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By W. G. Davenport

The Cu content of industrial flash furnace concentrates varies considerably. It is usually around 30% Cu (Tables 2.1, 3.1) but it may be as high as 55% Cu and as low as 20% Cu. The mineralogy of flash furnace concentrates also varies. The most common Cu mineral is chalcopyrite (CuFeSz), but many concentrates contain bornite (CuSFeS4), chalcocite (CU2S), covellite (CuS) and even native copper (CUO). Pyrite (FeSz) :is also present in many concentrates. This chapter examines how concentrate composition affects flash smelting -with specific reference to 'low-Cu-grade' FeS2-CuFeSz concentrates. Chapter 14 does the same with 'high-Cu-grade' CuzS-CuFeSz?concentrates.

Jan 1, 2001

By S. Korman, S. B. Tuwiner

Chalcocite flotation is affected by agitation intensity during conditioning. Sodium sulphide in minute quantity may activate or depress, depending on conditions. Oxygen is a depressant while oxygen and sulphide neutralize each other by re-action at the mineral surface. Diffusion across a stagnant film at the surface governs reaction rates, while film thickness is reduced upon increase of agitation intensity.

Jan 2, 1950

By T. C. Rao, N. Suresh, M. Vanangamudi

Experiments have been conducted on a 76¬mm water-only cyclone treating cowl below 2 mm size having different proportion of -0.075 mm fines. The effect of cone angle of the cyclone (compound cone) has been analyzed on water split, separation of -0.075 mm fines, separation of coarse solids, and on separation behavior of individual size ructions of the feed. It has been noted from the results that there exists a linear relationship between the flow rate of water in the feed and flow rate of water reporting to overflow stream. This relationship is independent of the cone angle and, with changes in the fines content in the feed, only the intercept of the straight varies, keeping the slope constant. Further, it has also been found that the percentage of fines below 0.075 mm reporting to the overflow is directly proportional to the percentage of feed wafer reporting to the overflow. This relationship is found to be independent of the cone angle and the fines in the feed. The performance of the water-only cyclone has been analyzed by plotting partition curves for different experimental conditions. In addition to this, the Rosin-Rammler equation has been fitted to the partition curves of the hulk feed and individual size-fractions. Tile analysis of the results has revealed that the specific gravity of separation increases with increase in the cone angle of the cyclone while it decreases with increase in percent fines present in the feed. Mathematical relationships have been developed to relate the variation in SG50 with cone angle and percent fines in the feed.

Jan 1, 1990

By L. E. Veki, S. M. Luukkanen, J. P. Karvonen, J. O. Leppinen

Today there is a consensus that xanthate adsorption on sulfide minerals is primarily controlled by redox reactions occurring at specific potentials on these semi-conductive minerals. Consequently, it is possible to control xanthate adsorption by controlling electrochemical conditions in the system by using oxidizing and reducing agents. The scope of this study was to investigate the possibilities to increase the selectivity of Cu-Fe-Zn ore flotation by applying electrochemical control in the conditioning of the flotation feed. In this work, mild steel grinding in a nitrogen atmosphere was used as the basis to provide a negative starting potential and minimize the amount of oxidation products on sulfide mineral surfaces. To study how different potential levels affect flotation results, a controlled conditioning procedure was utilized maintaining potential at a desired level by titrating the pulp with air. Xanthate adsorption kinetics during conditioning was examined by taking pulp samples for spectrophotometric analysis and laboratory flotation tests were conducted for samples that underwent the controlled conditioning procedure in the potential range of -200mV to +200mV vs. SHE. A clear correlation was detected between chalcopyrite recovery and the potential during controlled conditioning indicating that there was a constant increase in chalcopyrite recovery when the potential was shifted to more anodic values. It is possible that utilizing potential control in the conditioning stage, a smelter grade copper concentrate can be achieved directly in rougher flotation without cleaning stages. Conditioning in favorable conditions had significant positive effects on flotation selectivity of chalcopyrite. The improvement in copper concentrate grade being predominantly caused by the depression of pyrite. By applying the controlled conditioning procedure pyrite recovery in rougher flotation was reduced even low as under 1%, while in the tests without controlled conditioning, pyrite recovery varied between 7.5 – 65.7%. The result of this work indicate that affecting collector adsorption by electrochemical control in the conditioning stage can provide significant improvement in sulfide mineral flotation and industrial applications could lead to decreased chemical consumption, reduced equipment and maintenance costs.

