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By P A. Collier

The general view of the author is that all the good intentions of manufacturers can fail completely if the variations in circumstances in underground mining are not considered at all times. With a belief that it is the customer that has the experience and know ledge of problems which occur on long installations. Reilloc talk with customers in coal mines around the world, and have done so from their inception. With considerable experience in their home market, their technical approach was received with enthusiasm by coal companies in both Australia and South Africa, and whilst experience was obtained in other countries, it is the particularly close working relationship in these two areas that is covered in this paper. The refinement of manufacturing techniques and the fine tuning of the specification to which the chain is made was developed in conjunction with factual underground experience obtained by customers as they sought to improve their productivity and a reduction in working costs. With a reliable product the mines are able to concentrate on improved operational techniques to extend the useful working life and plan for multi-panel usage of the chain.

Jan 5, 1996

By T. T. Chen, J. E. Dutrizac, C. Canoo

The calcine consists principally of ZnO and ZnFe2O4, which occur as banded and porous grains, together with lesser amounts of Zn2SiO4, Zn-Fe-Pb silicate, sphalerite, quartz, PbSO4 and Fe2O3. Al is present in solid solution in most of the Fe-bearing phases and also as residual aluminosilicate minerals from the original concentrate. Si occurs mostly as Zn2SiO4, Zn-Fe-Pb silicate and as residual silicate minerals. As is commonly found in the ZnFe2O4, Fe2O3 and Zn-Fe-Pb silicate phases. The major As carrier may be calcium arsenate particles less than 1 micrometre in size which are dispersed throughout the calcine. The neutral leach residue consists mainly of ZnFe2O4 and precipitated masses of iron gel-silica gel. Lesser amounts of ZnO, Zn2SiO4, Zn-Fe-Pb silicate, PbSO4, sphalerite, Pb-K-jarosite and basic zinc sulphate are also present. Al occurs in minor concentrations in most of the Fe-bearing phases and in the Zn-Fe-Pb silicate. The residual aluminosilicates are also an important Al carrier. The major As carrier is the precipitated iron gel-silica gel phase, but some As is also present in the Zn-Fe-Pb silicate, ZnFe2O4 and Fe2O3 phases. Silicon is divided about equally between the iron gel-silica gel, Zn2SiO4, Zn-Fe-Pb silicate and residual silicate minerals. The weak acid leach residue is generally similar to the neutral leach residue except for its reduced content of ZnO and basic zinc sulphate.

Jan 4, 1993

By L. R. Chimimba

"The Trojan nickel deposit occurs within a pile of ultramafic lavas subjected to a lower amphibolite grade of metamorphism. The lavas form part of the Upper Greenstones (Bulawayan Group) of the Mazoe greenstone belt. The nickel mineralization occurs as disseminated, massive and near-massive sulphides. The massive and near-massive ore occurs along the basal contact of the serpentinite units and is overlain by the more abundant disseminated ore, which occurs within the serpentinite. The main sulphide minerals are pyrrhotite. pentlandite and chalcopvrite. Minor amounts of millerite and pvrite are present. The Ni : Cu ratio in all three types of ore averages 15:1.The intercumulus nature of sulphides in the near-massive ore and similar textures occasionally seen in the disseminated ore indicates a magmatic origin of the mineralization. The basal position of the near-massive and massive ore suggests that the sul­ phides settled out under gravity during the emplacement and crystallization of a peridotitic magma. The deposit has been deformed and some of the primary massive ore has been remobilized into veins and breccias. The disseminated mineralization now occurs mainly as blebs of sulphides intergrown with silicate minerals or as stringers of sulphides between foliation planes in the serpentinite."

Jan 1, 1984

By I. R. Stevenson, J. G. Dunn, T. N. Smith, L. C. Mackey

An experimental flash reactor has been developed to simulate the operation of an industrial flash-smelter reaction shaft. Four concentrate materials of differing mineralogical compositions were characterised and then oxidised in the reaction shaft. The products were examined by chemical analysis to determine the extent of oxidation and by electron-probe microanalysis to determine the fate of individual particles. This programme of work enabled the influence of mineralogical composition and particle size on the extent of oxidation to be assessed

Jul 1, 1991

By Ruddle R. W.

