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By J. L. Shultz

The investigation of organic compounds in respiratory coal dust by high-resolution mass spectrometry has shown that the organic components differ (1) with particle size, (2) with rank of coal, (3) in coals of same rank from different coal seams, and (4) in respirable mine dust and respirable coal dust (prepared) from the same mine. The eight respirable mine dusts studied are from coal seams in the Appalachian region where the incidence of coal workers' pnumoconiosis is relatively high. The molecular weights of the major organic components vary greatly among these respirable mine dusts; three show strong concentrations of polynuclear aromatic hydrocarbons.

Jan 1, 1972

By N. S. Dalal, B. Jafari, F. Y. H. Green, V. Vallyathan

"Using electron spin resonance (ESR) spectroscopy we have carried out a systematic study of the measurement of concentrations of organic free radicals in freeze-dried lung tissue. Sixty-six tissue samples were obtained from the National Coal Workers' Autopsy Study (NCWAS). The samples were characterized in terms of the concentration per gram of the free radicals, and examined in relationship to the histopathological parameters such as age, numbers of years in the mining atmosphere, the degree of disease, and smoking history. Preliminary results indicate a positive correlation between the free radicals in the lung tissue and the severity of pneumoconiosis.IntroductionThis paper summarizes our electron spin resonance (ESR) measurements of the concentration of organic free radicals in the freeze-dried lung tissue of autopsied coal miners. This work was undertaken because it is well known that most coals contain carbon-centered organic free radi¬cals,(1,2) and recent studies from our laboratories indicated that reactive free radicals might play a role in the biochemi¬cal mechanism of coal workers' pneumoconiosis (CWP) (3) Thus we obtained 144 lung-tissue samples from the Nation¬al Institute for Occupational Safety and Health (NIOSH) in Morgantown. The samples came from the data bank of the National Coal Workers' Autopsy Study (NCWAS). This selection was unique because fairly detailed histopathologi¬cal information was available for each sample.Other recent studies in this field are those of Ohta et al (4) who conducted ESR measurements on black dust deposited in autopsied human lungs, but no coal miner was included therein. Earlier Retcofsky (2) had examined one lung-tissue sample via ESR spectroscopy and had concluded that the free radicals in the lung tissue reflected simply the fusain (narrow component) ESR signals. The present study was thus undertaken to complement the earlier work (2-4) and the results indicate a positive correlation with the disease severity fairly strongly."

Mar 1, 1989

By A. H. Rhoades, D. T. King, R. J. Gray

Tests and methods of detecting oxidized coal are studied. Particular emphasis is placed on the microscopically discernible changes that accompany the chemical and physical changes affecting the technological properties of coal during oxidation. Coal samples were used from the low-volatile Pocahontas No. 3 Seam, McDowell County, W.V., and from the high-volatile Cedar Grove Seam, Mingo County, W.V. Tests conducted include: carbonization, free-swelling index, phase inversion, froth flotation, Gieseler plasticity, oxygen by difference and by neutron activation, volatile matter, pH of coal slurries, alkali solubility, and electrostatic charge.

Jan 1, 1977

By R. J. Gray

Oxidation of coal can best be described as a process of deterioration, since most of the uses of coal, such as for fuel and by-product chemical and coke production, are adversely affected by coal oxidation, and the inclusion of oxidized coal in most coal products detracts from their value. There are probably many mechanisms of coal oxidation, and the ways oxygen molecules combine as complexes with coal macromolecules to form new substances have been dealt with and speculated upon by many workers1)* but are not dealt with in the present work. This study deals with tests and methods of detecting oxidized coal, with particular emphasis on the microscopically discernible changes that accompany the chemical and physical changes that affect the technological properties of coal during oxidation.