Jan 1, 2018

By Andrzej Warczok

Intensive smelting of copper concentrate in Teniente Converter (CT) leads to the production of high grade matte and highly oxidized slag. Smelting slag is processed in Teniente vascular slag cleaning furnace. The slag composition and forms of copper affect the slag cleaning process and final copper content. Converting of high grade matte in Pierce-Smith converter faces some difficulties in proper slagging of iron oxides. Overblowing in copper making stage allows for slag liquidation but leads to high content of copper oxide in converter slag. Converter slag recycling into CT results in the increase of the participation of oxidic copper. Separate treatment of converter slag and its impact on the forms of copper in CT slag has been analyzed. Thermodynamic properties of a system and kinetic limitations pointed out the negative effect of converter slag recycling on the forms of copper and copper recovery in slag cleaning stage. Experimental results of slag cleaning tests in a crucible scale as well as microscopic examination of laboratory and industrial slag samples supported the above analysis and permitted to formulate recommendations of separate processing of converter slag. Keywords: copper, losses, slag, recycling

Jan 1, 2001

By Dagoberto Brandão Santos, Kairo de Barros Guimarães, Túlio Magno Füzessy de Melo

The effect of the cooling conditions on the microstructure and hardness of a Dual Phase hot-rolled steel 800 MPa strength was investigated. Simulations of the cooling conditions using a dilatometer were carried out from samples of a hot rolled coil with variations of the intermediary temperature from 620 to 740°C, isothermal holding time between 1 and 10 s and coiling temperature between 50 and 400°C. In addition, two CCT (Continuous Cooling Transformation) diagrams were developed to evaluate the effect of the isothermal holding time on the phase transformations of the remaining austenite. It was observed that the intermediary temperature has a strong influence on the kinetics of the phase transformation, as well as the isothermal holding time influences the amount of ferrite formed and, consequently, the final microstructure and hardness of the material. The coiling temperature did not cause significant changes in the amount and morphology of the ferrite, but a gradual replacement of martensite with bainite was observed, which, in addition to the self-tempering effect, contributed to the hardness reduction.

Oct 1, 2019

By F. Khomamizadeh

In this study the effect of solidification rate, T6 and T7 heat treatments on thermal fatigue resistance of A319 aluminum was investigated. Increasing of the solidification rate improved the thermal fatigue resistance of the alloy by refinement of the microstructure. The most sensible areas for thermal fatigue crack growth were the eutectic zones, T6 and T7 heat treatments improved the thermal fatigue resistance of the alloy by enhancing of the matrix resistance against the crack propagation. The slight reduction of the thermal fatigue resistance after T7 heat treatment is attributed to coarsening of the precipitates which reduces the matrix resistance.

Jan 1, 2005

By Ari Jokilaakso, Junjie Shi, Zhuo Chen, Pekka Taskinen, Xiang Gao

The amount of copper flash smelting slag has increased during the recent years along with an increasing slag-to-metal ratio. During slag tapping, some copper sulfide is mechanically entrained. As a result, it is necessary to recover copper matte from the slag by suitable methods. At present, the most common way is slow, controlled cooling in a transfer ladle. However, research on the detailed effects of slow cooling and the function of slag modification is rare. This paper described experiments that were performed at different cooling rates (0.5, 1.5, 3, and 7 °C/min), with and without additive. A detailed characterization of the copper-rich phase and its particle size was subsequentlymade using SEM-EDSmicrographs and image analysis software.With a decrease in cooling rate, the particle size of the copper-rich matte phase became larger. The addition of gypsum and carbon as a slag modifier affected the size of the copper-rich phase slightly, and its chemical composition was modified compared with the experiments without additive.

Jul 31, 2020

By Jinsheng Wang, Zhixiong You, Xuewei Lv, Yu Zhang, Jie Dang

Electro-titania slag is generally used as the raw material for titanium dioxide production by sulfate process. The phase composition of titanium as well as their disseminated grain size have significant effect on the acidolysis of titanium. Anosovite is considered as the most favorable Ti-bearing phase due to its high acidolysis ef ficiency, while silicates and rutile are not soluble in concentrated sulfuric acid. Different cooling rates will play a significant effect on the phase structure and particle size, which directly affects the acidolysis ratio of titania slag. In this paper, the influence on acidolysis ratio of titania slag at different cooling rates was studied. The results revealed that slower cooling rate resulted in the formation of larger particle size and a comparatively higher acidolysis ratio was obtained. On the contrast, rapid cooling was disadvantageous to the leaching of titanium as the smaller particle size anosovite was wrapped by glass phases.

