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By Y. M. Zhao, C. L. Duan, Z. F. Luo, X. L. Yang

"Fine coal beneficiation in a dry way is considerably imperative for the efficient utilization and conservation of coal resource in drought regions, especially for China. In this study, a continuous vibrated gas-fluidized bed separator was established and developed based on the results of laboratory batch separation results. The fluidization behavior and the effects of several main parameters including superficial air velocity, vibrational parameters, bed height and separating time were systematically investigated. The results showed that the bed expansion increased linearly with the superficial air velocity and theoretically, higher bed expansion benefited the hindered settling process of fine coal particles. However, larger superficial air velocity would induce intense fluctuation in bed surface and a poor performance of density segregation. The conveying velocity of particles was mainly determined by the vibration angle and a predicted model was established by the nonlinear regression analysis. A theoretical model of bed height distribution was established and this model fitted the measured value well. The beneficiation performance of this separator was evaluated by separating -3+1 mm Wuhai fine coal. The results showed that the probable error, E, is 0.225, indicating a continuous vibrated gas-fluidized bed separator could achieve a satisfactory performance.INTRODUCTIONFine coal beneficiation in a dry way is considerably imperative for the efficient utilization and conservation of coal resource in drought regions, especially for China. Meanwhile, it is also conducive to environment protect and low-carbon, green development of coal sector. In recent years, the increasing academic interest in the field of fine coal dry beneficiation has been aroused in most of big coal countries. In summary, recent processes of fine coal dry beneficiation are, according to their processing principles, mainly classified into two categories: dense medium beneficiation (Dong et al., 2015; Fan, Chen, Zhao, & Luo, 2001; Luo et al., 2008; Macpherson, Iveson, & Galvin, 2011) and improved pneumatic beneficiation (Patil & Parekh, 2011; Yang, Zhao, Luo, Song, & Chen, 2013; Yang, Zhao, Luo, Song, Duan, et al., 2013; Zhao, Zhao, Chen, & Luo, 2015). The former deploys artificial dense medium, such as magnetite powder and fine sand, to form a stable gas-solid suspension with certain density under the function of the upward fluidizing air flow and in some case, the external force field like vibration and magnetic field. Generally, it is believed that the process of air dense medium fluidized bed (ADMFB) is suitable for separation of coarse coal (-50+6 mm) and can't obtain a satisfactory result for fine coal separation (Luo, Chen, & Zhao, 2002; Luo et al., 2008). However, some recent laboratory efforts (Patil & Parekh, 2011; Zhang et al., 2014) attempt to find an improved performance for fine coal beneficiation in ADMFB with some modifications. The point of these works is to use a comparatively shallow bed and finer magnetite powder with appropriate size distribution. It is known that fluidization of finer magnetite powder is prone to arouse adverse fluidization properties such as channeling and slugging. Thus, the external force is introduced to an ADMFB in order to improve the fluidization quality of a magnetite powder bed. Some recent literature on air dense medium magnetically stabilized fluidized beds (Fan et al., 2001; Luo, Zhao, Chen, Fan, & Tao, 2002; Song, Zhao, Luo, & Tang, 2012), air dense medium vibrated fluidized beds (Luo et al., 2008) and Reflux Classifier (Macpherson, Iveson, & Galvin, 2010) reports that the separation efficiency, namely the probably error E value, of dense medium separation of fine coal ranges from 0.066 to 0.07, indicating a good separation performance. But, the main unresolved problems of dense medium beneficiation are located in the processes of product purification and medium recovery and are urgent to be solved befor"