Jan 1, 1974

By N. S. Dalal, B. Jafari, F. H. Y. Green, M. M. Suryan, V. Vallyathan

"Freshly ground and aged anthracite and bituminous coal samples were investigated by electron spin resonance (ESR) spectroscopy to detect the presence, concentration and reactivity of free radicals. Freshly ground anthracite coal produced greater concentration of free radicals than the bituminous coal, and the radical reactivity was also greater for the anthracite. The reactivity of the newly produced free radicals in the anthracite dust correlated with the dust's toxicity. Furthermore similar coal-based free radicals were detected in the lung tissue of autopsied coal miners, suggestive of persistent reactivity by the embedded coal dust leading to the progressive disease process. Results of the studies on the severity of coal workers' pneumoconiosis (CWP) and free radical concentration m lung tissue support this hypothesis.INTRODUCTIONCOAL WORKERS' PNEUMOCONIOSIS (CWP) has been an important topic of concern to miners, mining engineers, epidemiologists and medical researchers for decades. It is well known that the prevalence and severity of CWP differ markedly between different regions and mines despite comparable exposures to respirable dust (REISNER and RoBOCK, 1977; HURLEY et al., 1979). These variations in pathogenicity of coal mine dusts can only partially be explained by differences in the mineral composition and by rank of coal (CHRISTIAN and NELSON, 1978; CHRISTIAN et al., 1979; HATCH et al., 1980). Cytotoxity studies on mammalian cells do not correspond well with the human disease pattern (CHRISTIAN and NELSON, 1978; CHRISTIAN et al., 1979; HATCH et al.,1980; VALL YA THAN et al., 1988). For example, while epidemiological studies of coal miners (REISNER and ROBECK, 1977; HURLEY et al., 1979) indicate that the prevalence of CWP correlates roughly with the rank of coal, such correlation has not yet been established in biological studies, despite considerable effort (CHRISTIAN and NELSON, 1978; CHRISTIAN et al., 1979; HATCH et al., 1980). In order to help resolve this apparent paradox we have undertaken a systematic study to evaluate whether any correlation exists between the concentration of free radicals present in fresh or aged coal dusts from two well-characterized U.S. coals. This study was also prompted in part by observations reported in the literature that organic free radicals can be formed on the surface of freshly fractured coals (LEBEDEV et al., 1978; DULIBA and CLARKSON, 1984). In particular, ARTEMOV and REZNIK (1980) noted that the decay lifetimes and, hence, the reactivity of the organic free radicals formed on crushing Russian coals, .depended"

Jan 1, 1989

By V. Castranova, K. VanDyke

"INTRODUCTION A soluble mediator has been described which is released from activated rabbit leukocytes and induces histamine secretion from rabbit platelets (Barbaro and Zvaifler, 1966; Siraganian and Osler, 1971). This factor has been isolated, characterized and named platelet activating factor, PAF (Bcnveniste et. al., 1972). PAF has since been chemically identified as l-0-alkyl-2-acetyl-sn-glyceryl-3-phosphocholine (Benveniste et. al., 1979; Demopoulous et. al., 1979).PAF is a lipid mediator of broad biological activity. It causes smooth muscle contraction, contraction of lung tissue and decreased FEV 1; while enhancing capillary permeability thus causing edema (Pinkard, 1983). In addition, PAF is a chemoattractant and can lead to inflammation.PAF has been reported to stimulate the release of lysosomal enzymes, leukotriene B,, and lipid metabolites from neutrophils (Smith et. al., 1983; Shaw et. al., 1981; Lin et. al., 1982; O'Flaherty et. al., 1984). The objective of the present investigation was to further characterize PAP-induced stimulation of granulocytes and to develop a bioassay, i.e. chemiluminescence, for screening PAF receptor antagonists and inhibitors of PAP-induced activation of granulocytes. The possible use of the chemiluminescence assay to monitor PAF synthesis by human granulocytes is also described.METHODSBlood was drawn from healthy volunteers into a blood storage bag containing CPD anticoagulant. Granulocytes were partially purified by dextran sedimentation and further purified by centrifugal elutriation as described previously (Jones et. al., 1980). Granulocytes obtained by this procedure were approximately 95 percent pure. The number of granulocytes in this preparation was determined using an electronic cell counter (Coulter Model Z1, Coulter Instrument Co., Hialeah, FL). Isolated granulocytes were used to monitor membrane potential, hydrogen peroxide and superoxide release, oxygen consumption, calcium uptake and, in some cases, chemiluminescence. Studies of PAF receptor antagonists were conducted using neutrophils isolated by density centrifugation. Briefly, blood was layered onto Mono-Poly-Resolving Medium (Flow Laboratories, McLean, VA) and centrifuged at 22 °C and 300 g for 30 min. Neutrophils collected from the second band of this gradient were at least 90 percent pure."

