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By S. R. Droes

The U.S. Bureau of Mines investigated calcium fluoride (CaF2) assisted sulfuric acid (H2S04) leaching as an alternative to the melting-quenching procedure to obtain Mn from domestic manganese silicate resources. Pyroxmangite [(Mn, Fe) Si03] ore containing, in percent, 34.4 Mn, 22.8 Si, 2.6 Ca, and 1.3 Fe was leached in a 500-mL resin kettle. Ninety-six percent of the Mn was extracted under conditions of 330 g/L ore, 245 g/L H2S04, 35 g/L CaF2, 90' C, and 2 h. To incorporate electrowinning in recovering Mn, the ore was leached with a simulated spent anolyte solution containing, in grams per liter, 12 Mn, 140 H2S04, 130 (NH4)2S04 (ammonium sulfate), and 5 CaF2. Manganese extraction of 92 pct was achieved from 130 giL ore leached at 90° C in 3 h. The Fe, silica (SiOJ, and other impurities were precipitated from the pregnant solution by neutralization with ammonia (NH3). Manganese of greater than 99-pct purity was deposited at a cathode current density of 50 mA/ cm2 at 30° C, with a current efficiency of 65 pet in a two-compartment cell. A flowsheet was proposed for the leaching and electrowinning procedure.

Jan 1, 1990

By M. R. Geer

The widespread adoption during the past decade of the dense-medium process for cleaning coal increases the need for technologic studies of the process. Such studies provide information that will insure maximum usefulness of this process in its present form and may well lead to substantial improvements in design and opera¬tion. The Bureau of Mines has published the results of cleaning trials on a wide variety of coals in two dense-medium pilot plants5/ and reported the recovery of coal from waste by dense-medium treatment.6./ The present report deals with the viscosity of magnetite dense medium, an important subject about which virtually nothing has been published. Specifically, the report concerns methods for measuring viscosity, the influence of various medium contaminants on viscosity, the effect of viscosity on cleaning results, and the influence of viscosity on consumption of medium. Cleaning trials on four coals of varied density composition in a pilot plant, using mediums of different viscosities, showed a steady reduction in cleaning efficiency with increasing viscosity in every instance. However, the behavior of each coal in a viscous medium was distinctly individual. With one, an increase of only 1 centipoise in viscosity caused a reduction in recovery efficiency of 7.7 percent, whereas the same increase in viscosity with another reduced recovery efficiency only 2.7 percent.

Jan 1, 1957

By Robert J. Evans

Capital and operating costs were estimated using a wet suppression, fabric filter, and a combination system of the two for hypothetical hard rock stone crushing plants located in central Pennsylvania, operating at 300, 600, and 1,000 tons per hour. Fixed capital expenditure for the dust abatement systems ranged from $49,129 to $249,162. Annual operating costs for the dust abatement systems ranged from $8,394 to $46,606 (0.9 to 3.2 cents per ton). If these dust abatement systems are properly sized, installed, and maintained, efficiencies approaching 95 percent can be expected for reduction in weight of dust particles emitted before control.

Jan 1, 1975

By Ralph H. Espach

The value of careful fractionation in the manufacture of petroleum products is recognized more and more by petroleum refiners. Recent studies have shown that the quality of the products depends largely on the type of fractionating equipment and on the care used in operating the equipment. For example Rue3 has shown that careful fractionation of pressure distillate will greatly reduce the amount of chemical treatment necessary to produce finished gasoline. The advantages of the combination of pipe still and bubble tower in obtaining good fractionation are well recognized in the petroleum industry. However, the equipment designed in the past has in general been much too large for convenient laboratory use. The present paper describes a continuous-distillation apparatus for the laboratory study of fractionation. This apparatus has given very satisfactory results in the study of different crude oils and petroleum products. A discussion of the theory and action of bubble towers has not been given, as this subject has been discussed previously by Cooke and Rue4. It is believed that the distillation curves of the products obtained from this apparatus show clearly its capabilities.

Jan 1, 1928

By Jack E. Fraley

Because of their noncombustibility, silicate and magnesium oxycements are desirable for sealing shale in underground coal mines. In this Bureau of Mines investigation, cement samples were cured and tested (nonstandard tests) for submersion to note resistance to dissolution (breaking into parts), which is an important property for a coating. Nonappreciable dissolution during 1 week of submersion was set for passing the test. Over half of the coatings passed the test.

