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By Suzann C. Ambrosio

Crude petroleum, the only commercially exploited mineral resource in Cameroon, continued to dominate developments in the mineral industry sector. International mining concerns have expressed interest in developing Cameroon's bauxite and iron and steel potentials. Domestically, the mineral industry focused on production of fertilisers for agricultural development, infrastructure construction, and hydrocarbon development, through the nearly self-sufficient production of fertilizer materials, cement, and crude oil. The mineral sector contributed 5.6% to the estimated 1981 gross domestic product (GDP) of $6.5 billion.2 Petroleum exports accounted for approximately 4.5% of the 1981 GDP and exceeded coffee and cocoa exports for the second consecutive year. The trade gap widened during the fiscal year ending on July 80, 1981, owing to a 21% increase in exports and a 25% increase in imports. Offsetting these balance-of-payments difficulties, typical of developing countries' early economic stages, were increases in foreign exchange reserves to $71 trillion by May 1983.

Jan 1, 1983

By Travis Q. Lyday

The Other South Pacific Island states extend from Palau, also called Belau, near the Philippines in the west, to French Polynesia in the east. However, a number of countries and territories have been omitted, from this chapter because their mineral production was insignificant to the local economy. These include the French over-seas territories of French Polynesia and Wallis and Futuna Islands; independent states, including Kiribati, Marshall Islands, Micronesia, Palau, Tonga, Tuvalu, and Vanuatu; the New Zealand freely associated state of the Cook Islands, and the New Zealand dependency of Niue. What mineral production existed in these islands was limited to construction materials such as coral reef limestone, crushed stone, and sand and gravel in minor quantities solely for domestic consumption. FIJI The mineral industry of Fiji continued to be dominated by gold, although this sector contributed less than 1 % to the gross domestic product (GDP) of the country. Gold and silver together ranked second in value among the country's exports. Fiji's economy contracted 11% during the 8-month period following the first, on May 14, of two military coups. Although the island nation had been a member of the British Commonwealth of Nations since its independence on October 10, 1970, Fiji's membership terminated with the emergence of the Republic or Fiji on October 15.

Jan 1, 1989

By Jürgen F. PH. D. Brune, Alex C. Smith, Michael A. Trevits

Underground coal mine fires in the United States continue to present a significant hazard to the safety and health of mine workers. The leading causes of mine fires include flame cutting and welding operations, frictional heating and ignitions, electrical shorts, mobile equipment malfunctions, and spontaneous combustion The National Institute for Occupational Safety and Health (NIOSH) is conducting an in-depth program of research to address mine fire prevention, early and reliable fire detection and mine fire suppression and control technologies. One segment of the research portfolio is focused on remote methods for addressing coal mine fires. This research is important because remote methods represent the primary means of fighting a mine fire when conditions are too dangerous to fight the fire directly underground. Technologies under investigation include remote methods for installing ventilation control devices (mine fire seals) and remote methods for suppressing the fire using, the injection of inert gas, gas-enhanced foam and jet engine exhaust gases into the fire zone. This paper presents a summary of remote mine firefighting technologies used in the U.S. and the results of completed NIOSH research.

By Thomas E. Marshall, Roy H. Grau

The U.S. Bureau of Mines has developed an acoustic test for determining if a rock salt sample is from a "normal" nongassy salt face or from a gassy face where an outburst has the potential to occur. The test is based on the observation that a salt sample taken near an outburst-prone zone produces an audible popping sound when it is dissolved in water. The sound is produced when pressurized gas that is trapped in salt samples is released. In the acoustic test, the sound is electronically measured, digitized, and transmitted to a microcomputer; the output is an average decibel value that classifies the sample as "normal" or "outburst." The acoustic test procedure and equipment are described, and raw test results and data analysis are shown. Results are also shown for several salt samples that were analyzed using a laser Raman microprobe.

