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By Shoichi Tsukuni, Akihiko Uchida, Kazuo Konishi

"In order to investigate the effect of grid-form deep mixing walls as a countermeasure for liquefaction damage to roads and private houses in Urayasu, Japan, three dynamic centrifuge model tests were conducted. Urayasu is located in the Tokyo Bay area, and private houses in the city incurred severe damage due to liquefaction during the 2011 Tohoku earthquake. In grid-form deep mixing walls design, the distance between grid-form walls is critical to prevent liquefaction. This study clarifies the relationship between the settlement of private houses and the distance between grid-form walls under the conditions that exist in Urayasu.INTRODUCTIONMany private houses in Urayasu, Japan suffered severe damages due to liquefaction during the 2011 Tohoku earthquake (Photograph 1). Fig. 1 shows the location of Urayasu and the maximum acceleration of the observed seismic waves in the Tokyo Bay area. At Urayasu, the duration of the seismic waves (hereafter called the Urayasu Wave) was about 2 min. The maximum acceleration was 1.57 m/s2 (Fig. 2), which is relatively small. The damages occurred in the land reclamation areas that consist of loose sand with an SPT-N value less than 10.To prevent liquefaction in future, it is necessary to adopt suitable countermeasures in the areas where many private houses suffered severe damages. Grid-form deep mixing walls are one such countermeasure. Fig. 3 and Photograph 2 show grid-form deep mixing walls. Walls are constructed using the deep cement mixing method. Fig. 4 shows a plane view of planned grid-form deep mixing walls for roads and existing private houses in Urayasu."

Jan 1, 2015

By F. Karakas

In this investigation, one of the most energy consuming stage of the cement manufacturing process, grinding stage, was studied. The aim of the study is to reduce the energy consumption. Optimum operating parameters were determined. Experimental studies were performed at three differ-ent stages. Grinding of limestone, clay and marl which are the main components of the cement, to approximately below 90 microns, was the first stage of the cement grinding. At this stage, effect of feed size and ball charge were investigated. At the second stage, the Bond work index of clinker and additives (slag, trass, limestone and gypsum) was found separately. After forming composite cement with clinker and additives, the Bond work index of this mixture was also determined, thus the results of separate grinding and grinding of mixture were compared. The Bond work index of mixture was found as 13.59 kWh/t, while the arithmetic mean of the Bond work index values of components was 14.90 kWh/t. Finally, clinker and additives (slag, trass, limestone and gypsum) were ground under the same conditions. At this stage, laboratory type of ball mill was used in order to understand grinding characteristics of the cement components. As a result of the experiments, it was found that energy consumption for the grinding will be lowered if the mills with 38 % ~ 40 % ball charge are used in the cement grinding. Moreover, grinding with mixture of clinker and additives gave better results than separate grinding of these components in terms of energy consumption.

Jan 1, 2014

By Dharmendr Kumar, Pradip, Beena Rai, Venugopal Tammishetti

"Due to rapid depletion of high grade Indian iron ores, there is a need to utilize low grade fines and slimes. However, these fines and slimes, in their current form, cannot be utilized in steel making due to their high alumina (6-10%) contents. Several beneficiation strategies such as gravity separation, magnetic separation, flotation and selective flocculation are currently being explored for the upgradation of low grade fines and slimes. In our previous work density functional theory simulations were employed to come up with selective flocculants for beneficiation of iron ore slimes. Our simulation results suggested that starch and guar gum are more selective towards iron minerals than other minerals present in the sample. Grinding of iron ore fines becomes necessary in some cases to achieve adequate liberation for removing alumina impurities in Indian iron ores. We have thus investigated effect of grinding of iron ore fines on its selective flocculation-separation.In the present work, we have taken natural iron ore fines from one of the Indian iron ore mines and ground it to -400 mesh (<37 microns) in dry and wet conditions. X-ray diffraction study confirmed the presence of minerals hematite, goethite, gibbsite and kaolinite in the sample. The fine ground samples were used in selective dispersion-flocculation study with corn starch and guar gum flocculants. It is interesting to note that even though the dry and wet ground samples possess almost similar particle size distributions, significant differences were observed in yield and grades of the concentrates thus produced. These differences may be arising due to the coating of alumina containing minerals on iron minerals. We have also studied the effect of addition of dispersant while grinding. Our study suggests that grinding conditions determine the efficiency of the separation process."

