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By L. M. Abrantes, A. P. Paiva

"A brief review of some innovative methods for the direct recovery of metals from loaded organic phases is presented; emphasis is given to electroreductive stripping and cementation, which are described and illustrated by examples: of current research. The recovery of silver using a two-phase electrolysis - by direct application of an electrical potential to a mixture of a metal loaded organic phase· containing Cyanex 471X, obtained by solvent extraction, and a stabilized sodium thiosulfate solution - is more extensively discussed. The overall efficiencies are analyzed and compared with data obtained by conventional stripping procedures. Some preliminary results achieved for the recovery of the precious metal using galvanic stripping, applied directly to similar organic solutions and involving zinc and iron powders as reducing agents, are also evaluated.Introductory ReviewThe application of hydrometallurgical methods to the recovery of metal values from ores and concentrates has been receiving a growing interest, either from researchers or from the mining industry [1].For the concentration / purification of the relatively low concentrated metallic solutions resulting from the leaching of those raw materials, solvent extraction (SX) is a well established technique [2]; the loaded organic solvent is then conventionally contacted with a suitable aqueous solution, the metal in its final form being usually recovered from this solution by electrowinning.As an efficient and / or selective stripping is sometimes difficult to achieve, depending on the specific characteristics of the system under consideration, some alternative procedures have been analyzed in order to overcome this problem. One of the chosen routes, mainly developed by Hirai and Komasawa, is to promote the reduction of the desired metal species in the organic phase, in such a way that the stripping stage becomes feasible; for the selective stripping of vanadium from a solvent containing a mixture of vanadium and molybdenum, the authors successfully used reductive [3], electro-reductive [4,5] and photo-reductive [6] techniques. The two latter methodologies have also been applied to the recovery of europium from a solvent containing europium, samarium and gadolinium [7,8].However, further processing is necessary to recover the metal in its solid state; therefore, methods causing the direct reduction of the metal species in the organic phase to their fmal metallic form would be of interest, as an intermediate step would be avoided"

Jan 1, 1997

By E. V. Redin, B. A. Dubrovsky, E. V. Knyazev, A. I. Starikov

"Ti-V magnetite is one of the most abundant composite ore resources in the world. This ore cannot be fully processed via blast furnace technology because of high content of Ti02. According to the investigations carried out in the USA and Japan ITmk3 RHF (Rotary Hearth Furnace) technology is a breakthrough in Ironmaking. Reduction, melting and slag removal can be achieved in just 10 min. The main objective of the investigation is to establish optimum operation conditions for the production of iron nuggets from Ti-V magnetite ore via the ITmk3 by means of the lab scale testing. Samples of ore from the Maly Kuybas deposit (Southern Ural), carbon reductant and fluxes were chemically analyzed. Green pellets were processed via a lab chamber furnace to simulate RHF conditions. The nuggets and slag were chemically analyzed. This preliminary test work provides valuable information which may be used for large-scale testing in a commercially sized RHF.IntroductionThe ITmk3 process upon which this paper focuses was developed by Kobe Steel in its research facilities [l]. After pilot testing at Kobe Steel's Kakogava Works in 1999-2004 the pilot demonstration plant was built and operations were successfully carried out by Mesabi Nugget joint venture in 2002-2004. Steel Dynamics put into operation the commercial plant at the Mesabi Nugget site in Hoyt Lakes (Minnesota) in 2010. Results were consistent with nugget characteristics confirming ITmk3' s flexibility with respect to raw material inputs. At the same time, no research in the field of nugget from the Ti-V magnetite bearing ore with high content of Ti02 and Alz03 has been done. It is well known, if a lot of Ti02 and Alz03 enter the blast furnace, slag becomes viscous. The viscous slag is obstacle for stable operation of the blast furnace. Besides, high content of Alz03 raises the melting temperature of gangue minerals disturbing the coalescence of reduced iron to the nuggets."

