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By V. A. Chanturiya, T. N. Matveeva, N. K. Gromova, T. A. Ivanova

"The research is aimed at solving the problem of increasing the extraction of gold from refractory ores, which are the main source of growth in gold production in the next decades. The purpose of the research is the development and scientific substantiation of the reagent modes for flotation extracting of gold from refractory ores using eco-friendly low-cost herbal modifiers (HM), providing increase in gold recovery and quality of gold concentrates. In the course of research laboratory techniques for the preparation of experimental samples of HM were developed, which included the sequence of operations of grinding Heraclium leaves and stems grinding, 2-stages extraction at a temperature of 50-60 °C, short-term ultrasonic treatment, filtration and subsequent unification of extracts. According to the developed method, the experimental samples of HM and conducted research were tested to analyze their sorption and flotation activity related to the extraction of gold from refractory gold ores.New data on adsorption and flotation properties of Heraclium stems and leaves extracts (HSE) in selective flotation of Au-sulfide minerals were obtained using UV-spectroscopy, scanning electronic and laser microscopy and atomic force microscopy. The dimensions and shapes of adsorbed hydrophilic films of herbal reagents were identified and mechanism of formation of stable insoluble compounds on the surface of minerals in flotation was explained.Research flotation tests carried out on samples of refractory gold ore of one of Russia deposits showed the possibility of effective use of herbal modifiers to improve qualitative and quantitative indicators of enrichment compared with the standard reagent regime. New reagent modes, using herbal modifiers in an amount of 5 to 10 ml of the extract (300 - 600 g / t, respectively) improves the quality of the concentrate: gold content attains 14.7 g / t, 1.34 times higher than in the baseline experiment and provides a gain of 3.13% extraction.The developed reagent regime with herbal modifiers is the author's original design, patented (patent of the Russian Federation) and have no analogues in the world of mineral processing. (Application number 2015116125 from 04.28.2015, ""The method of flotation separation of sulfide minerals using herbal modifier"", Russia). Actual application of new plant extracts as modifiers in flotation of sulfide minerals is the possibility of replacing of highly toxic chemical compounds by environmentally safe substances of plant origin. Implementation of the developed methods of extracting gold from refractory minerals with herbal modifiers will help to improve gold recovery at 3-5% and the quality concentrate of not less than 1.2 times, leading to higher productivity and a reduction of the negative man-made effects on the environment ."

Jan 1, 2016

By S. Gregory

Many gold treatment plants have sulphides and coarse particle gangue components that contain gold in their tailings (cyanide leach residues and flotation tailings). Coarse and very fine liberated gold may also be present in some tailings streams. Two issues usually govern the economics of recovering additional gold from gold occluded in sulphide and gangue particles. The liberation characteristics of the gold in the sulphide and coarse gangue (gold liberation versus grind size) is the first and most important of the two. If fine grinding can liberate a reasonable amount of the gold, then the next important issue is how effectively these two constituents can be concentrated. Flotation will achieve high sulphide recovery but is usually costly. Selectivity is also an issue because of entrainment. Continuous centrifugal gravity concentration offers a viable solution to the recovery of both sulphides and coarse gangue however selectivity is also likely to be a problem. The possibility of improving concentrate grade by using a Falcon B separator was investigated. This paper describes a program of test work carried out on a gold leach tailings using a laboratory Falcon '13' separator. The program involved three different bowl angles: 10, 12 and 14 degrees and two bowl speeds (giving 250 and 350G accelerations). A number of tests were also performed on samples that had free gold present to ascertain the size-by-size recovery of gold in these samples.

Jan 1, 2005

By Martin Lebeuf

The phenomena occurring in the cathode and at the cathode surface of aluminum electrolysis cells are very important in regards to cathode voltage drop and cathode wear. In the current study, laboratory-scale aluminum electrolysis cell cathodes were analyzed by X-ray microtomography. This technique allows an excellent visualization of the distribution of different substances, if their respective X-ray attenuation coefficients are different enough. In the current case, the important difference in the mean atomic number between cryolitic bath and graphitic carbon results in good contrasts. The volumetric bath penetration profile, porosity and impurities distribution in the cathode were thus obtained. Furthermore, metallic impurities and bath heterogeneities were observed at the cathode surface. Observations were also made with Scanning Electron Microscopy - Energy Dispersive Spectroscopy (SEM-EDS).