Jan 1, 2016

By E. Ghali, A. D. Bas

"Treatment of oxide, e.g. roasted gold ores has received relatively less attention than sulphidic ones and recently, handling of oxide gold ores is becoming essential. In this study, the influence of roasted gold ore (RGO) slurry (at 35% solid ratio) on the electrochemical dissolution of gold has been examined using pure gold and iron oxide minerals (hematite, maghemite, and magnetite) as disc electrodes by zeroresistance ammeter mode either in one or two separate containers. The presence of slurry decreased galvanic currents, i.e. corrosion rates due to the release and increase in the amount of soluble and/or insoluble species that could retard further the anodic behaviour of gold. Higher galvanic currents were observed in two separate containers than that in one container indicating the primary importance of galvanic interactions. SEM-EDS results observed iron hydro/oxide coatings on gold surface in case of magnetite test. However, in case of RGO electrode it is not a perfect passivation, although somewhat decreasing trend was observed on gold dissolution. These findings have revealed that passivation is not only a laboratory phenomenon, but also it could be responsible for the slowdown of gold dissolution in industrial practice.INTRODUCTIONThe cyanidation of gold is an electrochemical corrosion process thus; the dissolution of gold can readily be studied by electrochemical techniques. The outcome/summary of previous electrochemical studies of gold leaching can partially be summarized as follows: Filmer (1982) and Lorenzen and van Deventer (1992) reported the negative effect of pyrite and pyrrhotite on gold leaching due to the galvanic interactions; Aghamirian and Yen (2005) studied gold galvanic corrosion in presence of sulphide mineral electrodes only in one cell using zero-resistance ammeter (ZRA) mode; Dai and Jeffrey (2006) discussed, individually, the anodic and cathodic behaviours between gold and sulphide minerals, and Azizi et al. (2010, 2011) used a bed reactor to examine the influence of sulphide minerals on gold dissolution in one and two separate cells. Accordingly, a slowdown in gold leaching has generally been attributed to the passivation phenomenon, although the indication of this phenomenon is still an undergoing debate. For instance, Mrkusic and Paynter (1970) identified the passivation as the film formation of dissolved species from calcine, Crundwell (2014) explained passivation, in the case of corrosion of metals, as the formation of a layer which is composed of a new chemical species on the mineral surface and this layer inhibits or blocks further reactions. He suggested that passivation is related to the oxidation of the metal, and the formation of a passive layer that retards the rate of dissolution by several orders of magnitude. Consequently, galvanic interactions, passivation phenomena, or combinations of them are considered significant electrochemical factors affecting gold dissolution (van Deventer, Reuter, Lorenzen, & Hoff, 1990; Azizi, Petre, & Larachi, 2012). It is important to note that generalizing the influence of a mineral/metal on gold dissolution may not be correct in all cases, since contrary behaviours/results (for pyrite) have been observed (Aghamirian & Yen, 2005). Therefore, electrochemical study of gold is still a subject of research and need to be examined further in detail."

Jan 1, 2016

By John H. Morris, R. Gwilym Roberts

"The Upper Beaver Mine, Kirkland Lake, Ontario, is a copper-gold deposit in mafic flows and sedimentary rocks. The deposit consists of a number of orebodies of two types: copper- and gold-bearing chalcopyrite-pyrite-magnetite ore; and gold-bearing quartz veins. Chalcopyrite-pyrite-magnetite ore occurs in two structural forms: as cherty interflow material in coarse clastic roks underlying flows; and as veins. Both sedimentary and vein ore occur in each orebody. The goldbearing quartz veins occur in interflow sedimentary units and at the contacts of oligoclase porphyry dykes.The deposit is in a localized, volcanic-sedimentary basin which began to develop during the emplacement of the upper units of the pyroclastic and sedimentary Gauthier Group, and continued to the early mafic flow activity of the overlying Kinojevis Group. The formation of the volcanic-sedimentary basin is ascribed to the D0 deformation. The deformation is significant in terms of the structural configuration in the mine area, and may be significant regionally, but this has not been demonstrated. The early deformation was followed by two tectonic deformations. D 1 is associated with a penetrative mineral foliation, axial planar to upright mesoscopic folds and striking parallel to the trend of regional fold structures. Mesoscopic flexural-slip folds, kink folds and fracture-crenulation cleavage are attributed to the D2 deformation. It is probable that no large-scale fold structures are associated with the D2 deformation. The gold-bearing quartz veins were folded during the D1 deformation.The close spatial relationship of copper-gold, chalcopyritepyrite- magnetite veins with chalcopyrite-pyrite-magnetite in cherty inter flow material is strong evidence for the derivation of the veins from the sedimentary ore by hydrothermal, metamorphogenic processes. By analogy, it is suggested that the gold-bearing quartz veins were formed by similar processes."

Jan 1, 1982

By D. A. Akinlade, N. L. Richards, D. C. Murray, W. F. Caley

To investigate the effect of adding Ti to a Ni-Cr-Fe powder metallurgy alloy, a thermodynamic software package was used to predict the phase transformations that occurred during thermal processing. Specifically, the effect of adding 3w/o Ti to a 6w/o Al modified ternary Ni-Cr-Fe alloy (the quaternary) was simulated and the phase transformations that might occur in the material on sintering were obtained using the thermodynamic modeling tool. These predictions were subsequently compared with experimental results obtained by X-ray diffraction and metallography. For comparison, selected compacts were prepared containing only the ternary + 3w/o Ti (no Al). Based upon compressibility curves, the optimum pressure for producing the new Ti compacts was 500 MPa vs 600 MPa for the quaternary composition with Ti. In each case, hardness of the base alloy was enhanced by the Ti addition whereas the residual porosity remained relatively constant at about 19%. Finally, although SEM/EDS failed to confirm the presence of Ti in the gamma prime intermetallic, XRD spectra showed a shift in lattice parameter on addition of Ti, suggesting that the intermetallic was of the form Ni3(Al,Ti).