Jan 1, 2016

By Z. G. Song

As a kind of complex physicochemical process, grinding would affect the subsequent mineral processing such as flotation considerably. In this study, the effect of wet grinding on malachite and calcite flotation using sodium oleate as collector was studied. And the mechanism of the effect of grinding was investigated. Laboratory scale grinding and flotation testing of malachite and calcite samples were performed. Different grinding media were used, including steel balls and zirconia balls. It was the aim of this work to study the effect of grinding on the pulp chemistry paying particular attention to flotation recovery. The effect of grinding media and different addition location of sodium oleate on malachite and calcite flotation was studied. The methodology used in this project involved grinding the ore with and without the addition of sodium oleate in mill, measuring the pH and metal ions produced by minerals after grinding, adding various quantities of sodium oleate and determining the copper recovery. The presence of species of products on the minerals after grinding was probed using X-ray photoelectron spectroscopy (XPS), and the metal ions produced by minerals after grinding were measured by atomic absorption spectrometry (AAS). It is showed that the mil-ling environments evaluated significantly affected the flotation of malachite and calcite. This study also discusses the effecting mechanism of grinding environment on floatability of malachite and calcite.

Jan 1, 2014

By M. E. Learmont, I. Iwasaki

Grinding with steel media adversely affects the flotation response of galena. Electrochemical measurements, flotation tests, and AES, XPS, and STEM examinations were employed to identify interactions between galena and mild steel. Iron oxide, hydroxide, or sulfate species that formed on the galena surface upon contact with mild steel decreased its floatability, with the time of contact and aeration condition affecting the severity of the flotation depression. Parallel tests performed with an active metal, magnesium, indicated that floatability was also affected by the presence of a surface coating involving lead species.

