Search Documents

By Richard J. Haslinger, C. Mark Rebagliati, James L. Oliver

Abstract - Exploration at the Specogna gold deposit has identified a geological resource of 65.0 Mt grading 1.63 g/t Au, which equates to 3 million ounces of contained gold. This resource is hosted in a low-sulfidation epithermal deposit of Miocene age that is localized along the northwesterlytrending Sandspit fault. The fault has juxtaposed Late Cretaceous mudstone of the Haida Formation to the west, with Late Tertiary coarse clastic sediments and lesser andesitic volcanic rocks of the Skonun Formation to the east. A plagioclase porphyritic dacite dike intrudes the Haida mudstone and Skonun sediments along the fault. Gold mineralization, in hydrothermal breccias, veins and stockworks developed mainly in Skonun sediments and dacite. These are formed in an 800 m long zone that roughly parallels the Sandspit fault. The gold zone is funnel-shaped in cross-section, approximately 300 m wide at surface, 220 m above sea level, and narrows to approximately 50 m, at sea level. The deposit lies within an elongate zone of moderate to intense hydrothermal alteration that, at surface, extends over a known area of approximately 2 km2. Its western extent is bounded by the Sandspit fault. There is an asymmetric alteration zonation, with a core of silicic-potassic (adularia) and smectite-illite clay alteration that is bounded to the east by argillic alteration. Similar zoning defined by the distribution of metals reflects the position of the main feeder conduit. Mineralization of altered wallrock is dominated by 1% to 4% auriferous pyrite and marcasite. Gold and silver occur as electrum; individual silver minerals have not been identified. Other sulfides are rare, and are identified only microscopically. The mineral suite is typical of low-sulfidation epithermal systems. Gold occurs in early, multi-phase, variably bladed and banded quartz veins and breccias, which are cut by barren, single phase, drusy quartz veins.

Jan 1, 1998

By A. Roy, T. LeBel, P. Coursol, P. Lind

At the early stage of a mining project, small amounts of concentrates are available for testwork. For gold concentrate or ores containing significant arsenic levels, batch bench scale roasting is often unreliable, leading to highly variable gold recoveries to be used in the project’s financial justifications. With an appropriate bench scale unit using continuous feeding and residence time control for solid and gas phases, reliable numbers can be obtained at small scale with only a few hundred grams per test condition. This paper describes the development of a pilot fluid bed roasting unit by Kingston Process Metallurgy Inc. (KPM) to perform representative trials on gold concentrates containing arsenopyrite, arsenian pyrite and carbonaceous components. Calcines produced under different conditions were characterised by chemical analysis and electron microprobe; the calcine microstructure obtained is described. The most important parameter affecting gold recovery is oxygen content in the roasting atmosphere, with the lowest controlled oxygen level giving the highest gold recoveries. Higher local temperatures in the bed may cause the formation of molten glassy phases which can also reduce the gold recoveries significantly. The impact of roasting conditions in the two inch fluid bed is compared with commercial results obtained in full scale operation.

Jan 1, 2014

By A. Valdivieso

Reducing accident rates keeps getting more and more complex as the usual tools enter a curve of diminishing results. Fortunately, nothing modifies behaviour in a stronger and wider way than having a robust safety culture. On the other hand, managing cultural change is difficult and the risk of back-fire is very high, especially if the workforce does not trust our intentions. A personalized approach of well chosen and targeted actions tends to be the only yet difficult option. We have found, via experience in the metallurgy and chemistry industries, a way of preparing the company and the workforce to accept these sorts of culture changing measures faster and easier. Using company-wide changes based on workplace perception, yields the most optimal acceptance. It is based in the principle that we all use clues in our environment as guides to choose our behaviour. So, controlling the perception that our workplace generates can affect behaviour and simplify our task before it even starts. It is a matter of using the tools that other disciplines such as marketing, social engineering and architecture bring to us and adapting them to a very defined objective: Having our installations “sell” safety so that our people unconsciously believe that they must adapt to safety values in order to “do well” in said environment. INTRODUCTION After decades of improvements in accident rates, we are understandably hitting a diminishing results curve: most actions that spectacularly reduced accidents in the past (e.g., Innovation in Personal Protection equipment, adapting international standards and legislation, and innovative safety programs; Figure 1) now hardly get us the exponential gains we saw years back, regardless of the investment we put on them. Furthermore, the improvements in safety of the last 3 decades have been creating new sets of issues that start to show their face such as: By reducing accidents we can create feelings of invulnerability as we lose view of the consequences. With innovative protection equipment we increase Risk Homeostasis, meaning that people behave in a more dangerous way in order to maintain a constant level of risk in their lives (Getting closer to fire after getting better fire-proof garments for example). Too much Legislation can create a feeling of disengagement from personal responsibility. And despite improvements, we haven’t really solved the production vs safety confrontation, it is now stigmatized and less visible, yet it tends to reappear in moments of weakness.

Jan 1, 2019

By Rodrigo Craig Cerello

The Brazilian economy has always presented a strong correlation with the mineral activity. Since colonization days, due to the territorial expansion caused by the explorers search for gold, mining in Brazil became a basic sector of national economy. Currently, the Brazilian mineral sector¹ estimates a 550% production increment (Figure 1A) in the last 10 years, reaching the US$ 50 billion value, reflecting the increased global demand for raw materials from mineral origin. According to the Brazilian Constitution², mineral resources belong to the Federal State and, consequently, their exploitation must be authorized, under penalty of engendering federal crime. Furthermore, activities of this nature are prone to cause environmental degradation such as, but not limited to, deforestation, pollution, soil deterioration and water contamination. The GPEMA represents the forensics group of the Brazilian Federal Police responsible for the technical analysis of traces related to crimes against the environment and consequently, illegal mining cases.