Jan 1, 2011

By M. Kreuh

An investigation of the pressure pulse spectrum generated by the gas dispersion processes in a Peirce Smith copper converter was undertaken via the simultaneous measurement of four tuyeres using high frequency pressure transducers. The data was captured, stored, and analyzed using digital data processing techniques; including power spectral density plots, band-pass filtering, and a principal component analysis (PCA). The process was characterized throughout by a dominant 3 Hz pulse signature attributed to the formation of lateral gas envelopes. In particular, test tuyeres in the tuyere line tended to operate synchronously at the dominant frequency, regardless of operating conditions tested and despite being distributed along the converter. Synchronous behavior is thought to arise from the acoustic coupling and possible resonance behavior of the gas delivery system on the converter.

Jan 1, 2007

By A. D. Walters

"IntroductionScreens are used in coal preparation plants for four basic functions, namely:I. Scalping off large size run-of-mine coal for initial size reduction;2. Sizing of coal treatment in different process streams;3. Removal of magnetite (dense medium) from clean coal and refuse;4. Dewatering.Canadian coal preparation plants use screens extensively in the above functions. Even plants where no beneficiation takes place, screening and crushing are carried out in the size reduction process.Description of Process UnitsThe type of screen used in coal preparation plants generally falls into the following categories:Fixed Screens and Grizzlies (for large coal)Often a simple rugged construction, either set horizontally above a bin or inclined with the coal flow.Fixed Sieves (for fine coal)They are used for dewatering and/ or size separation of slurried coal or discard. The sieve bend, the Vor-Siv, the Wilmot riffle and the cross flow screen fall into this category. The most commonly used in coal preparation plants is the sieve bend, Figure 1. Coal slurry is fed tangentially onto a fixed curve wedge wire screen deck. The solids are separated at a predetermined particle size, delivering a partially dewatered overproduct and a dilute underflow. The coal slurry is initially delivered to the sieve bend via a feed box. A series of baffles spreads the feed evenly across the width of the deck. The slurry drops from the last baffle, passes through the feed spout and is fed tangentially to the screen. It is important that the feed should contact the surface immediately at the front end of the sieve bend. It is possible to lose as much as 250Jo of screening area with a poorly fitted screen box.The full stream of coal slurry flowing over the sieve bend decreases in depth, in increments of approximately •;4 the slot width each time it passes a slot. Sieve bends make a size separation at 112 to 2h the slot width. This feature virtually eliminates blinding of the screen surface. Slot sizes are normally quoted in millimetres, available standard slot sizes are from 2 mm to 0.125 mm. The sieve bend is also widely used in coal preparation for preliminary dewatering."

Jan 1, 1989

By P. Coursol

The Noranda Reactor Process (NRP) has been in operation now for more than 30 years and this mature process has attained a high level of performance. The NRP at the Home Smelter of Xstrata Copper treats a wide range of feed materials and a thorough knowledge of both process control and smelting physico-chemistry has been beneficial to help meet the required plant flexibility. In this regard, some level of predictive knowledge related to slag chemistry, in particular, the liquid and solid phases such as spinels or olivines, has been found to be beneficial. In the last decade or so, the availability of commercial thermodynamic modeling packages, such as Factsage1m have been utilized with advantage to help the plant optimize slag chemistry and minimize problems from difficult slags, for example, those the could arise from undue feed variability. This paper illustrates the application of this software in examining a range of operating parameters such as: %Fe in product matte, the %Fe/%Si02 ratio in the slag, the levels of minor slag components including CaO, Ah03, ZnO, and MgO, and the level of oxygen enrichment on the operating conditions of the NRP. The slag composition boundaries at the conditions affecting magnetite control and solid magnetite/other precipitated solid phases, as well the conditions influencing the slag liquidus ranges of NRP slags are also discussed with respect to the overall process chemistry.