Jan 1, 1989

By A. Fahr, T. Byczkowski, M. Genest, C. Mandache

"Layered aluminum structures assembled with rivets are often found in aircraft fuselage. These structures are exposed to various mechanical loads and a range of environmental conditions that contribute to their ""aging"". The rivet holes are the source of stress concentrations and the location of crack nucleation and growth. Detection and sizing of second and third layer cracks under fasteners represent a major challenge for non-destructive evaluation (NDE) technicians. Electromagnetic methods are currently the most feasible NDE techniques that are capable of successfully inspecting such structures. However, different probe lift-offs, due to protruding rivets and paint coatings, or interlayer separations, due to sealant or air gaps, pose difficulties in detecting and sizing cracks. In addition, the use of conventional eddy current technique is limited due to the inverse relationship between the probe spatial resolution and its field penetrability. In this paper, we present an alternative approach that overcomes the previously mentioned shortcomings by using pulsed eddy current excitation and magnetoresistive sensor pick-up. Various signal manipulations are employed for defect detection and quantification."

Jan 1, 2006

By J. ?H. Chen

Remote sensing technologies have been applied to numerous fields and already benefited those in improving efficiency and recognition accuracy. Change of streamflow can be devastating to residents living along riversides. Still it is difficult to detect such deathly change in large area scale by traditional field surveys. The research aims at provision of detecting streamflow change using a mathematic method based on remote sensing technologies. The scope is on remote sensing stream images taken during the invasion by Typhoon Morakot, bringing one of the major catastrophes to Taiwan. An algorithm was adopted to deal with streamflow recognition on RGB images. The algorithm is capable of yielding change measured by meters and illustrates how main streams shift. An practical example for the Baolai area surrounded by Laonong stream shows that the streamflow moved 88 meters (36 pixels) toward the downtown area during the invasion by Typhoon Morakot. In addition, the results highlight all dangerous zones (scouring zones) for residents to prevent further potential damage.

Aug 1, 2013

By Rambabu Pothina, Rajive Ganguli

The economics of a mineral processing circuit is dependent on the numerous sensors that are critical to optimization and control systems. The sheer volume of sensors results in mines not being able to keep the sensors calibrated. When a sensor goes off calibration, it results in errors which can severely impact plant economics. Normally, these errors are not detected until the error grows and becomes a large (“gross”) error. Undetected errors are not remedied until the next calibration, which on average are a year apart Beamex (2019) [1] across all industries. Classical statistical methods that depend on linear relationships between input and response variables are typically used to find gross errors, but are not effective for highly non-linear and non-stationary operations in mining and mineral processing industries. Calibration of sensors is time-consuming and generally requires physical intervention that results in equipment downtimes causing production losses. Therefore, in situ detection methods are warranted that do not require physical removal of sensors to compare with standard measurements or well-calibrated sensors. Data-mining based techniques and algorithms have high success rate in tackling such problems. This paper presents results from a groundbreaking multi-year big data research project whose goal was to develop data-mining-based original techniques in a multi-sensor environment to identify when sensors start to stray, rather than wait for errors to grow. The carbon stripping (gold) circuit in the Pogo Mine of Alaska was selected for this project. Maintaining strip vessel temperatures at optimum levels is crucial for maximizing gold recoveries at Pogo, and hence the focus was on the temperature sensors of the two strip vessels. An automated algorithm to detect errors in strip vessel temperature sensors was developed that exploited data from multiple sensors in the strip circuit. This algorithm was able to detect with a high success rate when bias errors of magnitude as low as ± 2% were artificially induced into strip vessel temperature data streams. The detection times of about 1 month were much less than the industry average calibration frequency of 1 year. Thus, the algorithm helps detect errors early, without stopping the circuit. The algorithm alarms can serve as triggers when calibrations are done. Experimental methodology along with results, limitations of algorithms, and future research are also presented in this paper.

