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By L. R. Bottomer, G. M. Leary

"The Copper Canyon property is located in the Galore Creek area of northwestern British Columbia. Porphyry copper-gold mineralization on the property is notable for its high gold content and close spatial relationship with a distinctive suite of high level syenitic and monzonitic intrusions, and pseudoleucite-bearing volcanic country rocks. The style of alteration and mineralization is similar in many respects to the nearby Galore Creek deposits.The current geological resource of 32.4 million tonnes grading 0.75% Cu, 1.17 g/ t Au and 17.1 g/t Ag is insufficient to support a mining operation, but definition of additional reserves combined with improved transportation infrastructure in the region may change this in the future. The climate, topography and proximity to an active glacier indicate that the most likely production scenario is an underground bulk mining operation, with the ore being milled offsite.IntroductionThe property is located at 57°07' North latitude, 131 °21' West longitude, on NTS sheet 104G/ 3W, approximately 160 km northwest of Stewart and 90 km south of Telegraph Creek (Fig. 1). The Galore Creek camp and airstrip are located 6 km to the west. Current access to the property is via helicopter either from Galore Creek, or from the Bronson Creek airstrip 32 km to the south-southeast.The deposit occurs within the Boundary Ranges of the Coast Mountains, on the north side of the east fork of Galore Creek, which flows northerly into the Scud River and thence westerly to the Stikine River.Topography is rugged. In the deposit area, elevations range from 1130 m to 1750 m. Valley glaciers and permanent snow and ice fields are characteristic of the region at these elevations, and at its southern limit, mineralization is truncated by the East Fork Glacier.The property is entirely above the treeline, and except for areas of moraine cover and talus slopes, outcrop is abundant."

Jan 1, 1995

By M. Abumiya, N. Onodera

Stabilization of arsenic via the precipitation of large-sized scorodite (FeAsO4·2H2O) particles usually involves the use of expensive autoclave systems operated under high temperature and pressure conditions. Alternatively, DOWA developed a novel scorodite synthesis process (DMSP®) wherein the Fe(II) ions in solution containing As(V) ions were oxidized by O2 gas under atmospheric pressure. In this process, crystalline scorodite particles were formed via the formation of a gel-like precursor containing Fe(II). Based on this concept, in this study, we have demonstrated the synthesis of scorodite particles by the addition of Fe(III)-containing solution to the experimental solution containing Fe(II) and As(V) ions, without the O2 gas oxidation process. Ferric sulfate (Fe2(SO4)3) was used as the source of Fe(III) ions. Results indicate the precipitation of scorodite particles, comparable to that of the O2 gas oxidation method.

Jan 1, 2014

By A. A. Iranzadeh

The performance of a tunnel boring machine (TBM) depends on the efficiency of the cutters, which can be influenced by geological conditions and rock mass properties. In this study, a three-dimensional numerical model, based on a discrete element method, was used to evaluate the effects of joint orientation and its spacing on the fragmentation process by a TBM cutter. Several models were constructed to study the effects of variable orientation; these models incorporated different spacing, variable spacing, different orientations on the fragmentation process, and different sections of the block model. Three parameters, consisting of induced tensile stress, induced shear stress and maximum displacement, were calculated. The stress in each section that forms chips was considered as critical stress; critical joint spacing and orientation in each section were determined. Results show that the critical orientation was in the range of 45 to 60º, where there was a possibility to achieve the maximum penetration rate. The critical joint spacing was 200 mm and, by increasing joint spacing, the value of critical stress decreased significantly. Furthermore, joint orientation could influence more than joint spacing in the rock cutting process.

Jan 1, 2009

By G. Hamel

The LCL&L process (Low Caustic Leaching & Liming) is a patented hydrometallurgical route developed by Rio Tinto Alcan (RTA) to economically process spent pot lining (SPL) generated by aluminum cells. The three resulting end-products (carbonaceous, fluorinated and caustic liquor) are inert and have valorization possibilities. An industrial size pilot plant located in Saguenay (Quebec) was inaugurated in mid-2008 to demonstrate and optimize the technology. This paper describes characteristics of the LCL&L process and the experience acquired by RTA since the plant's start-up, including ramp-up capacity and technology challenges that were overcome. Possible end-products valorization methods are also presented. The carbonaceous end-product can be separated into carbon and brick rich fractions and used as either alternative fuel, reducing agents, or as raw material for third party processes. The development of a conversion process for the fluorinated end-product would allow its reuse as a substitute to fluorspar mineral for aluminum fluoride production. Finally concentrated caustic liquor is already valorized at the nearby RTA Vaudreuil alumina refinery.