Mar 1, 2018

By H. Yoshida, H. Hatta, T. Suzuki

"The effect of the copper and magnesium contents and quenching rate during quenching on the age hardening behavior of 2000 series aluminum alloys was investigated. For the higher copper-containing specimens as conventional alloys, like AA2024, precipitation of the stable phases increased as the quenching rate decreased under the as-quenched conditions. The maximum hardness after the artificial aging of air cooled(AC) specimens was much lower than that of the water quenched(WQ)specimens. On the other hand, for the lower copper-containing specimens, coarse precipitation did not increase even in the case of the AC. The age hardening behaviors of the WQ and AC were very similar such that the maximum hardness and aging rate were almost the same. Many parts of the fine precipitates that increased the hardness were thought to be the GPB zone or fine S’ phase for the WQ and relatively coarse S’ phase for the AC. From the calculated CCT(continuous cooling transformation)diagrams, the lower copper-containing specimens could maintain the copper and magnesium in the solid solution state during the AC, so they could be quenched at a rather slower quenching rate like the AC.INTRODUCTIONThe 2000 series aluminum alloys, containing copper and magnesium as the major chemical components, are some of the well-known heat treatable aluminum alloys. These alloys have a high quenching sensitivity, thus the age hardening ability of these alloys decreases with as low quenching rate. To prevent the decrease of the age hardening ability, quenching is done by a method such as water quenching, which is not very efficient in an industrial situation, because the method requires such large equipment. For these alloys, reducing the quenching sensitivity helps them to be produced in a rather convenient way. For example, 6000 series alloys such as A6063 have low quenching sensitivity, thus they could be quenched by only air cooling just after extrusion and they do not need water quenching. Based on these reasons, investigations of these alloys with high copper and magnesium contents have been conducted in the past to find a way to lower the quenching sensitivity by adding transition elements such as manganese, chromium and zirconium (Kanno, Suzuki, & Itoh, 1986; Suzuki & Itoh, 1986; Kanno, Sakuma, Muromachi, & Watanabe, 1988). However, very few studies have focused on the quenching sensitivity of the lower copper and magnesium containing alloys because of their usage for structural components with high strength, and most of the past studies have used only the fast quenching method like water quenching. On the other hand, from our recent results, there is a possibility to lower the quenching sensitivity of 2000 series alloys with lower alloying elements. In this paper, the effect of the copper and magnesium contents with lower alloying elements and quenching rate, especially in case of slower quenching rate than conventional quenching method, on the age hardening behavior of the 2000 series alloys is investigated by the hardness measurement, structure observation and thermal analysis."

Jan 1, 2018

By E. S. Leaver

THE presence of soluble base metals in precious-metal ores usually precludes cyanidation as the best method of treatment. The laboratory experiments described in this paper show the possibility of cyanidation of gold-silver ores containing less than 0.5 per cent, of cyanide-soluble copper and the effect of zinc in the cyanide solution. PART I.-COPPER IN CYANIDATION The proposed process of cyanidation of precious-metal ores containing copper is based on the regeneration of about 80 per cent., of the cyanide used in the dissolution of the copper. The method of regeneration involves a combination of the sulfide and the acid precipitation of the copper and silver. The resultant solution is made alkaline with lime, and the gold is precipitated with zinc dust. Solubility of Copper Minerals in Cyanide Solution In order to determine the solubility of copper minerals, including metallic copper, under the usual conditions for cyanidation, experiments were conducted with synthetic ores. Each ore sample was prepared by mixing the particular pure copper mineral with barren sea sand. Both the mineral and sand were ground to pass 100 mesh before they were thoroughly mixed. The percentage of copper in each head sample was determined by direct assay, excepting the metallic copper sample, which was computed on weights before mixing. Table 1 gives the results.

Jan 1, 1929

By E. S. Leaver

THE presence of soluble base metals in precious-metal ores usually precludes cyanidation as the best method of treatment. The laboratory experiments described in this paper show the possibility of cyanidation of gold-silver ores containing less than 0.5 per cent. of cyanide-soluble copper and the effect of zinc in the cyanide solution. PART 1.-COPPER IN CYANIDATION The proposed process of cyanidation of precious-metal ores containing copper is based on the regeneration of about 80 per cent. of the cyanide used in the dissolution of the copper. The method of regeneration involves a combination of the sulfide and the acid precipitation of the copper and silver. The resultant solution is made alkaline with lime, and the gold is precipitated with zinc dust.

