design and industrial production of both the mould and its steel ingot."

Jan 1, 2012

By J. Rostami, P. P. Nelson, A. Khetwaln

Tunnel boring machines (TBMs) can be considered as the method of choice for tunneling in many projects due to the high level of efficiency and high potential productivity, safety, and applicability in a variety of subsurface conditions. The muck transportation system in a TBM tunneling operation plays a significant role in the process and impacts the overall performance of the machine. This paper introduces a recently developed method of simulating TBM operation through discrete event simulation (DES), which allows for tracking of the various activities, incurred downtimes in the operations, and overall machine utilization. The study presented here compares two different muck transportation systems, conveyor and rail, under similar geological conditions to quantify the impacts of the choice of muck transportation systems on machine utilization. The results show the applicability and extent of redundancy in the use of the two systems relative to machine capabilities and their sensitivity to geological conditions.

Jun 13, 2021

By D J. Williams, C Zhang, F E. Herrera Cabrera

Farming on bauxite residue using screw propelled equipment (SPE) has been commonly practised to accelerate dewatering and as it promotes consolidation and enhances storage capacity. However, it is unclear when and how often farming should be conducted during the transition of bauxite residue from slurry to dry solids and how deep each slurry deposition should be. To address this issue, three desiccation tanks were established in the laboratory to investigate how much farming could enhance the desiccation and consolidation of tailings. The cuboid tanks, of 350 mm in height and 300 mm in width and length and with an opening on the top, were placed on load cells to monitor the water loss during desiccation and were instrumented with moisture and suction sensors designed and developed at the University of Queensland to measure the water content profile of the residue. The bauxite residue, composed of silt-size particles with low plasticity, was hydraulically deposited in the tanks as a slurry at 27% solid content, resulting in 100 mm depth of solid material settling. Evaporation was enhanced by placing two identical electrical fans above the tanks. Two phases were conducted. In the first phase, the two tanks were left untouched for evaluating non farmed conditions and for calibrating sensors, while in the second phase, three tanks were subjected to atemporal farming using purpose-built screw propelled equipment. The experiment was terminated when the residue was completely desiccated. This paper reports on the instrumented tank set-up and the results obtained to date.

Jul 1, 2021

We describe a new method of characterising the effect of dissolved materials on the rate of coalescence of bubbles in aqueous media. Single bubbles were allowed to rise to meet the surface of an aqueous solution, and the time of persistence between arrival and bursting of bubble was measured as a function of solute concentration. A laser beam was placed just above the surface of the liquid, with a detector in the light path, so that any disturbance at the surface could be seen as a break in the beam. The arrival of a bubble at the surface could be detected from the behaviour of the trace on an oscilloscope, and when the bubble broke, another significant change in the signal could easily be seen. The time between disruptions was reported as the persistence time. The effect of a homologous series of n-alcohols (C1 to C8) on the persistence time was measured, in aqueous solution. It was found that with increasing concentration of a particular solute, the persistence time increased up to a point, and then declined. However the magnitude of the persistence time was found to increase with increasing numbers of carbon atoms in the molecule. Bubbles of 1, 2 and 3 mm diameter were used. Persistence time increased with increasing bubble diameter, the maximum values observed being of order 100 secs. For a given solute, the persistence (drainage) time increased with increasing bubble diameter. The concentration Cmax at which the maximum persistence time was observed, was found to be independent of the bubble size. It decreased uniformly as the carbon number increased, and was well correlated by the function y1/2 (dy /dc) -2 I dc)-2 . There was no apparent correlation with the surface excess at maximum persistence time.

Jan 1, 2006

The floatability of a bituminous coal in NaG solutions was evaluated using a modified Hallimond tube to delineate the role of the electrostatic interaction between bubbles and particles in determining the coal hydrophobicity. Zeta potential measurements showed that bubbles are negatively charged in the entire pH range tested, while coal particles are positively charged below pH 6.0 and negatively charged above it. Also, both sodium and chloride ions were confirmed to act as indifferent ions without any specific effects for both coal particles and bubbles. Flotation as a function of pH exhibited a maximum and minimum at low salt concentrations which is shown to be determined mainly by the coal hydrophobicity as measured by a new hydrophobic levitation technique. At high salt concentrations (above 0.1 mole/dm3), the flotation without such maximum or minimum is controlled by the electrostatic interaction between the bubble and the particle.