Jan 1, 1977

By W. C. Hudson

"The Miami-West Palm Beach belt of silica sand, which may be suitable for the manufacture of high-grade glass, extends 65 miles northward from the neighborhood of Miami to the vicinity of West Palm Beach, The sand presumably originated in the host rocks constituting the oceanward slope of the Appalachian Mountains and the Piedmont Plateau of Georgia and the Carolinas. The sand now lies in a long, narrow, and probably thin belt that forms a dune-capped terrace marking a previous stage of submergence. The highest dune crests appear to be no more than 30 feet above sea level, and the water table is about 10 or 15 feet below the general level of the terrace.The width of the belt in several places is known to be more than a mile, and the thickness of the clean glass sand sampled ranged from 4 to more than 7 feet. Visual inspection and the meager data indicate the existence of bodies of glass sand large enough to supply foreseeable markets.Analyses of three samples indicate that beneficiation would make the sand suitable for the better grades of ordinary and flint glass.The prospective grade and quantity of sand, an available market in Florida for glassware, and the expectation of postwar expansion of the new industry of glass producing justify more detailed exploratory work and beneficiation testing.U. S. Route No. 1, Old Dixie Highway, the Seaboard Railway, and the Florida East Coast Railway, all substantially parallel and usually within a width of a mile or two, run along parts of the belt or between it and the coast. In addition to many streets and unpaved roads, a paved road crosses the belt at right angles about every 5 miles. Numerous towns are situated within or near the belt. Any area selected for a mining, processing, and manufacturing plant would be near a railroad, a highway, and water and also accessible to public utilities.The subtropical climate, famous for its pleasantly warm winters, would preclude seasonal interruption of plant operations."

Apr 1, 1946

By Bruce I. Thomas

The occurrence of tin-bearing gravels along Tozimoran Creek in central Alaska has been known for a number of years. In September 1944 the Bureau of Mines investigated an area approximately 1,000 feet long and 200 feet wide along Tozimoran Creek to deter-mine the cassiterite content of the stream gravels, which are about 4 feet deep and covered by 3 feet of overburden. Nine trenches and two shafts were excavated, from which samples of the underlying gravels were taken. This report contains a discussion of sampling methods and tables giving the results of analyses.

Jan 1, 1948

By Maria I. De Rosa

The U. S. Bureau of Mines performed experiments to determine if the primary gas toxicities evolved during the early (~300° C) and later (~400° C) combustion stages of chlorinated polyester-reinforced mine ventilation ducts could be predicted by a smoke particle characteristic, for the development of a test parameter. The experiments were conducted in an approximately 20-L furnace, at 14-min durations at set furnace temperatures of 2500 and 1,000° C, with an airflow through the furnace of 10 L/min. The variables studied, as a function of time, were the hydrogen chloride (HCI), carbon monoxide (CO), carbon dioxide (C02), and oxygen (02) concentrations, furnace temperatures, the sample mass weight loss, the average smoke particle diameter (dg and average number and concentration (no), and the product of the average smoke particle diameter and concentration (dgno). Results show that the inverse of the smoke particle diameter-concentration product [(l/dgn0)], correlates directly and significantly with the primary gas toxicities evolved during both early (HCI) and later (CO) stages of combustion.

Jan 1, 1989

By Clarence O. Babcock

This Bureau of Mines publication presents guidelines for mining near surface and underground bodies of water. The guidelines were based on information developed under contract in three phases of study, as follows: (1) Collection and documentation of data from worldwide sources; (2) application of existing guidelines, foreign, Federal, and State, to case histories of previous inundations; and (3) development of recommended guidelines for underground coal mining near bodies of water aimed at maximum efficient utilization of underground coal resources consistent with minimizing inundation hazards. While the contract guidelines were for the mining of coal seams, they may also be used for mining any tabular sedimentary mineral deposit. Tables are given for the determination of the size of coal pillars needed; for other bedded deposits, similar tables could be determined based on their strength properties.

Jan 1, 1977

By John C. Edwards

The Bureau of Mines developed a mathematical model to predict the oxygen requirements for a miner evacuating a mine. The model accounts for variations in the miner's escape speed with mine airway height, and for the empirically determined expressions for the weight-specific oxygen uptake rate for upright walking, stooped walking (duck-walking), and crawling. A Fortran computer program that is user oriented was prepared based upon the model's constitutive equations. Specific instructions for utilizing the program, as well as applications to miner evacuation from a mine, are presented.

Jan 1, 1986

By E. C. Tarpley, R. A. Drogowski, R. F. Abernethy

Three of the test methods frequently used for the determination of moisture in the analysis sample of coal were employed in analyzing a series of coals ranging in rank from anthracite to lignite . For most coals , the variation between the three methods are within the tolerances allowed between duplicate determinations by the same method . The processing variables studied included atmosphere , flow rate of atmosphere , inert atmospheres , oven temperatures , heating time , exposure of the dried coal to laboratory air , and surface area of the test sample . Unless close control is kept on these variables , erratic results will be obtained .

