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By F. F. Aplan, J. A. Gutierrez-Rodriguez

"Contact-angle and flotation techniques were used to evaluate the influence of oxygen - both that inherent in the coal and that introduced by ambient temperature, aqueous oxidation - on a wide range of coal ranks. Oxidation was found to decrease the hydrophobicity and floatability of coal; with the effect being minor for coals of high rank but becoming increasingly important as the rank of coal is reduced. As an approximation, oxidation makes a coal behave as if it were one of lower rank. Frother only flotation' of coal· correlates with the captive-bubble contact angle whereas when oil is used as a collector, the flotation appears to follow the pattern shown by the water sessile drop on a fresh, un-reagentized coal surface. Coal recovery lost through oxidation may often be recovered by use of a variety of collectors, of which No. 2 foe! oil is among the best of those reagents tested. A simple alkali-extraction test may be used to estimate the influence of oxidation on coal preparation processes and use.INTRODUCTIONThe hydrophobicity of coal is not only a function of its rank but also of the extent of oxidation of the coal during and subsequent to its formation. Weathering and oxidation processes may proceed in-situ for coal deposits that outcrop near the earth's surface, or the oxidation of the coal particles may occur during mining, stockpiling or processing. Such oxidation, whether it affects the bulk-coal sample or on1y a thin outer layer on the coal surface, can dramatically influence the wettability of the particle and hence such processes as flotation, filtration, flocculation and dispersion.Many of the studies made on the oxidation of coals ·were designed to study its effect on flotation, coking or pyrolysis. The. present study 'is directed exclusively toward the effect of oxidation on the hydrophobicity and floatability of the coal. One of the first studies of the effect of oxidation on coal flotation was that of Sun [l] who found that as oxidation proceeds, coal becomes progressively more hydrophilic. Low-temperature oxidation (100-150°C for 250 h) generally lowered the coal floatability with an oily collector only slightly, but more extensive oxidation (200- 3500 C for 250 h) reduced coal floatability seriously. Sun also found that cationic amines were effective collectors for the oxidized coal which infers that oxidation makes the coal more negative in solution. He attributed the loss of floatability to be due to the accumulation of water-insoluble oxidation products at the coal surface. Gayle et al. [2] found that oxidation adversely affected coal flotation when an aliphatic-alcohol frother was used, though a small amount of oxidation appeared to improve the floatability of some coals using a kerosene-pine oil, collector-frother mixture in pilot-plant testing. Prolonged oxidation adversely affected the flotation recovery of the coals tested, the effect being more pronounced when an alcoholic-type frother only was used. They also noted that the reduction in floatability of lower rank bituminous coals was more affected by oxidation than was that of higher rank bituminous coals."

Jan 1, 1989

By Laxman S. Sundae

The Bureau of Mines designed, fabricated, and is using an in-seam tester (1ST) for in situ determination of coal cutting forces. This re-port describes the results of field tests conducted in the Pocahontas No. 3 and Upper Freeport seams to obtain peak and mean cutting forces during coal cutting with several bit geometries, including radial and point attack bits currently used on drum-type machines. Comparisons were also made between new and worn bits, and using data obtained from a Bureau-modified chisel bit. The test results show that longwall plough cutting (horizontal cuts) in bony coal bands (shale) requires >3 times the cutting force for the same cuts in a vertical direction. When no bony coal is present, the cutting forces required to make horizontal and vertical cuts are equal. Worn bits require 4 to 5 times more cutting and normal force than new or undamaged bits. Normal force increased drastically for the worn chisel bit. Peak force encountered in making independent cuts was found to be ~3 times higher than that required to make interactive cuts using a spacing-to-depth-of-cut ratio of 2. Both rake and clearance angles were found to have a significant effect on normal and cutting force.

