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By A. W. Deurbrouck

This report presents the results of a washability study of 322 coal mine samples showing the sulfur forms and distribution in the coals. The samples were collected from mines which were principally utility coal producers. Generally, the data show the total sulfur content of the coals evaluated could be significantly reduced by some combination of stage crushing and specific gravity separation. However, few coals could be upgraded to a final product containing 1 percent or less total sulfur. The complete washability data are presented for each sample processed. A statistical evaluation is included for the coalbeds from which more than 10 samples were collected and for the geographical coal producing regions. A graphical summation is presented for the coal producing regions and selected coalbeds.

Jan 1, 1972

By Alvin M. Cummings

"INTRODUCTION During July and August 1943, the Bureau of Mines undertook an investigation of the Trego lead-zinc mine, near the town of Platteville in Grart County, Wis. as part of a general investigation of the zinc-producing area of southwestern Wisconsin. The work was done when every effort was being made to increase the production of metals important to the nation's war program.The Bureau of Mines completed eight churn-drill holes and sampled mineralized faces in the mine workings to determine if further exploitation was justified in an area between the mine and a zone previously drilled to the east.Following the investigation described herein, intermittent operations were resumed. Except where otherwise stated, this report describes conditions only to the time of completion of the Bureau of Mines investigations.ACKNOWLEDGMENTSIn its program of investigation of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. The Mining Division, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual investigative work and prepares the final report. The Metallurgical Division, O. C. Ralston, chief, analyzes samples and performs beneficiation tests.The investigation described in this report was conducted under the immediate supervision of the author and 0. W. Terry, mining engineer of the Bureau of Mines, with the assistance and advice of E. D. Gardner, re¬gional engineer, and E. P. Barrett, district engineer. Final data were prepared under the direction of Paul Zinner, acting chief, Minneapolis Branch, Mining Division.A. V. Heyl, Jr., and A. F. Agnew of the Federal Geological Survey cooperated with the Bureau's engineers and made lithologic studies required during the drilling program.The cooperation of W. N. Smith and O. E. DeWitt of the Vinegar Hill Zinc Co. and Francis Piquette of the Piquette Mining Co. facilitated the investigation to a great extent."

Mar 1, 1948

By James L. Hendrix

A study was made of the United States Bureau of Mines' chlorine-oxygen leaching process for complex sulfide concentrates. The investigation sought to determine the kinetic order and IT mechanisms involved in the reactions betweens sphalerite, and galena with chlorine. The influence of copper on the extraction rates was also studied. It has been shown the rates of reaction of chlorine in aqueous solutions with sphalerite and galena are both zero order at 373K with the rate limiting step being the chemical reaction. Addition of cupric chloride increased the extractions of both lead and zinc.

Jan 1, 1980

By Isaac A. Zlochower

This paper presents data on the limiting (minimum) oxygen concentration (LOC), in the presence of added N2, of methane (CH4), propane (C3H8), ethylene (C2H4), carbon monoxide (CO), and hydrogen (H2), and some of their binary mixtures. It also addresses the issue of the flammable concentration (flammability) limits of these pure gases in air. The study is based on spark ignited explosions in large, spherical laboratory vessels (120-L and 20-L) using a 7% pressure-rise criterion for explosion propagation. The results of the study are compared with the older values which used long flammability tubes with a diameter >5 cm together with visual evidence of substantial upward propagation. They are also compared to results reported recently using a 12-L spherical flask with a visual flame propagation criterion. Finally, they are compared to results reported in Europe using more modest flammability criteria and smaller chambers. The findings reported here show excellent agreement between the 120-L and 12-L results, good agreement with the 20-L results, and reasonable agreement with the earlier flammability tube values for the lower flammability limits. They disagree, however, with the more conservative European values. These results and those from the 12-L experiments also feature lower LOCs than are given by traditional flammability tubes. A model for the LOCs of such fuel mixtures based on the Le Chatelier mixture rule for lower flammable limits is seen to reasonably fit the observed results on binary mixtures and can accommodate more complex mixtures as well. One such set of ternary mixtures containing CH4 and 1:1 CO:H2 is well fitted by the model.