Jan 1, 1964

By N. S. Dalal, V. Castranova, K. Van Dyke, V. Vallyathan

"IntroductionInhalation of crystalline silica is often associated with the development of pulmonary disease (Ziskind et al., 1976). Recently, it has been proposed that freshly sheared silica .may have surface properties that make it more reactive with lung tissue than aged silica, and that this unique reactivity ·of freshly crushed silica enhances its pathogenicity. A recent study in our laboratory strongly supports this theory (Vallyathan, et al., 1988a; 1988b). We found that grinding of silica cleaves bonds in a silica tetrahedral lattice generating reactive free radicals sites on the surface of the silica particles. The presence of surface radicals on freshly ground silica was monitored by electron spin resonance (ESR) spectroscopy. The ESR signal generated from fresh silica in air is characteristic of Si-0 and Si radicals. Evidence, i.e., the ESR signal after the addition of a spin trap (DMPO) and its sensitivity to ethanol, indicates that these silicon-based surface radicals can react with water to form hydroxyl radicals (OH). Results also indicate that these surface radicals make fresh silica more cytotoxic than aged silica; i.e., fresh silica causes more membrane damage as evidenced by hemolysis and lipid peroxidation. Therefore, the presence of reactive sites on the surface of freshly cleaved silica may play a significant role in its pathogenicity.If surface· free radicals are related to cytotoxicity, then screening dusts for the existence of such radicals may predict their relative pathogenicity. Since an ESR spectrometer is not available to many laboratories, the objective of this study was to develop a quick and simple technique to monitor the existence of reactive surface sites on dust. The technique chosen was the measurement of chemiluminescence using a liquid scintillation counter; i.e., an instrument which·would be accessible to most investigators."

Jan 1, 1989

By A. D. Bauer

For several years the Bureau of Mines has conducted surveys to determine the changes in motor gasoline being sold throughout the United States. The present survey shows that far the districts in which samples were collected, the average gasoline is becoming more volatile instead of less so, as is sometimes supposed. This year's gasoline is much more volatile than that sold two years ago, and it has a somewhat better distillation range than last summer's samples. A comparison of the average figures for several years, shows that motor gasoline is also becoming more uniform in character. The large seasonal change is disappearing, but ?winter gasoline', still has a lower initial boiling point than "scanner gasoline". This difference in volatility is made intentionally to facilitate starting the motor in cold weather. The end point shown in the present survey is slightly lower either than that of last winter or of the summer of 1921.

Jan 1, 1922

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

APPENDIX B - DEVELOPMENT OF FOAM-CONCRETE SLURRY MINE SEALANT 1. Introduction This appendix describes the results of an experimental development and laboratory evaluation of foam-concrete as a rapid setting, lightweight, self-supporting mine sealant material. Foam concrete, otherwise known as Aerated Concrete, is a form of lightweight concrete whose structure consists of air bubbles held together by a hardened cement mortar. Its principal applications are found in roofing, insulation, shock absorbing, and backfill. The air bubbles in foam concrete are formed either by chemical reaction in the wet, placed mortar, or by introducing a stable foam into the mortar during mixing. The mortar is usually a cement slurry with fine sand or fly ash as filler. Our attention focused on preformed foam concrete, since this is most adaptable to field applications. Equipment is available,* which simultaneously mixes and pumps a slurry of foam concrete. Such a slurry can be produced at a rate of up to 50 yards/hr and has been pumped in a 2-inch-diameter hose 1000-feet horizontally and 250 feet vertically up without significant bubble deterioration. One very attractive feature associated with the use of foam concrete concerns site logistics. Foam concrete can be generated with densities as low as 20 lbs/ft3, and hence the total number of

Jan 1, 1973

By James S. Grichar

Interest in mergers in the nonfuel mineral industry developed when 5 were listed among the 50 highest valued mergers in the United States in 1981. This report presents a Bureau of Mines study of trends in merger activity from 1960 to 1979 and explores motives for mergers in the nonfuel mining and mineral industry. The objective was to determine precedent for or a trend toward the 1981 acceleration in merger activity and to examine certain financial motives for non fuel mineral mergers. Data indicate that the relative value of non fuel mineral mergers has grown since 1972 although the number of mergers has remained proportionate to historical trends for all mergers. Since 1974, the assets acquired in "large," nonfuel mineral firm mergers, those of $10 million or more, have comprised at least 93 pct of assets acquired. More nonfuel mineral firm mergers involved mineral companies as the acquiring firm than vice versa but mining and minerals firms acquired were of higher value than nonmining firms. A major motivation for mergers involving large mineral firms was the acquisition of assets at less than replacement costs. Univariate statistical testing, a methodology chosen for its applicability to the data, confirms this hypothesis while rejecting other financial motives. The remainder of the work is devoted to a discussion of suggested areas for future study.