Jan 1, 1986

By Herbert Tomlinson

The United States Bureau of Mines has engaged in a study of the conditions under which coal mine accidents, resulting in the loss of life, limb, or time to the injured person, occur from falls of roof and coal. This publication is devoted to the results of a study conducted in the coal mines of the Book Cliffs and Wasatch Plateau coal fields of Utah. To show the necessity of this study, a statement of the fatalities that have occurred during the period 1928-1930, inclusive, in the bituminous mines of the United States and of Utah, is presented (Table 1), followed by a brief description of this Utah district, its coal beds and immediate roof, thickness of cover, dip of coal beds, methods of mining, supervision, roof testing and timbering for roof support, all of which are factors in any plan devised for preventing accidents from falls of roof and coal.

Jan 1, 1932

By John E. Kelley

Laboratory equipment, which simulates abrasive impacts between steel and minerals that might be present during pneumatic transport of coal, was used by the Bureau of Mines to characterize the potential explosion hazard of such collisions in an atmosphere of fine coal dust, air, and methane. A variety of coal mine rock materials, including sandstone, limestone, and pyrite-bearing limestone, were impacted with specimens of pipeline steel. Tests were con-ducted in atmospheres containing zero to 6.4 vol-pct methane mixed with zero to 300 mg/l coal dust. Coal dust in air alone was not ignited by abrasive impacts, but additions of as little as 1 vol-pct methane to the coal dust and air mixture resulted in ignitions. Steel impacting against sandstone caused ignitions in mixtures of coal dust, air, and methane, and the probability for ignitions increased with an increase in methane. No ignitions occurred with impacts of steel on lime-stone or pyrite-bearing limestone, even when large showers of sparks were produced. Studies of the effect of tangential collision velocity showed that no ignitions of coal dust, air, and methane occurred below 900 fpm (4.57 m/sec). Ignitions in coal-air-methane mixtures were found to be caused by a hot friction-induced smear on the impacted rock at the impact site rather than by sparks. High-speed photography was used to verify this observation.

Jan 1, 1976

By A. Visnapuu

The U.S. Bureau of Mines investigated the oxidation of American Iron and Steel Institute (AISI) Type 304 stainless steel (SS) during annealing in simulated combustion products from several air-CH4 fuel ratios. Atmospheres representing air-CH4 ratios of 14:1 and 18:1 contained free 02, while atmospheres representing 10:1 air-CH, ratio did not. A Cr203 layer formed on SS samples annealed in atmospheres containing free 0, while a Cr-Fe spinel layer formed in atmospheres with no free 02. The Cr203 layer was adherent and presented a protective barrier to metal diffusion, effectively limiting oxidation of the metal substrate. The Cr-Fe spinel was not protective and allowed the diffusion of Fe through the spinel to the gas-oxide interface where it was oxidized to magnetite, which spalled from the surface. This resulted in thick scale layers on samples annealed in atmospheres containing no free 02, as compared to layers formed on samples annealed in atmospheres containing free 02. These results confirmed and explained industrial operators' observations that thick, smoky (fine spalled magnetite) scales form on SS annealed in low free-02 atmospheres, while thin protective oxide layers form on sheets in atmospheres containing free 02.

Jan 1, 2010

By W. L. Crentz

In Fayette County, the Pittsburgh bed has been the major source of production for almost two centuries. Although historical documentation is not available, there is evidence, that the Pittsburgh bed may have been discovered in Fayette County near Mt. Braddock, Pa., as early as 1753. The earliest known reference to coal in western Pennsylvania was recorded in 1758 by a Quaker trader, James .Kenny, who reported having seen coal in Fayette County. The production of coke from Pittsburgh coal was begun in 1841, when two 10-foot beehive ovens were erected in the Connellsville region to make coke .for shipment by river to the market. The Connellsville, region extends from Latrobe, Pa., in Westmoreland County to South of Uniontown, in Fayette County. Connellsville coke was used with great success in the Clinton furnace in 1859.