Jan 1, 2007

The dynamic breakage process of rocks by the impact of a hydraulic hammer is more complex than one normally assumes. It is even more difficult when one has to conduct the breakage under water. In such cases one does not know exactly what the surface topography and composition are at the bottom of the sea or river and, hence, it is more difficult to select the best position of the hammer before starting the hammering. Typically, an industrial hammer has a diameter of about 250 mm, a length of about 1.25 to 1.75 m and a mass of several tons. The hammer frequency can be up to 50 impacts per minute. The general principles of rock hammering can be easily summarized, but this knowledge is not sufficient to adapt adequately the method for less common rock conditions (e.g. less brittle rock, presence of vertical and subvertical fractures, etc.). That is the reason why we initiated a research project, whereby a scale model has been developed to conduct experiments in the laboratory and whereby discrete element simulations are being conducted. Both aim at a better understanding of the basic mechanisms of rock hammering. The scaled experimental model allows varying the impact energy and the static weight independently. Within the experiment, the hammer is in contact with the rock specimen under a certain confining pressure and with a certain contact pressure due to the static weight. A weight falls on the hammer, creating the dynamic action or impact; the height over which the weight falls can be varied. The penetration is recorded after each impact. After a certain penetration the test is stopped and the internal crack patterns are described. Some simulations have been conducted, allowing the modeling of individual fracture initiation and growth during the penetration of the hammer by either a constant displacement rate (using the UDEC-code) or by introducing the dynamic process (using the PFC-code). Some of the observed features in the laboratory experiments can be visualized in the simulations. However, further research is needed to allow the simulations being an adequate tool to well understand the dynamic process in laboratory experiments, as well as the in-situ behavior.

Aug 1, 2013

By L. M. Oshinowo

The incorporation of advanced analysis tools, such as CFD, into the process plant design process has become possible through advances in commercially available computational fluid dynamics software and faster computers. Multiphase modeling is now typically employed in the design phase of process plant design at Hatch. The multiphase models include Lagrange-Euler and Euler-Euler treatment of the multiple phases. Additionally, mixture models with interface-sharpening algorithms are applied to the prediction of free-surface flows in complex geometry. CFD is applied to applications where traditional design rules are not applicable. The additional rigor of CFD modeling in 2D and 3D allows process engineers to come closer to realizing true virtual plant design. The objective of this paper is to outline the benefits and pitfalls in the application of multiphase modeling for rigorous design. Several application examples in the hydrometallurgical field will be presented.

Jan 1, 2005

By L. B. Smith

Introduction The property of Wright-Hargreaves Mines, Limited is situated at the northeastern end of Kirkland lake, Ontario. It lies immediately east of the Lake Shore mine, and about in the centre of the Kirkland Lake camp. The district is served by the Swastika-Rouyn branch of the Temiskaming & Northern Ontario railway, the town of Kirkland Lake being four miles northeast of Swastika, which is 63 miles north of Cobalt and 392 miles north of Toronto. The mine is developed by three shafts and has more than twenty-eight miles of underground workings. There are two main producing veins, which lie in a porphyry boss 1,350 feet wide. Milling started in May, 1921, and to-date (January, 1933) the mine has produced gold to the value of $21,770,183. Present production is at the rate of 800 tons of ore per day. For a description of the geology, reference may be made to the report by E. W. Todd on the Kirkland Lake Gold Area (1). Structure and Ore Deposits The two major productive veins on the Wright-Hargreaves property are known as the North vein and the South vein. In the vicinity of the shafts these veins are approximately 550 feet apart. A third vein, known as the Inclined vein, has been worked from its junction with the South vein at the 2,000-foot level to its intersection with the North vein at the 800-foot level. This inclined vein has to date been found only in the area east of the eastern major north-south fault. The main North vein and South vein have a general vertical dip, although local rolls and post-ore faults throw certain sections out of line. From the surface to 3,900 feet, the North vein is displaced south less than 200 feet, and the South vein at the same horizon is almost perpendicularly beneath the surface showings.