Jan 1, 1984

By E. M. Tignor

A research program to aid development of improved methods for increased production of petroleum from partly depleted reservoirs is a vital part of the Bureau of Mines effort to effect true conservation of that mineral resource. This report presents results of an investigation to identify the clay minerals within some Appalachian petroleum-reservoir sands, the effect of clay content on the fluid-flow behavior of those sands, and the use of brines in water-flooding operations. Permeability measurements using kerosine, calcium chloride brine, simulated oilfield brine, potassium chloride brine, sodium chloride brine, and distilled water were made on reservoir-rock cores. Clay fractions were separated from sand grains of disaggregated portions of each core sample, and the clay minerals were identified by the differential thermal analysis method. Relations of the permeability to various fluids were developed.

Jan 1, 1957

By E. S. Shedd

The Bureau of Mines investigated electrowinning and tapping lanthanum metal from lanthanum oxide in a fluoride bath. The electrolyte was composed of LaF3, BaF2, and LiF. Metal containing 0.2 percent impurities was produced at a rate of over 2 pounds per hour. Principal impurities were carbon, aluminum, and silicon. Low-carbon metal was produced by continually discharging the carbon oxide gases and maintaining 0.1-atmosphere pressure. Anode reactions and cell design were found to be important factors in cell operation. Both frozen electrolyte skulls and tungsten metal crucibles proved satisfactory for collecting the metal and did not react with the molten lanthanum.

Jan 1, 1966

By Martin S. Oudenhoven

This Bureau of Mines report presents the results of a microseismic study conducted in the Climax block cave mine at Climax, Colo. Rock noises created by caving were monitored and their sources located during a 3-month period. A planar array of seven accelerometers, located above the block of ore being caved, detected the rock noise. A computer was used to calculate the location of the microseismic activity, using a traveltime difference method. The accuracy of these locations was estimated to be ±20 feet. An analysis of the data taken during the recording period showed a concentration of microseismic events located in the wall of the cave panel. This concentration of events was found to occur in a "high-silica" geologic forma-tion that cut across the caving panel approximately 200 feet behind the undercut.

Jan 1, 1973

By Jack L. Henry

The monocarbide region of the ternary system U-C-O has been investigated at 1,700° C as the first phase of a more extensive study of a portion of the four-component system U-C-O-N. An area bounded by the following compositional limits in atomic percent was studied: U, 44 to 55; C, 30 to 60; 0, 0.2 to 20. Compacts composed of mixtures of uranium, graphite, and uranium dioxide powders were sintered at 1,700° C under an equilibrium pressure of carbon monoxide to produce uranium oxycarbide specimens having a variety of compositions. Sintered specimens were evaluated by X-ray, chemical analysis, and ceramographic techniques. Solid-solution boundaries and phase relations have been established, and the effects of composition on the lattice parameter as well as the decomposition pressure have been investigated. Oxygen can be substituted for carbon in stoichiometric uranium monocarbide to the extent of about 17 atomic percent at 1,700° C. The composition range of the oxycarbide solid solution extends from about 48 to 51 atomic percent uranium in the low oxygen region. Above 10 atomic percent oxygen the composition range narrows to less than 1 atomic percent uranium. Carbon monoxide exists as a gaseous phase in equilibrium with all compositions which contain oxygen. Five separate phase fields were found bounding the solid-solution area. Other phases within this portion of the system include uranium, uranium dioxide, uranium dicarbide, and uranium sesquicarbide. Decomposition pressures of oxycarbide compositions at 1,700° C have been found to vary from a few microns for stoichiometric and uranium-rich compositions to 35 torr for carbon-oxygen-rich specimens. Lattice parameters were found to depend upon the U to C + 0 ratio as well upon the extent of substitution of oxygen into the stoichiometric monocarbide lattice.

Jan 1, 1967

By Bertrand L. Johnson

Langbeinite, a comparatively rare mineral that has been reported from only five countries in the entire world, has recently attained considerable economic importance in the United States and Poland. Since September 1940, several hundred thousand tons have been produced in one of the Carlsbad (N. Mex.), potash mines for chemical and fertilizer use. As it is a newcomer in this field, and as it is the source of fertilizers possessing special advantages, notably for soils deficient in magnesium or requiring sulfate fertilizers, a discussion of its properties, occurrences, uses, mining, and treatment is appropriate at this

Jan 1, 1944