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By Walter Kawa

The hydrogenation of phenyl ether, benzyl ether, and phenyl sulfide in the presence of iron catalysts was studied by the Bureau of Mines to gain a better understanding of the role of iron catalysts in the hydrogenation of coal. The carbon-oxygen and carbon-sulfur bonds in these compounds may be similar to some of the carbon-oxygen and carbon-sulfur bonds in coal which react during the early stages of liquefaction by hydrogenation. Experiments were made in batch autoclaves for 4 hours; hydrogen was at a pressure of about 540 atmospheres. In the hydrogenation of phenyl ether at 400° C, metallic iron catalyzed both hydrogenolysis (splitting-hydrogenation) and nuclear hydrogenation (addition of hydrogen to aromatic rings) reactions, Products were principally benzene and cyclohexane. The activity of metallic iron was decreased by adding carbon monoxide or a reactive sulfur-containing organic compound. Ferrous sulfide catalyzed the conversion of phenyl ether to benzene, phenol, and small amounts of cyclohexane. Hydrogenolysis of benzyl ether was catalyzed by metallic iron and to a lesser extent, by ferrous sulfide at 250° C. No nuclear hydrogenation was observed with either catalyst. Conversion of phenyl sulfide to benzene was nearly quantitative in experiments made at 250° C with equimolar quantities of phenyl sulfide and metallic iron or iron as ferric oxide. Conversions of metallic iron and ferric oxide to ferrous sulfide were nearly stoichiometric. No reaction of phenyl sulfide occurred in the presence of ferric oxide and water, and very little occurred in the presence of metallic iron and water. Ferrous sulfide also catalyzed the hydrogenolysis of phenyl sulfide to benzene, but conversion was lower than in experiments with metallic iron or ferric oxide. The activity of ferrous sulfide was increased by adding water and decreased by adding hydrogen sulfide. The results of this study suggest that ferrous sulfide is an active form of iron when iron is used as a catalyst for the hydrogenation of coal.

Jan 1, 1963

By W. S. Landers

This report presents a study by the Federal Bureau of Mines of technical factors related to the production of special carbon and tar from selected Wyoming coals. Certain Wyoming high-volatile bituminous and subbituminous coals were processed in bench-scale apparatus to determine potential carbonization yields and in pilot plant retorts to produce sufficient char and tar for testing. These tests have shown that a critical selection of coal is necessary when the coal is processed for a specialized carbon. Generally high yields of tar are obtained from low-temperature carbonization of Wyoming high-volatile bituminous and subbituminous coals, and the yield of tar usually increases with increase in rank within this range of coals. The production and evaluation of industrial carbons from Wyoming coals by using pilot plant and bench-scale techniques is part of the continuous program of upgrading western coals. It has been found that: 1. Most Wyoming coals are nonagglomerating and may be carbonized in fluidized systems. Chars produced in pilot plant retorts at low temperatures contain about 17 to 23 pct, residual volatile matter and are easily ignited. These chars appear suitable as power plant fuel. The tar-plus-light-oil yields range from 14 to 40 gal./ton of raw coal processed. 2. Wyoming high-volatile coals produce a slightly smaller and somewhat weaker coke than currently mined Western United States high-volatile coals used commercially as blending stock in metallurgical coke production.

Jan 1, 1961

By S. P. Kinney

Economy in blast-furnace practice depends largely upon efficient gas-solid contact in the shaft of the furnace. If efficient work is not done in the shaft the hearth and bosh will not function properly. A condition may be readily imagined where the particles of ore in the shaft are so large that the time entailed in the descent of these materials into the bosh is not sufficient to permit proper reduction and preparation prior to the time the ore enters the bosh of the furnace. Another condition may be pictured where the density of the stock column and the flow of stock is such that the ore will take one course and the gas another. Both of these examples will result in insufficient contact between the gas and the ore. Unreduced ore will reach the hearth, and gas which has not been efficiently oxidized will reach the stock line. The result is the use of an excess of carbon in the smelting process. An example of the result of inefficient gas-solid contact in the shaft of a blast furnace is shown by the curves in Figure 1.