Jan 1, 2009

By C. W. Davis

Before listing the laboratories and the work performed there, it is proper to make clear what is done and what is not done by Federal bureaus, States, and Territories, as well as by countries to the north and south of the United States. FEDERAL Bureau of Mines. - The Bureau of Mines does not make assays or analyses for individuals or firms unless the samples are part of the ore-testing and ore-dressing investigations of the Metallurgical Division on representative ores from mining districts and of possible benefit to the entire mineral industry through published reports. All significant results obtained in this way are made public. Any mineral sample sent to this Bureau for simple identification will be examined.

Jan 1, 1938

By Roy T. Sorensen

This Bureau of Mines report presents the results of a study to rank technologies for extraction of alumina from bottom ash and coal shale. The available literature on composition and availability of coal waste was reviewed, and papers pertinent to alumina extraction are referenced. Types of coal waste were categorized by method of waste generation, coal content (heating value), location, coal type (ash nomenclature), and alkaline earth content. The differences and similarities among the categories of coal waste are summarized as to factors that my affect aluminum extraction, especially factors concerning chemical composition, current production, storage problems, and accumulated tonnage. Data available on physical characteristics and mineralogy did not correlate well with the individual categories of coal waste, and discussion on these two aspects is limited to the differences between coal ash and coal shale.

Jan 1, 1983

By R. E. Peterson

The Bureau of Mines has undertaken beneficiation investigations on samples representing large tonnages of oxidized taconites in order to develop and evaluate applicable technologies for producing iron oxide concentrates from these materials. Information derived from the investigations can be used to expand the domestic iron raw-materials base and to establish the impact these taconite deposits may have on future national iron ore requirements. This report describes a process that includes reduction roasting, magnetic separation, and flotation, applied to a western Mesabi Range sample taken near Coleraine, Minn. The sample contained 36.8 pct iron and 46.0 pct silica, and represented 0.5 to 1 billion tons of crude material. An average of 962 lb/hr of oxidized taconite was roasted with 33 lb/hr of lignite in a 35-foot-long rotary kiln. Pulverized lignite and natural gas maintained the kiln operating temperature at 850° C. The roasted taconite was beneficiated by magnetic separation and cationic flotation in a 900-lb/hr pilot plant and yielded a product analyzing 68.1 pct iron and 4.6 pct silica, and containing 82.4 pct of the iron in the kiln feed.

Jan 1, 1981

By B. W. Gandrud

[The meaning of the term "bauxite' has always been somewhat vague and indefinite, and the term has been used in various applications to denote sometimes a rock, sometimes a mineral, but more frequently an ore. It seems logical to think of bauxite as an ore, however, because a very large part (probably at least 85 per cent) of the entire world's production of bauxite is at present being used as a source of aluminum and aluminum chemicals. In the United States there are two districts that, produce bauxite - the Arkansas district and the Alabama-Georgia-Tennessee-Mississippi district. The deposits in Mississippi have been discovered recently and are riot as yet productive but it seems reasonable to consider them as apart of the-district hat includes the deposits of Alabama, Georgia, and Tennessee. The, two districts are often referred to as the Arkansas field and the Appalachian field. Of these two the Arkansas field has been by far the largest producer, and at present over 90 per cent of the bauxite production of they United States comes from the Arkansas field. The bauxite industry in the Appalachian field had its beginning in 1889, and since that time the total production of the states of Alabama, Georgia, and Tennessee has been, nearly a million tons. The production of bauxite in this field has languished in the last five, or six, years, and In 1927 its production was only about 14,000 tons, according to Harder4. The recent decrease in production is due mainly to the fact that many .of the known deposits of commercial-grade ore have become exhausted. There are, however, considerable quantities of low-grade bauxite in the Appalachian field, but these have not been available because there has been no satisfactory way of concentrating low-grade bauxite. The quantity, of low-grade material in the Appalachian field is probably, fully as large as the tonnage of commercial ore which the field has already produced.]