Jan 1, 1990

By M. J. Sapko

The Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) has conducted full-scale explosion experiments, to evaluate the strength characteristics of various seal designs, used for safely isolating worked-out areas in underground coal mines. Large-scale explosion tests conducted within the multiple entry section of PRL's Lake Lynn Experimental Mine (LLEM) is currently the only accepted test method used by the Mine Safety and Health Administration (MSHA), for deeming a seal design suitable for use in American mines. These explosion tests are labour intensive, expensive to conduct, and can interfere with other critical underground safety and health research programs conducted by NIOSH. The PRL has developed an alternative seal evaluation method, based on a hydrostatic pressure loading concept that can facilitate the in situ testing of seals in an operating mine. Two chambers within LLEM and one within PRL's Safety Research Coal Mine (SRCM) were used for hydrostatic pressure loading various seal designs. The results from these chamber tests compare favourably with those from the large-scale explosion tests in the multiple entries. In addition to testing seal designs at the required 20 psi static pressure level, the chamber test approach also allows for the determination of the seal's ultimate design strength. Six-scaling relationships for predicting the strength of seal designs as a function of entry size are also presented.

By C. B. Manula, R. L. Sanford, R. A. Rivell

A central requirement for using simulation models is the need for retrospect testing to validate experimental conclusions. Acceptance of a model by managers and safety practitioners is more likely to depend on its tested performance in-the field rather than on the underlying logic or the validity aspects of the model itself. It is here that simulation bridges the gap between theory and useful design procedures. The original version of the rail haulage sub-assembly was success¬fully tested in the field (Sanford, 1969). However, the case studies that were described here involved single-stage haulage and restricted jobtypes from UGMHS. Since this report together with Volume VI (Production Subsystem) describes extensive changes and modifications to the rail haulage sub-assembly and UGMHS, field tests were necessary to verify both the rail model and the linking concepts to the Produc¬tion Sub-system. Mine Description The candidate mine selected for model verification works the 6 1/2 foot Pittsburgh seam. Shaft openings are used for manways and ventilation and a dual compartment slope for materials handling. In the bottom half of the slope, a hoist with track handles supplies and equipment. In the upper half, a 42 inch belt conveyor travelling at 450 fpm moves coal from a rotary dump to the surface. The immediate roof is shale with the first 12 inches taken during development mining. About 4500 raw tons are produced daily from seven face units and one spare working three shifts. At seven of the sections,

Jan 1, 1974

By Will H. Coghill

Titanium is a well-known component of bauxite ores, sometimes occurring in sufficient quantity to mace its recovery worth considering. This question has been raised by some of the companies lixiviating bauxite ores. At the East St. Louis plant of the Aluminum Ore Co., a subsidiary of the Aluminum Co. of America, the waste sludge discharged daily contains over 75,000 pounds of Ti02. The sludge is all through 20-mesh, and a large proportion is slime. A supple of the waste was deslimed so that a gravity-concentration test of the "sand" could be made. The Aluminum Ore Co. cooperated in the work and made the chemical determinations In order to anticipate the results of table concentration a series of specific gravity fractions (float-and-sink) was made with heavy liquids. Acetylene tetrabromide was used for a density of 2.95, methylene iodide for 3.33, and thallium formate for 3.78, and the double salt of thallium formate-malonate made the separation at slimed sample appears in Table 1.

Jan 1, 1928

Continuously separate mixture of non-magnetic materials (such as scrap, precious metals, or certain ores) at a reasonable cost. Approach Nonmagnetic materials of different densities are rapidly float/sink separated by an augmented lifting force produced In a magnetic fluid (liquid) by the effect of an external magnetic field. The magnetic fluid is a colloidal suspension of magnetite In kerosene, prepared by a low-cost process. How It Works Separation is accomplished in an open trough filled with magnetic fluid. A magnetic field is established in the fluid, by energizing an electromagnet having poles on each side of the trough. Due to the design of the magnet poles and air gaps, the magnetic field is strongest at the bottom, about 10,000 oersteds, and uniformly decreases in strength to about 2,000 oersteds at the top of the fluid. Therefore, the magnetic field gradient increases with depth. The magnetic force attracts the entire separation medium (magnetic fluid) creating a reaction force of equal magnitude and acting in the opposite direction. This reaction created within a magnetic fluid/magnetic field combination is called a magnetic levitation force. It increases with the field strength. In this case because the magnetic field is strongest at the bottom of the trough, the magnetic levitation force will quickly float lighter material while heavier material sinks.

Jan 1, 1980

By Eugene Baker, Joseph Cervik, Albert Sainato

In Europe, water infusion is used widely to reduce generation of respirable dust during mining. Its use in the United States is limited to a few plow operations in the Pocahontas No. 3 Coalbed. This Bureau of Mines report describes the technology for infusing water in to a longwall panel and reports the results of a recent demonstration in the Lower Sunnyside Coalbed that achieved dust reductions averaging 58 pct. Because water infusion increases moisture content of the coalbed, face air velocities in excess of 500 ft/min (2.5 m/s) are possible, further diluting dust levels before dust entrainment occurs. An economic analysis shows a 23-pct reduction in operating costs when coal production is increased by changing from unidirectional mining to bidirectional mining with water infusion.