Jan 1, 1992

By H. Matsuoka, M. Kawata, K. Mitsuhashi, C. Tokoro, T. Kato

Copper sulfide minerals generally have high floatability, but their floatability decreases when surfaces are oxidised under some conditions. Sodium hydrosulfide, NaHS, is known both as an activator and as a depressant for copper minerals. NaHS at low concentrations activates copper oxides by sulfurising surfaces, but at high concentrations depresses copper sulfides by interfering with the adsorption of collectors. In this paper, we applied NaHS to activate oxidised chalcocite and bornite and focused on the conditions of NaHS treatments such as dosages and pH, and the effect of these conditions on the floatability of those minerals. The pure minerals treated with NaHS were analysed using zeta potential analyser and X-ray photoelectron spectroscopy. Analyses indicated that the reactions of NaHS and the products on the mineral surfaces after the reactions (i.e. oxidation, pH change) depended on whether NaHS reacted with copper or iron, and the reactions between NaHS and iron depend on NaHS concentration and pH. Flotation tests using a small column cell were performed with a single pure mineral, and using a Denver-type flotation machine with a copper sulfide ore. The results of each flotation test were utilised to clarify the floatability. The relation between flotation behaviours and analysis results were also discussed. Keywords: Chalcocite, bornite, NaHS activation, flotation, floatability

Jan 1, 2020

By Nadia H. Rafat, Iman S. El-Mahallawi, Hussein Badr, N. Khattab, Ahmed A. Abdel-Rehim

The basic part of solar water heaters is the collector and the main functional part of the collector is the absorber layer. In this work, a commercial locally available black painting (PACEN code 10382 colour 890), used for swimming pools solar heating, was modified by adding nano-graphite dispersion. The effect of nano-graphite particles percentage on the spectral absorbance of the material was examined on samples containing two values of 1.5 and 2.5% nano-graphite particles by weight. Fourier transform spectroscopy (FTIR) analysis was also used to identify the functional groups in the developed material. A simple experimental setup was designed to evaluate the performance of the developed nanodispersed selective coating polymeric based material, by measuring the increase in temperature of circulating water. It was shown that adding 1.5–2.5% nano-graphite particles to a polymer based black coating causes an increase in the optical absorptance, and an increase in the circulating water temperature.

Mar 1, 2018

By M. Fan

Froth flotation is the most widely-used method of separating fine coal, especially coal with coking properties. However, froth flotation is not efficient for treating ultrafine coal and coarse coal particles. Our previous fundamental test results demonstrated that cavitation-generated nanobubbles can significantly improve coal and phosphate flotation performance over a wide particle size range. In this study, the effect of nanobubble on the flotation performances of different particle size fractions of coal was investigated using a bank of 10-liter flotation cells, a specially designed 50 mm inside diameter column and a 152 mm inside diameter column. It was found that nanobubbles that were either directly formed on or subsequently attached to the surface of coal particles during coal froth flotation process improved flotation efficiency. The use of nanobubble in a bank of mechanical cells flotation and column flotation significantly increased the flotation recovery at a given product grade. Nanobubbles increased the flotation rate constants of different coal particle sizes. The presence of nanobubbles in flotation slurry could extend the lower and the upper particle size limits for effective coal flotation.

Jan 1, 2012

By M. Fan

Coal has in general a wide range of density from minus 1.3 to plus 2.0 g/cm3 because of its variations in purity, rank, and porosity, etc. The coal density has great impact on froth flotation performance, but much less attention has been paid to particle density than particle size. Our previous research results demonstrated that cavitation-generated nanobubbles around 700 nm in diameter can significantly improve coal and phosphate flotation performance over a wide particle size range. In this study, the effect of nanobubble on the flotation performances of different density fractions (minus 1.3, 1.3-1.4, 1.4-1.5, 1.5-1.6, 1.6-1.8, 1.8-2.0, 2.2-2.2, and plus 2.2 g/cm3) of coal was investigated using a bank of 10-liter flotation cells, a specially designed 50-mm-inside-diameter column, and a 152-mm-inside-diameter column. It was found that nanobubble has the biggest impact on the flotation performance of 1.4-1.8 g/cm3 medium-density coal particles.