Jan 1, 1928

By Joseph Cervik, Gerald L. Finfinger

The Bureau of Mines conducted an experimental degasification project in Island Creek Coal Co.'s Virginia Pocahontas No. 5 mine. Methane from the over- lying Pocahontas No. 4 coalbed was entering mine workings in the Pocahontas No. 3 coalbed through fractures in the roof rock. Small-diameter (1-5/8-inch) holes were drilled into the overlying coalbed to reduce the gas pressure and intercept methane flows, which were piped to the surface through an under- ground 6-inch-diam steel pipeline. The total methane flow rate from the vertical holes averaged 150,000 ft3/day for the first month. Methane flows into the mine were reduced by 47 pct, thereby demonstrating the effectiveness of this form of degasification in reducing ventilation requirements and providing a safer working environment.

Jan 1, 1979

By Seth C. Schaefer

The Bureau of Mines has determined the standard Gibbs energies (AGf°) of CoS1.035 (cobalt sulfide) and Ni2.515S2 (nickel sulfide) with high-temperature galvanic cells using stabilized Zr02 (zirconia) as the electrolyte. Potential measurements were obtained for the cell Pt, CoS1.035, CoO, S02(g, 1 atm)//Zr02//02(g, 0.0114 atm), Pt, with the overall cell reaction C0S1.035(c) + 1.535 02(g, 0.0114 atm) = CoO(c) + 1.035 S02(g)¬ These results, combined with the best available data for ?Gf° of CoO and S02 from the literature, give the standard Gibbs energy of formation of CoS1.035 for the reaction Co(c) + 0 5175 S2(g) = CoS1.035(c) ?Gf° = -38.890 + 18.87 x 10-3T ± 0.185 kcal/mole (866.0 - 1,104.9 K), where temperature (T) is expressed in kelvins. Similar measurements were obtained for the cell Pt, N12.515S2, NiO, S02(g, 1 atm)//Zr02//02(g, 0.0122 atm), Pt, with the overall cell reaction Ni2.515S2(c) + 3.2575 02(g, 0.0122 atm) = 2.515 NiO(c) + 2 S02(g). Combination of these results with data for ?Gfo of NiO and S02 from the literature yields the standard Gibbs energy of formation of Ni2.515S2 for the reaction 2.515 Ni(c) + S2(g) = Ni2.S1SS2(c) ?Gf° -65.377 + 24.67 x 10-3T ± 0.541 kcal/mole (968.6 -1,053.7 K).

Jan 1, 1981

By David P. Lindroth

The Bureau of Mines has developed and successfully tested a hangup clearance module for use in clearing hangups in underground mine chutes and ore passes. The Bureau's tests showed that the hangup clearance module can be effectively used to clear mine hangups. Furthermore, it is believed that clearance using this module is quicker, safer, and more efficient than the method currently used. The hangup clearance module uses a ballistic disk explosive charge that can clear hangups located as far as 50 feet (15.2 m) from the position where the charge is detonated. Mine personnel can therefore set up the module and the charge it contains without being exposed to dangerous areas. This report describes the principles of operation of the module, provides data and drawings for its construction, and gives instructions for its setup and use. The report also summarizes the development of the module, briefly discusses preliminary and underground tests, and lists the current and potential applications of the hangup clearance module to underground mining.

Jan 1, 1982

By J. B. Gayle

Numerous investigators have studied the addition of inert4 substances to coking blends. Generally, the results have yielded trends applicable only to the particular coals and inerts studied. Recently, somewhat more general results were obtained for cokes produced from blends containing added inerts, using the sole-heated oven. The present investigation represents an extension of this work to include a wider range of inerts and to determine the applicability of the various conclusions to cokes produced with the Tuscaloosa oven. The results indicated that an increase in dry-coal charge density of 1 pound per cubic foot (p.c.f.) caused a corresponding change in the hardness (1/4-inch tumbler index) of Tuscaloosa oven cokes of 0.9 percentage points. This value compares favorably with the value of 0.7 determined previously for the sole-heated oven and Bureau of Mines-American Gas Association (BM-AGA) retort.