Jan 1, 1985

Effect of Grinding Media on the Flotation of Sulfide Minerals

Sep 13, 2010

By H. Ipek

Industrial grinding machines used in the mineral processing industries are mostly of the tumbling mill type. These mills exist in various types: ball, rod, pebble, autogenous, and semi-autogenous. Balls and rods are traditionally media shapes used in the tumbling mills. In resent years, as an alternative to balls, grinding charges with various shapes are being used. Cylpebs are slightly tapered cylindrical grinding charges with length equaling diameter, and all the edges being radiused. Cylpebs of equal diameter and length have 50% greater surface area and 45% greater weight than balls of the same material. In addition, they have 9% higher bulk density than steel balls, or 12% higher bulk density than cast balls. An important advantage of cylpebs over balls is that cylpebs produce narrower granulometric distribution due to their shapes. However, some discrepancies were found in the literature regarding the milling performance of cylpebs in comparison with balls (Chi, 2004). In recent studies, Chi (2004) has provided detailed information on cylpebs and has compared these to balls in relation to media mass, size distribution, surface area, and input specific energy. Ipek (2006) has investigated the effects of cylpebs and balls with equal mass and surface area on the breakage rate of quartz, using cylpebs and balls separately. Similarly, Lameck and Moys (2006) have investigated the effects of balls and worn balls on breakage rate of material using worn balls as grinding environment. However, no study has attempted to investigate the effects of grinding environment other than balls on the brekage distribution. As indicated by Prasher (1987), the breakage distribution function is independent of the following variables in ball mills: hold-up (Mika et al., 1967; Kelsall et al. 1969), mill speed and ball load (Herbst and Fuerstenau, 1972), media load and ball density (Kelsall et al., 1973), mill diameter (Malghan and Fuerstenau, 1976), and powder charge (Shoji et al. 1980). The aim of the present paper is to compare the effects of cylpebs and balls on the breakage distribution function of quartz with respect to same mass and same surface area. BACKGROUND Comminution as a rate process is called kinetic approach. Studies on the kinetic approach are reviewed by Oner (2001). Oner states that grinding kinetics are based on studies by Kolmogorov in 1941 and that Robert (1950) is the first to suggest this approach. Later, Melzak, Loeveday, and Reid have improved the grinding kinetics equation; and, Austin and Lynch have conducted two basic studies on the analytical solutions of these equations. Considering the results of studies comparing the size reduction mechanisms, it has been accepted that breakage constitutes of two operations. These two basic operations, first defined by Epstein (1948), are those of selection of material for breakage and the distribution of breakage material to particle sizes smaller than the initial size (Lynch, 1977). Epstein defined the two operations as: ? Pn(y), the probability of breakage of a particle size in the nth step of the breakage process. ? F(x,y), the cumulative distributions by weight of particles of size x<y arising from the breakage of a unit mass of a size y. Probability of breakage is called a selection or a breakage-rate function (Si). Characteristics size distribution after breakage is called a breakage distribution or appearance function (Bi,j). Due to the difficulties in representing particle size distributions mathematically and constantly, the batch equation based on particle size fraction is suggested. Thus, as is the case in breakage distribution and specific rate of breakage, the breakage parameters were defined by batch grinding experiments conducted in laboratories (Oner, 2001). When effective breakage occurs in the mill, the breakage of material with single feed size fraction usually fits first order grinding kinetics and the specific rate of breakage values can be calculated through the slope of semi-log plot. The values of the breakage distributions are deduced from the size distributions at short grinding times where there is mainly size 1 material breaking and only small amount of smaller sizes to rebreak (Austin et. al., 1984). B values can be calculated by using BII. [ ] where j is the top size of the charge, Pi(t) is the cumulative percent undersize of i th size interval at the short grinding time which gives no more than about 30% broken out of the top size interval. Cumulative primary breakage distribution, Bi,j, is also defined in an empirical form by [ ] where xi is the top size and Bi,j is the weight fraction of primary breakage products. The parameters F, ? and ß define the size distribution of the material being ground. On plotting size versus Bi,j on log scale, the slope of the lower portion of the curve gives the value of ?, the slope of the upper portion of the curve gives the value of ß, and F is the intercept as in Fig.1. [ ]

Jan 1, 2009

By M. Saghaeian, R. Hejazi, Sheikhzadeh. V., A. Abazarpoor

"The morphology of iron ore concentrate particles is known to influence several properties of iron ore pellets, including drop number, compression strength, and reduction properties. This study aimed to determine why grinding methods and particle morphology influence green pellet properties. Particle morphology can be directly related to the grinding method: ball mill (BM) or high pressure grinding roll (HPGR). In this research, two iron ore concentrates, namely Gol-e-gohar and Ardakan, were ground by a BM and HPGR to produce a suitable Blaine value for pelletizing (nearly 1,900 cm2/g). Morphological features of particles were subsequently investigated by sieving and cyclone sizing for particle size distribution, the Brunauer-Emmett-Teller (BET) and Blaine methods for specific surface area (SSA) and scanning electron microscopy (SEM) for the evaluation of shape descriptors. It was concluded that HPGR resulted in generating a greater proportion of fine particles compared to ball milling. The BET results showed that the SSA of HPGR pellet feed was higher than that from the BM due to a greater proportion of cracks, indents and bulges and the creation of new fracture surfaces. SEM images processed by ImageJ software indicated that particles ground by the BM tended to be more rounded and less elongated than HPGR particles because of the breakage model of each method. To show the effect of morphology on the green pellet quality, green pelletizing was performed in a pilot pelletizing disc. The HPGR pellet feed had a higher drop number in comparison to the BM pellet feed, due to the angular and rough shape of the particles.INTRODUCTIONThe demand for fine or ultra-fine particles as feed material for ceramics, composite materials, and mineral processing is on the rise (Kotake, Kuboki, Kiya, & Kanda, 2011). The final concentrate of iron ore processing plants (filter cake) has a size range roughly between 0 and 300 µm, depending on the liberation of Fe containing particles (Meyer, 1980). In general, to produce a suitable pellet feed of appropriate quality, Blaine numbers of 1800–2000 cm2/g should be achieved (Van der meer, 2015)."

