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By A. F. Colombo

Laboratory-scale tests were conducted by the Bureau of Mines on an argillaceous Michigan copper ore and mill tailing to determine the feasibility of leaching with acidified ferric sulfate solutions. The ore and tailings, containing 1.24 and 0.24 percent copper, respectively, were from the White Pine Copper Co., Ontonagon County, Mich. The investigation showed that ferric sulfate leaching of the ore and tailings followed a predictable pattern. Thus, with 4 hours of leaching, up to 58 percent of the copper in the ore was extracted, but prolonged leaching (2 to 3 weeks) was required to dissolve more than 90 percent of the copper. Similarly, about 50 percent of the copper in the mill tailings sample was dissolved in a few hours, but 8 days or more were required for extractions of over 90 percent.

Jan 1, 1962

By H. B. Brunot, L. C. IlsLey

The design , construction, inspection , and test for permissibility of a storage- battery locomotive outfit in accordance with the requirements of Schedule 15* represents a large amount of work, first on the part of the locomotive manufacturer and secondly on the part of the Bureau of Mines . Detailed information of the first investigation under the schedule is presented here . This investigation covers the inspection and test of a storage- battery locomotive manufactured by the Geo . D. Whitcomb Co. , Rochelle , Ill . , to which Approval No. 1500 was assigned ,

Feb 1, 1923

By A. W. Khair, S. J. Jung

"IntroductionIn a typical incremental loading test, the AE activity increases rapidly in the initial stage of the loading. It is associated with initial closure under compression of favorably oriented cracks already present, together with sliding of crack faces against each other /1/. After the initial stage, crack closure and movement largely cease and the AE activity drops to a barely detectable level /2/. In the final stage of loading test, cracking associated with the onset of inelastic deformation' occurs, and the rate of AE rapidly increases /3/ indicating an increase in the •number of events associated with higher number of microcracks. To understand better primary fragmentation process, Anderson and Ruzzi conducted tests to identify a practical method of monitoring fracture development in rock, as caused by an excavation tool /4/. They proved that a relationship existed between the AE activity, generated during fracturing and the amount of fracture surface area created.A process of fragmentation, demonstrated by conical bits acting orthogonal to the flat surface of block of coal specimen with and without lateral confining pressure is presented here. The monitoring of AE during the fracturing process of rock/coal has been a very useful indirect method in studying fracture mechanism.Specimen PreparationLarge blocks of Waynesburg coal were obtained from a surface mine. These blocks were then out and molded to approximate dimensions of 25.4 x 25.4 x 15.2 'an (10 x 10 x 6 in.). These specimens were instrumented with three strain gages in a 45 degree rosette. One was mounted parallel to the bedding plane direction, another was tinted at an angle of 45 degree from the bedding plane direction and the third was mounted perpendicular to the bedding .plane direction. Each of the three strain gages were set 5.1 an (2 in.) away from the impact point.Typical Test ProcedureIn a typical experiment, the specimen was placed in the confining chamber.Predetermined equivalent in-situ stresses were applied to the specimen by using two sets of hydraulic cylinders. Two 1 in. thick steel plates ware positioned between the sample and the hydraulic cylinders in order to distribute the pressure uniformly over the whole surface of the specimen. The LVDT null position was adjusted with respect to the coal face. After setting the LVDT, the bit and associated weight was lifted to a predetermined height (equivalent to a predetermined kinetic energy) by a win. The three strain gages were balanced using the signal conditioner and the output was recorded by a 6 channel strip chart recorder. The experimental set-up is shown in Figure 1."

Jan 1, 1989

By D. B. Dow

The study of oil production methods with reference to the amount of oil originally pressent in the oil-bearing, formations has developed the fact that-ordinary methods-of production remove only a part of the oil actually present. In fact, it is generally realized that when a field is abandoned more oil remains in the sand than has ever been removed. As a consequence of this realization, the petroleum engineer has devoted considerable tine in recent years in devising methods for increasing the percentage of recovery. His studies have indicated that in most cases the total production of a field is dependent upon the available gas rather than upon the available oil. Mien the gas in the sand is exhausted, oil production ceases even though there may be enormous quantities of oil remaining unrecovered. Consequently, any method of conserving the gas or increasing the supply of gas will increase the ultimate recovery from a field. The practice of producing oil under vacuum increases the effectiveness of the gas remaining in the sand, as well as furnishing more gas by evaporating the light fractions of the crude. Pumping ' compressed gas or air down selected wells of a lease has been found to increase the production of oil from the surrounding wells. Studies of oil and gas ratios have indicated that much of the available gas has been wasted as far as its effectiveness on oil production is concerned. his has led to the development of "stop cocking"3 and the practice of producing under back pressure3, which methods aim, to obtain more effective work from the gas with reference to the amount of oil delivered to the well.