The slags produced in copper smelting are largely composed of silica and ferrous oxide and may therefore be regarded as essentially ferrous silicates. A fair amount of information is available on the constitutions of the liquid slags used in copper smelting and, in this connection, the large volume of work being carried out on steelmaking slags should be helpful. Constitutional diagrams are available for most of the principal systems involved (SiO2-FeO; SiO2-FeO-Al2O 3; SiO2-FeO-CaO; SiO2-FeO- MgO; and SiO2-FeO-CaO-Al2O3) and these show that additions of Al2O3 and CaO reduce the freezing points of SiO2-FeO slags but that additions of MgO increase the freezing point. A certain amount of information is available on the thermodynamics of slags, but much further work on this subject is required. Modern theories of the constitution of liquid slags deny the existence of molecular compounds but consider that liquid slags are mixtures of various ions such as, Fe2+. O2- and SiO4(4-). Little appears to be known of the reactions between matte and minor constituents dissolved in the slag

Jan 1, 1953

By O. Dojcar

Equations for calculating the parameters of controlled blasting (burden and spacing of boreholes and weight of the bottom charge) are derived and analysed on the basis of empirical values and made more precise through incorporation of the properties of the rock being blasted and explosive applied. For the success of controlled blasting the correct choice of the blasthole diameter/charge diameter ratio is critical. This relation is defined as the coefficient of radial decoupling of the charge; it is recommended that it is chosen to be between 3 and 3.5. Analysis of smooth blasting, cushion blasting and presplitting indicates that cushion blasting is a less destructive alternative to smooth blasting, but it has a slightly higher blasthole consumption and limited possibilities of use. There are definite economic advantages to controlled blasting, especially in rock masses of low and medium strength

Dec 1, 1996

By J. Drzymala, K. L. Wolters, T. Chmielewski, T. D. Wheelock, D. H. Birlingmair

Microflotation tests were conducted with a modified Hallimond tube equipped with a fritted glass disk and magnetic stirrer to determine whether the results would support an equation that predicts a linear relationship between particle size and the reciprocal of particle density in water for a specified flotation recovery in a given time. Data obtained with the tube for either hydrophilic or hydrophobic solids fit the equation satisfactorily. It was also shown that the natural flotability of molybdenite is somewhat less than that of elemental sulphur and that sodium dithionite is a good depressant for sulphurised pyrite. In addition, it was found that the untreated pyrite and galena used in the study were hydrophilic and did not float by particle-bubble attachment.

Jan 4, 1992

By R. E. T. Hill

"A laboratory study was undertaken to determine the condensed equilibrium phase relations at 600°C in that portion of the quaternary Fe-Ni-Cu-S system which lies in the neighbourhood of the monosulphide solid solution (MSS). The study sought to determine to w hat extent copper affects the temperatures of stability and compositions of iron-nickel sulphides in bulk compositions similar to those of massive Fe-Ni-Cu ores. Experimental data, including stable phase assemblages and phase compositions, are presented.In the quaternary system at 600°C MSS forms stable phase assemblages with pentlandite, chalcopyrite solid solution, pyrite and vaesite. Over the range of bulk compositions displayed by natural ores copper as well as metal/sulphur ratio have a significant effect on the thermal stability of pyrite and pentlandite. Errors therefore accompany the widespread practice of ignoring copper or chalcopyrite when the mineralogical and compositional changes that have accompanied the initial cooling of primary magmatic sulphides or their subsequent homogenization during isochemical metamorphism are being deciphered. These errors are most significant for ores the bulk compositions of which lie tow ard the sulphur-deficient side of the cupriferous MSS. Temperatures as much as 300°C above the copper-absent value are possible for the interpreted upper stability limits of pentlandite in these ores.The experimental data show that up to 2.0 at% copper can occur in pentlandite stable at 600°C in a bulk composition equivalent to natural magmatic ores. This is equivalent to nearly 10 vol% chalcopyrite. Pentlandite contains more copper than coexisting MSS and the copper content of both phases increases with increasing iron."