Jan 1, 2010

By K. Kim

"All milling operations would like to achieve the best possible recovery in combination with the highest achievable throughput. Unfortunately, many operations have problems with low recovery, low throughput or both. In the majority of these cases investigated by the author, the solutions to improve recovery and throughput were simple. The solutions did not include implementation of new technology or major capital, but rather a return to fundamentals. In most cases, problems occurred because the operation was not following their own operating procedures, because the design of the circuit was changed without adequate change management or understanding of the implications of changes, or because basic metallurgical measurements and control were not taken or ignored. In this paper, examples of these problems and their solutions derived from long and varied experience will be discussed. The objective of this presentation is to provide the milling operator with practical and readily implementable solutions to common milling issues to improve throughput and recovery.INTRODUCTION Mill operations can be evaluated by many operating parameters, but the two best indicators are recovery and throughput. These two parameters summarize the wellbeing of an operation. The grade to the mill is also a good indicator, but this is usually controlled by the mine. The best recovery and throughput are achieved through a team work involving operators, maintenance workers and metallurgical staff. The milling operations include many unit operations, such as crushing, grinding, flotation, leaching, carbon in leach, Merrill Crowe, roaster, autoclave and refinery. The tools available to the operations are plant design, process measurements, assays, metallurgical balance, and operating strategy. Twelve real life examples of improvements of recovery and throughput are presented in this paper. EXAMPLE 1: CRUSHING CIRCUIT WITHOUT FINE ORE BIN At this operation plant throughput could not be maintained at a high rate because feed to the mill became coarse during the day. The cone crusher was feeding the ball mill directly. As the day wore on, the gap on the cone crusher would slowly increase, which would cause the product size to increase. This would increase the re-circulating load on the ball mill. The throughput would decrease accordingly. Furthermore, the throughput would decrease more with high frequency of maintenance on the cone crusher."

Jan 1, 2019

By J. P. Harrison, R. Roostaei

"In this paper we investigate the consequences of using conventional triaxial peak strength criteria in the polyaxial stress conditions that occur around the end of a long circular underground opening. A series of 3d boundary element analyses were performed using Examine3D to determine the stresses induced around the tunnel in different in-situ stress conditions. To discuss the applicability of a triaxial strength criterion in failure prediction, strength factors were computed for both the Ottosen polyaxial strength criterion and the triaxial Hoek-Brown criterion. Assuming that the Ottosen criterion is an accurate indicator of strength factor, the discrepancy from this value due to the Hoek-Brown criterion is the error in prediction.In order to simultaneously show the error in prediction and actual strength factor, a quantitative bivariate colour scheme is used to visualize the results. This allows rapid identification of regions with large error, and where either unsafe or overly conservative conditions occur. We show how the inappropriate use of triaxial criteria rather than polyaxial criteria leads to an under- or over-estimation of strength factor, and can result in uneconomic or unsafe design. Extending the analysis to different in situ stress regimes shows how the in situ stress conditions affect the assessment."

Jan 1, 2015

By W. J. Wolfe

"THE DETECTION OF BURIED MINERAL DEPOSITS by chemical analysis of vegetation (biogeochemistry) or visual observation of plant cover type (geobotany) is based on fundamentally simple principles. The root systems of vegetation collect aqueous solutions from a large volume of moist ground below surface and act as efficient sampling mechanisms by providing a composite sample of a reasonably large area. These aqueous solutions constitute a source of ore-associated metals that may ultimately be concentrated in the upper parts of the plant. Although certain plant species have a limited ability to break down primary minerals and extract elements, biogeochemistry normally detects only metals capable of moving in solution. Metal concentrations in the underlying soil must therefore exist in a form that is immediately available for uptake by the root systems - generally in the ionic state in aqueous solution or in readily exchangeable form on the surfaces of soil clay minerals. As a result, biogeochemical responses are closely related to variables such as soil pH, Eh, exchange capacity and complexing agents that control metal mobility in the surface environment. In terms of cost, reliability and anomaly contrast, soil geochemistry will normally be more useful than biogeochemistry in locating buried mineralization in regions of residual overburden or thin transported cover. However, in areas where the root systems penetrate thick deposits of transported post-mineralization overburden, plants can provide an effective mechanism of sampling below the transported material. Biogeochemical research in Canada, Scandinavia and the U.S.S.R. has therefore focused on the potential use of plant prospecting methods (1) in areas where the upper horizons of podzolic soils do not provide an adequate response to anomalous conditions under thick deposits of glacially transported till and (2) in widespread regions of peat and muskeg terrain where near-surface mineral soils are absent."