By Rambabu Pothina, Rajive Ganguli

The economics of a mineral-processing circuit is dependent on the numerous sensors that are critical to optimization and control systems. When a sensor goes off calibration, it results in errors that can have a severe impact on plant economics. Classical statistical approaches fail to detect when errors are “subtle,” unless they grow and become large enough to be “gross,” whereas methods based on signal processing and artificial intelligence fail in dealing with the complexity of process fluctuations. Due to the sheer volume of sensors, undetected errors are not remedied until the next calibration, which on average are a year apart across all industries [1]. This research aims to detect such subtle errors (2 percent bias) in shorter time spans of about a month — rather than wait for errors to grow — using innovative data-mining techniques and algorithms.

By M. Z. Naghadehi, F. F. Nasategay, J. Sattarvand, R. Battulwar, E. E. Gohari

After the recent increase in catastrophic failures of tailings dams such as the Burmadinho, Brazil failure in 2019, the mining industry has actively engaged in the stabilisation of tailings dams. Most of the tailings storage facility (TSF) guidelines suggest a laborious action that can be facilitated through imaging by unmanned aerial vehicles (UAVs). Although UAVs are not unknown to most mining operations, automated rill detection through aerial image processing is a new concept. This study utilises images from sites in the U.S. and employs semantic segmentation with a UNet architecture to detect location and size of these rills. The developed model can be used as a tool for monitoring surface erosion of TSFs.

Sep 1, 2021

By S. Banisi, M. R. Yarahmadi, S. R. Mortazavi

Nowadays the development of automatic on-line sampling systems has enabled large amounts of data to be available to plant managers. These data are inevitably prone to random and sometimes systematic errors. Data reconciliation methods are used to deal with random errors. In these methods, the measured data are adjusted in accordance to their error, so that the mass conservation law is satisfied at the same time. Measured data may also contain systematic errors, using these data in mass balancing software will result in inaccurate or even irrational results. In this paper three methods for detecting systematic errors (global test, node constraint test and maximum power constraint test) were presented. A step by step method to locate the systematic errors was demonstrated. Then, the new version of Movazen©, a mass balancing software, was introduced and used to locate systematic errors in the measurements taken from the Sarcheshmeh pilot plant copper flotation circuit. Keywords: Mass balancing, data reconciliation, random error, systematic error

Jan 1, 2020

By Romel B. Villanueva

At the Yanacocha gold mine, in the Andes of northern Perú, the first instrumental tests were carried out in October 2019 to detect the initiation sequence of a production blast by detecting the EMF signal produced by the detonation from each blast hole in the sequence. Several experimental tests were carried out to choose the correct antenna and find the best setup of the high-speed Data Acquisition device (DAD) to detect these electromagnetic waves. Finally, the first measurement was obtained. With the instrument recording at a rate of 1 million samples per second, the initiation sequence was detected with 99.5% accuracy. It was found that it corresponded, without a doubt, to the designed scheme. The main result is that these tests provide us with a method and instrumentation to verify if the planned initiation sequence is carried out correctly in the field. In this way we can find operational deviations and detect possible misfires. This method has proven to be accurate, fast and easy to implement, mainly requiring an EMF signal capture equipment that can record at very high speed, something that is increasingly easier to satisfy with the development of microcontrollers. On the other hand, the type of antennas used in this method are low cost and very commercial. These tests have improved our understanding of the nature of detonation and have marked a new milestone in the development of blasting instrumentation in Peru.