Jan 1, 2013

By M Pernechele, U König

Most of the operating steelmaking capacity currently relies on conventional, coal-based steelmaking processes. Currently, direct reduced iron (DRI) is only produced in regions where energy is available at low cost. To align with net-zero emissions goals, steelmaking capacity must transition to loweremissions steelmaking technology. Direct reduction of iron ore will get one of the preferred methods in the future due to its high technology readiness. New reduction technologies include hydrogenbased direct reduction processes. To ensure optimal efficiency during DRI production and to cope with newly developed technologies, processes need to be monitored more frequently and accurate. Traditionally quality control of raw materials and DRI has relied on time consuming physical testing, wet chemistry or the analysis of the elemental composition. The mineralogy of DRI that defines its properties is not frequently monitored. Process monitoring and quality control of DRI is possible by using modern X-ray diffraction (XRD) methods. In addition to the metallic iron content (Femet), metallisation (Metn) and the total carbon content (Ctot), XRD analysis also identifies the overall mineralogical phase composition. This allows additional information about the reduction process and enables fast counteractions on changing raw material mixtures. The benefits of the quantitative determination of the phase composition and the calculation of process critical parameters to produce DRI will be demonstrated with a case study

Sep 18, 2023

By A. G. Oppegaard

Most iron ores treated by the R-N direct reduction process yield metallic iron products considerably lower in titanium, manganese, and chromium oxides and alkaline metal sulfates/sulfides than were contained in the original ores. These metallic iron products are suitable as feed stock for the open hearth and electric steel-making furnaces. The elements which are rejected in part are acceptable in the product since the product is designed to by-pass the blast furnace. R-N reduction conditions (PCO+H2-1 atmosphere, 1830° to 2150° F.) are adjusted for each ore. The iron ore which is reduced to 90 to 95 percent metallic iron is then subjected to the conventional beneficiation techniques. Under these conditions, 55 to 80 percent of titanium oxides, 75 to 95 percent of manganese oxides, 60 to 90 percent of chromium oxides and up to 97 percent of alkaline metal sulfates contained in the ore are rejected with the gangue to the non- magnetic tailings. The metallic iron products illustrated in this work contained 89 to 96 percent total iron, one to five percent TiO2, 0.2 to one percent MnO, 0.3 to 1.6 percent Cr2O3 and/or up to one percent alkaline metal sulfide. Usually only one of these components was present. Recoveries ranged from 80 to 96 percent of the iron in ore.

Jan 1, 1958

By Zongliang Zuo, Mengqi Wei, Huaqing Xie, Qingbo Yu, Qin Qin

The resource utilization of copper slag is an attractive option of iron resource. Thermal energy recovery and direct reduction (TER-DR) system was proposed in this study. By theoretica lanalysis,the exergy efficiency of this system can reach to 57.3%. To investigate the feasibility of TER-DR system, copper slag composite pellets within lignite were prepared. As a new binder, pinesaw dust was added into the pellets. The diameter of pellets was 20 mm in experiments and the compressive strength of them was up to 831 N when the addition ratio of biomass was 29%. The results showed that the overall iron recovery reached to 90% and the separated iron concentrate was up to 93.5% when thetemperature is at 1423 K for 90 min with CaO addition ratio of 0.3. The process reduces the secondary environmental pollution of copper slag and will be applied well in the future.

Mar 1, 2018

By Roberto Parra

The selective reduction smelting of Cu2O in Cu2O-FeOx-SiO2 melts has been studied at laboratory level, using as a feed a dead roasted calcine from a copper concentrate. The purpose of the study was to evaluate the kinetic and mechanisms of the indirect reduction with CO and the direct reduction with graphite from 1260°C to 1350°C. The reduction rate by CO was found to be 10-2 to 10-1 mole Cu2O m-2s-1. The graphite reduction macrokinetics for FeO and. Fe2O3 containing melts, was found to be a first order reaction with respect to the Cu2O concentration, with a kinetic constant of 104 to 10-3 s-1. The reduction rate was not sensitive to temperature nor to stirring, in the range studied. The measured reduction rate is almost one order of magnitude larger than the observed rate for the direct reduction of FeO.