Jan 1, 1971

"Successive seismic waves may cause progressive weakening of a fault zone, which has been recognized as the mechanism of earthquake aftershocks. However, it is unclear that how a fault zone slips under each wave cycle and how slip displacement accumulates under continuous wave cycles. This laboratory study provides direct evidences on the slip process of a simulated granular fault zone dynamically induced by an incident wave without the effects of late-arriving and reflected waves. The experimental observations show forward and backward slip paths of the fault zone and partially recovered slip displacement after a wave incidence. The unrecovered slip displacement after each wave cycle can be accumulated until it reaches a critical slip distance for seismic faulting, which may reinterpret delayed triggering in earthquake dynamics. The limited interseismic period restricts fault self-healing in strength. The experimental results also indicate that the dynamically induced frictional slip on the fault zone is associated with a complex frictional system, including seismic wave radiation, frictional slip initiation and normal stress vibration. Different from the dynamically induced frictional slip on the fault zone, the statically induced frictional slip causes a permanent increase of slip displacement along the shear loading direction. INTRODUCTIONAn earthquake mainshock may induce aftershocks by suddenly changing external stresses applied to another fault zone in the near field (Kilb et al., 2000) and by slightly perturbing a fault zone from a critical steady state to stick-slip faulting in the far field (Gomberg and Davis, 1996). The dynamically induced frictional slip on a fault zone has been recognized as the mechanism of earthquake aftershocks (Marsan and Lengliné, 2008; van der Elst and Brodsky, 2010). Although earthquake aftershocks have been extensively studied by many seismological methods, a simplified laboratory fault zone can provide possible interpretation on real faulting and detailed analysis on a friction process (Dieterich, 1979; Nielsen at al., 2010). According to a few laboratory experiments related to the dynamically induced frictional slip on a simulated fault zone (e.g., Uenishi et al., 1999; Johnson et al., 2012), the slip process induced by successive seismic waves exhibits continuous motions. However, it is unclear that fault slip response under each wave cycle and slip displacement accumulation under continuous wave cycles."

Jan 1, 2015

By W. T. Gotheridge

The principal sources of coal-dust underground are, of course, coal, and the working of coal. Coal-dust is most dangerous when it is in the finest state of division. This class of dust is found mostly on the roads, being blown or shaken off the loaded trams in transit, or carried in suspension by air currents. The air current passing from the working faces may also carry dust in suspension into the return airway, and the air current from the surface may carry dust from the shakerscreens into the intake airways. The mosl dangerous dust we have to contend with is, (a) that which is most finely divided, and (b) that which contains the most volatile matter, including the inflammable occluded gases, and also oxygen absorbed from the air. According to experiments, coal-dust in a fine and dry state would intensify an explosion, in air free from fire-damp carrying in excess of 3 ozs. of fine dust or 6 ozs. of coarse dust per cubic yard. The volatile matter in the dust must be between 12 and 31 per cent. in the ash-free coal, the latter percentage giving the highest flame velocity. It is vary difficult to propagate flame where coal-dust contains a large percentage of stone-dust, (say 50 per cent.). Shale-dust or other incombustible dust containing no volatile hydro-carbons or carbonaceous matter will prevent the extension of an explosion if mixed with coal-dust in proportion of say 70 per cent., and if the dust is finely divided and dry.

Jan 1, 1924

By N. Aslin, R. Clark, G. Heferen

The methods of harvesting copper from stainless steel mother plates has been investigated from fundamental and operational experience perspectives. At least five different harvesting techniques have been identified that have different effects on product quality, current efficiency, current distribution, growth morphology and ease of stripping. Each method is examined from fundamental principles to understand what occurs during the harvesting process and why the particular effects are manifested. Experience from plants operating the harvesting method is provided to show that the fundamental understanding is relevant. Best practice harvesting method and harvesting management are described.