Jan 1, 1983

By Donald N. H. Chi

This Bureau of Mines report is concerned with a theoretical study of the aerodynamic response of a single mine entry to flame-induced disturbance. The unsteady, one/dimensional, compressible flow equations were solved using the method of characteristics. This study was primarily undertaken to determine the feasibility of extending the method of characteristics to study the aero-dynamic response of complex mine networks. It was demonstrated that although the technique has merit in studying the complex wave interaction in single entries, it appears to be too unwieldly and too expensive for network analysis. Effort was also directed at a further study of the dispersion and filtering characteristic of aerodynamic disturbances in mine passageways.

Jan 1, 1975

Provide respiratory protection and a clean work environment for stationary or semimobile workers at minerals processing plants. Approach An Overhead Air Supply Island (OASIS) was developed which filters, conditions, and evenly disperses an envelope of clean air over a worker's head, thereby insuring reduced dust levels and a clean work environment. How It Works The concept for the OASIS derives from an earlier Bureau development of a canopy air curtain for continuous mining machines (see Technology News #21). In this application, the benefits of a reliable, self-contained, self-cleaning industrial-duty air filtration and distribution system are extended to the minerals processing field. The OASIS draws dust-laden room air into a filtration system, removing the dust and delivering clean air to a specific 16-square-foot area. It consists of: ? a self-cleaning primary filter ? a heater (cooling coil optional) ? an airflow distributor and secondary filter (combined)

Jan 1, 1985

By D. J. MacDonald

The Bureau of Mines has carried out investigations on a method for producing zirconyl sulfate solution from zircon sand, comprising (1) reacting zircon sand with molten NaOH, (2) leaching the resultant fusion frit with water to remove sodium silicate and to convert sodium zircon-ate to hydrous zirconium oxide, and (3) leaching the hydrous zirconium oxide from unreacted sand with hot, dilute H2S04 to produce crude zirconyl sulfate solution. The following conditions were found to be suitable: reacting 0.6 kg of NaOH per kilogram of zircon sand for 10 min at 600° C; leaching the frit with 3 to 4 liters of water per kilogram of solids; leaching the residue with 5.1 liters of water and 1.25 liters of 98-pct H2S04 per kilogram of original solids for 10 min at 90° C; and filtering or decanting to recover unreacted zircon sand. A preliminary cost estimate is included.

Jan 1, 1982

By R. D. Currie

"A million tons of coal mined in the Pennsylvania anthracite region without a fatality is a feat of which to be proud and one that deserves the commendation of the entire mining industry. The average production per fatality in this region for 1933 was 206,823 tons, an exceptional record showing the results of an intensive drive made by the Pennsylvania Department of Mines and the anthracite operators and-workers to curtail the high accident rates heretofore prevailing in the region.This paper gives information about a mine with a record five times better than the average which should prove to the industry that mine accidents can be reduced through the proper safety organization and effort. The Pine Hill Coal Co., managed by Weston Dodson & Co., Inc., and located at Minersville, Schuylkill County, Pa., has made such a record at its Oak all colliery by studying its accident experience, realizing the facts, and pursuing a definite safety policy with a view to bettering its accident occurrence.As a direct result of its safety policy this colliery has produced 1,044,000 tons of anthracite without a fatality; within 3 years it has reduced its total accidents from 645 to 105 per year, its compensable accidents from 204 to 45 per year, and its lost-time accidents from 335- to 67 per year. In addition, it has set up a smoothly functioning safety organization that will go fax in aiding in the continuance of this great work of mining anthracite at a lower .cost in human suffering.This circular describes the accident-prevention methods perfected and the results obtained by this colliery in the belief that similar methods will produce essentially similar results at any other colliery where they may be adopted.The writer acknowledges his indebtedness to the officials of the company who furnished him with the details of the safety organization and the data from which this report was prepared. He especially desires to thank Messrs. Stockett, general manager, Wells, general superintendent, Morgan, safety engineer, and Kistler,- statistical department, for their hind assistance.The mine is opened by shafts, slopes, and drifts, a characteristic of minas in the Southern anthracite field. Thirteen different beds of coal are being mined. The thickness of the beds ranges from 3.5 to 16 feet and the pitch from 0 to 900. The roof and floor exhibit the entire range of conditions found in anthracite mines. Table 1 describes the coal seams being worked."