Jan 1, 1999

By Alex Stewart

Most iron bearing ores treated by the R=N Direct Reduction Process yield products lower in phosphorus than the initial ores. The sulfur is also removed and generally is in the range of 0.02 to 0.05 percent in the final R=N product, independent of the sulfur content of both the ore and carbon fuel used. The mechanism and thermodynamic justification of the principal reactions leading to the removal of both phosphorus and sulfur and the control of sulfur in the iron concentrate produced are discussed and supported by the results of laboratory experiments. In substantially all iron ores (containing up to 4% sulfur as sulfate) and solid carbon fuels (containing sulfur from 1 to 8%) tested, the rejection of sulfur has been in the order of 90-95%, with not more than 0.02 0.05% sulfur in the final metallic iron product. With respect to phosphorus-bearing iron ores ranging up to 0.70% P205, the rejection to tailings has been in the order of 70-95%, resulting in not more than 0.03 - 0.07% phosphorus in the final product.

Jan 1, 1958

By M. Ramachandran, R. G. Reddy

"A direct route for the reduction of magnesium oxide to magnesium using thermal plasma processing, with methane as the reducing gas, has been systematically evaluated. A feasibility study of the reduction reaction has been performed on the MgO-CH4 system at different methane concentrations and temperatures. The effects of changes in the key process parameters, such as the oxide-to-methane ratio and plasma power, on the yield of magnesium have been systematically evaluated. A maximum yield of about 61 mol% Mg was obtained using power of 20.0 kW and a molar ratio of MgO:CH4=1:1. Phase, morphological, elemental and binding energy analyses were performed on the product powders to understand the reduction reaction. Surface oxidation was observed in smaller magnesium particles in all the experiments, while the in-situ sintering of magnesium rods was observed at a molar ratio of MgO:CH4=1:1.5. Magnesium carbide (Mg2C3) was observed in the product, and its mechanism of formation is proposed using phase equilibrium data and a predominance diagram.IntroductionMagnesium has an excellent combination of low density and high strength. These properties have increased worldwide demand for and use of magnesium. Two major processes are used in the commercial synthesis of magnesium metal. The first method is electrolytic reduction and the second is thermal reduction using Pidgeon process. These processes can be classified as traditional techniques, but there are numerous emerging technologies that aim at reducing the production cost of Mg, its environmental impact and energy consumption. Thermal plasma processing is one emerging technique that has great potential in all the abovementioned key areas of magnesium production.Traditional reduction techniques. Two major reduction techniques, namely electrolytic and thermal reduction, have been used in the commercial production of magnesium. Electrolytic reduction is typically carried out in electrolytic cells from magnesium chloride (obtained from seawater or well and lake brines) (Tripp, 2009). The following simplified reaction shows the reduction of magnesium chloride to liquid magnesium and chlorine gas:"

Jan 1, 2015

By Lee H. G, El-Rahaiby S. K

The literature relating to reduction of sulphides by carbon using lime as sulphur-absorbent is reviewed. A stage-wise thermodynamic model is employed to evaluate the practical feasibility of the direct reduction smelting of galena (PbS) concentrates with a carbon reductant in the presence of lime; a coke-rate of 65 kg/ton Pb is predicted by the model. The experimental data on the reduction of PbS:4CaO:4C mixtures under nitrogen were correlated by means of a finite difference numerical method and the values of the intrinsic rate constant I1 were derived. The results for the uncatalysed reduction are represented satisfactorily with log I1 = 1.247(±0.522) - 5540(±610)T-1.The catalysed PbS:4CaO:4C mixtures contained 2.5 wt% of ternary (K, Li, Na)2CO3 catalyst. For the catalysed reduction it was found that log I1 = 3.981 (±0.301) -7790(±353)T-1, where I1 (in both relations) is expressed in moles.(g.C.)-1.atm-1.s -I. The catalytic enhancement faclor was found to be quite large in the 1068 to 1262°K temperature range investigated here.

Jan 1, 1991

By Ryosuke O. Suzuki

A combined process of electrolysis of CaO in the molten CaCl2 and of calciothermic reduction, so-called OS process, was applied to prepare metallic vanadium directly from V2O3. The fine metallic powder containing 1860 mass ppm oxygen was obtained using 0.5mol%CaO-CaCl2 melt for 10.8 ks at 1173 K. The oxygen level did not decrease further even when twice electricity was applied. Because the metallic vanadium could be electrochemically deoxidized to the level of 10 ppm oxygen from 1.48 %, the large amount of by-product, CaO, due to reduction and the large surface area of the fine particles are the reasons of high oxygen content in the reduced powder.