Jan 1, 2014

By J. Desroches, J. Burghardt, B. Lecampion, A. P. Bunger

"We present detailed comparisons between theoretical predictions and experiments for the initiation of radial hydraulic fractures transverse to a wellbore. Most of these experiments provide a measure of the time evolution of pressure, length, opening and flux entering the fracture during the test. We compare all these measurements simultaneously to our theoretical predictions, thoroughly testing hydraulic fracture initiation theory, which is shown to be predictive. These comparisons notably emphasize the difference between the initiation pressure (the wellbore pressure for which the fracture initiates) and the breakdown pressure (a misnomer which simply corresponds to the maximum pressure recorded during the test). INTRODUCTION In this paper, we will compare hydraulic fracturing laboratory experiments performed in different tight materials (PMMA, cement, shale) with the predictions from a numerical solution of the governing equations of hydraulic fracture mechanics (e.g. Geerstma & de Klerk, 1969; Detournay & Peirce, 2014). We focus on transverse radial hydraulic fractures initiating from a radial notch at the wellbore wall (see Figure 1). In particular, we will clarify the difference between the initiation pressure (the wellbore pressure at which the fracture initiates) and the breakdown pressure (a misnomer which simply corresponds to the maximum pressure recorded during a test, usually carried out at constant pump rate). This difference stems from the strong viscous effects at play during wellbore pressurization, fracture initiation and early propagation (i.e. fluid entrance in the newly created fracture). It has been observed on a number of experiments (e.g. Weijers, 1995; Zhao et al., 1996) and has a strong practical application, first because the maximum pressure is the most obvious value to report and second because that maximum value is necessary to specify injection systems."

Jan 1, 2015

By N. Saeidi

"For a mine section comprising 100 different stoping activities, there are ~10158 different possible stoping sequences to explore in the mine schedule optimization search and this figure is indicative of the challenge posed in maximising profitability through mine schedule optimization. Any viable excavation timetable must satisfy all conditions that will constrain feasible sequences. In general, consideration of additional constraint will tend to reduce profitability. Geomechanical constraints on mine schedules, introduced with the aim of avoiding excavation instabilities, can be established for underground mine schedule optimization processes but, currently, this is done only rather crudely; precedence relations between excavation activities (stoping or development) are encoded to produce particular stope sequence patterns (e.g. ‘chevron’ or pyramidal sequences).The work reported aimed to investigate automated processes for formulation of such geomechanical constraints. The timetable optimization approach to the problem precipitated a fresh look at time dependent, and excavation sequence dependent, deformation. Abundant evidence emerged that supported the notion that any methodology developed that failed to account for such time and sequence dependencies was itself bound to failure. Yet, it was also recognised that any deviation at all from an assumption of linear elasticity for geomechanical numerical modeling, adopted to inform geomechanical constraint formulation, would rapidly lead to impractical levels of computational effort.Thus the approach presented here represents a compromise: the elastic stress fields induced by individual mining activities are computed for each activity, independently considered within a computational domain identical to that of all other activities. These are stored in a database. Instability risk for a specific sequence of mine activities can be assessed through superimposition of stress fields drawn from the pre-computed database. Time stamps allocated to events corresponding to the excavation processes permit the conversion of the sequence of elastic stress fields into a time table of stress fields. For specific locations within the computational domain, the aggregate effect of the sequence of mine activities leads to stress-time histories having a castellated appearance, a result of the near instantaneous response of an elastic medium to the excavation perturbations. Time dependent deformation responses are crudely allowed for through the re-profiling these castellated histories through graphical construction of curved responses, where the curve gradients are related to a viscous parameter. Such curves form the basis for a geomechanical constraint formulation to be adopted for mine schedule optimization."

Jan 1, 2015

By W. L. Uglow

In recent years, the microscope has come to be recognized as a valuable aid to engineers whose business is the discovery, development, concentration or reduction of metallic ores. In many of the large treatment plants microscopical research has already an important status; and in the hands of efficient operators the microscope has indicated methods of solving ore problems resulting in the saving of thousands of dollars that otherwise might have been lost in tailings, or expended in freight rates or smelter charges. Failure to procure all the information that the microscope can supply concerning the physical and mineralogical characteristics of complex ores has in many cases led to the construction of unsuitable concentrators, just as the failure to investigate in detail the geological conditions of an ore deposit has often results in the squandering of money on shaft sinking, and mechanical installations which subsequent development of the deposit failed to justify. The great progress recently made in the selective separation of minerals by means of the various processes of flotation and leaching brings strongly to our attention, the scope of the field in which microscopical methods may be advantageously employed. The microscope enables one to observe the minute details of rock, ore, gangue, concentrate, tailing, matte, slag and metal, that are invisible to the naked eye. Furthermore, the technique of microscopal research has been so highly developed that a microscopist can not only observe, but deter-mine the compositions and measure the diameters of the mineral constituents in the ore to be treated. Magnifications of these constituents up to 3,000 diameters may be produced by the proper combination of eyepiece, objective, and projection apparatus, and the images thus viewed may be photographed through the microscope, and permanent records made of them.