Jan 1, 2011

By T. T. Wang, T. H. Huang, Y. C. Chiu

Quantitatively analyzing deformation of a tunnel with lining anomalies for structural safety evaluation is essential for sustainable tunnel engineering. However, a complete theory and associated methodology accounted for displacement of a built tunnel is absent. This manuscript introduces a novel characteristic matrix method proposed by the authors which is an integrated procedure that analyzes displacement of rock tunnels in operation. First, establish a numerical model expressing a specific state of the tunnel in interest. Derive the characteristic displacement modes by a unit disturbances and check their independency. Once the characteristic displacement modes are proved to be orthogonal (independent), they are ready for use. Given a tunnel displacement, modal decomposition returns the magnitude of each characteristic displacement modes that together consist the given displacement. By realizing the definite value of horizontal and vertical translation, rotation, uniform compression/expansion, elliptic deformation, triangular deformation…etc. for a tunnel displacement, one can distinguish tunnel displacement and deformation types from their modal composition. A circular tunnel with elastic structure and surrounded by elastic rock mass is chosen to demonstrate the outcome of characteristic modes and how they work. The influences of tunnel shape, elastic modulus ratio between rock mass and tunnel structure, and numbers of monitoring points on a tunnel profile were also discussed. Identifying possible tunnel deformation causes is attainable if further connections between mode combination and force increments were built.

Jan 1, 2015

By Peter N. Calder

The orientation of planes of inherent weakness (joints) with reference to an excavation in rock is the critical factor determining stability. The purely frictional 'residual' strength remaining following the breakdown of initial cohesion is the only strength which can be counted on to resist sliding for the long term. A simple method of resolving driving and resisting forces in three dimensions along joint intersections 'undercut' by the excavation is presented. Contrary to the case of slope failure in soils, it is shown how significant changes in the slope angle sometimes have no effect on the degree of stability pre-sent in rock slopes. Wall control by reorientation of the slope, the use of cable bolts and water diversion are briefly discussed.

Jan 1, 1970

By M. M. Holgate

"Porosity neutron deflection scales can be derived more easily by cumulative correlation than by the conventional method of plotting corresponding points on a graph. The micro-log can be used as a porosity datum for the neutron log by transforming the permeability cut-off it shows to a porosity cut-off by a permeability-porosity function obtained from core analysis. Porosity footage values calculated in this manner from the neutron log are within 20 per cent of core analysis values."

Jan 1, 1960

By J. T. McGrath, R C. A Thruston

The structural changes which take place in polycrystalline copper under the action of alternating cycles of torsion stress were studied, using the optical microscope and the X-ray dif-fraction camera, and an attempt was made to correlate them with changes in the shape of the cyclic stress-strain curve. It was found that the period of work-hardening was less than one per cent of the fatigue life, and that persistent surface marking, which are assumed to be incipient or actual microcracks, occur upon completion of work-hardening. X-ray diffraction patterns revealed considerable grain distortion at the completion of work-hardening in specimens cycled at a high strain amplitude. This distortion became progressively less as the strain amplitude de-creased. Mechanisms for the completion of work-hardening and the formation of microcracks are discussed.