Jan 1, 2016

By Wantae Kim, Hoon Lee, Kwanho Kim, Sangbae Kim

Mechanochemical activation of starting minerals and their effect on the solid-phase synthesis and properties of ceramics with lower thermal expansion coefficient was examined. The mineral mixture, pyrophyllite-gibbsite-lithium carbonate, was prepared for the synthesis of ?-eucryptite (Li2O•Al2O3•2SiO2). Dry grinding using a planetary ball mill promoted the amorphization of the starting mixtures. XRD and FT-IR results showed that the crystallization of the target materials occurred from the ground mixtures by calcination. The crystallization of them increased with increment of grinding time and calcination temperature. In the synthesis, the trace of undesired phases such as quartz and cristobalite once formed during calcination at the temperature range from 750 to 850 °C almost disappeared and monophase ?-eucryptite was formed in the ground mixture at 950 °C. The lowest liner thermal expansion coefficient (TEC) of ?-eucryptite prepared was -2.5x10-6•°C-1. The thermal expansion behavior characteristics of the calcined

Jan 1, 2014

By Bern Klein, Randy Blaskovich, Reem Roufail

"Morphology is a tool that is rarely used for mineral breakage mechanism evaluation. Ground particles are typically assessed for their size distribution. They are also visually analyzed using image analysis. However, image analysis is not a comprehensive evaluation of the particle surface texture. It evaluates particle’s size parameters such as area, diameter, and perimeter amongst other features. On the other hand, morphology analysis takes the particle assessment to another level of detail. Morphology analysis evaluates particles’ roundness, elongation and angularity that would indicate the degree of roughness of the particle. According to Roufail and Klein (2009), rougher surfaces are generated due to breakage along grain boundaries – intergranular breakage. Mill operation, particularly mill speed, dictates the dynamics in the mill. Stirred mills are known to break the particles via abrasion under standard operation. However, if the dynamics of the grinding media in the mill are changed, the particles could be more exposed to impact and compression loading that would lead to a different mode of breakage.In this paper, the effect of material properties and mill operating conditions on particle morphology will be studied. Hard non-sulfide versus soft sulfide minerals are compared, namely quartz and galena, respectively. Extreme mill speeds are tested covering the range of 1000 to 2000 rpm for a 4-litre Netzsch (ISA) mill. In addition to particle size distribution, micro-analysis is executed in the form of morphological analysis using a tested manual roughness point counting technique.INTRODUCTIONGrinding in general and stirred milling in particular are processes that are used to break particles to liberate metal-bearing minerals for further separation downstream. The energy required to achieve the target particle size versus maximum possible liberation has been studied intensively and it is usually the breaking point for the grinding system chosen in a process flowsheet. Operating conditions are dictated by the energy consumption. Becker et al. (2001) related different forms of energy such as input, specific, volume/mass specific energies to stress intensities and final product fineness. Other research studies focused on energy input in a stirred mill (Zheng, Harris and Somasundaran, 1996)."

Jan 1, 2011

By L. L. Chasko, D. W. Alexander

Researchers from the National Institute for Occupational Safety and Health’s Office of Mine Safety and Health Research conducted an assessment of the effects that ground control mesh might have on rock and float coal dust distribution in a coal mine. The increased use of mesh to control roof and rib spall introduces additional elevated surfaces on which rock or coal dust can collect. It is possible to increase the potential for dust explosion propagation if any float coal dust is not adequately inerted. In addition, the mesh may interfere with the collection of representative dust samples when using the pan-and-brush sampling method developed by the U.S. Bureau of Mines and used by the Mine Safety and Health Administration for band sampling. This study estimates the additional coal or rock dust that could accumulate on mesh and develops a means to collect representative dust samples from meshed entries.