Jan 1, 1924

By Z. Zhang, M. -Y. Liu, X. -G. Chen, F. Breton

"The microstructures of AlSi10Mg foundry alloy in permanent mould (PM) and high pressure vacuum die (HPVD) castings were analyzed and compared. The as-cast microstructures of two castings mainly consisted of eutectic silicon particles, primary Mg2Si and Fe-rich intermetallic phases. The surface layer in HPVD castings, which has a unique feature and different structures, was carefully characterized. The dimension variation of microstructural phases along the cross section in PM samples is less than that in HPVD samples, although the size of microstructural phases in PM samples was much larger than that in HPVD samples. The mechanical properties of PM and HPVD samples were evaluated on as-cast and T6-treated conditions. The tensile properties of HPVD castings are remarkable better than those of PM castings on the as-cast condition. The T6 heat treatment greatly improves the tensile strength of PM castings while it has limited impact on the tensile strength of HPVD castings.INTRODUCTION The AlSi10Mg alloys are widely applied to the high pressure die casting (HPD) and high pressure vacuum die casting (HPVD). In the HPD process, the melt is injected into the die cavity under a high speed (30–50 m/s in the gate velocity for aluminum alloys), and solidified under a high pressure (up to 200 MPa in the cavity) and with a high cooling rate (up to ~103 Ks–1) (Gourlay, Laukli & Dahle, 2007; Ji, Wang, Watson & Fan, 2013). This results in a unique microstructure feature that is different to other casting processes under gravity. One major concern in HPD castings is porosity due to trapped air in the cavity (Ji et al., 2013), which seriously restricts the application of a heat treatment on the improvement of mechanical prosperities because of the formation of blisters on casting surfaces. For the process improvement, the high pressure vacuum die casting was developed in 1980s (Uchida, 2009). In this process, the melt is injected into the die cavity under reduced pressure (vacuum), which greatly reduces gas porosity in castings due to effectively avoiding the trapped air. Consequently, HPVD castings are heat-treatable without the formation of blisters on castings surface during heat treatment. The HPVD process has been widely applied to produce high quality structural castings in recent years attributed to reliable vacuum system development (Uchida, 2009). However, the microstructure features of HPVD castings are not systemically characterized yet."

Jan 1, 2018

By M. Mahdi Aboutalebi, Roderick I. L. Guthrie, Mihaiela Isac

"A preliminary computational fluid flow model has been developed to simulate the flow field of liquid steel in the mold region of billet mold casting. This study reports the effect of different Submerged Entry Nozzles (SEN) on the fluid flow in round and square billet, curved mold, casters. In this study, ANSYS Fluent 14.5 software was used to model the 3-D turbulent flow of liquid steel. The standard k-0 model was used to simulate turbulence in the mold region. Similarly, the species transport equations were discretized to simulate the dye injection test into the mold cavity. The behavior of flow in the mold region was validated against previous experimental work. Predicted results showed that different nozzle types plus the slight curvatures in the molds can significantly influence the flow patterns generated within the mold region, and thereby affect the finished quality of the billet products.INTRODUCTIONConventional Continuous Casting (C.C) processes are presently used to solidify more than 95% of the 1.5 billion tons of steel now produced in the world annually (World Steel in Figure, 2014). This overwhelming contribution of C.C processes for steel production is the prime motivation for this study, in order to understand and optimize the casting processes and thereby reduce internal defects and minimize energy consumption. The primary objective of all C.C processes is to maintain liquid metal purity during the casting process and to create a uniform flow within the caster so as to avoid internal and external defects. In this regard, studying fluid flows in the mold region of continuous caster has attracted many research groups, in both academia and industry, in recent years. The mold region is one of the most critical parts of the C.C. process, in which the transport phenomena associated with this region can significantly affect the quality of the final products. Thus, proper control of fluid flows within this region can be expected to greatly decrease both internal and surface defects such as Oscillation Marks (OM), inclusion entrapment, and Mold Powder Entrapment (MPE). In the casting process, the fluid flow in the mold region can be affected by a number of variables, such as; the flow control system (stopper rod or slide gate), nozzle geometry, SEN (Submerged Entry Nozzle) depth, casting speed, mold dimensions, gas injection, and the application of electromagnetic fields. One of the most influential and easily-changed fluid flows are the jets of steel issuing from the SEN. Nozzle geometries are variable, consisting of a number of exit ports, different port angles, and/or port sizes, the bottom shape of the nozzle, and the SEN immersion depth (Thomas, 2001). The SEN characteristics can markedly affect meniscus surface velocities, surface level profiles, and turbulence levels that can vary in terms of the frequency and the magnitude of their fluctuations."

