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By C. E. Schmidt

Condensate waters from the Bureau of Mines Synthane process for coal gasification have been investigated by mass spectrometric methods to determine the organic contaminants. Waters from the gasification of six coals were extracted with methylene chloride, yielding 0.6 to 2.4 weight-percent extractable material. Using high-resolution mass spectrometry (HRMS), combined gas chromatography-mass spectrometry (GC-MS), and low-voltage mass spectrometry, 60 to 80 percent of the extract was found to be phenolic. About 20 organic contaminants have been identified and are present in the condensate waters from each coal gasified. The relative distribution of contaminants in the condensate water was nearly the same for the six coals gasified under various conditions; phenolic compounds were the most abundant in all cases.

Jan 1, 1974

By T. T. Campbell

Research conducted by the Bureau of Mines demonstrated the feasibility of preparing columbium and tantalum metals by the application of Kroll-process techniques. Yields in excess of 95 percent were obtained in a modified Kroll-process reduction apparatus constructed from nickel and Inconel.4 Operating conditions during reduction and distillation were determined. Optimum temperatures during sodium reductions ranged from 650° to 750° C and for magnesium from 700° to 800° C with retort pressures ranging from 3 to 7 psig. Undesirable vapor phase reactions occurred when temperatures exceeded 750° C during sodium reductions or 850° C with magnesium. Vacuum distillation at 850° C effectively removed volatile salts and excess reductant from the reduced metals. Calculations based on the results obtained in small scale tests indicate that reaction rates of up to 34 lb/hr could be obtained during columbium reductions and up to 60 lb/hr during tantalum reductions in production scale reac¬tors. The small, laboratory-scale techniques used in this study could be adapted to commercial practice. The reduced powder or sponge metals can be consolidated by conventional arc-melting techniques, and the arc-melted metals can be fabricated into ductile sheet at room temperature. Analyses of arc-melted buttons prepared from Kroll-process tantalum or columbium showed that tantalum of greater than 99.8-percent purity was obtained and that columbium purity exceeded 99.7 percent. A significant purification of the reduced metals occurred when they were consolidated by electron-beam melting, and the purity and ductility of electron-beam-melted Kroll-process tantalum and columbium compared favorably with the commercial metals. After electron-beam melting, the purity of the tantalum exceeded 99.95 percent, and columbium purity was approximately 99.9 percent.

Jan 1, 1962

By R. Hogg, T. F. Dumm

"It is generally agreed that dust characteristics play a role in the development of Coal Workers' Pneumoconiosis (CWP). Unfortunately, there is a serious lack of information on what the characteristics of mine dust actually are and how they vary among different mining regions, coal seams, etc. This paucity of data can generally be attributed to the serious problems encountered in collecting sufficiently large quantities of dust for conventional analytical procedures.Personal samplers are widely used in coal mines for regulatory and enforcement purposes. Generally, these provide information only on the total (respirable) dust loading in the mine atmosphere and on the mineral matter (primarily quartz) content of the respirable dust. A procedure has been developed by which samples collected with a slightly modified personal sampler can be analyzed for particle size distribution, total mineral matter content and elemental composition, in addition to the standard mass and quartz measurements. These analyses could readily be performed on a routine basis. Shape analysis by Scanning Electron Microscope (SEM) could easily be included if appropriate shape criteria are established. Extension of the procedure to include the determination of complete size/specific gravity (composition) distributions is quite straightforward provided sufficiently large samples (at least 10 mg) can be collected. Typical sample sizes for a personal sampler carried by a miner for one shift range from about 0.5 to 2 mg.The basic procedure was developed and evaluated using synthetic mine dust prepared in the laboratory. Field tests in three working mines in Pennsylvania and West Virginia have confirmed the applicability of the approach to the real world. Particle size distribution measurements on mine dust collected in the modified personal sampler were found to agree closely with the results of simultaneous in situ measurements obtained using cascade impactors."