Jan 1, 1929

By Y. -H. Cho, J. -M. Lee, J. -G. Jung

The effects of copper on the microstructure and mechanical properties of ultrasonic melt treated Al-xCu (x=0, 4) alloys were investigated. The densities of alloys were increased and their grain sizes were decreased by UST. The hardness and electrical resistivity measurements revealed that the amount of solute Cu within Al matrix was increased by UST. Both the yield and tensile strengths of Al-4Cu alloy were increased by UST. The improved mechanical properties of Al-4Cu alloy by UST were probably due to the reduced amount of casting defects (e.g. pore), grain refinement, and enhanced solid-solution hardening of Cu.

Jan 1, 2014

By A. G. Doll

The Bond low energy impact (crushing) work index test is specified to be performed on rock specimens between 50 mm and 75 mm in effective diameter. NQ-diameter drill core, frequently used in mineral exploration programs does not meet that specification, it being 45 mm diameter or less. This paper reports the effect of performing the impact test on contiguous sections of HQ diameter and NQ diameter core, exploring the hypothesis that the contiguous intervals give equivalent results in spite of the core diameter difference.

Jan 1, 2012

By R. Phillips, A. G. Doll, D. J. Barratt

"The Bond low energy impact (crushing) work index test is specified to be performed on rock specimens between 50 mm and 75 mm in effective diameter. NQ-diameter drill core, frequently used in mineral exploration programs does not meet that specification, it being 45 mm diameter or less.This paper reports the effect of performing the impact test on contiguous sections of HQ diameter and NQ diameter core, exploring the hypothesis that the contiguous intervals give equivalent results in spite of the core diameter difference."

Jan 1, 2012

By HASSAN E. EL-SHALL, AYMAN A. EL-MIDANY, KERRI-ANN A. HUE

Modifying the hydrophobicity of clay is necessary to accommodate large mycotoxin molecules such as zearalenone (ZEN). In this study, tricaprylmethylammonium (TCMA) chloride and common corn oil were used to modify clay. The results indicate that more than 90 percent of ZEN could be removed using clays modified by TCMA and corn oil at acidic and neutral pH due to the expansion of intergallery spacing as a result of TCMA surfactant intercalation within the clay-forming layers. The removal percentage depends on the pH and amount of clay used. Complete removal can be achieved at acidic pH and small clay amount.

By Ayman A. El‑Midany, Hassan E. El‑Shall, Kerri‑Ann A. Hue

Modification of clays is necessary for the zearalenone (ZEN), as long-chain mycotoxins, removal. The organic-cations were usually used to modify the clay hydrophobicity to accommodate the large mycotoxin molecules. In this study, tri capryl methylammonium (TCMA) chloride and common corn oil were used in clay modification. Several characterization techniques such as XRD, FTIR, and TGA were used to identify the d-spacing changes after modification either by TCMA or corn oil. The results of applying the TCMA-corn oil-modified clays in ZEN removal indicated a noticeable improvement where more than 90% of ZEN could be removed in vitro at acidic and neutral pH values. The success of eliminating a high percentage of ZEN molecules is due to the expansion of intergallery spacing as a result of TCMA surfactant intercalation within the clayforming layers. The removal percentage does not depend only on pH but also on the amount of clay used. In addition, the ZEN removal in the presence of corn oil is better at acidic pH and small clay amount where the ZEN can be fully removed.