Jan 1, 1926

By Arne Landsberg

Experiments were made with a batch reactor to determine the effect of gas pressures, temperature, and gamma radiation intensity on the reaction CO + Ch ? COC12. The equation, [dp = 0.0110 (1 - 0.01t) (PCOI)1/2 PC12] where [dP] is the change of pressure of phosgene with time (atm/hr), t is the temperature (°C), PCO and PC12 are the reactant pressures (atm), and I is the radiation intensity (r/hr), was found to best fit the data. Oxygen and a large ratio of reactor surface to volume retarded the reaction, but inert gases had no effect. A low-temperature reactor system is proposed to take advantage of the conditions which give a high reaction rate with gamma radiation and a simple scheme of product purification.

Jan 1, 1970

By Gloria L. Walker

The Bureau of Mines Information and Analysis Directorate collects worldwide data on virtually every commercially important nonfuel mineral commodity. These data form the base for tracking and assessing the health of the minerals sector of the U.S. economy. This data collection activity was instituted by the 47th Congress in an appropriations act of August 7, 1882 (22 Stat. 329), to place the collection of mineral statistics on an annual basis. The most recent authority for the Bureau of Mines Information and Analysis activity is the National Materials and Minerals Policy, Research and Development Act of 1980 (Public Law 96-479, 96th Congress), which strengthens protection for proprietary data provided to the U.S. Department of the Interior by persons or firms engaged in any phase of mineral or mineral-material production or consumption.

Jan 1, 1990

By A. B. Cecala

A new prototype bag nozzle system has been designed under a Bureau of Mines contract to reduce dust generated during the bagging operation on fluidized air baggers. A field analysis of the new system has shown that the bag operator's dust exposure was reduced 83 pet. The amount of blowback was reduced 89 pet, which corresponds to a significant product savings. The new prototype system has been operating for a substantial period of time with no major problems.

Jan 1, 1984

By G. B. Shea

The accident experience of the California petroleum industry for 1927 was characterized by a decrease it .the number of fatalities. The year closed with a total of 41 fatal accidents, as compared with a total of 54 for the preceding year. 3 In percentage, the figure for 1927 represents a decrease of 24 per cent from that of 1926 and evidences the promising results of organized safety work, in which the industry in California has taken an absorbing interest. The percentage of decrease for 1927 is the largest recorded in any one year since the compilation of the fatality record in the California petroleum industry was begun. Although good progress has been made during the past few years, much remains to be done to reduce still further the human and economic waste caused by accidents. This review is intended to show the employee, as well as the employer, the proximate and contributing cause of accidents. To increase the value of the report, preventive measures in various instances are suggested, on the theory that accidents of a similar nature will occur unless remedial action in taken to remove the cause.

Jan 1, 1928

By Robert E. Barieau

In the design of plants to separate helium from natural gas , it is necessary to estimate the enthalpies of the various streams at various positions in the process . This Bureau of Mines report surveys the various methods that have been used to determine enthalpies and gives information on the organizations with such capabilities . The minimum information required for developing an enthalpy diagram is presented , and the relative merits of the various methods are discussed . It is concluded that methods that require no mass flow rate or energy measurements are to be preferred .

Jan 1, 1965

By John Campbell, E. S. Baker, G. W. Jones

"INTRODUCTION In previous reports 5,6./ results were given showing the amount of natural ventilation that takes place in manholes (capacities, 74.1 to 308 cubic feet) when the number of ventilation openings in the manhole cover ranged from no openings to a maximum of 4g.The tests warranted the general conclusion that the ventilation or air changes taking place in, a manhole increase as the area of openings in the cover of the manhole is increased, and are proportional (with the exception of a few erratic tests) to the area of the openings in the cover. The area of the openings was the chief factor that affected ventilation.The results did not show any marked change in rate of ventilation due to increased capacity or shape of manhole, when the results were expressed in terms of air changes per day versus area of ventilation openings in square inches per 100 cubic feet of manhole space.It was observed during these investigations that in certain tests that showed erratic results (that is, did not agree with the general average for a given set of test conditions) the wind velocity during the test period was also abnormal. In view of these findings it was decided to conduct a series of tests in which the wind velocity across the openings in the manhole cover could be controlled accurately to determine the effect of wind velocity on ventilation rate."