Mar 1, 1989

By M. S. Seehra, R. S. Pandurangi

"A comparative study of the intensities of the IR modes in the pjlotoacoustic and. FrIR spectroscopy of amorphous and crystalline SiO2 particles is presented. It is observed that in photoacoustic spectroscopy of amorphous SiO2, IR modes of surface species are enhanced by over an order of magnitude compared to the bulk IR modes of SiO2. This effect, though not yet understood, may find applications in surface science.Since the publication of the Rosencwaig-Gersho theory of the photoacoustic effect in solids in 1976 [1], a great deal of attention has been paid to the development .of photoacoustic spectroscopy (PAS) into an analytical technique for condensed matter studies, especially when combined with the modern Fourier transform infrared (FTIR) spectrometer [2-8]. PAS has now been applied to a variety of experimental situations [2, 3] and it is particularly suitable for opaque powders and for cases where ~ample preparation (e.g. mixing with KBr as is usually done in FTIR spectroscopy) is not desirable. Another area of interest is the depth profiling feature of PAS, which is studied by varying the modulation frequency of the incident radiation [2-8]. The one-dimensional Rosencwaig-Gersho theory for non-porous samples has been extended to other cases [9-12]. Recently it has become known [11, 12] that for porous samples with porosity the IR modes are enhanced by a factor proportional toe. This enhancement is due to the pressure wave set up in the interstitial gas in the porous sample and this enhancement has been reported by a number of groups [12-14].In this Letter we report the observation of anomalously large enhancement of the PAS signal for certain surface IR modes on the surface of amorphous silica particles. This observation differs from the previous reports in that certain surface modes are enhanced by over an order of magnitude compared to the bulk IR modes. Although the reasons for this enhancement of the surface IR modes in PAS are not understood at present, this observation may open up new approaches to the study of surfaces. Results of these initial observations are given in this Letter. ·Experimental studies reported here were carried out on an FTIR spectrometer (Mattson Instruments, Model Cygnus 100) equipped with an MCT detector. The same instrument was used for PAS studies in conjunction with an MTEC (Model 100) PA cell. The sample cell and the spectrometer are continuously flushed with dry, CO2 free air obtained by the use of Balston Instruments Air Dryer Filter System (Model 75-60). Usually data were collected for 32 scans at 4 cm-I resolution, although both scan and resolution can be varied. For FTIR studies, samples were mixed with IR-grade KBr and pelletised. For PAS, no sample preparation is necessary and data are ratioed against dry carbon black [4, 5]."

Jan 1, 1989

By Samuel A. Goldberg

The Federal Coal Mine Health and Safety Act of 1969 delegated to the Bureau of Mines a yearly program of health inspections. Respirable coal mine dust concentrations are measured by Bureau inspectors. Samples of respirable coal mine dust are weighed to determine dust concentration and then analyzed for ash and quartz content. This paper describes the laboratory procedure for determining the percent quartz in the respirable coal mine dust samples.

Jan 1, 1972

By A. B. Hooker

Investigations at the Pittsburgh Experiment Station have shown that the satisfactory operation of a flame safety lamp depends not only upon proper design and assembly of the lamp but upon the kind of fuel used, and that much of the trouble experienced with permissible flame safety lamps at mines is due to the common use of motor gasolines, none of which is suitable in the present types of permissible flame safety lamps. This report gives the results of a limited study to determine what satisfactory fuels are available, the specification limits of such fuels, and to suggest modifications of assembly and care of the lamps to improve performance with any satisfactory fuel.

Jan 1, 1938

By J. T. McCartney

Thin sections of coal have been prepared for many years either by cutting on a microtome (1,2)5 or by grinding and polishing (2,1). Specimens of most coals had to be demineralized in hydrofluoric acid and softened in caustic solutions before they could be successfully cut with a conventional microtome. Some lignites could be cut without pretreatment. Jeffrey (1) obtained sections from coals of all ranks, although long and tedious pretreatment was required for anthracite. His sections were less than 1 cm.2 in area (probably much less for high rank coals) and about 5 microns thick. Thiessen (2) also cut sections of softened coals, mostly of low rank. His sections were a few square millimeters in area and about 3 microns thick. However, Thiessen preferred ground and polished sections for detailed studies because they were larger and had not been chemically attacked by softening media. He prepared ground sections as large as 4 cm.2 in area and usually 5 to 10 microns thick. Thousands of such sections, covering complete column samples of many coal beds, were studied for a number of years (4). With the development of the electron microscope and increased interest in quantitative optical studies of coals, a need for much thinner sections arose. However, no suitable technique for preparing such sections was known until Fernández-Morán developed a diamond knife for cutting ultrathin sections of hard materials (5). Workers at the Centre d'Etudes et Recherches de Charbonnages de France applied this new tool to the cutting of coal sections and have recently described their technique to the Burg, of Mines. Using their methods, with some modifications, researchers of the Bureau of Mines have succeeded in cutting ultrathin sections of coals ranging in rank from lignite to