Jan 1, 2014

By L. L. Chasko, D. W. Alexander

Los investigadores del National Institute for Occupational Safety and Health’s Office of Mine Safety and Health Research han evaluado los efectos que la malla de control de suelos podría tener en la distribución de polvo flotante de roca y carbón en minas de carbón. El creciente uso de mallas para controlar el desconchado o caída de material del techo y las vigas introduce superficies elevadas adicionales para recolectar el polvo de roca o de carbón. Es posible que el potencial para la propagación de explosión del polvo se incremente si el polvo flotante de carbón no es convertido en inerte de manera adecuada. Adicionalmente, la malla podría interferir con la recolección de muestras representativas de polvo cuando se usa el método de recipiente y brocha desarrollado por la U.S. Bureau of Mines y usada por la Mine Safety and Health Administration para muestreo de banda. Este estudia hace una estimación del polvo de roca o carbón adicional que pudiera acumularse en la malla y desarrolla un método para recolectar muestras de polvo representativas atrapado en las mallas.

Jan 1, 2014

By R. K. Rath

Adsorption, electrokinetic and flotation studies were carried out. The maximum density of adsorption of guar gum was obtained at pH 7.5 on sphalerite and at pH 11.5 on galena. Flotation recovery of sphalerite was reduced only marginally by the presence of guar gum in the pH range investigated, whereas recovery of galena was reduced to about 20% at pH 12. Differential flotation tests on binary mixtures indicated that 10 ppm of guar gum can depress galena and separate it from sphalerite at around pH 12.1. Co-precipitation tests confirmed the formation of a metal ion-guar gum complex in the bulk solution, suggesting that this is the precursor to adsorption. The adsorption isotherms for both minerals followed Langmuirian behaviour, but adsorption of guar gum on galena was significantly higher than on sphalerite and dissolution tests indicated that the concentration of Pb ions released from galena was an order of magnitude greater than that of Zn ions dissolved from sphalerite

Jun 21, 1905

By Clarence Merritt

STAINLESS iron, as mild stainless steel is usually called, an alloy ranging from 11.50 to 15.00 per cent chromium with carbon under 0.12 per cent, has been considered to be not appreciably affected in respect to corrosion resistance by heat treatment. This metal, while one of the most widely used of the "straight" chromium stainless alloys, has failed in many applications because of insufficient information regarding heat treatment. These failures have been attributed to many possible causes from an inherent lack of resistance to corrosion and misapplication to mysterious electrolytic effects or comparatively minute non-metallic inclusions. Many uses for a steel with such excellent physical properties is are latent in this alloy have been lost on account of corrosion failures which could have been avoided by applying proper heat treatment. The alloy has not received the recognition or attention it should because of the fact that&apos; the details of its metallurgical behavior were not thoroughly understood. Response to heat treatment of the steel is well known as regards tensile properties, 1,2 but its application has been for improvement in tensile characteristics or on account of machining considerations rather than for corrosion prevention. The potential user of this steel has not been clearly advised in papers, either technical or commercial, that have been written about it in the last 10 years or more, of particular features that are of prime importance in developing the excellent properties of this metal. The data to be presented in this paper are concerned mainly with the effect of heat treatment on the corrosion resistance, but a study has also been made of the concurrent microstructural changes and an explanation developed for the phenomena revealed, as well as a correlation to the other physical properties-hardness, tensile characteristics and impact strength. Stainless steel, largely used for cutlery purposes, an alloy of approximately 13.00 per cent Cr with 0.30 per cent C, must be hardened and the surface prepared by polishing or pickling for best resistance to staining and corrosion.3 Monypenny reports that a loss of hardness is

Jan 1, 1932

By E. Dalgaard

During linear friction welding of titanium alloy Ti-5A1-5V-5Mo-3Cr (Ti-5553), the weld zone exhibits beta (B) grain refinement and alpha (a) phase depletion that have the combined effect of deteriorating the mechanical performance of the weldment. In this work, linear friction welded Ti-5553 was subjected to pre- and post- weld heat treatments in order to determine the conditions under which a phase depletion could be mitigated in the weld zone and thermomechanically affected zone (TMAZ). The mechanical response of the welded samples to the heat treatments was determined by performing tensile testing at room temperature. While the pre-weld heat treatments had no significant effect, the post-weld heat treatments were instrumental in restoring the strength of the starting (heat-treated) material.