Jan 1, 1962

By Dogan Paktunc, Larry J. Hulbert, Robert C. Carne, D. Conrad Gregoire

A thin layer of stratiform Ni-Zn-PGE sulfide mineralization of sedimentary-diagenetic origin was deposited during the Middle to Upper Devonian in the euxinic "Nick basin". The mineralized unit (=3 cm thick), which seems to have been developed over the entire sedimentary basin of > 80 km2, consists of pyrite, vaesite (NiSz), and sphalerite. The average grade of the mineralization is about 5.30/0 Ni, 0.73% Zn, =770 ppb (pGE+Au), and up to 61 ppm Re. Anomalous Se, As, Mo, P, Ba and U are present. A minimum of 0.90 x 106 tonnes of Ni were deposited in the basin (based on a bed thickness of 3 cm) during the Devonian. The unique metal association, extensive lateral distribution, persistent metal grade, mineralogical makeup, and stratigraphic control demonstrate that this is a new deposit type and a new geological environment for Ni and PGE + Au. The sulfide layer occurs at the base of a Phosphatic Chert Member which is underlain by a distinctive marker unit consisting of concretionary limestone structures. The limestone spheroids may represent a vent-specific carbonate facies developed adjacent to faults that emanated nutrientrich hydrothermal discharges just prior to the main mineralizing event. The suite of elements associated with the Nick mineralization suggests that the ore-forming metals were originally bound to organic matter derived from decaying marine organisms. Discharge of hot brines bearing organic matter-bound metals took place along numerous conduits within basin faults that are now manifest as bitumen veins. Our syndiagenetic model proposes that these fluids were discharged laterally from the conduits into the unconsolidated bottom sediment (ooze). The introduction of this metalliferous fluid, rich in organic matter, stimulated biological activity and bacterial reduction of its contained 804 to sulfide. Hot, dense, laterally migrating hydrothermal fluid precipitated thin sulfide-rich larninae within bottom sediment. Published thermodynamic studies suggest that the diagnostic vaesitepyrite assemblage crystallized at approximately 138°C. The 034S values range from -14.7 0/00 to -10.00/00 and are up to 340/00 lighter than locally surrounding sulfides and age-equivalent mineralized strata elsewhere in the Selwyn Basin. The Ol3C values of calcite in the footwall of the mineralized unit (- 12 0/00 to -6 0/00) are isotopically much lighter than regional values. The lighter isotopic character is attributed to the hydrothermal discharge of fluids enriched in organic compounds. Although geochemical profiles of the lower Earn Group sediments that host the Nick mineralization reveal that these black shales are not distinctive, the unusual Ni, Zn, PGE, U, Ba, and P elemental associations and their anomalous concentrations in stream sediments can be used to explore for this deposit type.

Jan 1, 1992

The rate of liquid copper deoxidation during top blowing of reducing flames has been investigated using a high capacity thermogravimetric unit at 1200 °C. For 1 kg copper samples, it was observed that the rate of deoxidation was proportional to the flow rate of the reducing reagent (H2 or CO). Under similar experimental conditions, it was found that H2 is more effective than CO even though both have similar thermodynamic potential to deoxidize liquid copper. The rate of deoxidation of liquid copper with reducing 0 2/CH4 flames was measured for 0 2/CH4 molar ratios of 1.5 to 2. The deoxidation rate depends on the 0 2/CH4 ratio and decreases as it approaches the stoichiometric ratio (02/CH4 = 2). Estimation of the rate of deoxidation of liquid copper with top blowing flames based on the thermodynamic composition ofH2 and CO in the product gases, agrees well with measured values.

Jan 1, 2007

By V. J. Hucka, J. H. Tu

"A computer model has been developed for evaluating the performance of truck and shovel operations in an open-pit mine. The data required for describing the haulage network are simplified and shift startup and ending procedures specific to any given mine can be incorporated into the model readily . The model uses a FORTRAN-based simulation language SLAM and can be tailored to the conditions and practices of a particular mine.The model is used to analyze truck and shovel operations, evaluate different haulage layouts in the planning stage, or compare the expected performance of alternative truck dispatching systems.Stochastic simulation is used to model the random variation in time required f or the individual activities. This gives a more realistic representation of the processes under study. Simulation runs show good agreement with actual performance. The model is especially useful for examining alternatives in equipment acquisition , haulroad design, truck-shovel allocation and dispatching methods. The results of such simulations provide a sound basis f or making major management decisions.IntroductionTruck haul age is widely used in open-pit mining operations. It is also the largest cost item in the operating costs of an openpit mine, in some cases accounting for an estimated 50% of operating costs(1) , Truck replacements, which are necessary from time to time, involve large amounts of cap ital. Increasing depth of mining and consequent increase in stripping ratios require additional capital investment in the truck-shovel fleet. The sharp rise in energy costs over the last decade has also contibuted significantly to an increase in truck fleet operating costs . All these factors have led mine operators to search for ways to improve the effectiveness of the truck-shovel fleet, in order to lower costs and maintain a profitable operation in the face of declining markets and increasing world wide competition.Control of truck haulage in an open-pit mine is usually done in one of two ways."