Jan 1, 2006

By Clements R. J, Davey J. M

Development of the process from the pilot stage to the current operation of the Capel, WA plant is briefly described.The design criteria for a larger sized plant are discussed together with factors that relate suitable feedstocks and coal types to the capital cost, capacity and product grade of future plants at locations other than Capel. The application of the process to the direct reduction of iron ores is briefly discussed including its commercial application at Rockwood, Tennessee.

Jan 1, 1980

By Clements R. J, Davey J. M

Development of the process from the pilot stage to the current operation of the Capel, W.A. plant is briefly described. The design criteria for a larger sized plant are discussed together with factors that relate suitable feedstocks and coal types to the capital cost, capacity and product grade of future plants at locations other than Capel. The application of the process to the direct reduction of iron ores is briefly discussed including its commercial application at Rockwood, Tennessee.

Jan 1, 1979

By Jack R. Miller

This session has been organized to suggest to you that the development of direct reduction is important to the iron ore mining and coal mining industries. The papers presented this morning will include a discussion of the costs of making direct reduced iron (DRI), the iron ore and coal supplies needed to produce DRI, the financing of direct reduction (DR) projects and, probably most important, the impact of the DR development on the iron ore and coal industries. For starters, this opening presentation offers a brief statement about DR practice and DRI, under the title that should surprise no one: "Direct Reduction: What Is It?" There is always the chance? that a brief statement may become long and complicated. But, by mixing some slides borrowed from Hal Lownie with a larger number of photographs accumulated from other sources, I hope to avoid such pitfalls.

Jan 1, 1978

By T. J. Goff, G. M. Denton

Mintek has developed the EnviroplasTM process for the treatment of solid wastes from the metallurgical industry, especially steel plant dusts, without requiring agglomeration to produce inert slag and at the same time recover metal values such as nickel, chromium and zinc. The products that are generated in the plasma-arc process are usually a metal and a non-toxic slag, which are tapped from the furnace in liquid form. The metal is mainly composed of chromium, nickel and manganese. During the production of stainless steel between 30 and 70 kg of dust and fine waste is generated per ton of steel. Mintek has successfully processed around 1000t of AOD/EAF dust on a toll treatment basis in order to recover the contained Cr and Ni. The metal produced contained 18.5 per cent Cr, and 5.5 per cent Ni. All slag samples tested conformed to US EPA regulations for disposal. The chromium and nickel recovery to metal was 90 and 98 per cent respectively, on a once through basis i.e. no baghouse dust recycle. Slag tapping temperatures varied between 1650°C and 1750°C. The average actual energy requirement excluding furnace heatlosses of smelting steel plant dust with anthracite as reductant was 1.36MWh/ ton of dust. The total mass of feed reporting to the off-gas stream was 10 per cent. The average ZnO content of the fume was 35.5 per cent.