Jan 21, 2025

By N Winkelmann

Underground coal heating is a significant hazard in some coal mines. The broad principles of how underground coal heatings occur is reasonably known, however the technique for locating the heatings in often inaccessible goaf has been proved to be difficult. Since 2002, CSIRO, with the support of the Australian Coal Association Research Program (ACARP) has been undertaking investigations to apply and develop innovative surface-based radon technique for locating the underground heatings in Australia. This paper presents the progress of the investigation.

Jan 1, 2005

By Charles D. Litton, Margaret R. Egan

In order to reduce the number of nuisance fire alarms in underground mines that use diesel-powered equipment, the U.S. Bureau of Mines has developed a diesel-discriminating fire detector (DDD). It was designed to discriminate between smoke produced by a fire and the smoke-laden exhaust of a diesel engine. Welding and cutting with arc or flame can also produce combustion products capable of triggering nuisance alarms. In this report, the response of the DDD to the emissions from diesel exhaust, arc welding, and flame cutting are compared to the response of conventional smoke and carbon monoxide (CO) detectors. The data show that when the DDD is set at an alarm threshold of 0.05 v, it will reliably detect a developing conveyor belt fire while remaining insensitive to other sources of nuisance combustion products. The alarm times of the three types of detectors were also compared. The DDD alarmed first in response to a smoldering conveyor belt in two of four experiments.

Jan 1, 1992

By Mónica P. Arenas

Aços austeníticos resistentes ao calor apresentam propriedades mecânicas que permitem seu uso em altas temperaturas e pressão, sendo frequentemente utilizados em fornos de reforma e pirolise. Devido às severas condições de operação danos de carburização podem ser induzidos. No presente trabalho foram analisados corpos de prova provenientes de fornos de reforma que apresentaram baixos níveis carburização. Com a finalidade de desenvolver uma metodologia que permita detectar e separar diferentes níveis de carburização, foi projetado, simulado e construído um sensor magnético constituído por um yoke e um sensor Hall. De acordo aos resultados obtidos, concluiu-se que o sensor permitiu determinar confiavelmente o nível de carburização em ligas austeníticas que estiveram expostas a diferentes temperaturas de operação.

Oct 30, 2017

By Volney Viana Nogueira

A recirculação interna de gases em bombas de vácuo é uma falha frequente em estações de desgaseificação de aço e está associada ao aumento dos tempos de processo, a um maior consumo energético e a não obtenção da pressão de trabalho adequada. O tratamento de tais desvios pode ser complicado pela falta de informação disponível sobre os modos de falha dos equipamentos. Este artigo descreve um método experimental para encontrar valores de referência para testes que podem ser realizados na planta para a detecção de não conformidades em bombas de vácuo constituídas de ejetores a vapor e condensadores; tal método é composto por testes lógicos, sequenciais e não intrusivos. São fornecidas tabelas com os valores esperados das grandezas testadas, assim como diversas causas de redução de desempenho e de perda de função dos componentes.