Jan 1, 1985

By J. B. Hinzer, J. D. Harvey

"Noranda's Lyon Lake property in the Sturgeon Lake area of Northwestern Ontario was staked by Mattagami Lake Mines Limited in May 1969 to cover airborne Input anomalies. Subsequent ground geophysical and diamond drilling programs resulted in the disco very of the Boundary Extension, Lake and Creek ore zones. As of December 31, 1978, ore reserves were estimated at 3,945,000 tons assaying 6.53 per cent Zn, 1.24 per cent Cu, 0.63 per cent Pb, 3.42 oz/ton Ag and 0.010 oz/ton Au.These deposits are hosted within the South Sturgeon Lake volcanic pile of Archean age, which consists of several cycles of basic intermediate and felsic volcanic materials overlain by a sedimentary iron formation and built upon a plutonic base (Franklin , ' 1975). The top 50 m of the second felsic cycle, according to mine terminolo gy, contains the mineralization within Quartzphenocryst- bearing felsic lapilli tuff and underlying thin discontinuous graphitic sediments and altered coarse pyroclastics. The basal andesitic member of the overlying cycle forms the hanging wall to the ore deposits.Although there is no alteration pipe below the deposits, the coarse footwall rocks are permeated by chlorite, garnet, carbonate, iron sulphide and magnetitie-bearing veins intensifying from west to east.Immediate host rocks are alkali depleted and MnO, FeO, Zn and Cu enriched compared to Goodwin's (1972) average Archean rhyolites. Bedded pyrite-pyrrhotite-chalcopyrite lenses with sphalerite-rich tops are underlain by weakly developed stringer mineralization.Traversing eastward from the Lake Zone to the Creek Zone and toward the Sturgeon Lake Mine deposit, more rapid facies changes, more pronounced chloritic and carbonate alteration, the presence ofgarnets, greater MnO, FeO, CaO and Ag abundances, and increasing Zn/Cu and MnO/FeO ratios are apparent."

Jan 1, 1981

By Albert G. Zima

THE conservation of strategic materials during war rime gives rise to many problems not commonly encountered in times of peace. During normal times, when world trade is unrestricted, we are apt to become lavish to a point of extravagance in our use of those materials which, during rime of war, become scarce owing to inadequate transportation and production facilities or because the enemy may be in position to control sources of supply. It becomes necessary, then, to enforce rationing of available sup-plies, and in some cases, where such supplies are wholly inadequate, we find we must resort to the use of substitute materials. We are now confronted with such a problem to an extent never before experienced, with the result that many of the commodities upon which our civilization depended are now either shut off completely or, because of the heavy demand occasioned by war production, are not available in sufficient quantities to meet requirements predicated on peace-time standards and manufacturing methods. It has become necessary, therefore, to make many changes, some of them very drastic indeed, to enable us to carry on our war effort effectively. This? discussion will deal briefly with one phase of this problem, namely, the conservation of alloys required in the making of steels necessary for war production. In line with a request from the War Production Board, the Technical Committee on Alloy Steels of the American Iron and Steel Institute made a study of experimental steels embodying the !east amount of alloying constituents, with the objective in mind of substituting these steels wherever possible for the standard alloy steels used heretofore. This study embraced the following phases: (1) The availability of silicon and manganese; (2) The average quantity of alloying elements recoverable from scrap; (3) The effect of increases in manganese and silicon contents on the general properties of steel; ( 4) The elements and ranges of elements which might be used to duplicate the hardenability of the steels now in use; (5) The effect of combining several elements in small quantities upon the properties of steel at various hardness and strength levels; (6) A determination as to whether or not the steels selected would suffice for general application. Working on this basis, the Committee arranged for the manufacture of several heats of steels containing various combinations of different amounts of such elements as silicon, manganese, chromium, nickel, and molybdenum. The steels thus produced were compared by hardenability tests.

Jan 1, 1943

By A. Shakoor, T. P. Gautam

The long-term slaking behavior of clay-bearing rocks in the field can be quite different than the short-term slaking behavior in the laboratory. To assess this difference, 12 replicate samples of each of 20 clay-bearing rocks, including 5 claystones, 5 mudstones, 5 siltstones, and 5 shales, were exposed to natural climatic conditions for 12 months. After each month of exposure, one replicate sample of each rock was removed from natural exposure and its grain size distribution was determined. Disintegration ratio (DR), defined as the ratio of the area under the grain size distribution curve of the slaked material for a given rock to the total area encompassing all grain size distribution curves of the tested samples, was used to quantify the amount of disintegration under natural climatic conditions. DR values of naturally exposed samples were then compared with the corresponding values of second-cycle slake durability index (Id2) determined in the laboratory. The relationship between Id2 and DR after, 1 month of exposure, exhibits an R2 value of 0.65 but the relationship deteriorates when DR values for 6 and 12 months of exposure are used, with R2 values of 0.63 and 0.25, respectively. However, when DR values for laboratory samples, computed from grain size distributions of slaked material after second cycle, are compared with DR values of naturally exposed samples for the three periods of exposure, the relationship improves with the corresponding R2 values being 0.61, 0.71, and 0.41. These results suggest that DR may be a better parameter for assessing the long-term disintegration behavior of clay-bearing rocks than Id2.