Jan 1, 1984

By S. V. Shiraishi, H. B. Bell

Report of discussion at February, 1971, IMM general meeting (Chairman: M. J. Cahalan, President) of a paper published in Transactions/Section C (Mineral Processing & Extractive Metallurgy), vol. 79, June, 1970, pp. C120-C127, with a contribution by Wright P.A. on the miscibility gap

Dec 1, 1971

By T. Guyaguler

An analytical technique using computer-based multiple-regression methods was employed to determine the relation between the dust-producing index and inherent rock properties of typical samples from a coal-producing area, one of the aims being to provide a preliminary predictive tool for practical use. The investigation demonstrated that factors varied in their influence under different conditions, the brittleness:toughness ratio and the hardness being the most significant inherent properties with hardness showing the highest positive correlation coefficient

Jun 13, 1905

Discussion of the paper presented at the North Staffordshire Institute of Mining and Mechanical Engineers' general meeting held in Stoke-on-Trent, March 27th 1916, with Mr. John Gregory, President, in the chair, included contributions by Gregory J., Cadman J., Hartley J.W., Wain E.B. and Henshaw A.M., followed by the author's reply

Dec 1, 1916

By Ruddle R. W.

Magnetite occurs in the reverberatory furnaces, blast furnace and converter (a) as the result of its presence in the materials charged, and (b) as the result of oxidation of the FeS in the charge in the absence of sufficient SiO2 to slag the FeO as it is produced and thus prevent its subsequent further oxidation. Magnetite is reduced by FeS according to FeS+3Fe3O4=10FeO+SO2 and similar reactions. This reaction is markedly affected by temperature and does not proceed to any important extent below about 1200°C. To ensure comparative freedom from magnetite it is therefore necessary to raise the temperature of the furnace to the highest practicable figure and to use plenty of siliceous flux. Since the maximum operating temperature is likely to be limited by the resistance of the refractories to attack by the slag, investigation of the factors affecting this attack should be helpful. It is reasonable to suppose that the formation of magnetite might be minimized by ensuring intimate admixture of matte and slag during conversion so that silica is readily available for combination with ferrous oxide as the latter is formed. The literature gives no clue to the importance of this factor and some experimental work on this aspect might be fruitful

Jan 1, 1953

By D. G. Skinner, J. H. Griffiths, F. T. Williams, A. G. Withers

"The absence of homogeneity, in dust-clouds underground indicates the use of a method in which the volume of air sampled is an appreciable proportion of the total volume under consideration. Of the available methods, only the impinger and gravimetric techniques seem to comply with this requirement. In practice, greater efficiency of collection of the smaller particles is possible by the use of a gravimetric filter than with the impinger. For this reason if, as seems desirable, a standard method of sampling be sought, the adoption of a gravimetric technique is to be recommended.Provided that the amount of dust collected is reasonably large, the paper filter would seem to be preferable to the solid crystal type of filter on account of its greater convenience in use.Alternative methods of sampling are desirable to cover the wide range of practical conditions."

Jan 1, 1947

By R. Patel, J. Ephraim

The production of titanium dioxide (TiO2) from its minerals such as ilmenite is challenging, and subsequent isolation of titanium from TiO2 is even more difficult because of the metal-oxygen bond strength. Currently, titanium sponge is mainly produced via the Kroll process, which is energy intensive and generates large quantities of waste. A number of international research groups have come up with technologies for the production of titanium metal. However, none of them have been commercialised, because of engineering or economic issues. The team at Bradford have confirmed that ultra-pure titanium powders can be separated from TiO2 powder through metallothermic reduction and are working to scale up the process.

May 1, 2015

By K. El-Barawi, Hussein M. Kamal

Chlorination was performed of iron-rich chromite ore from Barramyia, United Arab Republic (UAR), together with its concentrate. The effects of change of grain size, chlorine gas flow rate, time and temperature were studied. The extent and mechanism of chlorination were followed through chemical and structural analyses of the feeds and complete chemical analysis of the chlorination products. By conducting the chlorination process for short periods at 600°C or lower temperatures, products having high Cr-Fe ratios suitable for ferrochrome production can be obtained.