Aug 1, 1934

Provide guidance on the selection of millisecond initiator delays between blastholes in surface mine blasting to provide a desired degree of rock fragmentation consistent with safety and vibration considerations. The Problem Blasting remains the primary means of fragmenting, rock for all kinds of mining, quarrying, construction, and excavation activities, and it is the only practical and economic method of breaking up and moving large amounts of material such as coal overburden and stone aggregate. Because of the large amount of blasting done, typically using 4 billion pounds of explosive to break about 8 billion tons of rock annually in the United States, a small improvement in blasting performance will have a significant productivity impact. Standard blasting practices involve the selection of time delays in a blast for at [cast three purposes: (1) to control energy flow to minimize adverse vibrations, (2) to provide sufficient time relief for good rock displacement, appropriate muck pile shape for digging, and the prevention of collar violence, misfires, and flyrock, and (3) to provide an appropriate amount of interhole stress wave and gas pressure action for a desired fragmentation size distribution. Timing guidelines that exist are based on subjective observations rather than measurements, even for the relatively new casting methods. Until this Bureau study, no definitive analysis had been done to quantify the fragmentation and productivity of full-scale blast rounds as functions of precision delay timing.

Jan 1, 1989

By David C. Oyler, Paul W. Jeran, William P. Diamond

The Bureau of Mines is cooperating with the U.S. Department of Energy in a directional degasification project at the Emerald mine near Waynesburg, Pa. This project is designed to combine the highly successful underground horizontal degasification technology with surface drilling methods. The objective of this program is to demonstrate that directional drilling can be used as a technique for degasifying coalbeds ahead of mining to reduce the hazards of methane-air explosions in coal mines. The directional hole at the Emerald mine is designed to start vertically and enter the Pittsburgh coalbed horizontally. A 3-inch-pilot hole entered the Pittsburgh coalbecl at a vertical depth of 999 feet, The hole will be reamed to 8-3/4 inches in diameter, and 5-1/2-inch casing will be cemented in place. Three individual 3-inch-diameter, 3,000-foot horizontal gas collection holes will be drilled into the coalbed in a “bird foot” pattern. A corehole and vertical dewatering hole have been completed at the anticipated coalbed intercept. The dewatering hole was drilled to130 feet below the Pittsburgh coalbed, a depth of 900 feet, and 880 feet of 7-inch-OD casing was cemented in place. Seven vertical holes for monitoring the extent and progress of degasification have been drilled within the horizontal drilling area.

Jan 1, 1979

By K. O. Bennington

The thermodynamic properites of petalite (Li2A12Si8O20) were determined by the Bureau of Mines. The enthalpy of formation was determined by hydro-fluoric acid solution calorimetry. The values from the elements and from the oxides are ?Hf°298.15 = 2,335.8 ± 3.0 kcal/mole and ?H°295 (from oxides) = -50.60 ± 1.20 kcal/mole. Low-temperature heat capacities were determined by adiabatic calorimetry from 10.69 to 302.11 K. The derived standard entropy is S°298.15 = 111.0 ± 1 cal/deg-mole. Enthalpy increments above 298 K were measured by copper block calorimetry from 298 K to 1,193.6 K. The various experimental data were combined with other data from the literature to calculate the Gibbs energies of formation and equilibrium constants of formation over the temperature range of the measurements. Tables of enthalpies of formation and Gibbs energies of formation are given as a function of temperature from the elements and constituent oxides. The Gibbs energy of formation is ?G°f298.15 = 2,203.8 kcal/mole.

Jan 1, 1980

Control surface stream loss by identifying and selectively sealing water loss zones in stream channels overlying underground mines. Approach Electromagnetic terrain conductivity surveys, coupled with stream gaging, are performed within a stream channel to identify saturated fracture zones associated with loss of stream water. This information is used to target locations for the injection of expandable polyurethane grout. The grout is injected two to three feet beneath the surface of the strcambed, across each loss zone, to seal the fractured strcambed and restore stream flow across the damaged area. How It Works Multiple zones of infiltration (natural and induced) normally exist in stream channels overlying mined areas, causing water handling and/or acid drainage problems in the mines as well as loss of stream flow. It is typically difficult to accurately locate these loss points. Therefore, Conventional methods of stream repair, such as using plastic membranes or clay and rock rip-rapping, are applied to long lengths of a stream channel. The two step approach developed by the Bureau of Mines First quickly and accurately locates loss zones using electromagnetic ground conductivity survey and gaging instruments. Conductivity is measured at fixed spacings (typically 25-50 ft depending on the instrument and desired observation depth), Ground conductivity increases when saturated conditions exist at depth. These apparent flow loss zones are confirmed by gaping, to eliminate possible effects due to unobservable metal debris adjacent to or buried in the stream sediment.