Aug 1, 1938

By R. F. Tenney

No detailed information has been published heretofore on the performance of small industrial-type anthracite stokers in building-heating service, apparently because of the difficulty of comparing the performance of one unit with that of another over an entire season's operation. Studies of competitive heating fuels have been similarly handicapped, and attempts to compare fuels are seldom technically sound in this investigation, the performance of a 60-in. Losch4 stoker burning rice-size anthracite in a standard commercial boiler was observed during a 4-month winter-spring season. It was used to heat two buildings at the Bureau of Mines' Anthracite Research Center at Schuylkill Haven, Pa., with the customary type of automatic pressure-range control. Attendance was limited to inspecting, fuel weighing, data recording, and ash removal. Results were computed daily and grouped by weekly periods to minimize daily irregularities. The same stoker-boiler unit had already been tested in a series of American Society of Mechanical Engineers (ASME) test code runs, with the stoker running continuously and with other conditions well stabilized A comparison of results from the code test and the building-heating tests provided information not available in the past for a single stoker unit, assisted in analyzing heat losses not computable in a cyclic operation, and established a basis for evaluating stoker performance in heating service.

Jan 1, 1963

By R. W. Stahl

Gas accumulation and dust suspension are the major safety hazards in coal stockpiling and reclaiming operations. This report presents a schedule of safety precautions and plant design features devised by the Bureau of Mines to reduce danger from these and other sources.

Jan 1, 1965

By B. W. Gandrud

In the summer of 1950, Bureau of Mines engineers visited a number of coal-preparation plants in western Europe and Great Britain to obtain information on European and British coal-cleaning and froth-flotation practices. In view of the growing importance of froth flotation as a process for cleaning fine sizes of coal, it was felt that such data and information would be of value in this country, for, although froth flotation has been adopted for use in a few of our plants, it has not as yet been employed as extensively as in British and European preparation plants. Many of the important coal beds in western Europe, especially in the Ruhr Valley of Germany and in the Dutch coal-mining region of Limburg, Netherlands, are very friable, with the result that the run-of-mine product contains a large proportion of the sizes too fine to be treated successfully by any other method than froth flotation. Furthermore, the relatively high cost of producing coal from these beds has for many years made it economically feasible and desirable to treat the fines by froth flotation, especially in the coking-coal fields.

Jan 1, 1951

By N. S. Dalal, X. Shi

"The oxidation of NADPH by vanadate(V) in the presence of glutathione reductase showed typical enzymatic kinetics. The oxidation was inhibited by N-ethylmaleimide, a glutathione reductase inhibitor. Superoxide dismutase had no significant effect on the oxidation, indicating non-involvment of the superoxide radical. The vanadate(V) reduction was found to be a one-electron transfer process. These results suggest a new pathway for vanadate(V) metabolism and a new function of glutathione reductase. Compounds of vanadium(V), such as NaV03 , exert potent toxic effects on a wide variety of biological systems (1-3). Despite intense current activity, however, the biochemical mechanism of vanadate(V) toxicity is still not well understood (1- 14). It is believed that one of the important pathways involves the oxidation (by vanadate(V)) of NAD(P)H (15, 16), but, to our knowledge, there has been no report of the identification of any vanadate(V) reductase. With a view to finding if there exists any vanadate(V) reductase, we have investigated the oxidation of NADPH by vanadate(V) in the presence of glutathione reductase. Glutathione reductase (GSSG-R)2 was selected because our previous studies have shown (17) that GSSG-R can act as a reductase for chromate(VI), which is isoelectronic with vanadate(V). We find that GSSG-R does indeed function as a NADPH-dependent vanadate(V) reductase, thus pointing to a new pathway for the metabolism of vanadate(V), as well as to this property for GSSG-R. MATERIALS AND METHODSSodium metavanadate (NaV03 ), henceforth vanadate, was purchased from Aldrich and its solution was always freshly prepared. The GSSG·R used was from bovine intestinal mucosa and was purchased from Sigma. The oxidation of NADPH was followed photometrically as the decrease in absorbance at 340 nm. The spin trap, 5,5-dimethyl- pyrroline-N-oxide (DMPO), was purchased from Aldrich and used without further purification, since very weak or no spin adduct signal was obtained from the purchased sample when used alone.ESR spectra were obtained at X-band (9.7 GHz) using a Bruker ER200 ESR spectrometer. The magnetic field was calibrated with a self-tracking NMR gaussmeter (Bruker, Model ER035A) and the microwave frequency was measured with a digital frequency counter (Hewlett-Packard, Model 5340A). An ASPECT 2000 computer was used for data storage and analysis. The concentrations given in the figure legends are the final concentrations. All experiments were carried out in the phosphate buffer solution (pH 7.2) and at room temperature."