Sep 27, 2021

By Zhan Zhang, Hiromi Nagaumi, Zhen Li

"Recently, the remarkable strengthening effect of ??-Al(Mn, Fe) Si dispersoids at both ambient temperature and elevated temperature were found by several researches. A large amount of dispersoids can be formed by applying special heat treatments and within a suitable range of chemical composition of AA3xxx alloys. In the present work, the influences of Cr addition on the mechanical properties and microstructures of the Al-Mn-Mg-Si alloys were investigated. The mechanical properties at ambient and elevated temperatures were evaluated by micro-hardness and yield strength. Moreover, the microstructures in as-cast and heat-treated conditions were quantitatively analyzed by optical and electron microscopes. Results revealed that Cr also had effect on the number density and volume fraction of dispersoids. Micro-hardness and yield strength at ambient temperature increased with the increasing content of Cr, and the Cr addition increased the yield strength at elevated temperature as well. Moreover, the creep resistance at 300°C improved dramatically with the increasing content of Cr.INTRODUCTION Traditionally, AA3xxx aluminum alloys were widely used in packaging, automobile and architecture industries, because of its good formability, excellent corrosion resistance and weldability. And AA3xxx alloys were considered as non-heat-treatable alloys. However, the strengthening effect of dispersoids in AA3xxx alloys was discovered recently (Li & Arnberg, 2003;Li, Muggerud, Olsen, & Furu, 2012; Li, Zhang, & Chen, 2016; Liu & Chen, 2015).Alarge amount of dispersoids could precipitate by a proper heat treatment.In order to further improve AA3xxxalloys, the composition of the alloys should be optimized. A few previous studies were reported to investigate the influence of compositions on AA3xxx alloys. Adding Mn element could enhance the precipitation of ??-Al(Mn, Fe)Si dispersoids and improve the yield strength(Muggerud, Mørtsell, Li, & Holmestad, 2013), as long as the concentration of Mn was under the solid solution limit. Fe decreased the solubility of Mn and accelerated the precipitation rate of ??-Al(Mn, Fe)Sidispersoids(Li & Arnberg, 2003), the yield strength and creep resistance at elevated temperature could increase with an optimized content of Fe(Liu & Chen, 2016). Mg element would affect the nucleation process of ??-Al(Mn, Fe)Sidispersoids by forming metastable Mg2Si(Hirasawa, 1975; Li, Zhang, & Chen, 2017a; Lodgaard & Ryum, 2000), metastable Mg2Si precipitated during heating process and promoted the precipitation of ??-Al(Mn, Fe)Sidispersoids, moreover, Mg provided solid solution strength for AA3004 alloys(Li et al., 2016). Si increased the volume fractionof ??-Al(Mn, Fe)Sidispersoids(Muggerud et al., 2013)and decreased the size of ??-Al(Mn, Fe)Sidispersoids(Li, Zhang, & Chen, 2017b). With the addition of Mo, the size of dispersoids became finer with a higher volume fraction, the volume percentage of dispersoid free zones was reduced. Elevated temperature yield strength and creep resistance improved due to Mo addition (Liu, Ma, & Chen, 2017).However, the effect of Crelements on microstructure and mechanical properties of AA3xxx alloys were rarely reported."

Jan 1, 2018

By Lifeng Yang, Xiang Zhang, Liang Yuan, Yonghui Wang, Bing Hou, Mian Chen, Rixing Zhang

Large-scale hydraulic fracturing technique has been widely applied to the development of shale gas reservoirs, where the interaction between natural fractures and critical fracture zones has substantial impact on the propagation of hydraulic fractures. Therefore, it is of significant importance to understand and experimentally verify such mechanism. To reach this end, tri-axial fracturing tests were implemented on 400mm×400mm×400mm block samples collected from Longmaxi shale outcrops. The interplay between hydraulic and natural fractures was investigated during the tests, factoring in the role of pump rate in affecting the created fracture network. Based on the experimental results, the critical fracture zone, defined as the weak formation zone nearby the wellbore created by staged pressure implementation that is observed rapid fracture propagation upon next stage of pressure increase, was thoroughly investigated. The analysis illustrates that given the high brittleness of the shale formation, abundant critical fracture zones are generated around natural fractures with pressure building up at a relatively low pump rate. As the pump rate increases, hydraulic fractures initiate and come into play with critical fracture zones, implying emergence of a large number of micro-cracks. A changing pump rate modifies the way of interaction between hydraulic and natural fractures and the subsequent formation of fracture network. Long term fracturing fluid injection with relatively low pump rate below the activation of critical zones is suggested. Also proposed is appropriate timing when applying a specific pump rate that will contribute to the improvement of hydraulic fracture propagation.

Jan 1, 2015

By P. N. Anyalebechi

The effects of a cross-hatched grooved mold surface topography, casting speed, and superheat on the morphology of solidifying shells of aluminum alloy 3003 have been characterized by a series of immersion tests. The cross-hatched grooves were 0.232 mm deep with wavelength or spacing between 1 mm and 15 mm. The shells solidified at casting speed of less than 10 mm/s on the 1 mm spaced cross-hatched grooved mold surface were fairly uniform with little or no localized variations in thickness. However, the propensity for non-uniform shell growth morphology was exacerbated by an increase in casting speed, melt superheat, and the wavelength of the cross-hatched grooves. This is provisionally attributed to their effects on interfacial heat transfer and wetting of the mold surface by the molten metal.

Jan 1, 2008