Jan 1, 1961

By Thomas C. Miller, Charles E. Mongan

"This publication is a progress report on Bureau of Mines studies in applying sonar techniques to roof-control problems in coal mines. Preliminary tests in the laboratory were made on layers of roof rock. To apply the experience thus obtained, a unit was designed and constructed and was used underground.The term ""sonar technique"" refers to the system of generating a beam of sound waves, shaping and directing the beam, introducing the beam into a medium to be studied, and examining any returning waves with a view of inferring the nature of the material traversed by the waves and the presence of interfaces or obstacles in the medium.The theory and actual underground experiments indicate that the sonic method is feasible. Information from physical tests made in the Bureau's Experimental mine confirmed the validity and potential usefulness of the sonar method. Lighter and more compact apparatus is desirable, and permissible equipment suitable for use in gassy or dusty mines must be developed. However, no particular difficulties are anticipated; consequently, this scientific approach to the exploration of roof strata shows definite promise. INTRODUCTIONThe problem of roof control in the coal-mining industry is of major importance. More than 50 percent of all coal-mine fatalities and 25 percent of all nonfatal serious injuries are caused by falls of roof, face, or ribs. The Bureau estimates that more than $128 million was spent by the coal-mining industry in 1958 for supporting roof."

Feb 1, 1960

By Industrial Research Office

"The U.S. Bureau of Mines established on August 15, 1983, the Generic Mineral Technology Center for Respirable Dust within the Mining and Mineral Resources Research Institutes (MRIs) at The Pennsylvania State University and West Virginia University in association with participating MRIs at Massachusetts Institute of Technology and the University of Minnesota. The Center's research program has been developed with recognition of the stated objective of the Federal Mine Safety and Health laws which is to ""... permit each miner the opportunity to work underground during the period of his entire adult working life without incurring any disability from pneumoconiosis or any other occupation-related disease . . . ."" The Center's program is designed to permit an accelerated attack on the fundamental research problems for the control of respirable dust in mines.The primary goal of the Center is to reduce the incidence and severity of respirable dust disease through advancing the fundamental understanding of all aspects of respirable dust associated with mining and milling and the interaction of dust and lungs. The Generic Technology Center's research program explores these concerns with the objective of refining existing strategies and developing new respirable dust control techniques that are consistent with the fundamental dust-lung interaction processes that lead to mine worker disability. The work concentrates on: (1) control of dust generation; (2) dilution, dispersion and collection in mine airways; (3) characterization of dust particles; (4) interaction of dust and lungs; and (5) relationship of mine environment, geology, and seam characteristics to dust generation and mobility. The fundamental aspects of this work are applicable to the control of respirable dust problems in both hard rock mines and coal mines and to other dusts such as diesel-generated. The Center activities involve the training of engineers and scientists, graduate students and undergraduate students through their respective institutions, and the technology transfer to the industry. The Center also serves as the reference center for publications' in the respirable dust area.The Center is composed of faculty from the four universities/institutes listed above. The personnel, facilities and equipment that are available to the Center from these entities are diverse, complementary and comprehensive. More than fifty scientists, engineers; and medical personnel in the Center are engaged in respirable dust research. Additionally, the expertise and facilities of the NIOSH--Division of Respirable Disease Studies are available as a result of the existing relationship between NIOSH and West Virginia University.The breakdown of the dust research program into the five areas mentioned above recognizes the importance of an integrated fundamental research approach to the respirable dust problem compatible and complementary with the existing and ongoing U.S. Bureau of Mines activities. The specific projects in the research areas are a result of a careful evaluation of the past and ongoing research activities, the identification of areas where data and information are scarce, and awareness of the recommendation of the National Academy of Sciences Study on the Measurement and Control of Respirable Dust. Penn State is the administrative unit for the Center. Funding to date is nearly $6.5 million."