Jan 1, 1961

By Henry E. Blake

The purpose of this Bureau of Mines investigation was twofold. The first phase of the work was to determine the technical and mechanical feasibility of defluorinating low-grade siliceous fluorspars on an intermediate scale by high-temperature pyrohydrolysis in a rotary kiln. The second phase was to react the liberated hydrogen fluoride (HF) offgas with alumina monohydrate to produce commercial-grade aluminum fluoride (85 percent AIF3). The two phases of the work were to be integrated into a single continuous process. Evaluation of the data shows that low-grade siliceous fluorspars can be successfully defluorinated, either in a solid or a molten state, in a gas-fired rotary kiln in the presence of water vapor at 1,250° to 1,350° C. The water produced by combustion of propane was sufficient to yield defluorinatians of 75 to 85 percent.

Jan 1, 1962

This chapter analyses the parameters influencing initial design of communication systems, for new mines and upgrading existing systems. Paragraph 5.2 outlines those variables that must be taken into account during the design stages of a new wired phone system. Recommended features, general requirements, and how they can be implemented are treated in this section. Paragraph 5.3 describes ways of improving or extending the range of trolley carrier phone systems and pager phone systems already installed in the mine. 5.2 New Phone System Design The task of designing an adequate communication, control, and monitoring system for an underground mine must be addressed on a system basis. In addition to insuring that effective voice communication is established, any new system should take into account present and future requirements of remote control and monitoring functions. Chapter 4 illustrated the drastic savings in response time that can be realized when remote control and monitoring are integrated into the overall communication system. The importance of including control and monitoring in the overall design plan for any system cannot be overemphasized. Because each mine is unique, and thus usually has its own special operating characteristics and communication requirements, there is no such thing as "the one best system" to meet the requirements of all mines. The optimum communication, control, and monitoring system for a mine must be one that has been tailored to meet the special requirements of that particular mine. Factors that must be considered during system design include- a. Type of mine and mining methods (low- or high-seam coal, deep hardrock mine, stope caving, longwall, room and pillar, etc.). b. Maximum number of working sections. c. Expected mine growth rate and eventual maximum size. d. Haulage methods (tracked trolley, diesel, belt, etc.). e. Underground power distribution system (dc, ac, or both). f. Features desired (two-way radio paging, private line capability for emergency use, etc.). g. Redundant or backup systems for use during outages of the normal system. Although no two mines are alike, the following items have been established as the main characteristics desired for any underground communication system: 1. Multiple Communication Paths to Outside--the objective here is to give all telephones a second method of communicating with the surface. 2. Audible Emergency Signaling--the communication system provides the main means of alerting miners during emergencies. The system should include means to broadcast distinct audible signals for emergency signaling. Initiation of these signals should probably be controlled from. a central outside point, such as a surface control room. 3. Emergency Override--provisions should be included to permit any conversation to be overridden with emergency communication. 4. Selective Area Page--as mines grow larger it is apparent that the entire telephone system paging mode need not be activated each time a call is initiated. When the general area of a

Jan 1, 1984

By G. S. McCaa

Rock-dusting is an. effective means of preventing coal-dust from propagating an explosion in a coal mine, but it will not prevent gas from igniting-explosively and with much attendant damage locally. Ventilation must therefore be effective at all times, regardless of the employment of other explosion-prevention methods, if gas explosions are to be avoided. This paper describes a gas explosion which occurred in as bituminous mine that was well rock-dusted at the point of ignition and which exemplifies the value of rock-dusting, the necessity of maintaining effective ventilation, and the need of permissible rock-dusting machines receiving power from a permissible locomotive. Description of Explosion The mine in which this explosion occurred is developed on a panel system in a practically level seam; the panel entries are driven in pairs, and the air current intakes on the right entry and returns on the left entry. Near the mouth of the intake a door is placed to control the ventilation; board stoppings are placed in crosscuts, except the second from the face, in which a brattice cloth curtain is hung, the last crosscut is left open and line brattices conduct the air current from the last crosscut to the faces. In No. 7 entry the last cross-cut was 152 feet from the face, the line brattice being within 38 feet of this face, and the second crosscut was 250 feet outby the face of the back entry or return. Seven days prior to the explosion the intake and return entries were rock-dusted to within 38 feet of the face, and as the entry had advanced during the week, the rock-dusting was to be extended.