Jan 1, 1951

By W. P. Yang, L. B. Berger, G. W. Jones

"Any burning carbonaceous material, unless supplied with enough oxygen for complete combustion, will liberate carbon monoxide. Since tobacco in its many different forms consists largely of carbonaceous material, and duo to the conditions under which it is smoked (burned), carbon monoxide should be liberated. That this is true has been shown by Armstrong.***** who found that undiluted smoke from cigars contained in some tests more than 3.00 per cent carbon monoxide, the amount present depending upon the size and closeness of packing of the tobacco during manufacture and on the rate of burning.****** Cigarets gave much less CO, varying from 0.06 to 1.40 per cent. The rate of consumption and carbon content of the tobacco are not g.ven, so that a correlation of the values reported to conditions in closed spaces where people might be assembled are difficult, if not impossible.The Bureau of Mines is interested in the general question of carbon-monoxide hazards from tobacco smoke, mainly with regard to mine ventilation. In non-gaseous mines, especially metal mines, the question arises, whether, if groups of miners are permitted to smoke while working at unventilated faces or entries, would the accumulation of tobacco smoke in these places create an' additional hazards the to carbon-monoxide poisoning. The results should, in addition be of general interest in connection with ventilation of building and inclosed places where people may be assembled and smoking is permitted. The investigation described in this report was made with the above idea in view."

Oct 1, 1923

By F. D. DeVaney

[In the course of the investigation by the U. S. Bureau of Mines and the Missouri School of Mines and Metallurgy at the Mississippi Valley experiment Station at Rolla, Mo., on the beneficiation of the low-grade manganese ores of the country, some samples from the Cuyuna District, Minn., have been examined. The work was done under the direction of W. H. Coghill, supervising engineer of the Mississippi Valley Experiment Station. Josoph and Kinney5 in venting about the relative importance of Minnesota deposits of low-grade ore compared to the total reserves say:]

Jan 1, 1930

By Valois R. Shea-Albin

An accurate assessment of the vertical stress on a coal seam at depth is important for mine design. Vertical stress calculation techniques presently available either are not sufficiently accurate or cannot handle complex surface topography. Therefore, the U.S. Bureau of Mines developed a computerized method to calculate vertical stress exerted on surfaces at depth that includes the effect of topography. Two input data sets are required: a digital elevation model containing topographic elevations and a coal seam file defining coal seam elevations at depth. Boussinesq's equation then quantifies the vertical stress resulting from topography. The computerized method was tested on a coal seam overlain by a complex topography where a vertical stress map encompassing several square miles was produced. Results show that depth mitigates the affects of surface topography, while the coal seam topography has a direct effect on the vertical stress. In comparison to the computerized method, the direct stress method overestimates stress under hills and underestimates stress under valleys. The largest difference between the two methods occurs under the steepest topographic relief. A limitation of the computerized method is that stresses cannot be accurately determined near an outcrop.

Jan 1, 2010

By J. D. Davis

"Introduction.Sixty years ago, M. Berthelot found that ethylene could be selectively absorbed from gaseous mixtures by concentrated sulphuric acid, and that the compound formed by the chemical union of the gas and acid was readily decomposed by heating with water, yielding ethyl alcohol. Only within the last few years has there been any attempt to make use of this discovery technically.Bury*, working in England at the Skinningrove Iron Works and on a commercial scale, developed a technical method for converting, the ethylene of coke-oven as into alcohol. With a gas containing less than 3 per cent of ethylene, he obtained a yield of 1.6 gallons of alcohol per ton of coal carbonized.De Loisy** perfected a technical method for treatment of coke-oven as for alcohol. Evidently this work was carried out on a semi-commercial scale. His method is based on the use of catalytic agents for hastening the absorption of ethylene by sulphuric acid. He uses part of the spent acid for drying the gases and pact for the manufacture of ammonium sulphate. Excess acid is reconcentrated by waste heat. Others have worked on the problem, but so far there has been no large recovery of ethylene from coke-oven gases. The chief difficulty seems to lie in the low efficiency (about 50% of methods and tae relatively low concentrations of ethylene in the gases treated. Gas from Trent amalgam*** contains much larger percantages of ethylene than does coke-oven gas, as Will presently be shown, and if it should ever prove practIcal to treat industrial ;as for alcohol, this gas would offer attractive possibilities,* Bury, Ernest, Ethylene as Alcohol from Coke-Oven Gas: Gas Journal' Vol. 148, D. 30, 1919, pp. 718.** DC Loisy, M.E., Sur un procede' industrial de fabrication syntlotique de l'alcool et de l'ether a partir des gaz de distillation de la houil Comp Rend, vol. 170, Jan. 1920, p. 50-3.*** A paste consisting of approximately part oil such as that obtained as for cleaning coal. See Perrott. in cleaning coal, Chem 3 parts finely pulvarized coal and 1 final product in the Trent, process StJ, and Kinney, S.P. The use of oil Vol. 35 August 3, 1921, p, 183.. & Met."