Jan 1, 2015

By M. M. C. Lima, L. C. S. Solimani, M. A. Quintela

Galvanized steel scrap is recycled to B OF converters where zinc escapes from the bath and is captured by the gas control system, appearing in BOF sludge. As BOF sludge contain high iron content, it could be recycled, but due to its zinc content, it is disposed in landfills. In this study techniques were evaluated for zinc layer removal from scrap by sulfuric acid leaching. The effects of coating weight, temperature, time and sulfuric acid concentration were evaluated for three different galvanized scrap. The results showed that the behavior of each galvanized scrap was different. Nevertheless zinc removal efficiency was more than 80% with low dissolved iron in the leached solution.

Jan 1, 2011

By D. J. Xue

Four kinds of coal-rock combination were subjected to three kinds of stress waves in the SHPB numerical simulation. The wave propagation and the changes of the strain energy in the coal-rock combination during the dynamic impact process were recorded as well as the contact force. The dynamic response law of coal-rock combination was obtained. It was found that the coal had better reflectivity than the rock because of coal with larger impedance. In contrast the rock had better transmissivity. As the crest value of the incident wave increased, the increment in the crest value of the transmitted wave weakened in the coal-coal group, coal-rock group and rock-coal group, in contrast, the increment in the rock-rock group increased.

Aug 1, 2013

By Namavari. H., M. Ashouri, M. R. Sarhadi, S. H. Mansouri, A. Sarrafi

The splash phenomenon and its effective parameters in metallurgical converters have been studied thoroughly for decades. The detailed studies of processes such as tuyere blockage, wave formation during air injection, entrapped phases, and also processes which control the formation of bubbles in viscous fluids are not feasible yet. In this research, we have used a converter-shaped vessel made of flexi-glass. Water and oil have been used as matte and slag phases respectively. The effective operational factors responsible for creation of splashing have been studied such as air flow rate, tuyere angles, depth of tuyere submergence, tuyere blockage, density and viscosity of liquids, liquids heights, etc. The results have been found as follows: the amount of splashing increases slowly as air flow rate increases. However, as the air flow rate reaches a critical value (depending on the physical specification of converter) the amount of splashing rises sharply, because the flow of air inside the liquid changes from bubbling into a jet stream; and most of the splashed materials are in the form of filaments instead of droplets. Changing tuyere angle from horizontal towards vertical position will increase the turbulence level on the fluid surface and causes an increase in the amount of splashing. The effect of tuyere submergence is related to the converter opening angle. As the converter opening angle is shifted towards the hood position, the amount of tuyere submergence and splashing will increase. As density of the liquid increases, the number of droplets splashing increases with a decrease in drop size. Therefore, the total amount of splashing decreases. However, as viscosity of the liquid increases, the splashing material increases due to the changes in the splashed material from droplet shape into filament form. The height of liquid inside the converter, depending on the relative height of heavy phase and light phase, is an important parameter regarding splashing. As the relative height of heavy phase to light phase increases the splashing will decrease. The tuyere blockage will cause the pressure in the inlet manifold to increase; and in real cases will increase the splashing. Finally, we have development a model based on dimensional analysis to relate the above parameters in order to calculate the amount of splashed material.