Jan 1, 1930

By S. L. May

Investigations by the Federal Bureau of Mines indicate that hafnium and zirconium compounds of acceptable purity can be extracted from Nigerian zircon concentrates. Chlorination and caustic soda fusion techniques were used to extract 85 to 95 percent of the valuable metals from the concentrate. The extracted hafnium and zirconium compounds were purified by recrystallization of the oxychlorides or by formation of complex salts during chlorination. The zirconium-hafnium product of the recrystallization method contained 15 parts per million of uranium, and the product of the salt-complex method contained less than 10 parts per million of uranium. The hafnium was separated from zirconium by solvent extraction methods. A zirconium product containing 0.3 percent hafnium and a hafnium product containing 4 percent zirconium were obtained. At the request of the Atomic Energy Commission (AEC), work was started to develop techniques for processing Nigerian zircon concentrates in commercial installations presently engaged in producing zirconium and hafnium metals from ores. The Nigerian zircon has a high hafnium content, but the presence of uranium and thorium is a problem not normally encountered in processing zircon concentrates.

Jan 1, 1961

By J. H. Perkins

The Bureau of Mines has conducted desorption work on fine coal particles at near atmospheric pressure. An apparatus Iris been developed that uses a capacitance manometer to measure desorption of methane from coal particles up to, 2 inches in diameter and pressures up to 1,000 psi. This will make it possible to duplicate the desorption process as it occurs in its natural underground environment.

Jan 1, 1969

By A. D. German

This paper presents one of a series of digests of foreign mining legis- lation and court decisions which is being prepared in advance of a general report relative to the right of American citizens to explore for minerals and to own and operate mines in various foreign countries. This interpretation of tie laws of Ecuador has been prepared from the best available information in Washington, but is released subject to correction and amplification, if necessary, by the proper American diplomatic and consular officers to whom it is being referred through the courtesy of the Department of State..

May 1, 1930

By R. H. Nicholas

Shuttle cars have undeniably proved their worth as a means of transporting coal underground; however, several factors have arisen in connection with their possible improvement. This report .discusses the effect of shuttle cars that employ rough-tread and smooth-tread tires on mine roadbed, the amount of dust thrown into suspension by the use of such tire treads, and the service rendered by each type of tire. Involved, also, in this study are observations on the use of different amounts of calcium chloride on the haulageways.

Jan 1, 1949

By L. C. IlsLey

A list of permissible mine equipment, tested and approved p or to July 1, 1934, was published in Bureau of Mines Information Circular 6813/. The present list4/ includes virtually all the electric air compressors, coal drills, mining machines, loading machines, conveyors, mine pumps, room hoists, mine telephones, rock-dusting machines, switches, electric cap lamps, flame safety lanes, electric hand and trip lamps, electric flood lamps, methane detectors, blasting units, storage-battery locomotives, tandem locomotives, mower trucks, and concrete mixers tested and approved by the Bureau to January 1, 1937. The system under which these devices were tested permits the manufacturer, after his equipment has passed certain tests prescribed by the United States Bureau of Mines, to mark his equipment with a seal showing that it has been approved by the Bureau. These tests are designed to insure that equipments have the minimum requirements for safety in use. The only object of the bureau in making such tests and publishing lists of permissible equipment is to help decrease the hazards of mining.

Jan 1, 1937

By C. K. Lee

This Bureau of Mines report presents results from experimental studies on wood fires in a laboratory-scale tunnel network. Experimental measurements include ignition delay time, flame spread rate, ventilation air and gas flow rates, wood temperature, gas temperature, pressure and composition, thermal flux, and smoke particulates. These measurements form a data base for fire-scaling studies and provide information on various fire processes, such as flow interaction between ventilation air and fire, fire throttling and reverse flow, and duct fire energetics. Results show how hazards of duct fires relate to the development of (1) asphyxiating and toxic fumes, (2) explosive gas mixtures, (3) throttling of ventilation air, and (4) high-temperature combustion products. Such fire hazards should be carefully considered when testing flammabilities of materials used in a confined underground mine environment.

Jan 1, 1980

By A. C. Fieldner

"Purpose and Nature of Tests:The rapidly increasing use of motor vehicles and trucks in the United States is creating an entirely new problem in the proper ventilation of tunnels, subways and other confined spaces through which such machines must pass. This problem has become of immediate importance because a tunnel 3,000 ft. long is being designed to pass under the Hudson River between New York City and New Jersey. Another tunnel at Pittsburgh 5,700 ft. long through the South Hills, is already under construction, and a third tunnel, 6,000 ft. between Boston and Past Boston is proposed. It is probably that other tunnels will be started in various parts of the United States in the near future.The ventilation of such tunnels is a serious matter, on account of the poisonous nature of automobile exhaust gases. It not uncommon to read about finding a man dead in his garage. Generally this happens on a cold, winter morning, after he has been running the engine with the doors and windows closed."