Nov 1, 1922

Mining men and State officials in their efforts to make mining safer are confronted from time to time with various complicated questions. In recent gears these questions have tended to increase with the use of mechanical appliances. Twenty-five years ago electricity had been used but little in mires; today there is practically no other means of transmitting power employed in American mines, except that in metal mines compressed air is used, chiefly for drilling and for operating small portable hoists. In coal mines there has been a great increase in mechanization, which tends to concentrate the work of production in small areas and to increase the local difficulties of ventilation; also, it has intensified locally the hazard from coal dust as well as firedamp in bituminous and subbituminous mines. The answers to the questions that arise are not always obvious, as is shown by the fact that even able, experienced men differ in their opinions of the best, way to overcome a particular mining hazard. The difficulty of .solving the problems is also demonstrated by the varying provisions in mine-safety rules, both in official regulations and in the rules of those mining companies that are endeavoring to do more than follow the letter of the law. Such differences of opinion as to the best way of meeting a difficult situation are often found within the same mining organization, and, similarly, varying opinions are held by different members of the Bureau of Mines staff.

Jan 1, 1937

By A. Tewarson

Combustibility data are presented for 14 samples representing commonly used mine materials (treated and untreated wood, conveyor belt and brattice cloth). The combustibility data were obtained in the Factory Mutual Small-Scale Combustibility Apparatus (sample area -0.008 m ). The hazards associated with the mine materials were evaluated in terms of: 1) ignition/ surface flame spread using an ignition parameter (IP). A reasonable correlation was found between IP values and U.S. Bureau of Mines ratings for conveyor belts and brattice cloth and large-scale fire test data for treated and untreated timber sets; 2) generation of combustible vapors, using a vapor generation parameter (VP); 3) heat release using a heat generation parameter (HP). A reasonable correlation was found between HP values and the large-scale fire test data for treated and untreated timber sets; 4) generation of "smoke," toxic and corrosive products using a chemical compound generation parameter (CP); and 5) light obscuration by "smoke" using the light obscuration parameter (LP). All the wood treatments, except Fireguard, were found to be effective in reducing the fire hazard. The effectiveness of the treatment appears to be due to enhancement of carbon formation in the solid phase and enhancement of water formation in the vapor phase. Concepts are presented for establishing 1) the relationship between various parameters (IP, VP, HP, CP, and LP) and basic properties of materials, and 2) the usefulness of the parameters as criteria for the combustibility and fire hazard evaluations of the mine materials.

Jan 1, 1982

By George S. Rice

The prevention of coal-mine explosions has been one of the chief purposes of the Bureau of Mines. In facti the first Federal appropriation relating to mining methods, in 1908, authorized the investigation of the causes of mine explosions and the possible methods of preventing them. When that investigation started the mining industry had not determined the real causes of a succession of terrible coal-mine explosions in various countries, culminating in the great disasters at CoulTièl'es, France, and Monongah, W. Va. Coal dust as an agent of widespread explosions had been under suspicion, and watering to allay the dust was recommended by some mining engineers but the watering of coal-mine dust was adopted in comparatively few mines of the United States and Great Britain, and had not been introduced widely in any country except Germany. Rock dusting, another method of preventing explosions of coal dust, was early tested with success by the Bureau of Mines in its fist gallery at Pittsburgh and, beginnig in 1911, at the experimental mine, Bruceton, Pa. Several of the fist publications i of the bureau suggested that rock dust be used in gaseous or dusty bituminous mines, and in 1915 Technical Paper 842 strongly recommended it. Since that time additional tests in the experimental mine have fully confied this :ft judgment.