Feb 23, 2014

By Yuemin Zhao, Daniel Tao, Rick Honaker, Maoming Fan

"Froth flotation is the most widely used method of separating fine coal, especially coal with coking properties. However, froth flotation is not efficient for treating ultrafine coal and coarse coal particles. Our previous fundamental test results demonstrated that cavitation-generated nanobubbles around 700 nm in diameter can significantly improve coal and phosphate flotation performance over a wide particle size range. In this study, the effect of nanobubbles on the flotation performance of different particle size fractions of coal was investigated using a bank of 10-L flotation cells, a specially designed 50-mm inside diameter column and a 152-mm inside diameter column. It was found that nanobubbles that were either directly formed on or subsequently attached to the surface of coal particles during the froth flotation process improved flotation efficiency. The use of nanobubbles in a bank of mechanical cells flotation and column flotation significantly increased the flotation recovery at a given product grade. Nanobubbles increased the flotation rate constants of different coal particle sizes. The presence of nanobubbles in flotation slurry could extend the lower and the upper particle size limits for effective coal flotation.IntroductionFor minus 0.6 mm fine coal or minus 0.15 mm ultrafine coal particles, froth flotation is known to be the most efficient and the most cost-effective separation technique. However, flotation efficiency decreases sharply with ultrafine and relatively coarse coal particles. Studies have shown that the low flotation efficiency of ultrafine particles is mainly due to the low probability of bubble-particle collision (Yoon et al., 1989; Ralston and Dukhin, 1999). Enhanced flotation of fine and ultrafine coal can be achieved by increasing collision and attachment probabilities.The top size of particles that can be recovered by flotation depends on the combination of mineral properties and flotation devices. Turbulence in flotation devices is an important factor that affects the stability of bubble-particle aggregates. Even in the flotation of fine particles, bubble-particle detachment can significantly influence the kinetics of flotation taking place in mechanical cells, which provide intensive turbulent agitation (Deglon et al., 1999). Coarse particle flotation is more difficult, because increased agitation is required to maintain particles in suspension and coarse particles are more likely to detach under turbulent conditions (Mankosa and Kohmuench, 2002; Soto and Barbery, 1991). More efficient attachment of particles and improved flotation rate has been observed when tiny bubbles coexist with conventional-sized flotation bubbles (Attalla et al., 2000; Tao et al., 2010; Fan et al., 2010a, b, c, d; Fan et al., 2012)."

Jan 1, 2015

By Wenqing Qin, Yunfan Wang, Ximei Luo, Fen Jiao

In order to investigate the effect of nanobubbles on adsorption of surfactant on mineral surface, the nanobubbles on the surface of calcite with -37µm fraction in the sodium oleate system were controlled by pressurization and decompression to mixing vessel. Subsequently, the adsorption amount of sodium oleate on the surface of calcite were detected by ultraviolet spectrum at different stirring times and different pressures. At the same time, the nanobubbles on the calcite surface were imaged with atomic force microscopy (AFM). In addition, a homemade vacuum Hallimond tube device was used for the flotation of single mineral, and the grade and recovery of minerals in concentrate was used to determine the influence of the nanobubbles on flotation. The experimental results showed that a large number of nanobubbles were found on the calcite surface by AFM under the dissolved oxygen difference (DOD) condition of -4 mg/L. And a large difference in adsorption capacity of sodium oleate on the surface of calcite was observed under different air pressure conditions. It indicated that the ambient pressure had a certain effect on the adsorption of sodium oleate on the calcite surface, and this effect did not depend on the constant low pressure or constant normal pressure, but depended on the changing process of pressure. The single mineral flotation experiment results indicated the recovery of calcite under decompression condition (formation condition of nanobubbles) was 1.5-2 times that under constant normal pressure, and the flotation time is much shorter. Moreover, the recovery under constant normal pressure was greatly influenced by flotation time. In this paper, only one aspect of the effect of nanobubbles on mineral flotation was preliminarily explored. It was confirmed that after vacuum-pumping, the adsorption of sodium oleate on calcite surface could be increased, the flotation time also was greatly reduced and the recovery of calcite was increased.

Jan 1, 2018

By M. O. Pekguleryuz, D. S. Aydin

The high temperature oxidation and ignition resistance of Mg-(0-6) wt% Nd alloys have been investigated via isothermal and continuous heating experiments conducted in air atmosphere. Alloy composition is observed to be effective in low levels (~ 0.5 %) in the ignition temperature (Ti) of the alloys; the Ti of pure Mg increased from 630 °C to 770 °C with 0.5 wt% Nd addition. However, no noteworthy improvement was achieved with further additions up to 6 wt% Nd. The initial microstructure was observed to determine the oxide structure on the surface due to the differing oxidation behavior of the phases (a-Mg + Mg12Nd intermetallics). It has been found that the formation of a Nd-depleted region at the subsurface due to extensive Nd oxidation at the oxide/intermetallic interface lowers the protective ability of the oxide scale.