Mar 1, 1920

By Albert W. Deurbrouck

The preparation characteristics of the coals of Buchanan County, Va., are described in this Bureau of Mines report. Twenty-one samples ,,,ere collected from 9 coalbeds in the county. Of these samples 13 were of metallurgical quality as received, and 8 required some upgrading to provide acceptable products. In general, the coals were of low to medium ash and sulfur content, and ranked as medium-to high-volatile bituminous. In 1963, production in the county was in excess of 13 million tons, of which 2.2 million tons were mechanically cleaned.

Jan 1, 1966

By William O. Vanderburg

Some mines after passing through the prospecting stage and becoming sizable enterprises still adhere to the development program of the prospect, extending their workings without definite plans. In mining operations where definite structural conditions do not exist, a prearranged layout of mine development is not feasible; but where exploration and preliminary development have indicated the extent and probable limits within which the ore is expected, careful planning of development will result in a lowering of mining costs and a consequent increase is profits. A lack of definite plane for laying out mine workings is one of the contributory factors to unnecessarily high costs. Although this paper deals primarily with the influence of level spacing on mining costs, still other phases of mine development, such as the proper spacing of ore chutes and raises, can be analyzed on a cost basis in a similar manner, as shown herein. LEVEL SPACING The problem of establishing a new level or levels in order to exploit steeply dioping ore deposits and prospect the ground at depth recurs at intervals during the active life of mines. Driving levels is largely "dead work" and therefore costly. By the judicious selection of the proper level interval after balancing the opposing factors involved in the problem, a considerable saving in mining costs can be effected. Although much has been written in regard to the various methods employed in ore extraction, mining literature is still incomplete in regard to the factors-influencing level spacing at various mines. Level spacing involves procedures not lending themselves readily to description, and, moreover, it is a phase of mining operations that is apt to escape criticism, because only those in close contact with the operations are equipped with the necessary familiarity with the conditions to pass judgment.

Jan 1, 1932

By Kenneth L. Kreamalmyer

"The demand for open-hearth iron ore and the existence of suitable smelting facilities in the St. Louis area seemed to warrant investigation of several Missouri iron-ore deposits of the filled-sink type. Preliminary examinations were made in the autumn of 1944 by an engineer3/ of the Bureau of Nines, and in December of the same year funds were allotted for the exploration of these properties by churn drilling. Three properties, the Silver Hollow Bank and the Newbauer and Coleman properties, were drilled. Work was completed May 8, 1945.The Federal Geological Survey and the Missouri Geological Survey and Water Resources assisted in the project by determining the stratigraphy from drill cuttings and by mapping the drilled areas.The properties explored are in the hilly section of east-central Missouri and are connected by all-weather graveled roads with various shipping points of the St. Louis-San Francisco Railway system within 3 to 6 miles of each property.The Silver Hollow Bank, in sec., 8, T, 40 N., R. l W. Franklin County, Missouri, is in the Meramec State Game Reserve. The nearest town and shipping point is Sullivan, Mo„ which is 6 miles distant. The Newbauer property, in sec. 28, T. 41 N., R, 2 W., Franklin County, Missouri, is approximately 3 miles west of Stanton; The Coleman property, in sec. 14, T. 38 N., R. 3 W., Crawford. County, Missouri, is within a short hauling distance of the railway at Elayer, Mb. These are shown on figure 1.The region surrounding the explored areas contains a series of low-lying hills or ridges and narrow winding valleys drained by the Meramec River system. These hills seldom rise more than 200 feet above the valley floors, most of which are approximately 700 feet above sea level. Except for numerous small farms and a few small towns, the entire region is covered by a dense growth of timber and small brush. The St. Louis-San Francisco Railway system, U. S. Highway 66, and numerous all-weather State and county roads traverse the area."