Jan 1, 1924

By A. L. Engel

This report is a compilation of results of brief preliminary tests on sulfide ores that contained gold and silver and, in some cases base metals. It is a companion paper to a recent similar report on oxide ores. Simple treatment methods employing the least possible equipment sometimes produce satisfactory results on marginal ores and in small-scale operations. Investigations of typical ores from newly discovered or recently explored mining districts have been made in continuation of a long-established part of the hydrometallurgical and ore-dressing program of the Reno station, Bureau of Mines. The purpose of such investigations is to encourage the search for and development of mineral resources and particularly to assist in the economical exploitation of low-grade and marginal ores as well as the conservation and recovery .of values in products that were discarded from former operations because of inability to treat them profitably. Several of these investigations have been limited to preliminary tests of samples from prospecting operations, whereas same involved samples of old dumps or tailings piles. The test work in these cases was not extensive enough to warrant publication as individual reports, but is of considerable interest inasmuch as it indicates the possibilities as well as the limitations of treating the respective materials. The samples were representative of the districts from which they wore obtained, so this information should be helpful in the future development of these districts.

Jan 1, 1951

By N. A. Gokcen

This Bureau of Mines report reviews and summarizes recent studies of the rates of chlorination of aluminous resources with CO and C12 mixtures with and without COC12. No reaction mechanism could be obtained from the existing results; however, diffusional barriers in the gas and solid layers probably control the chlorination rate in thermogravimetric experiments. Fluidized beds of particles smaller than 0.1 mm appeared to show very little solid layer diffusional barrier. For optimum chlorination the particle size should probably be less than 8 mm, the calcination temperature approximately 700° C, and the chlorination temperature from 650° to 750° C. Relatively rapid chlorination with COC12 in thermogravimetric experiments was attributed partly to the simultaneous supply of reductant and chlorinator by one gas to the sample reaction site. Comparable results for chlorination of fluidized beds with COC12 are not available. Equimolar mixtures of CO and C12 produced the optimum rate of reaction. Addition to the calcine of 10 to 20 wt-pct NaCl accelerated the rate of chlorination, and addition of SiC14 to the gas mixture decreased the rate of chlorination of SiO2 drastically, but at the expense of chlorination of significant fractions of Al2O3. Further research in various areas is suggested.

Jan 1, 1983

By John C. Feeley

The methods used and the funds available for the development and oper- ation of shall mines and the reopening of small abandoned mines frequently present problems that tax the ingenuity and resourcefulness of the mining engineer far beyond that required in the mass production from large deposits. The objective of this paper is to describe in considerable detail the means whereby engineers have solved local problems in reopening an abandoned mine at which equipment, facilities, and funds were limited... The Etowah Coal & Iron Co. Gadsden red-iron-ore mine at Gadsden, Ala., 18 of interest in this category since it is the only independent red-ore mine under active development in the State. All other red-ore mines in Alabama are owned or controlled by the large iron or steel companies. The The mine, located on the southwest end of Shinbone Ridge in the outskirts of Gadsden lies in an ares once productive. but now idle, for many years. ore is relatively highgrade compared with that in the Birmingham area, but the bed is thin and somewhat lenticular. The presence of a large blast furnace at Alabama City, 3 miles from Gadsden, and the growing scarcity of red-iron ore supplies for it offered inducements for reopening the mine in 1946. Up to the time this circular was prepared (1947) only a small quantity of ore (about 1,500 tons) has been produced and shipped to the furnace. A force of 14 men was employed in sinking the main slope and developing a third "lift" (a local term for level) 100 feet below the old mine workings.