Jan 1, 2015

By Richard Moldenke

The paper describes the making of pig iron from the Mayari iron ores of Cuba. The outstanding feature f this pig iron is a considerable content f nickel and chromium. As a marked improvement in the quality of castings has been noted when this iron is used in the foundry mixtures, a series f melting tests f mixtures of great variety of composition was conducted with the idea f getting comparative strengths from which the effect of nickel¬chromium could be seen. These tests, on account of their number, and degree of accuracy desired, were made by the crucible melting method. The paper gives the tables of results, a series f curves showing the inter-relation of the elements involved, and a summary of the conclusions derived. THE presence of nickel-chromium in pig iron made from Cuban ores is so well known that the word "Mayan" is unconsciously associated with it. Since 1904, when exploration of the Mayari deposits of iron ore in northeastern Cuba was undertaken, there has been increasing interest in these ores. The TRANSACTIONS contain numerous references to them. This iron ore, which is shipped to the. United States in the nodulized state, has been thoroughly tested and found very valuable; the deposit covers over 25,000 acres and there is in sight over 500,000,000 tons of ore that, by systematic mining, runs practically constant in composition. With nickel and chromium present, also titanium in sufficient quantities to attract attention, as well as extremely low phosphorus and sulfur contents, the iron founder is naturally interested in the utilization of Mayari ore for pig iron for the better grades of finished iron products. The present point of consumption of Mayari ore is at Sparrow's Point, where Mayari pig iron of any desired composition is made. The com-

Jan 9, 1922

By Kodi Ranga Swamy, N. Sankar, M. Akhila

"Until recently, liquefaction-related studies concentrated on clean sands believing that only sands are susceptible to liquefaction. However, a few earthquakes like 1976 Tangshan earthquake, the 1989 Loma Prieta earthquake, the 1999 Kocaeli earthquake, the 2010 Chile earthquake, and the 2011 Christchurch earthquake, etc. showed that sand with fines could also liquefy. The research findings on liquefaction of silty soils are limited, and several structures constructed on such soil deposits are damaged during the past earthquakes. Some previous results of research on earthquake events show an increase of liquefaction resistance in silt soils with increase the fines content, but some report the opposite trend. This study presents the results based on undrained triaxial cyclic tests which were carried out on the fine sand with fines (0%, 10%, 20% and 40% fines). The samples were prepared at the required unit weight (Dr = 50%) and saturated by using back pressure and cell pressure increments. Each consolidated sample is subjected to cyclic loading with sinusoidal wave load form at a frequency of 1 Hz. The liquefaction resistance is evaluated in terms of cyclic stress ratio required to cause 100% pore pressure or 20% failure strain occur at 15 numbers of load cycles. Results are presented in forms of pore pressure build up and axial strain propagation plots. As the fines content increased, an increase in liquefaction potential was observed.INTRODUCTIONLiquefaction and related phenomenon have been responsible for tremendous amounts of damage all around the world. In general, the liquefaction may occur in fully saturated sands, silts and low plastic clays. When the saturated soil mass is subjected to seismic or dynamic loads, there is a sudden buildup of pore water within a short duration, and it could not dissipate which leads to reducing the effective shear strength of soil mass. In this state, the soil mass behaves like a liquid and causes large deformations, settlements, flow failures, etc. This phenomenon is called soil liquefaction. As a result, the ability of soil deposit to support the foundations of buildings, bridges, dams, etc. is reduced. Liquefiable soil also exerts a higher pressure on retaining walls.This lateral movement of soil could cause settlement of the retained soil. A sudden build-up of pore water pressure during quake also triggers landslides. Liquefaction damages of structures are commonly observed in low-lying areas near the rivers, lakes, and oceans."

Jan 1, 2017

By Raj P. Singh Gaur

Due to high concentration of NaOH in the digested slurry after scheelite digestion, it is diluted to about 4N before filtration to separate sodium tungstate solution from the sludge (residue). However, in practice there may be deviations in the normality of NaOH present in the slurry. There may also be variations in the temperature of the slurry and filtration time. Slight variations in these parameters could cause tungsten losses in the sludge via the back reaction: Ca(OH)2 + Na2WO4? CaWO4 + 2NaOH This paper pertains to the effect of normality, temperature and time on the tungsten losses in the sludge that is separated from ?diluted-scheelite-slurry-in-NaOH? via filtration. Results indicated that tungsten losses in the filtered residue (sludge) were quite significant when the slurry temperature was kept at 70°C or higher. The effect of high temperature was less significant at the slurry normality of 3.6 or higher. Combination of low slurry normality (<3.6) and high temperature (>60°C) resulted into large W-losses in the sludge.

Jan 1, 2006