Jan 1, 1934

By M. Nzotta, L. Teng, S. Seetharaman, A. Chychko

The objective of the present work is to optimize the EAF practice towards Mo alloying with maximum retention of the alloying element in molten steel. During Mo additions, there were significant losses to the dust (ca 7 %) and to the slag phase (ca 2 %), which had serious economic and environmental impacts. The present work was aimed at designing a suitable Mo precursor, an alternative to ferromolybdenum, as the Mo source and a process sequence for optimal retention of Mo in the steel. The design of the Mo source should be in such a way that low cost raw materials such as MoO3 concentrate have to be used, stable during the addition so that the vapour phase losses as MoO3 are kept minimum and the dissolution of the precursor in molten steel is easy without loss to the slag phase. After thermodynamic considerations, three precursor materials were chosen, viz. CaMoO4, MgMoO4 and Fe2MoO4. Synthetic mixtures of the component oxides in each case as well as pure MoO3 were investigated by TGA and high temperature XRD in order to find out the temperature range in which the compounds were formed. Experiments were also conducted separately where the evolved gases were analyzed. All the three precursors were formed easily and the loss of MoO3 to the vapour phase was found to be extremely low. Addition of the oxide mixtures to steel melts were conducted in three different scales, viz. 16 g, 500 g and 3 tons (induction furnacle). Initial experiments showed that MgMoO4 was not suitable since the Mo yield in the steel melt was not very high. Fe2MoO4 was found to perform best, the Mo yield reaching 98 %. Further trials were conducted in the 65 ton Electric Arc Furnace (EAF) at Uddeholms AB in Hagfors. Mixtures of mill scale, MoO3 and carbon in suitable proportions were added in a pre-determined addition sequence. It was found that, in the actual practice, the Mo yield reached 99 %, equaling in performance the addition of ferromolybdenum. The process offers an effective use of cheaper raw materials and very high Mo yield avoiding a pre-treatment step like the production of ferromolybdenum. This is both cost effective and environmentally advantageous. The process has been patented and is being currently implemented at Uddeholms AB, Hagfors, Sweden.

Jan 1, 2011

By M. K. Jain, Z. T. Xu, M. Bruhis, V. Hegedekatte

"Strain rate and temperature dependent deformation conditions are present during elevated temperature forming of aluminum and other metallic materials. While many constitutive laws have been proposed to represent such deformation conditions, a closer investigation often reveals their limited applicability in terms of fit to the experimental data, and interpolation within and extrapolation outside of the range of experimental stress-strain curves. This is often because material-specific primary deformation mechanisms of temperature-dependent strain and strain rate hardening are poorly captured. In the present work, the Voce-Kocks constitutive model based on mechanics of dislocations storage and annihilation has been found to be suitable for many metallic materials. The model was modified to include the effect of temperature dependent shear modulus. The modified model is then employed to represent the experimental data obtained from uniaxial tensile tests on AA7075-O sheet at elevated temperatures and strain rates. Also, hot gas bulging tests were conducted to verify the applicability of this model. Further, finite element simulation of the hot gas bulge test was performed by incorporating the model as a user material subroutine. Good general agreement was observed between the experimental and FE model predicted results. Some sources of discrepancy in the prediction are also discussed.INTRODUCTION There has been much interest in light-weighting of automobiles from automotive related industries to reduce overall carbon footprint and increase energy efficiency of the vehicles. Aluminum alloys, and especially the medium-strength 5xxx and 6xxx series alloys, have been the primary focus in the last 3 decades to reach the above environmental goals (Huo, Hou, Zhang, & Zhang, 2016) whereas aerospace industry has traditionally focused on high strength 7xxx series aluminum (Al-Zn-Mg-Cu) alloys for structural components (Deng, Yin, & Huang, 2011). Recently, there has been much interest in high strength 7xxx series aluminum as a replacement for heavier steel automotive structural parts such as A-pillar, B-pillar, side impact beams etc. (Harrison & Luckey, 2014). This is both interesting and challenging since the above aluminum structural parts will need to not only meet impact safety standards but also possess sufficient formability for manufacturing such complex parts. Since the formability of high strength 7xxx series materials is quite poor at room temperature, much interest has focused on improving both formability and final part strength via high rate hot stamping, in-die quenching, and subsequent artificial ageing process steps (Kumar & Ross, 2016)."