Aug 31, 1989

By J. M. Stuve

Provisional values for the heat of formation of europium trichloride and europium sesquioxide were determined by solution calorimetry utilizing europium metal of more than 99-percent purity. The resulting values for the heats of formation of Eu203 (cubic) and EuCls (hexagonal) were -386,970 ±l,200 cal/mole and -218,740 ±650 cal/mole, respectively, measured at 298.15° K.

Jan 1, 1965

By Liming Yuan

In order to reduce fire hazards caused by spontaneous combustion in longwall gob areas, a computational fluid dynamics (CFD) study is being conducted by National Institute for Occupational Safety and Health (NIOSH) to simulate the spontaneous heating of coal in longwall gob areas. A CFD model was first developed to model the spontaneous heating process in a two longwall panel district using a bleeder ventilation system with a stationary longwall face. The spontaneous heating is modeled as the low-temperature oxidation of coal in the gob using kinetic data obtained from previous laboratory-scale spontaneous combustion studies. Heat generated from coal oxidation is dissipated by convection and conduction, while oxygen and oxidation products are transported by convection and diffusion. CFD simulations were then conducted to model the spontaneous heating in longwall gob area with a bleederless ventilation system. A single longwall panel with a bleederless ventilation system was simulated. The effect of gob permeability on the spontaneous heating was also investigated.

Jan 1, 2009

By Allen L. Frank

A portable radon diffusion chamber has been tested with electrical collection of the radon daughter nuclei for enhancement of sensitivity. The detector size was small enough to be worn suspended from the belt. With a battery-supplied high voltage the sensitivity was found to be 1.43 tracks/cm2 per pCi-hr/l of ambient radon at Sot relative humidity. The track densities on the surfaces of the CR-39 plastic nuclear track detectors were found to be non-uniform, making difficult the determination of average densities with high accuracy. The fabrication of electrets for use in the detector was investigated in accordance with published techniques with negative results.

Jan 1, 1983

By A. L. Engel

The sample of ore on which the work described in this paper was done came from Mina Oriente, Carrizal Bajo, Provincia de Atacama, Chile, South America, and was sent at the request of the Chil.ean Government through the Foreign Minerals Division of the Bureau of Mines. This ore had been tested locally for treatment by flotation and cyanidation without satisfactory results. An additional difficulty was the absence of water near the ore deposits, so that in any treatment method considered the water requirements would have to be very low. It was desired to develop a practical method of recovering the gold and, if possible, the copper in the area. No data of previous investigations were made available. The sample received was mostly quartz, highly brecciated, with limonite and hematite in the fractures. Copper occurred as malachite and azurite, also in the fracture s and to a slight extent as a stain in the quartz. Some fine-grained pyrite with a little arsenopyrite occurred within the quartz. An occasional grain of chalcopyrite was observed. No free gold was seen during examinations of the ore, but amalgamation indicated that some was present.

Jan 1, 1949

By H. S. Caldwell

This report describes work by the Bureau of Mines on the vacuum distilla¬tion of some of the more volatile metals such as cadmium, zinc, and magnesium from lead and tin. Evacuation within a distillation apparatus allows rapid diffusion of vapor away from the evaporation surface and prevents reaction of the vapor with residual gases. A reduction of pressure to several tenths of a millimeter makes possible practicable distillation rates, at temperatures for which the partial pressure of the metal vapor exceeds 10-3 atmosphere. The rate and selectivity of distillation depend primarily on the volatility and molal ratios of the alloy metals, and their chemical activity to each other. For very rapid evaporation or low concentration of the more volatile constituent, the rate is determined by the rate of diffusion of the evaporating metal, to the surface of the melt. Cadmium, zinc, magnesium, and tellurium were found to volatilize readily from both lead and tin. Tellurium appears to volatilize as an intermetallic compound rather than the pure metal. Antimony could not be removed from lead at 1,000° C.; the condensate was nearly all lead. Antimony, bismuth, and lead were removed from tin.

Jan 1, 1960

By Charles P. Lazzara

Concentration profiles of low-pressure, slightly lean CH4-02-Ar flames have been measured in situ for the following unstable species: oxygen atom, hydrogen atom, hydroxyl radical, methyl radical, and formyl radical. The observed maximum mole fractions were 2.0X10-2 for H, 1.1X10-2 for OH, and 0.8X10-2 for 0; the maxima occurred in the recombination zone. Methyl and formyl radicals have maximum mole fractions in the reaction zone of 2.2x10-3 and 6x10-5, respectively.