Jan 1, 2016

By F. J. Guevara

A two-dimensional mathematical model for fluid flow and heat transfer in a sixin- line electric smelting furnace was developed to study the effects of temperature on slag viscosity in both the liquid and mushy zones. The model focused on the fluid dynamics of the molten slag and the effects on the formation of a slag freeze layer on the hot face of the furnace wall. Previous experimental and mathematical work, carried out under Ra number of 109 and using a fluid with Pr number of 65, showed that it is possible to mathematically describe the freeze layer formation over a vertical wall using a fixed-grid model. The chemical composition of the slag was taken into account through its effect on the viscous activation energy as well the solidus and liquidus temperatures. The results show that the flow pattern is strongly modified in areas of high viscosity, in front of the cooling system and at the slag-matte and slag-calcine interfaces. The results are discussed in terms of heat flux over the refractories and their effects on cooling system design.

Jan 1, 2007

By M. Cala

Underground coal gasification is technology which enables energy to be extracted from coal beds where mining by means of classical methods is either impossible or uneconomical. The process of coal gasification itself is a complex phenomenon which includes chemical and physical processes: thermal, hydrological and mechanical. Additionally, the analysis of underground coal gasification is difficult to carry out for environment reasons, this being due to the local characteristics of the areas where it is carried out. This paper deals with interaction of geo-reactor with surrounding rock mass, it omits the chemical processes inside geo-reactor itself. Due to the complexity of the processes proceeding and during underground coal gasification coupled with minimal practical experience in using this technology, it is difficult to estimate its influence on the surrounding rock mass. Within this scope, the use of numerical programs can be useful. This paper presents a trial of modeling the processes accompanying underground coal gasification. The processes proceeding and during the underground coal gasification are characterized, and the significant, specific phenomena are discussed, with respect to the influence on the surrounding rock mass. For the chosen processes, examples of numerical calculations are presented. These enabled conclusions to be drawn and also provided directions for the modeling of the underground coal gasification processes.

Aug 1, 2013

By Michel Épiney, COREM, Mario Drapeau, Caroline Olsen, Claude Bolduc, Benoit Levasseur

"Several metal sulfide minerals (such as copper, zinc and iron), generally abundant in precious metal-containing ores, are known to dissolve during the cyanidation process. These unwanted reactions consume a significant amount of cyanide and oxygen, which is required for the extraction of gold and silver. Leaching kinetics of sulfide minerals are very fast in contact with oxygenated cyanide solutions. Therefore, the solution quickly becomes charged with oxidation products that are mostly metal ions, metallo-cyanide complexes, metal oxides and other sulfur species including thiocyanate, sulfides, polysulfides, thiosulfate, sulfites, sulfates, etc. COREM’s Extractive Metallurgy team has been conducting a research program on the improvement of the gold cyanidation process. As a part of this program, the current study aims to investigate the effect of certain operating parameters on the reactions involved during pre-oxidation and cyanidation. The effect of pre-treatment under ozone was investigated using an industrial pulp recreated from process water (charged with thiocyanates) and homogenized flotation tailings material from Agnico Eagle's LaRonde mine. In terms of mechanisms, the ozone treatment provides a complete deactivation of the material surface (characterized by EDTA extraction) and the solution (characterized by Ionic chromatography). This resulted in a lower reactivity of sulfide minerals that led to substantial gains in terms of consumption of cyanide and thiocyanate formation during the cyanidation process. The ozone-pre-treatment edges the classical pre-oxidation treatment (such as oxygen, hydrogen peroxides, etc) providing a quicker deactivation of the sulfide matrix and higher reagent savings in subsequent cyanidation process.INTRODUCTIONThe presence of sulfur in the process of gold leaching by cyanidation is a major drawback to optimizing the reagents consumption with suitable operating conditions. The coexistence of sulfide mineral species, such as pyrite, chalcopyrite, pyrrhotite or sphalerite along with the gold-bearing ore have, indeed, a negative impact on the extraction of precious metals by cyanidation (Bayat et al., 2003), (Azizi et al., 2010). These minerals are known to dissolve with cyanide under alkaline conditions and release in the slurry different kinds of sulfide by-products like polysulfides, thiosel, sulfite and sulfate (Seal II & Hammarstrom, 2003) (Breuer et al., 2008a), (Marsden & House, 2006) (Ghasemian Langeroudi et al., 2013). Once these sulfide by-products are released in solution they react with cyanide to form thiocyanate (Marsden & House, 2006) (Breuer et al., 2008b). The consequence of the dissolution of these cyanicides, is a significant increase in cyanide consumtpion as well as a slow-down of gold extraction."