Jan 1, 2018

By I. Yutronic

Compañía Minera Doña Inés de Collahuasi's (CMDIC) Concentrator Plant is located at 4300 meters above sea level, approximately 2000 kms north from Santiago, Chile. The concentrator has three grinding lines. Each one, Lines 1 and 2, have one SAG mill at the primary grinding stage followed by a secondary grinding and classification stage consisting of one ball mill, two hydrocyclone batteries and a sump with two pumps. Line 3 has one SAG mill (Gearless Mill Drive), followed by a secondary grinding and classification consisting two ball mills, four hydrocyclone batteries and a sump with four pumps. Average throughput for these three lines is 150 Ktons per day. Peak values of 180 ktons per day have been achieved. Since late 2008 and throughout 2009 and 2010, Operations and Automation areas developed an optimization program for the grinding process, considering the implementation of Model Predictive Controllers (MPC) for the three SAG mills, and later, extending MPC to the secondary grinding and classification stages. The implementation of a MPC solution was based on stability considerations (high variability of the SAG process, high interaction between sump level control and classification efficiency, etc), requirements for an automated and consistent operation, the need to maximize throughput under timevarying scenarios and, in the long term, optimization of grinding process considering Specific Energy Consumption, among other parameters. MPC solutions had proven control robustness and strong optimizing capabilities in terms of helping in discovering new operational points and so achieving all of the aforementioned goals. On the first stage of the program, MPC implementation considered identification of dynamical process control models based mainly on historical data, in order to know the impact of a group of Manipulated Variables over Controlled Variables. Also, the impact of measured Disturbance Variables was modeled in order to take into account the high impact and interaction of these variables over the processes. At the end of this stage, 4 controllers were successfully operating for the 3 SAG mills and the secondary grinding and classification process. In response to challenges made by the working group, the second stage of the development of control applications in the grinding process required to achieve a design and implementation of a solution capable of governing the milling process, in addition to stabilization and optimization of both processes (SAG milling and secondary grinding), to integrate from a point of view of process control and automation. Therefore, in the second stage, MPC performance was continuously monitored and optimized through advanced tuning, inclusion of more process models (with proper step tests), redefinition of specific optimization criteria and adjustment to new process needs. Finally, successful MPC implementation at Collahuasi has proved that fast development and deployment of process control solutions is possible and allows immediate process stability, higher throughput, specific energy consumption reduction, and successful product size control, among many others.

Jan 1, 2012

By Fatemeh Saeidi, Luis Marcelo Tavares, Malcolm Powell, Mohsen Yahyaei

"Understanding a single breakage mechanism is fundamental to the development of breakage testing techniques appropriate for mechanistic modelling of any breakage equipment. In the light of this insight, it is also possible to compare any two breakage events in a mechanistic manner. This paper presents a new method to compare breakage mechanisms of two-point impact with compression, different in their applied strain rates. This approach regards a single breakage event as a process affected by three sub-processes; first fracture, capture and spatial distribution of fragments. Spatial distribution is influenced by the kinetic energy of fragments and their brittleness. Using this methodology allows us to examine how each sub-process is influenced by applied strain rate and its impacts on progeny size distribution. For this purpose, two rock types of widely different strength, magnetite and silicate, were tested at various energy levels using the impact and compression mechanisms. To isolate the effect of spatial distribution of fragments, particles were forced to remain in the breakage zone. In this condition, similar progenies were generated from compression and impact mechanisms at similar energy levels. However, allowing natural distribution of fragments, coarser progeny was produced from compression of silicate. Additionally, using this approach provides a physical meaning and explanation for rock strength parameters such as A×b in the t10-Ecs relationship. INTRODUCTIONComminution models are rapidly progressing toward a destination that enables us to explain the complete physics of a breakage process as well as the properties of the ores. Eventually, they will be able to take into consideration the micro-events that take place during the comminution process (Bourgeois and Banini, 2002). Thus, considerable efforts have been made in the last few years in the area of ore breakage characterisation to comprehend and unlock a single breakage process that has been treated as a black box event in the majority of conventional methods. In this paper, an attempt is made to explain the effect of applied strain rate on the breakage properties of rock by using the knowledge that has been gained by understanding a breakage event. This is particularly important due to its application for various comminution devices that operate within a relatively broad range of speed."