Oct 30, 2017

By Tracy Morris, Weldon Read, Luis Navarro

"During the leaching of anodic slimes, tellurium dissolves into the leach liquor together with copper and must be removed before the solution is sent to liberator cells for copper recovery. Prior to the installation of autoclaves, tellurium was precipitated using raw slimes that caused a recirculation of tellurium in the leaching circuit. After autoclaves were installed the old leach tanks were converted into tellurium reactors utilizing copper chips, steam and agitation to form a copper telluride precipitate. Tellurium levels of less than 10 rng/L are achieved in a timely manner.IntroductionThe electrolytic refining of copper consists of an electrolytic cell provided with an anode of impure copper, a cathode of substantially pure copper (starter sheet) and an electrolyte made of copper sulfate and sulfuric acid [1]. When a direct electrical current is passed between the anode and cathode inside the cell, the impure copper anode dissolves in the electrolyte and pure copper is plated onto the cathode. During this operation, many of the impurities are deposited on the bottom of the cell as an anodic slime residue composed of insoluble chemical compounds. Slimes are a major source of rare and precious metals in the copper industry [2-5],In the Amarillo Copper Refinery (ACR), the anodic copper slimes are sent to the Precious Metals department in order to extract and then refine the gold, silver, platinum and palladium from them. The remaining impurities, in the form of a soda slag or copper slag are sent to the Hayden smelter for further processing. Copper telluride is sent to the Selenium/Tellurium department inside the plant for selenium and tellurium recovery. During the leaching process of the anodic slimes, copper, tellurium, and other metal species in the slimes are dissolved into leach liquor that cannot be returned to the tankhouse unless the tellurium concentration is below 10 mg/L."

Jan 1, 2012

By L. M. Chan, D. H. Carlson, J. B. Johnson

"Abstract — Concentrations of tailpipe pollutants from diesel-powered. underground mine vehicles change over time due to engine wear and the need for maintenance. Since this deterioration in pollutant emissions may adversely affect the air quality in an underground mine, it should be monitored and controlled. This paper presents decision criteria concerning when to service a mine vehicle diesel engine. These criteria, based on mine air and tailpipe concentration measurements, are designed to maintain the tailpipe concentrations within limits that assure satisfactory mine air quality.Application of the deterioration criteria to mine vehicle emissions involves:establishing, for each pollutant, the allowable deterioration factor, anddetermining the deterioration factor, from the mine air and tailpipe diesel pollutant measurements, and the mine air threshold limit values (TLVs).If the deterioration factor is greater than or equal to the allowable deterioration factor the vehicle is removed from service for maintenance.An analysis applying the criteria to measurements made in an underground coal mine is presented. The tailpipe pollutant concentration data were collected using the Emissions Mea-surement Apparatus (EMA) developed by Michigan Techno-logical University. Since the TLV for diesel particulate matter (DPM) has not yet been established assumed mine air DPMTLVs of 15 and 1.0 mg/m3 were used in the analysis. For all of the diesel haulage vehicles included in the analysis. DPM was found to be the critical pollutant (the one most in need of control). For an assumed mine air DPM TLV of 15 mg/m3 none of the diesel haulage vehicles would he removed from service. However reducing the DPM TLV to 1.0 mg/m3 would make it necessary to remove two of the three vehicles tested from service."

Mar 1, 1992

By Horace C. Porter

Much has been written of the changes undergone by coal in storage and the deterioration of coal through exposure to the weather. In order to obtain definite information for the benefit of the Government departments and of all who store coal in large quantities, a series of tests was begun in the fall of 1909 under the supervision of J. A. Holmes, then chief technologist of the United States Geological Survey, and was continued by the Bureau of Mines after its establishment in 1910. The tests were confined to determinations of the loss in heating value of the coals and did not include a study of other deterioration; for example, in coking quality or the yield of by-products in coking. The Bureau of Yards and Docks of the Navy Department cooperated in tests of New River (W. Va.) coal, a variety largely used by the Navy. A preliminary report presenting a brief account of the early results of these tests has been published by the Bureau of Mines as Technical Paper 16.a The detailed report is presented in this bulletin, which gives a full account of the tests and the analytical data covering a period of five years' storage. Data of somewhat similar experiments for shorter periods with gas coal from the Pittsburgh bed, with Pocahontas coal on the Isthmus of Panama, and with Sheridan, Wyo., subbituminous coal, which is used for railroad and other purposes in the West, are included.

Jan 1, 1917