Jan 1, 1990

By Wesley A. Grosh

The Allah Cooper mine, in Louisa County, Va., formerly was a producer of lead and zinc. It was believed that the critical shortage of leach and zinc and the fact that some ore had been produced at this mine justified exploration of it. A preliminary examination was made on April 30, 1943, by J. E. Hill, a Bureau of Mines Engineer. Diamond drilling was done on the property from November 30 to December 18, 1943, to determine whether the sulfide body extended to depth. One hole drilled to a depth of 650 feet and located so as to cut the Allah Cooper ore shoot about 150 feet below the lowest known mine workings failed to disclose sulfide vein at that depth.

Jan 1, 1949

By R. R. Allen

Gieseler plastometer tests were performed on eight western coking coals at retort - immersion depths ranging from 2 to 3-3 /4 inches (measured to the center of the coal charge ) . Increased maximum fluidities were associated with greater retort - immersion depths , the most pronounced increases being observed on highly swelling coals when tested at 3-3 /4 inches . The maximum fluidity of one of these coals when tested at 3-3 /4 inches was 146 percent greater than that observed at 24 inches . Retort - immersion depth had no significant effect on the temperatures of initial softening , fusion , maximum fluidity , end of fusion , and solidification .

Jan 1, 1964

By D. J. MacDonald

The Bureau of Mines investigated two alternative methods for treating a zirconium-bearing chloride-sulfate strip liquor to obtain reactor-grade Zr02. One method involves neutralization with NH3 and the other hydrothermal precipitation. The strip liquor was derived from zircon sand by a Bureau of Mines method for separating zirconium and hafnium via solvent extraction with a tertiary amine. Neutralization with NH3 to precipitate hydrous zirconium oxide required 0.9 to 1.1 g NH3 per gram of zirconium. The NH3 can be recovered for recycle. Zr02 that met reactor-grade specifications was produced by precipitation with NH3? Hydrothermal precipitation of Zr02 from strip liquor required that the solution be maintained at 2600 C and 680 psi for 10 min and in a non-corrodible pressure vessel. In bench-scale experiments both methods gave-zirconium recoveries greater than 99 pct.

Jan 1, 1984

By E. G. King

THIRD-LAW entropy data for zirconium-containing compounds are sparse. Kelley a lists entropies at 298° K. for the oxide, tetrachloride, nitride, and silicate, as well as for the metal. The present paper presents heat capacities between 51° and 298° K. and entropies at 298.15° K. for the zirconates of the alkaline-earth metals-calcium, strontium, and barium. The authors believe magnesium zirconate does not exist as a stable compound at room temperature. Entropies of formation from the constituent oxides also are given. MATERIALS The materials used in this investigation were synthesized and analyzed in the Berkeley Laboratory of the Bureau of Mines. Calcium zirconate was prepared by heating an intimate mixture of reagent-grade calcium carbonate and pure zirconia for 30 hours between 1,200° and 1,300° C. and for 32 hours between 1,400° and 1,500° C. As part of the heating schedule, the sample was ground and mixed seven times. Periodic analyses and minor adjustments of composition were made. Analysis of the final product gave 31.19 percent calcium oxide (theoretically 31.28 percent) and 68.67 percent zirconia (theoretically 68.72 percent). The X-ray diffraction pattern agreed with that in the ASTM catalog.

Jan 1, 1960

By John Taber, JOHN B. HOPKINS

During World War II , a critical shortage of domestic abrasive corundum developed . Late in 1944 , the shortage became so acute that it was deemed advisable to investigate certain low-grade corundum prospects in Madison and Gallatin Counties , Montana . The Gallatin , the Bozeman , and the Bear Trap deposits were the principal ones investigated . The Bear Trap deposit was examined by E. W. Newman and Robert S. O'Brien , engineers of the Bureau of Mines , in August 1944. Exploration was started in October 1944. Field work was completed late in the spring of 1945 . report presents the data obtained from the exploration .

Mar 1, 1947

By L. B. Pankratzt

The heat content above 298.15° K of ferroelectric lithium columbate (LiCbO3) was measured to 1,770° K. The Curie temperature was determined to be 1,450° K, the melting point 1,540° K, and the heat of fusion 16.94 kcal/mole. Heat content and entropy increments have been tabulated for the temperature range from i98.15° to 1,800° K. Heat contents are also given in equation form.

Jan 1, 1966