Jan 1, 2011

By S. K. Shaha, W. Kasprzak, D. L. Chen, J. Friedman, F. Czerwinski

The role of solutionizing conditions within the T6 heat treatment of the cast Al-Si-Cu-Mg alloy with micro-additions of Zr-Ti-V was assessed in terms of their influence on microstructure and mechanical properties. As a solution treatment, a single step process at 485 and 510oC and a two-step process at 510 and 525oC for varying time intervals from 0.5 to 9 h, were examined. In all cases, solution treatment was followed by isothermal aging at 150oC for 100 h. The microstructural analysis showed that the solution treatment changed the eutectic silicon morphology from needle-like, present after casting, to spherical shape in the T6 state and that the extent of changes was strongly influenced by temperature and time. The Cu- and Mg-rich phases completely dissolved during solution treatment while the Fe-containing phase, Al8Si6Mg3Fe, remained partially in the microstructure. The Ti, V and Zr containing phases, Al13Si2Ti3Zr and Al3Si26FeTiV10, present in as-cast state, were partially dissolved during solution treatment, reducing their size by 10 - 48%. The studied alloy reached the maximum ultimate tensile strength of 335 MPa and yield stress of 303 MPa for two-step solutionizing with a total time of 4.5 h. It is concluded that the two-step solution treatment resulted in higher tensile properties than the single-step process.

Jan 1, 2015

By M. M. Kim

As-electrogalvanized coatings of pure Zn, Zn-11% Fe, and Zn-18% Fe coatings were characterized in terms of initial crystal structure and surface morphology. Samples were then subjected to heat treatments simulating the paint bake cycle of automobile manufacturers. Surface morphology changes were correlated with the process variables, and crystallo.graphic changes were interpreted by mapping heat treatment routes on the Fe-Zn phase diagram. The morphology of pure zinc electrogalvanized coatings with heat treatment from platelets to smeared platelets. The zn-11% Fe coating changes with heat treatment from tetrahedral nodules to a mixture of round and tetrahedral nodules, with the Zn-:18% Fe coating always having round nodules. Regarding crystal structure, a critical transformation time can be defined at any selected temperature, below which the crystal structure does not change. This temperature is related to iron content.

Jan 1, 1990

By Haofeng Xie, Lijun Peng, Xujun Mi, Xue Feng, Xiangqian Yin, Zhen Yang, Guojie Huang

The Cu/Al composite wires have been widely used in cable industry. Especially in the development of aerospace, the light weight character of wires is particularly important. The wires are fabricated by a drawing process and heat treatment. Mechanical and electrical properties are measured and analyzed. The bending behavior is studied by scanning electron microscope. INTRODUCTION Cu/Al composite is a typical bimetallic composite that has been used in plenty of fields such as automobile and aerospace. The composite has the advantages of excellent conductivity as well as low weight, which cannot be obtained from single copper or aluminum. Industrial products of Cu/Al composite include Cu/Al composite joints (Uscinowicz, R., 2013), Cu/Al bimetallic sheets (Li, X. et al., 2011), Cu/Al flat bar (Wu, Y. & Liu, X. & Xie, J., 2014) and CCA wires (Ahmed N., 1978). CCA wires refer to the composite wires that copper layer concentrically coated on the surface of aluminum core conductor, implementing solid combination of two metals on the interface and forming an integral. At present, the aircraft cable generally use copper or copper alloy conductor, which makes the wire in the aircraft occupy a considerable proportion due to the large density of copper. Therefore, the use of Cu/Al composite wires instead of copper wires for weight loss, is of great significance to the development of aerospace technology industry. Heat treatment is an indispensable procedure to improve plasticity during cold working process, which is of great importance to preparation of wires (Wang, Q. et al., 2008). During the heat treatment, the Intermetallic Compounds (IMCs) are inevitable formed at the contact area of Cu/Al due to the occurrence of diffusion (Lee, S. et al., 2012). According to the results of former researchers, kinds of IMCs were discovered. Antoine Gueydan (2014) identified the formation of three IMCs (Al2Cu, AlCu, and Al4Cu9) at the interface between copper and aluminum after thermal aging. IMCs have a significant effect to the properties of Cu/Al wires. Bending performance is a vital property for the actual application of wires. The brittle IMCs may create a stress concentration that can cause crack initiation during bending process. This work focus on the mechanical properties of Cu/Al composite wires after heat treatment. The effect of various annealing condition on mechanical and electrical properties are studied, in order to find the appropriate annealing conditions, which produce optimal combination properties of Cu/Al clad composite wires. Bending fracture of composite wires is discussed by morphology observation.