Jan 1, 2004

By Rui-Qing Li, John G. Peacey, Peter J. Hancock

"Noranda has been investigating a pyrometallurgical process for the direct recovery of zinc from zinc concentrate and zinc and iron containing residues. The process consists of injecting dry zinc concentrate and secondary zinc materials into a molten iron oxysulphide bath, volatilizing metallic zinc into furnace off gas essentially free of sulphur or S02, fixing sulphur contained in the feed materials as iron oxysulphide matte which is disposed, and recovering metallic zinc in an ISP type lead splash condenser. Combustion of petroleum coke with air or oxygen enriched air inside the oxygen containing matte supplies part of the heat, and the products of combustion dilute the zinc-laden gas to a desired level.This paper describes the process concept, thermodynamic background, experimental tests, mass and heat balance calculation for a conceptual flowsheet, environmental stability of the residue and advantages and disadvantages of the process. Experimental tests have successfully proved the process concept and thermodynamic predictions. Direct smelting of zinc concentrate and residues inside an iron oxysulfide bath has a great potential to become a cost effective and flexible zinc smelting process.1. INTRODUCTIONZinc is mainly produced by a roast-leach-electrowinning process route, which accounts for about 80% of the world primary zinc production. This process produces high quality zinc with very high zinc recovery (>95%) but suffers from several major drawbacks such as using high cost electricity as reductant, producing environmentally problematic iron containing leach residue (jarosite or goethite) and the difficulty in treating secondary zinc feed materials containing high impurity levels, such as electric arc furnace dusts from the steel industry, and other complex sources. Also in some areas, markets for sulphuric acid are distant resulting in negative realizations on acid sales.The Imperial Smelting Furnace (ISF) process is the major pyrometallurgical process to treat zinc-lead concentrate. The advantage of this process over the electrolytic zinc process is its flexibility in treating high-lead, bulk concentrates with high recoveries of lead, copper and precious metals. However, this is a two-stage process involving sintering of Zn-Pb concentrates followed by blast furnace reduction. The process requires large amounts of high-quality coke which is a major operation cost, and the sintering process which results in serious environmental problems."

Jan 1, 1996

By W. K. Connor, O&apos

Thermal Treatment Technology Division Albany Research Center, U.S. Dept. of Energy Oregon. This evaluation included a characterization study and direct smelting tests conducted in a bench-scale electric arc furnace (EAF). In contrast to other thermal treatment technologies considered for these wastes (i.e., fluidized bed combustion), direct smelting in the EAF can process 100% of the wastes without prior beneficiation, and utilizes solid oxidant additions (in this case iron ore) rather than air to oxidize the carbon. This solid oxidant addition is advantageous because it results in the production of several value-added furnace products. These products include cast iron resulting from the reduction of the iron oxides, baghouse dust containing virtually all of the zinc from the residues, and a clean (nonhazardous) slag product suitable for recycle as concrete aggregate or construction fill. Offgas from the smelting furnace also holds potential as fuel gas for cogeneration. The direct smelting tests conducted thus far were successful at producing the desired furnace products, exhibiting the potential for complete recycle of the waste pile. A cast iron product of comparable quality to conventional cast irons was produced, at nearly 80% iron recovery to the metal. The slag product was determined to be nonhazardous, based on the EPA TCLP. Lead and zinc partitioning to the dust product was greater than 99%. The material balance over the furnace indicates that for every ton of feed processed, 540 lb. of cast iron, 600 lb. of slag, and 150 lb. of dust would be produced. Energy consumption was roughly 1.10 kWxh/lb of feed material. Prior experience suggests that these figures measured in the bench-scale furnace would translate to 0040 to 0.50 kWxh/lb at the industrial-scale.

Jan 1, 2000

By K. Soldenhoff

The Bulong deposit, situated near Kalgoorlie in Western Australia and owned by Resolute Limited, is a lateritic deposit containing on average 1.1% nickel and 0.09% cobalt. A process has been developed and tested at the mini-plant scale for direct solvent extraction and separation of Co and Ni from solutions derived by acid pressure leaching of Bulong ore. In this paper, two solvent extraction processes are described. The first process uses Cyanex 272 to extract cobalt and reject nickel to the raffinate. The second process uses Versatic 10 to extract and purify nickel. The loaded strip nickel solution is suitable for electrowinning. Results of both batch laboratory tests and continuous mini-plant trials are presented. The selectivity of the solvents with respect to the major impurities such as Mn, Mg, Ca, and Zn is also discussed.