Jan 1, 2016

By P. H. Rodriguez

The aquatic hazard classification system of the OECD and EU requires that sparingly soluble metal substances (SSMS) be tested using the OECD Dissolution/Transformation protocol in order to quantify the release of the ecotoxicological relevant species (dissolved ions). The SSMS category contains massive forms of metals, which due to their low solubility and slow transformation characteristics are a special case. The main factors that produce the release of metal into solution are exposed surface loading, pH, and stirring rate. The classification system at present prefers the use of mass loading as opposed to surface loading, in which case the amount of metal released will primarily be a function of the pH, and mass loading. Within the framework of the European Copper Voluntary Risk Assessment, coordinated by the European Copper Institute, we have proposed and developed a methodological procedure in which we demonstrate that surface area is an intrinsic property of a SSMS and we link the exposed surface loading to the toxicity reference value in order to obtain an aquatic hazard classification for massive metals. As example, the aquatic hazard classification for copper massive will be discussed. This approach is recommended for metal massives and metal powders.

Jan 1, 2007

By M. Abumiya, N. Onodera

"The synthesis of large scorodite particles in non-ferrous metallurgical industries usually requires a high-cost operation involving heating and high-pressure autoclaving. To overcome these obstacles, an atmospheric-pressure process for scorodite synthesis (DMSP®) was developed, in which ferrous ions were oxidized by oxygen gas in the presence of pentavalent arsenic ions. This process gives scorodite of good crystallinity with particle sizes as large as 15-20 µm. The solutions used for scorodite synthesis in the DMSP® are prepared from various residues containing arsenic from non-ferrous smelters. The solutions may be contaminated with Cu, Sb, and Bi, for example, and therefore the effects of such impurities on the formation of crystalline scorodite need to be investigated. In this study, the effects of Cu, Sb, and Bi contaminants on the formation behaviors of scorodite particles in the DMSP® were investigated systematically.INTRODUCTIONThe synthesis of crystalline scorodite (FeAsO4·2H2O) is a suitable method for arsenic (As) stabilization and storage of As-containing by-products such as flue gas dusts in non-ferrous smelters. It is expected that the formation of large, highly-crystalline scorodite particles would be an ideal method for avoiding the release of arsenic to the environment. Generally, autoclave methods under pressurized oxidation conditions at temperatures above 100°C have been used for the formation of arsenic minerals such as scorodite. However, the autoclave method requires sealed vessels that are resistant to high pressure, heat and acids. This process is also unfavorable on account of the high construction expenses, and high running costs as a result of vapor heat loss. Processes for synthesizing scorodite under atmospheric conditions at temperatures below 100°C which do not need an autoclave have therefore been extensively investigated (Demopoulos, Droppert, & VanWeert, 1994; Demopoulos, 1996; Demopoulos, Lagno, Wang, & Singhania, 2003; Droppert, Demopoulos, & Harris, 1996; Filippou & Demopoulos, 1997).Recently, Fujita et al. (Fujita, Taguchi, Abumiya, Matsumoto, Shibata, & Nakamura, 2008a, 2008b, 2009; Fujita, Taguchi, Kubo, Shibata, & Nakamura, 2009; Fujita, Taguchi, Shibata, & Nakamura, 2009) developed a new method for producing large scorodite crystalline particles with improved filtration and washability properties at normal atmospheric pressure and temperatures below 100°C. In the new method, oxygen gas (O2) is blown into solutions containing a high concentration of arsenic ions (As(V)) and ferrous ions (Fe(II)). The Fe(II) ions were subsequently oxidized to ferric ions (Fe(III)), resulting in the formation of large scorodite particles. High supersaturation of solutes such as Fe(III) will result in excessive nucleation, and the formation of poorly crystalline phases. The scorodite formation must therefore be conducted in a manner that avoids the critical supersaturation level being exceeded. It is supposed that the oxidation of Fe(II) to Fe(III) by O2 gas in the new method suppressed the supersaturation of Fe(III) during scorodite formation. The low Fe(III) supersaturation resulted in formations of highly crystalline scorodite particles of size of around 20 µm. In June 2008, based on the developed process described above, DOWA began experiments to verify the industrial capability of a plant with a capacity of 30 MT/month of As. It was successfully proven that it is possible to produce crystalline scorodite industrially on a commercial scale. This process was named and trademarked as DMSP® (Kubo, Abumiya, & Matsumoto, 2010)."

Jan 1, 2012