Jan 1, 2007

By V. G. Papangelakis, A. Dani

"Alkaline pressure oxidation, particularly in the presence of trona as additive, can be used to oxidize high carbonate refractory gold ores as it prevents the formation of CO2 in the autoclave. However, the presence of silica in the ore can lead to the encapsulation of pyrite due to the solubility of silica in alkaline solutions and its subsequent reprecipitation on the reacting pyrite surface, leading to the formation of a passive layer. This fundamental study investigates the chemical composition and thickness of the passive layer on a rotating pyrite disk using XPS and SEM, as a function of process conditions at 230°C, in an aqueous slurry containing silica sand, sodium carbonate and calcium carbonate under 100 psi of oxygen overpressure.INTRODUCTIONAlkaline pressure oxidation (POX) has been used successfully to treat high carbonate refractory gold ores, which contain carbonates in addition to sulphides, most notably at Mercur and Goldstrike mines operated by Barrick Gold. There are several advantages to using alkaline POX over its acid counterpart, especially due to high carbonate content. First, it eliminates the production of CO2 in the autoclave without resorting to pre-acidification, which allows for high oxygen utilization. Second, alkaline POX suppresses the formation of elemental sulphur and intermediate sulphur oxyanions (such as thiosulphates and dithionates), which reduce gold recovery. Third, the use of sodium hydroxide or salts prevents the formation of anhydrite scale by forming soluble sodium sulphate. Other advantages are the use of cheaper materials of construction and the formation of non-acidic residue that do not require further treatment prior to cyanidation (Thomas, 2005).Sodium carbonate in particular is a promising reagent for alkaline POX because it was shown to significantly accelerate the kinetics of pyrite oxidation by molecular oxygen, when compared to other reagents such as sodium hydroxide, sodium borate and calcium hydroxide. This has been attributed to the following factors: a) the faster oxidation kinetics of Fe2+-CO3 complexes compared to Fe2+ oxidation, b) the buffering effect of carbonate ions on the acidic pyrite surface, and c) the increased solubility of oxidizing Fe(III) species due to carbonate complexation (Caldeira, 2010)."

Jan 1, 2012

By Yongsheng Song, Yong Chen, Wenjuan Li

"Detailed characterization and improved recovery of a micro-fine, low-grade refractory gold ore from a beneficiation plant in Yunnan Province, China, was investigated. Different analytical techniques, such as videlicet size analysis, scanning electron microscopy, and mineral analysis by a Mineral Liberation Analyser, were used for mineralogical characterization of the ore. This paper describes an experimental study on the effect of the grinding fineness and the use of various flotation reagent regimes involving collectors, depressors, and activators on the flotation behaviour of micro-fine auriferous pyrite. Two-stage flotation resulted in high gold grade (32.71 g/t) and gold recovery (80.02%) of the bulk gold concentrate. This process opens the possibilities of maximizing Au recoveries in a micro-fine low-grade refractory gold ore where low recoveries are common.INTRODUCTIONWith the rapid development of the gold industry, refractory gold ores are becoming increasingly important resources for gold production (O’Connor & Dunne, 1994; Agorhom, Skinner, & Zanin, 2012). Among these refractory gold ores, sulfur and micro-grained native gold ores represent a significant challenge, since they are not amenable to gold recovery by direct cyanidation. The gold contained in this type of ore is very finely disseminated and encapsulated in sulfides, which makes it inaccessible to the cyanide solution during direct cyanidation (Bulatovic, 1997; Allan & Woodcock, 2001). Autoclave pressure oxidation (AC POX) of the sulfide ore and subsequent cyanidation is a common technology used to recover the gold in such types of ore. Flotation is often used as a pre-treatment method to refractory gold ore (Monte Lins, & Oliveira, 1997).As the gold-carrier minerals are usually finely disseminated (sometimes under 10 µm) and intimately associated with gangue minerals, a fine grind is necessary to get a high degree of liberation. At the same time, the fine grind usually causes the production of significant quantities of slimes, which comprise easy-to-float gangue minerals such as mica, dolomite, and calcite. These mineral phases are naturally hydrophobic and float readily, competing with the value minerals in the froth phase and resulting in lower concentrate grades."

Jan 1, 2016

By C. A. Sosa-Blanco

Minera Sabinas in central Mexico treats a complex sulfide ore containing galena, chalcopyrite, sphalerite and argentite as valuable minerals, and in some cases important amounts of non-magnetic pyrrhotite. For high pyrrhotite ores, results obtained by selective flotation showed good grades and recoveries in the lead-copper circuit, but a commercial zinc concentrate could not be produced due to the high floatability of pyrrhotite. When this is the case, an alternative method was proposed to produce a bulk concentrate by flotation which is then leached to recover copper and zinc from liquor in a SX-EW circuit. Leaching was conducted in an autoclave in order to study the effect of temperature and pressure, but bioleaching tests were also conducted. Leaching lead-silver residues were treated by cyanidation in order to recover silver values. The results obtained by selective flotation and by bulk flotation with leaching of the bulk concentrate showed that the latter alternative increased zinc recovery by 30 % with similar recoveries of the other metals.

Jan 1, 2007