Jan 1, 1998

By Guiqing Zhang, Liansheng Xiao, Zuoying Cao, Li Zeng

A new process of direct solvent extraction of nickel from sulfuric acid leach solutions of low grade and complicated nickel resources using a novel extractant HBL110 was proposed. The basic performance of new organic system was investigated and the continuous pilot plant and the industrial test were conducted. The results indicated that the extractant of HBL110 can be used to directly extract nickel selectively over iron, aluminum, manganese, magnesium, calcium and chromium from sulfuric acid leach solutions. The loaded organic solution can be easily stripped using dilute H2SO4 solutions. Both kinetics of extraction and stripping of nickel were fast. The continuous pilot plant test with the sulfuric acid leach solution of laterite containing 6.22g/L Ni2+, 14.1g/L Fe3+, 0.73g/L Fe2+, 33.9g/L Mg2+, 1.58g/L Al3+, 0.495g/L Ca2+, 0.97g/L Mn2+ and 0.5g/L Cr3+ as feed in mixer-settlers showed that the process had run stably with 98% recovery of nickel. The concentration of nickel in strip liquors reached as high as 50 g/L while the removals of Fe3+, Fe2+, Mg2+, Al3+, Ca2+, Mn2+ and Cr3+ were 98.5%, 91.5%, 99.95%, 99.8%, 99.1%, 98.6% and 99.5%, respectively. The industrial test with the sulfuric acid leach solution of electroplating sludge containing 11.5g/L Ni2+, 2.68g/L Fe3+, 7.54g/L Cr3+, 0.61g/L Mg2+, 2.09g/L Al3+, 0.68g/L Ca2+, 0.022g/L Mn2+ and 0.154g/L SiO2 as feed in mixer-settlers also showed that the process had operated successfully with 99.5% recovery of nickel. The concentration of nickel in strip liquors reached 42.7 g/L while the removals of Fe3+, Cr3+, Mg2+, Al3+, Ca2+, Mn2+ and SiO2 were 99.2%, 99.77%, 99.73%, 99.56%, 99.57%, 98.51% and 98.75%, respectively. The new process exhibited big advantages of short flow sheet, high recovery of nickel, high removal of impurities, low chemical reagent consumption and low cost. Application of this process in industry is expected to make important impact on the extraction of nickel from sulfuric acid leach solutions and to deliver good environmental and economical benefits.

Jan 1, 2016

By Travis Davidsavor, David Provost

A segment of high-pressure steel petroleum pipeline needed to be replaced on a hillside and beneath a waterway within an existing right-of-way containing multiple petroleum pipelines. The pipeline replacement required excavation of sedimentary rock to allow placement of the new pipe. As a result of an existing right-of-way limitation, steep slopes, and hard rock, blasting would be required as close as 7.8 meters (25 feet) from two operating pipelines. Existing pipeline company standards would have effectively precluded the construction of the replacement pipe by blasting rock. To facilitate the required construction and evaluate actual pipe stress during blasting to ensure pipeline integrity, a comprehensive evaluation methodology was developed by a team of pipeline, mechanical, geotechnical, instrumentation, and blasting engineers. A total of 60 strain gages were affixed to the steel pipe and seismographs were buried at the surface near the blasting area. Test blasting allowed pipe stresses with corresponding ground motion to be monitored. A conservative analysis approach evaluated individual peak strains and revealed that only small pipeline strains, and therefore stresses, were induced in the pipeline as a result of blasting. This evaluation allowed specific procedures to be developed to inform the blasting operation of maximum explosive loading and minimum charge distances. Additionally, this effort provided the pipeline operator with appropriate pipeline operating pressures during blasting activities to limit total stresses in the pipeline to be below allowable stresses imposed by code, regulators, and company operational limitations. Recommendations were developed to measure the blast generated ground vibrations with seismographs buried at the depth of the pipe, near the pipe, and limit the ground vibrations from blasting to 150 mm/s (6 in/s). If ground vibration intensities of 120 mm/s (4 in/s) or more were observed, additional engineering review is recommended. Finally, all blasting would be suspended and all activities reviewed at peak ground vibration intensities of 230 mm/s (9 in/s). The evaluation effort resulted in effective and efficient construction of the pipeline replacement and allowed the pipeline operator to better understand blasting induced stresses on their assets.

By Travis A. Davidsavor, David A. Provost

A segment of high-pressure steel petroleum pipeline needed to be replaced on a hillside and beneath a waterway within an existing right-of-way containing multiple petroleum pipelines. The pipeline replacement required excavation of sedimentary rock to allow placement of the new pipe. As a result of an existing right-of-way limitation, steep slopes, and hard rock, blasting would be required as close as 7.8 meters (25 feet) from two operating pipelines.

Feb 1, 2020