Oct 1, 1945

By John W. Cole

The Butte district has been the principal producer of metallurgical-grade manganese in the United States since World War I. Manganese dioxide nodules are produced from rhodochrosite ore by concentrating the rhodochrosite and roasting the concentrate in rotary "cement-type" kilns. The Anaconda Copper Mining Co. is the only producer at present. Under the stimulus of a purchasing program administered by Metals Reserve Company during World War II, however, several independently owned or operated mines (including the Norwich) produced manganese carbonate ore. These mines were examined in Juno 1949 by John W. Taber, mining engineer, Bureau of Mines. A core-drilling program to develop ore in the Norwich mine was recommended and approved. drilling was completed early in 1950. This report gives factual data obtained.

Jan 1, 1951

By J. P. Coughlin

The U.S. Bureau of Mines has developed a monitoring system that acquires and analyzes data for use in determining the conditions that may precede mountain bumps in coal mines. Based on a UNIX workstation linked to an array of geophones in a working longwall operation, the system captures complete waveforms of microseismic events and simultaneously obtains continuous samples of the voltage levels of each geophone. Event rates and locations are calculated and displayed in real time on the UNIX workstation, which is situated in an underground instrumentation room. These results also are transmitted from the workstation to a display computer near the longwall face. The system runs continuously and has the capability to acquire, analyze, display, and archive microseismic (transient) data and single point data, such as closure and pressure changes, simultaneously.

Jan 1, 1993

By Frederick L. Hoffman

These extracts are sufficient for the purpose of emphasizing the practical difficulties of averaging iron-mining conditions so as to make general vital statistics concerning iron miners useful Tor scientific. purposes. It is self-evident that conclusions based upon iron miners, so called, working largely above ground and employed chiefly in open-cut blasting ~perations or the management of steam shovels, etc., can not be made to apply to miners working continuously underground with an exposure of dust and other conditions quite similar to underground mining methods in the extraction of gold, silver, copper, lead, and other ores. The so-called "milling" process as practiced on the Mesabi Range may here be referred to, the same being explained in the report of the Immigration Commission to consist "in the sinking of a shaft on the edge of the ore body from which a tunnel is run in under the ore and connected with a vertical, funnel-shaped hole from under the surface, through which the ore is 'milled' down into the tramcars placed under the opening under the tunnel. After being loaded at the bottom of the funnelshaped hole, the cars are run out to the bottom 0.£ the shaft. where the ore is dumped into skids or elevators and raised to the ~urface and unloaded into the tipple, where it is loaded into thecal'S ready for shipment." It is properly pointed out that the so-called " milling" process employs some of the features of both the open-pit and underground methods of mining. For these and many other reasons it is self-evident that general statistics concerning iron mining are quite likely to be inconclusive and possibly seriously misleading. Aside from the foregoing the problem is seriously complicated by the extensive employment of foreign labor in the iron-mining ind ustries of the Lake Superior districts and of Negro labor in iron mining in Alabama. Within recent years, according to the report of the Immigration Commission, a considerable displacement has occurred in t~e quality of labor employed in iron mining, the displacement bemg referred to as "progressive," in that one race or group of races has entered the region and taken up the work offered in the lower occupations, the race or races already holdinz such positions having. moved up in the scale of occupation leaving the field to the newcomers. This statement is quite suggestive in that it indicates a comparatively short average trade life or trade exposure, quite at variance with the relatively long average ascer- MINES, QUARRIES, ORE REDUCTION, AND SMELTING. 377 tained for the iron mines of New <Tersey. It is said in the report of the Immigration Commission that- The Scandinavians and the other northern European races have given way to the Finns and Slovenians, and in the open-pit mines the Finns and Slovenians have given way to the south Italian, Montenegrins, Croatins, and other southern European races. In the underground mines the common labor and mining is chiefly done bv Finns and Slovenians because the races from the southern countries can not stand the heavy physical work required in this kind of mining. Here, too, is found the same upward movement, for formerly the English (Cornishmen) and Scandinavians' were in the lower occupations in the underground properties, At present the south Italians, Serbians, Montenegrins, and Croatians are performing the most menial work and are the races who are now at the foot of the scale of occupations. It is a matter of conjecture on the ranges as to who will push these races up or whether they will remain the commou laborers of the region. Inquiry was made into the prevalence of diseases OIl the ranges, but more with reference to outside sanitary conditions than to occupational exposure. The most common diseases on the ranges, however, were ascertained to be pulmonary tuberculosis and typhoid fever, and to a lesser extent smallpox and venereal diseases. With -cgard to pulmonary tuberculosis it is said that the disease is most Eevalent among the Finns and the Swedes, and is chiefly imported, I'here is no reference to a possible connection between disease occur- ~ence and occupational conditions, above or below ground, but there .s no evidence that this aspect of the iron-mining industry was made .he subject of a special investigation.