Jan 1, 2019

By H. Jung

The microstructures and grain sizes of nanocrystalline Co and Co-1.1 wt % P alloys were characterized by X-ray diffraction. The corrosion properties of as-deposited and annealed Co-l.l wt % P alloys and pure nanocrystalline Co were studied in a deaerated 0.1M H2SO4 solution using electrochemical measurements and XPS surface analysis. Potentiodynamic polarization testing and impedance measurements revealed that an addition of P to pure nanocrystalline Co improved the anodic-corrosion resistance, however, this enhanced corrosion resistance was compromised by the heat treatment process at 350 and 800°C. The corroded surface of annealed nanocrystalline Co-1.1 wt % P at 350°C exhibited a more porous P-enriched layer compared with the as-deposited case. A sample annealed at 800°C corroded uniformly showing second-phase precipitates. The enhanced corrosion resistance of as-deposited nanocrystalline Co-1.1 wt % P was attributed to the elemental P on the surface that acted to hinder the anodic dissolution kinetics of surface Co following an initial selective dissolution of Co. However, at a higher anodic overpotential region, the superior corrosion resistance of Co-l.l wt% P alloys did not last because of the formation of a non-protective surface film consisting of mainly hypophosphite and phosphate as well as elemental P.

Jan 1, 2005

By Onder Guney, Erdem Demirkesenm

"In this study, the crystallization behavior and thermal expansion coefficient of a lithium disilicate (LS2) based glass-ceramic derived from SiO2-Li02-AhO3-K2O-ZrO2 system was investigated by using x-ray diffraction (XRD), high temperature x-ray diffraction (HTXRD), differential thermal analysis (DTA) and dilatometer techniques. Analytical reagent grade chemicals were chosen as raw materials for preparing glass batches. Nucleation and crystal growth heat treatments were planned according to DTA results. The amounts of the amorphous and crystalline phases developed during the heat treatments were determined by quantitative XRD. XRD results of crystallized samples showed simultaneous formation of lithium silicate (LS) and quartz in the early stage of the crystallization followed by formation of lithium disilicate (LS2) at higher temperatures. The thermal expansion coefficients of glassceramics were also measured depending on the applied heat treatments.IntroductionSignificant developments occurred in all ceramic materials provide the fabrication of high quality dental implants [1]. Glass ceramic based dental restorations like dental inlays, crowns, bridges and veneers are becoming increasingly popular with their reliable and durable performance [2,3]. In addition to their advanced functional properties, glass ceramic implants especially lithium disilicate glass ceramics also face the esthetics expectations of patients and dentists and in this way they are starting to take the place of metal based restorations today [1,3,4,5]. Lithium disilicate glass-ceramics derived from multicomponent glass systems have some superior mechanical and optical properties comparable to natural teeth [ 6]. In restorative dentistry, mechanical characteristics of biomaterials play very crucial role in order to resist the masticatory forces occurred during biting and chewing [7] According to three point bending test results of Roland, flexural strength of the lithium disilicate glass-ceramics were 400±40 MPa and their fracture toughness (K1c) are approximately 3,3 MPa m112 [2,6]. In addition to high mechanical strength, aesthetic appearance is another important prerequisite as material for dental restorative applications. Translucency and light transmission of the LS2 glass ceramics mimic enamel. Moreover, opacity of the material can also be adjusted depending on the restoration types [2,6, 7]. These superior properties of the LS2 glass ceramics are directly related with chemical composition of the base glasses and controlled crystallization heat treatments [ 4, 7]. The aim of the present work is to determine the effect of heat treatment schedules on the crystallization behavior and thermal expansion of the LS2 glass-ceramics."

Jan 1, 2011