Jan 1, 1973

By G. R. Palmer

The Bureau of mines evaluated the elution of uranyl carbonate from a strong base resin with a mixed carbonate eluant in a fluidized system. The system consisted of a multiple-compartment ion-exchange (MCIX) elution column with a continuous flow of solution, except for short periods when the resin increments were withdrawn. The exchange of uranyl carbonate from the mill-loaded strong base resin with an eluant composed of 1.0 [M] NaaCOs plus 1.0 [M] NH4HCO3 was studied. The effects of solution flow rate, aqueous-to-resin flow ratio, column diameter, compartment height, initial resin concentration, and column length were examined. The experimental data indicate that for the eluant examined, a resin residence time of 240 minutes is necessary to attain 90-percent elution efficiency. Also provided is a technique for sizing an elution MCIX column form pilot plant experimental data.

Jan 1, 1979

By John C. Machisak

THIS CHAPTER reports employment data and injury experience in the metal, nonmetal, quarrying, sand and gravel, and slag (iron blast furnace) industries of the United States in 1959. Each industry is treated separately, and no attempt has been made to combine data to show an overall total for this group of mineral industries. The slag canvass is included for the first time (data on employment and injuries were not collected before 1958), and, like other canvasses included in this chapter, data are voluntary. Employment and injury experience for all mineral industries can be found in volume III. The employment and injury information in this chapter came from reports submitted to the Bureau of Mines before May 31, 1960; therefore, figures are preliminary and subject to revision. Voluntary reports submitted by operators have contributed substantially to safety promotion since 1911, when the Federal Bureau of Mines started collecting employment and injury facts.

Jan 1, 1960

Provide reliable, early-warning fire detection instruments, telemetry, and control systems for noncoal underground mines. Approach Industrial-grade fire detection instruments and signal telemetry equipment were modified for long-term exposure to harsh underground mine conditions, then were installed in four mines to evaluate long-term performance and reliability. How It Works The elapsed time between the onset of a fire and its detection is critical because fires tend to grow in size and intensity with time. Early fire detection and warning permit the initiation of a mine's emergency plan (evacuation, fire fighting, etc.) while the fire is still small, or ideally, while it is still in the incipient stage. Fire detection and warning systems, utilizing sensitive heat, flame, smoke, and gas analyzers, provide the most rapid and reliable indication of a developing fire.

Jan 1, 1987

By Philip W. Holland

The Bureau of Mines has developed a trace helium analyzer for deter-mining helium-4 in the parts-per-billion range. The instrument is used for analyzing pure gases, laboratory-prepared standards, and atmospher-ic samples. Accuracy at the 95-pct confidence level in the 50-to 20,000-ppb range is within ±2 ppb or ±0.4 pct, whichever is greater. The minimum detectable helium-4 concentration is calculated to be 5 ppb. The analyzer consists of a modified helium leak-detector mass spec-trometer, a laboratory-built sample inlet system, and a liquid-nitrogen-cooled charcoal trap. A programmable integrator and event-control module make automatic operation possible. The portability of the analyzer allows it to be used in the field.

Jan 1, 1984

Develop computer software that can aid in improving the visibility and illumination in underground mines by providing quick analysis of existing equipment and conditions and the effects of potential modifications. Background Poor visibility and illumination are common problems in underground mining. Mining equipment often restricts operators' fields of vision. Also, fighting systems are often positioned where they cause excessive glare, which restricts the visibility around the machines even further. To help address these problems, the U.S. Bureau of Mines (USBM) has developed a PC-based software package to analyze certain human engineering aspects (ergonomics) of mining equipment design. The software is available for use by equipment manufacturers and mining companies for design work on new machines, as well as for evaluating proposed modifications to existing machines. Approach The Crewstation Analysis Programs (CAP) package includes assessments of visibility, illumination, and glare in the surrounding work area. The advantage of using computers for these types of analyses is that numerous design iterations can be tested quickly and efficiently to determine the effects of changes on visibility. This cuts down the need for expensive testing using physical mockups. Another advantage is that design ideas can be tested in situations where testing would not normally be possible. For instance, the effects of modifications to a lighting system or canopy design could be tested while the machine remained in service.

Jan 1, 1993