Jan 1, 1918

By J. B. Littlefield

This study is one of a number conducted to determine the concentration of dust in the air during the complete cycle of operation in wet drilling information as to various factors connected with drilling in mining operations is considered to be of definite value in the control and prevention of air dustiness, and it is particularly desirable to ascertain What features of present-day wet-drilling operations in mine work contribute to dust disease and to remedy deficiencies when they are found. ACKNOWLEDGMENTS A testing alit through rock strata is being developed by the Mining Division of the United States bureau of Mines at Mount Weather, Va., and the tests discussed in this report were conducted there. This experimental alit in rock, constitutes a typo of laboratory where mine conditions can be closely simulated and where many of the variables likely to occur in an actual mine can be eliminated or at least controlled with reasonable effort, thus affording maximum opportunities to secure fundamental data uncomplicated by extraneous conditions. The authors wish to acknowledge the valuable assistance and cooperation of several members of the Mining Division, particularly C. F. Jackson, chief engineer, McHenry Mosier, associate mining engineer, and G. E. McElroy, supervising engineer, mine ventilation.

Jan 1, 1938

By Edward D. Thimons

Because of the high number of accidental methane gas ignitions in metal and nonmetal mines, the Bureau of Mines searched for a simple guideline that would allow mine personnel to evaluate the methane hazard in a given mine. Air samples were collected by the Bureau in 53 metal and nonmetal mines and analyzed for trace evidence of methane gas. Samples were collected in the returns and at the working faces. Those mines classified as gassy by the Mine Safety and Health Administration had a significantly higher average methane concentration than those classified as nongassy. Of the 9 gassy mines sampled, 7 had methane concentrations above 100 ppm, whereas only 1 of the 44 nongassy mines had a concentration above 100 ppm. The 100-ppm concentration may be used as a simple and convenient guideline for forecasting the methane hazard in a mine, whether or not the mine is classified as gassy. There was no consistent correlation between commodity mined and methane concentration, nor was there a correlation between mine depth and methane concentration. Neither of these factors can be considered a guideline for predicting methane hazards.

Jan 1, 1979

By Sidney Katell

An estimated capital investment of $76,499,800 will be required for a plant designed and built to produce 90 million standard cubic feet per day (std.c.f.d.) of synthetic pipeline gas through Lurgi gasification of bituminous char. This investment figure does not include the pretreatment plant, the cost of which is assumed to be reflected in the cost of the char fed to the gasification system. Shift conversion, C02 removal, and methanation are required after gasification in the Lurgi unit to make a gas suitable for pipeline transmission. Capital investment data are based upon equipment costs, January 1959. Based on a 90-percent or 330-day operating year, the operating cost before profit and Federal taxes with the char price as a variable will amount to the following: [ ]

Jan 1, 1959

By Edward L. McHugh

Twelve properties in the Riverside Mountains have moderate to high potential, for silver, gold, copper, and molybdenum. Six properties in the Big Maria Mountains have moderate potential for zinc, lead, copper, silver, iron ore, and limestone. The Big Maria Mountains also have occurrences of building stone. Four properties in or near the study area have low-grade gold-silver-copper resources totalling more than 300 thousand tons (270,000 t). An estimated 29 million tons (26 million t) of limestone and dolomite, and 620,000 long tons (630,000 t) of iron ore are in the Big Maria Mountains section of the study area. INTRODUCTION The Big Maria Mountains Wilderness Study Area covers about 50,538 acres (20,453 ha) near the Colorado River in eastern Riverside County, California (fig. 1). The study includes portions of both the Big Maria and Riverside Mountains. It lies north of Blythe, California and south of California Highway 62 in the Mojave Desert province of the California Desert Conservation Area. The study area consists of two mountain ranges surrounded mostly by broad alluvial slopes or bajadas. It extends for 25 mi (40 km) from the Riverside Mountains on the north, to the south end of the elongate Big Maria Mountains.

Jan 1, 1982