Jan 1, 1991

By D. Harrington, B. W. Dyer

"Two recent occurrences in Western metal mines in each of which 3 men were killed due to breathing fumes from explosives, have aroused keen interest among mining men not only as to the exact cause of such accidents, but also as to possible preventive measures.In sinking the forty five degree incline Marsh *haft near Burke, Idaho, on May 13, 1920, a round of holes containing about sixty pounds of 40 per cent gelatin explosive was blasted by the night shift upon leaving at 11:30 P.M. It was customary for the night shift to leave compressed air blowers open at bottom of abaft until the compressor was shut down slightly before midnight. Presumably this was not done on the night of the lath as the fumes were so heavy in the shaft bottom on the morning of the 14th that at about 8 o'clock, Superintendent Bergen and one of the shaft men, on reaching the shaft bottom, were overcome and fell from the bucket into the sump containing about six feet of water; and when two other men went down in the bucket a few minutes later to investigate, one also fell into the sump and the other was barely able to roach the shaft collar. The three bodies were later on recovered from the sump.At 400 P.M., June 10, 1920, at the Dominion Mine, Colville, Washington, a round of 11 holes containing about fifteen pounds of 60 per cent nitro¬glycerine explosive was blasted in a fifty degree raise about fifty feet above the main tunnel level by the shift going off for the night. in this mine it was the practice not to try to blow out the fumes until just before the shift went to work the next morning, Although no work was being done on the night shift, one of the raise men, curious to ascertain the effect of the shots, about 7:45 P.M., wandered into the mine (which was a tunnel only a few hundred feet in length), and was missed by one of his companions about an hour later. When three men tried to remove the body of the inquisitive miner, two of them were also overcome; ultimately these two and the first man were removed from the point at which all were asphyxiated, which was practically at the foot of themaise."

Jul 1, 1920

By Sarah P. Guerrino

This chapter summarizes data on crude nonfuel mineral production for the United States, its island possessions, and the Commonwealth of Puerto Rico. Included also are the tables that show the principal nonfuel mineral commodities exported from and imported into the United States and that compare world and U.S. mineral production. The detailed data from which these tables were derived are contained in the individual commodity chapters of Volume I and in the State chapters of Volume II of this edition of the Minerals Yearbook. Although crude mineral production may be measured at any of several stages of extraction and processing, the stage of measurement used in this chapter is what is normally termed ?mine output.? It usually refers to minerals or ores in the form in which they are first extracted from the ground, but customarily includes the output from auxiliary processing at or near the mines.

Jan 1, 1987

By B. W. Jong

The U.S. Bureau of Mines investigated anhydrous chlorination and caustic-acid leaching processes to recover Ni, Co, Mo, and W from waste hydroprocessing catalysts. In batch laboratory-scale equipment, the chlorination process extracted 61 to 99 pet of the metals. Final recovery was 65 to 99 pct. The caustic-acid leaching process extracted 81 to 98 pct of the metals. Final recovery was 36 to 99 pct. Chlorination processing included roasting, chlorination, hydrolysis of metal chlorides for recovering Mo or W, water leaching of Ni or Co from the spent charge, purification, and solvent extraction or precipitation of Ni or Co from the purified solutions. Caustic-acid leach processing included NaOH leaching, solvent extraction of Mo or W from the NaOH leach liquor, H2S04 leaching of the NaOH leach residue, purification, and solvent extraction or precipitation of Ni or Co from the purified solution. The estimated fixed capital cost for a commercial-scale plant processing 39,000 Ibid of waste Ni-Mo-AI catalyst was $8 million for the chlorination process and $9.6 million for the caustic-acid leaching process. The estimated operating cost was about $0.20 and $0.40 per pound of the waste catalyst, respectively, for the two processes.

Jan 1, 1989