Jan 1, 2016

By Magnus Evertsson, Johannes Quist

HPGRs have since introduced in the 1980s (Kellerwessel, 1993; Schönert, 1988), now become integral comminution units at several minerals processing plants around the world. Even though a lot of the initial issues concerning performance, availability and wear have been addressed and solved there are still phenomena and aspects which can be improved and understood further. Schönert and Sander (2002) presented experimental results and a mechanistic model including the internal force dynamics between the rollers and the compacted bed. They derived expressions for the pressure distribution involving most of the influencing terms and effects. However, in order to solve the differential equations several of the terms vanish by assumptions. The Schönert and Sander model reflects the experimental data in many aspects but the predicted shear force distinctly deviates from the experimental results at the angular position of the peak pressure level. This finding suggests that the particle to particle interaction and breakage process in the different zones seen in Figure 1 are complex and difficult to model using analytical models. A numerical modelling approach using DEM does not require the same amount of assumptions and simplifications of boundary conditions. Hence such modelling may provide further knowledge and vital understanding. In this paper the breakage process is simulated in order to investigate the shear slip behaviour and how it relates to different operating variables. A laboratory scale HPGR corresponding to the experimental setup used by Schönert (2002) have been modelled in EDEM (DEM-Solutions). The bonded particle model (BPM) is used for modelling quartz particles (Potyondy, 2004). The breakage model strength parameters are calibrated against interparticle breakage experiments in an Instron 400RD compression device. The contact model parameters are calibrated using calibration methods developed by Quist (2015). The floating roller dynamics are modelled using a spring-damper system. Results present insights regarding the interparticle slip behaviour as well as the frictional tangential force distribution on the rollers. The simulated roller pressure distribution shows good correspondence with previously reported findings in the literature.

Jan 1, 2016

By Kirsten Corin, Margreth Tadie, Cyril O’Connor, Jenny Wiese, Wonder Chimonyo

"Relating flotation performance to the electrochemical characteristics of a pulp remains a complex issue both in fundamental research and in practice. For example, in the case of thiol collectors different Eh values can result in the formation of the dimer or the metal thiolate which may or may not enhance the hydrophobicity of the mineral. Reducing or oxidizing conditions in a flotation system, viz. changing the Eh value, are usually manipulated to achieve an optimum flotation response by the control of pH and dissolved oxygen levels in the system. It is also possible to vary the potential by the addition of modifiers such as sodium hydrosulphide (NaHS), sodium hypochlorite (NaClO) or hydrogen peroxide (H2O2). The objective of the present study was to investigate the effect of the addition of the oxidising agents, NaClO and H2O2, on valuable mineral recoveries and grades in the flotation of sulphides from a PGM bearing Merensky ore. Batch flotation tests were conducted at pH 9.2, the natural pH of the system, in the absence and presence of a xanthate collector and Eh modifiers, viz. NaClO or H2O2. Most importantly in this way it was possible to vary Eh at constant pH and DO levels. The results indicate that in the absence or presence of xanthate the addition of H2O2 reduced both the recovery and grade of copper and nickel. In the absence of xanthate, the addition of NaClO improved the recovery of copper slightly and both the recovery and grade of nickel significantly, but in the presence of xanthate NaClO addition resulted in unchanged copper recovery and grade, but those of nickel were reduced. Based on anecdotal evidence that the addition of trace amounts of a potential modifier could improve flotation performance further tests were conducted the results of which suggest improved flotation performance.INTRODUCTIONIn the Merensky Reef, platinum group minerals (PGM) are commonly associated with base metal sulphides (BMS) and this has an effect on the way in which these minerals can be concentrated by flotation (Vermaak, Venter & Pistorius, 2004; Wiese, Harris & Bradshaw, 2005; Schouwstra, Kinloch & Lee., 2000). A major problem stemming from this association has been reported to be the loss of valuable minerals (PGM) associated with the loss of BMS (Wiese et al., 2005) during flotation. Shackleton (2007) suggested that PGMs behave in a similar manner to sulphides during flotation. Therefore, in order to recover the PGM, base metals are targeted. There is thus a need to investigate ways to improve the flotation performance of the sulphide minerals. The electrochemistry of the flotation of sulphide minerals has been studied for over half a century and there is consensus that sulphide minerals float only under a suitable redox environment (Heyes & Trahar 1979). This implies that reducing and oxidizing conditions during flotation of ores such as Merensky can be manipulated/varied to achieve an optimum flotation response.During flotation, sulphide minerals interact with thiol collectors in an electrochemical reaction to form hydrophobic species at the mineral surface (Finkelstein & Goold 1972; Rand & Woods 1984). The sulphide minerals are semiconductors and their interaction with collectors involves transfer of electrons. As such, a potential difference results which is responsible for driving electrons between reacting species (Fuerstenau, Jameson & Yoon, 2007). The magnitude of the potential difference affects the relative energies of charge carriers (electrons) at the mineral/solution interface hence controlling the direction and rate of charge transfer or rate of reaction (Bard & Faulkner, 2001). In a mixed mineral system the mineral/solution interface potentials account for the mixed potential which is critical to the process of flotation (Chander, 2003; Woods, 2003)."