Dec 1, 1971

By J. H. E. Jeffes, K. T. Jacob

The activity coefficients of oxygen in liquid Pb-Sn alloys have been measured between 550 and 1100°C by use of solid oxide galvanic cells: Pt, Ni-NiO | Zr02 Solid electrolyte | O (Pb + Sn), Cermet, Pt; and Pt, Fe-FeO | Zr02 Solid electrolyte | 0(Pb + Sn), Cermet, Pt. Alcock and Richardson's quasi-chemical equation, with the coordination number of atoms set to 2, is found to predict successfully the activity coefficients of oxygen in these alloys. The relative partial molar enthalpy and entropy of oxygen at 1 atom per cent in the alloys have been calculated from the variation of the activity coefficient with temperature. The addition of Sn to an unsaturated solution of O in Pb is shown to decrease significantly both the partial molar enthalpy and entropy of O. As the measurements were restricted to a narrow range between 750 and 1100°C in Pb-rich alloys, however, the pronounced variation of the partial molar enthalpy of O with temperature at constant alloy composition predicted by the quasi-chemical model could not be verified.

Dec 1, 1971

By R. W. Ruddle

The advent of new methods of roasting, “flash roasting and fluidisation”, which are now under development, combined with the use of oxygen-enriched air, may markedly increase the SO2 content of roaster smokes. Skogmo suggests that the production of smokes containing as much as 50 per cent SO2 should be feasible. The use of flash smelting processes may well enable a similar increase in the SO2 content of smelter smokes to be made. In this event the recovery of sulphur would be greatly cheapened and the process might well be much more economic, even if allowance is made for the cost of generating the oxygen

Jan 1, 1953

By L Zhang

The Chinese coal industry is the largest coal producer in the world. The total production in I995 was 1.28 bnt. On the way towards introducing a market economic system, this mature industry is facing major challenges. The main problems are a large surplus of manpower, shortage of current assets and capital, low productivity, high casualties and a huge deficit. This paper discusses the present situation and the future developments in the Chinese coal industry. The current policy can be stated as ‘rapidly developing the state collieries and improving the village and private mines; integrated development to achieve an economic operating scale and encouraging a diversified economy; rapidly exploiting and developing in the North west and South west; promoting productivity and efficiency; welcoming multi-sources and types of investment; setting up coal exchange markets; and the careful control of resources and the environment'.

Jan 11, 1996

By A. G. Waters, N. J. Bristow

A comparative study was made of an untreated and a heated haematite ore and a sinter produced from a feed consisting of 100% ore, to study the influence on reduction behaviour of sinter bonding phases such as SFCA (silico-ferrite of calcium and alumina). Under low-temperature reduction conditions the order of increasing reducibility followed that of increasing porosity and surface area but under similar conditions at 900 degrees C the sinter exhibited higher reducibility than the ores even though the total porosity and chemical reducibility of the individual phases were lower. This behaviour can be explained in terms of the higher total porosity of the natural ore at low temperatures and the higher level of fine pores in the sinter at high temperatures due to the presence of SFCA, which acts to support the fine (c.0.1 micrometre) pores created by the reduction process. This leads to the conclusion that the main role of SFCA in sinter during high-temperature reduction is to maintain a high level of fine porosity. Some implications of this work for granule design and sintering practice are discussed

Apr 1, 1991

By A. B. Holland-Batt

Two graphical techniques which are commonly used to assess batch separations are analysed in terms of reaction kinetics to provide a more powerful method of evaluation. An alternative and more general approach, based on the selection and application of suitable efficiency criteria, is also presented. The method proposed distinguishes between selection and collection efficiency in flotation and can be used to estimate the degree of liberation in the feed. Two examples are given: table concentration of monazite and ilmenite from a beach sand, and flotation of a pyrite-haematite ore

Dec 1, 1971