Jan 1, 1929

By Curtis H. Elder

In studies conducted by the Bureau of Mines, two test areas were hydraulically stimulated and exposed by mining: One in the Pittsburgh coalbed at the Vesta No. 5 mine, Washington County, Pa.; and one in the Illinois No. 6 coalbed at the Inland mine, Jefferson County, Ill. Induced fractures were contained totally within the coalbed with no adverse effect on the stability of associated rock strata. Induced fractures were vertical and were propagated normal to the direction of least residual tectonic stress. Gas production was increased fivefold to twentyfold by hydraulic stimulation.

Jan 1, 1977

The latest Active List of Permissible Explosives and Blasting Devices was published in July, 1929, as Bureau of Mines Report of Investigations 2947, 2 under the title or "Active List of Permissible Explosives and Blasting Devices Approved Prior to June 30, 1929.' Subsequent Reports of Investigations 2253, 2958, 2962, 2972, 2988, 2992 and 3000, were issued to record the official actions taken during July, August, September, October, 1929, and January, February, and March, 1930. No changes were made during November and December, 1929, and April, 1930. The following additional changes in the list recording the actions taken during May, 1930, are now authorized. [ ]

Jan 1, 1930

By Alex U. Miller

Since its beginning, the occupation of coal mining has been considered hazardous. It is true that there are hazards inherent in mining, but it is believed that most of them, at least, can be guarded against. Moreover, many man-made hazards can be eliminated by officials and workers adopting safer practices. Notwithstanding the hazards in coal mining, the fatal accident rate in the United States has improved. During the, period from 1911, to 1941, inclusive, the fatal accident rate varied from 5.35 to 2.22 per million tons of coal. With many handicaps during the war period, 1942-45, such as the lack of experienced manpower. and the, employment of untrained men, the increased average age of workers, and the shortage of equipment and supplies, the industry s ill further reduced its accident rate, so that it ranged from 2.30 to 1.724/ deaths per millon tons of coal. During 1944, 684,000,000 tons of coal was produced with a rate of 1.91, and during 1945, 631,000,000 tons was produced with a rate of 1.724/ deaths per millon tons of coal. The accident rate for 1945 was the lowest for the industry since records have been compiled.

Jan 1, 1946

By R. E. Mussler

Electrowinning of copper from chloride solutions in a diaphragm cell was studied by the Bureau of Mines. The copper powder product was shaken periodically from the cathode and removed from the bottom of the cell. The effects of copper concentration, brine concentration, copper chloride species, and cell voltage were investigated. Power consumption of 1.1 and 2.1 kW-hr/kg were obtained with cuprous and cupric chloride solutions, respectively.

Jan 1, 1975

By D. R. Tesarik

An instrumentation and numeric modeling study was conducted by the Bureau of Mines at the Magmont Mine in Bixby, MO. An isolated section of this room-and-pillar mine was monitored with borehole and closure extensometers during a pillar recovery program to determine stress redistribution. In situ stress measurements were taken in the rib before pillar extraction began. Sample cores from the boreholes were taken for analysis of the properties of the host rock in the laboratory. The extensometers recorded no measurable displacements during most of the operation. Two-dimensional, finite-element; three-dimensional, finite-element; and three-dimensional displace-ment discontinuity codes were used to model the area of study. The finite-element models were run with two initial stress conditions, i.e., stress due to gravity only and stress obtained by in situ measurements. Horizontal stresses in the models reduced the calculated factor-of-safety in the mine back by up to a factor of 10, but did not have a significant effect on calculated pillar stability.

Jan 1, 1989