Jan 1, 2016

By F. Chevarin

The reaction of O2 with the carbon anode is considered as the main parasitic chemical reaction affecting Hall-Heroult process anodes. The current study aims at investigating the influence of the microstructure of baked anode on its overconsumption. Samples were removed from different positions of an industrial anode. Density, porosity, Lc and BET specific surface area were measured. The anode reactivity was evaluated based on the weight losses for the samples resulting from the reaction of anode with air at 550°C after 7h. The essential parameters determined to control the air reactivity are closed porosity, Lc and pores with a pore entrance radius of 1.5, 8.5 and 12 p.m. The knowledge of effects of these parameters allows better understanding of the reactivity of anodes and consequently reduction of their overconsumption in electrolysis bath.

Jan 1, 2011

By J. Dubinski

Poland is the ninth largest coal producer in the world and Coal Company is the largest Polish producer of this deposit yielding 51% of national production. Coal Company mines are located in the Upper Silesian Coal Basin. These are underground mines which operate in difficult geological conditions at great depths of up to 1200 m. One of the most common natural hazards in Polish mines are rockburst and seismic hazard impacting on surface infrastructure and habitants. In the assessment of the rockburst and seismic hazard methods of mining seismology play a leading role. This paper presents progress that was achieved in the last few years in the implementation of new seismic monitoring systems and seismic interpretation methods for the prevention of hazard deriving from seismicity induced by mining. This progress in assessment of rockburst hazard and impact of seismic activity on the surface infrastructure was achieved through close cooperation between the Coal Company and Central Mining Institute ? the country?s leading scientific institute in the field of mining seismology. New theoretical solutions are in the process of testing in mines of Coal Company where seismic monitoring systems are installed and controlled by well-qualified personnel. Some directions of further joint actions to increase the effectiveness of rockburst and seismic hazard assessment are presented as well.