May 1, 1949

By John P. McDonnell

Coal mine bounces and bursts are major problems facing U.S. mine operators. Bounces and bursts have the potential to inflict severe injury on mining personnel, damage equipment, and cause mine closures. High- stress conditions, at or near the working face, are the common denominator in the burst problem, If mine operators can locate high-stress and potentially burst-prone zones, they can then use stress-relief methods to control the burst condition. One method of locating the high-stress zone is the probe-hole-drilling or drilling-yield method. Probe-hole drilling is used frequently in Europe, the U.S.S.R., and Japan as a means for locating potential burst zones. Consequently, the Bureau of Nines performed tests in the laboratory and in a deep, burst-prone western mine to analyze probe-hole drilling. The in-mine method, very simply, involves drilling a hole into the coal seam and measuring the volume of cuttings obtained. A certain volume of cuttings can be expected from a certain diameter and length drill hole. A significant increase in the volume of cuttings means the zone around that particular hole is highly stressed. In-mine use of the drilling yield method has shown it to be a useful tool for locating highly stressed and potential burst zones. Results from laboratory testing confirm that high stress applied tri-axially to a cube specimen will cause a significant increase in the volume of cuttings from a small-diameter drill hole in the specimen.

Jan 1, 1988

By James Westfield

A brief resume follows of some recent activities of the Division of Coal-Mine Inspection that have had a favorable effect on health, safety, and the reduction of injuries at coal mines: 1. The Federal Mine Safety Code for Bituminous-Coal and Lignite Mines of the United States was issued originally by the Director of the Bureau of Mines on July 24, 1946, after consultation with management and labor representatives of the coal-mining industry. The code has been used by Federal coal-mine inspectors during their inspections of bituminous-coal and lignite mines as a basis for determining the existence of unhealthful and unsafe conditions and practices in these mines. A revised code was issued by the Secretary of the Interior October 8, 1953, following further consultations with representatives of management and mine workers, and was incorporated by reference in the 1952 and subsequent bituminous-coal wage agreements. The agreement of May 29, 1946, between the Secretary of the Interior, acting as Coal Mines Administrator under authority of Executive Order 9728, and the United Mine Workers of America, covering bituminous-coal and lignite mines in Government possession, charged Federal coal-mine inspectors with the responsibility of making periodic investigations of the mines and reporting to the Coal Mines Administrator any violations of the Federal Mine Safety Code. The inspectors were active in making prompt investigations of hazardous mines that had been closed by order of the Coal Mines Administrator to determine if enough improvements had been made to allow the mines to reopen. Federal coal-mine inspectors also had temporary authority to close mines they found to be imminently dangerous, but such authority (under Executive Order 9728) was removed on June 30, 1947, when Government control of the mines was terminated.

Jan 1, 1957

By R. J. Leary

A small electronic digital computer employing punched cards has been used to facilitate the solution of a variety of problems in Bureau of Mines pyrometallurgical research. In this work the computer has been found to be economical for solving both simple problems that occur repeatedly and those involving complex or iterative calculations. Each of these classes of problems and their respective solutions are described. These small computers can be used effectively by researchers when they work in consultation with a computer specialist. Close team work produces the required solutions in less time, and, oftentimes, in a more useful form. Participation in programming by researchers develops in them a skill for evaluating the suitability of problems for electronic computing.

Jan 1, 1960

By M. C. Malamphy

A general description of the activities and results of bauxite investigation by the Bureau of Mines at its bauxite project in Saline and Pulaski Counties, Ark., has been given in Report of Investigations No. 4251. The factual data obtained during the project are reported in a series of Reports of Investigation beginning with No. 4251, of which this is the seventeenth. The data are accompanied by maps showing the location of holes drilled and the deposits developed. Each area upon which work was done is reported by half townships. Each bauxite deposit investigated was assigned a name and a number for ready reference and identification, and its location and name are shown on the appropriate half-township map. The description of each half township is followed by a description of each deposit developed in that half township. The 14 half-township maps and 77 detail maps of the bauxite deposits in this series of reports give the locations and numbers of all the holes drilled on the project, except the deep holes drilled to test the geophysical anomalies. The locations of those holes show on figure 13 in volume 1. The descriptions of the deposits developed are followed by complete detailed logs of the drill holes.

Jan 1, 1948