Aug 1, 2013

By O. Hungr, V. Gischig, G. Preisig

Deep-seated landslides are characterized by slow time-dependent movements induced by constant gravitational creep, and periods of acceleration associated with stress changes within the rock and the preexisting fracture network. Natural stress changes are typically caused by seasonal variations in surface temperatures and groundwater pressures, but also by rare and more violent events such as earthquakes. These processes are responsible for cyclic loading and unloading that leads to rock mass damage, fatigue and progressive failure with time, and may explain sudden, unexpected rock slope acceleration phases. In this work, we present a set of distinct-element models to investigate and compare the role of hydromechanical fatigue and seismic fatigue in the history of a deep-seated landslide. Hydromechanical fatigue arises from the fluctuation of pore pressure in fractures accompanying periods of significant groundwater recharge. In alpine areas, there are usually one or two cycles per year associated with snow melt and intense rainfall periods. In the presence of a deep confined aquifer within the rock slope, the amplitude of pressure fluctuations may reach values of 0.25-0.5 MPa. Hydromechanical models considering such pressure changes are able to reproduce observed slope accelerations-decelerations phases. Substantial accelerations may occur even in the absence of a cycle of exceptional amplitude, depending on the current state of fatigue. At a given time, one or more fractures may be critically-stressed, and a small change in applied stress is enough to cause local failure and induce a crisis of enhanced slope acceleration. This is augmented if the rock slope contains planes of weakness associated with its tectonic history, glacial debuttressing, etc. The corresponding behaviour is analogous to laboratory experiments on rock and metal fatigue. Similar fatigue effects have also been proposed for repeated earthquake events in seismically active regions. Unlike hydromechanical stress changes that occur in a more localized portion of the rock slope, those induced by passing seismic waves involve the entire rock mass. Moreover, the frequency and amplitude of stress perturbations due to earthquakes are different than those induced by pore pressure variations, although both likely contribute in combination to the degradation and progressive failure of large deep-seated landslides when both are present. The results presented illustrate that: (1) assessment of slope stability near critical infrastructure (e.g., hydroelectric reservoirs) should not only consider static stability, but also failure mechanisms related to fatigue that evolve over time and may result in an apparently stable slope progressing towards a critical state due to relatively small but repetitive stress changes; and that (2) characterization of fatigue processes affecting a deep-seated landslide requires multiparametric continuous monitoring at different observation points.

Jan 1, 2015

By J. E. Quinn, S. Wolstencrof, K. H. Soldenhoff

Ion Exchange (IX) using Strong Base Anion Exchange (SBA) resins is conventionally used to purify uranium from sulfuric acid pregnant leach solutions (PLS), particularly when uranium grades are relatively low. However, the presence of chloride in the PLS interferes negatively with conventional SBA based IX processes, by reducing the uranium loading on the resin. Chloride can be present in the PLS due to the use of saline bore or seawater in leaching, or chloride containing leach/IX reagents. ANSTO has been examining strategies to combat this problem for several years. ANSTO previously reported that a recently developed high-capacity SBA resin was capable of extracting uranium efficiently from saline leach liquors produced at Boss Resources’ Honeymoon in-situ recovery mine in South Australia. The resin was tested successfully in a 2017 Field Leach Trial carried out onsite in the existing wellfield area. While the piloting was extremely promising, the elution was more challenging, with eluate tenors limited to 2 g/L U3O8 using NaCl. This is due to the resin’s strong affinity for the uranium complex, which makes it difficult to elute efficiently by standard methods. In this paper, we describe a novel elution process developed for strong base resins that significantly improves upon conventional methods. The process, developed by ANSTO, is based upon conversion of the extracted uranyl sulfate species to uranyl carbonate, followed by elution with sodium chloride. The loading and elution process was demonstrated in continuous locked-cycle piloting conducted at ANSTO in 2019. The results were excellent, with eluate tenors of 8–9 g/L U3O8 achieved from Honeymoon PLS containing 50 mg/L U3O8, with very little transfer of impurities. In subsequent test work, the eluate was shown to be amenable to uranium peroxide precipitation. The results represent a huge step forward for the purification of uranium from saline leach liquors.

Jan 1, 2020

By P. M. May, V. Gella

The deportment and speciation of trace elements during mining and minerals processing is becoming an area of increasing concern with regards to potential health and environment risks. The use of chemical modelling can enhance our basic understanding of the deportment and speciation of trace metals under conditions present in gold processing solutions, and assist in laboratory and field investigations. In this paper, we report the results of chemical speciation modelling using the JESS software package for the trace toxic elements Pb, Cd, Hg, Se and Te in cyanidation solutions of varying salinity and relate the models to experimental data. The speciation of mercury is examined in detail.

Jan 1, 2011