Aug 1, 2013

By A. Ghahremaninezhad, E. Jorjani, A. Riahi, Islamic Azad University, B. Nazari, H. Hani, Z. Manafi

The presence of a high iron concentration, 9.1 g/L, in the raffinate of the Sarcheshmeh copper heap bioleach process led to the formation of various types of jarosite, (K,Na,NH4,H3O)Fe3(SO4)2(OH)6, on the heap mineral surfaces. This study probes iron removal from the raffinate using a bio-oxidation process based on A. ferrooxidans bacteria in the presence and absence of jarosite seed. The jarosite seed was biologically synthesized using A. ferrooxidans bacteria. The effect of solution pH (1.5 to 2.5) and jarosite seed dosage (0 to 15 wt.%) on iron removal was examined. It was demonstrated that the concentration of iron ions present in the raffinate decreased from 9.1 g/L to 2.5 g/L with the addition of 10 wt.% jarosite seed at pH 2 and 130 rpm mixing rate at 32°C. Three different types of raffinate including (1) native raffinate containing 9.1, 3.4, 5.7 g/L of total, ferric and ferrous iron, respectively, (2) bio-oxidized raffinate in the absence of the jarosite seed containing 8.5 g/L total iron (mainly ferric with negligible ferrous), (3) bio-oxidized raffinate in the presence of jarosite seed containing 2.55 g/L total iron (mainly ferric with negligible ferrous) were used in mesophilic, moderate thermophilic and thermophilic bioleaching processes. The results of the flask tests showed that the highest copper bioleaching recoveries of 9.4, 49.4 and 90.8 % were achieved using raffinate (3) with mesophilic, moderate thermophilic and thermophilic bioleaching processes, respectively.

Jan 1, 2016

By D. -A Tremblay

Dynamic wetting spread factors and interfacial heat transfer coefficients were determined for aluminum droplets solidifying on copper substrates, The spread factors were determined from the droplet geometries while the heat transfer coefficients were obtained by solving inverse heat conduction problems, 1-D and 2-D heat transfer models are presented and the results they provided are compared, For the latter, a sensitivity analysis was also performed to determine the influence of thermophysical properties and boundary conditions. Experiments were alternatively carried out with three different gaseous atmospheres and the dynamic wetting spread factors were correlated to the interfacial heat transfer coefficients.

Jan 1, 2005

By M. Laframboise, M. Buarzaiga

High-pressure acid leaching (HPAL) of nickel laterites has received considerable attention in recent years. High paymetals extraction, good selectivity, and advances in pressure hydrometallurgical technology are some of the reasons for this interest. Falconbridge Limited (Sudbury. Ontario) investigated the HPAL process using both fresh water and seawater for ore processing. The use of seawater resulted in a chloride concentration of 7.8 g/L in the autoclave feed. A test program was developed to study the effect of process water and leach temperature on the leaching behaviour of different ore compositions from the Koniambo deposit in New Caledonia. The work showed that salinity has a major effect on autoclave chemistry. This paper explores the results.

Jan 1, 2004

By C. H. Buck, A. J. Taylor

"In 2015 Vale’s Clarabelle Mill began the process change to enable a higher degree of Cu separation. The flowsheet modification was part of a complete divisional flowsheet change being implemented in Vale’s Sudbury Operations. This paper will centre on some of the Operational Readiness (OR) work, culminating in the commissioning of the circuit in March 2017. The emphasis will be on the implementation of an integrated test plan to prepare for the process flow change through the mill.BackgroundClarabelle Mill (CBM) began making a saleable Cu concentrate in 2006 with the installation of the Cu separation circuit. Typical separation rate was 35-40% of Cu in feed reporting to Cu concentrate based on a target Ni concentrate Cu:Ni target of 0.7-0.8. The remainder of the recovered Cu (55-60%) reported to Ni concentrate and was smelted through the Copper Cliff Smelter.In 2013 a capital project, Surface Facility Upgrade (SFU), was implemented to focus on matching the surface plants capacities with the future mine plan to maximize revenues. This was to be achieved by redistributing the metal flow, specifically Cu, through CBM to increase metal unit content through the Smelter. The amount of redistribution of Cu was determined to be based on maintaining a stable Cu to Ni ratio (Cu:Ni) in the Ni concentrate.The change in Cu:Ni ratio in the Ni concentrate would affect the Sudbury divisional flowsheet, and required process changes across the all of the surface plants. The detail that surrounds the flowsheet changes as a whole will not be discussed, but the outcome of the decisions plays a large role in the operational readiness interactions between the mill, its suppliers and its downstream customers."

Jan 1, 2018

By Q. Li

"The precursor of In2O3 was prepared by hydrolysis precipitation/hydrothermal method using In(NO3)3 solution as the feed material and ammonium hydroxide as the neutralizing agent. The crystallinity, morphology and particle size of the products were characterized by SEM, XRD, BET and LPSA. The results showed that the hydrolysis product consists of an aggregate of cubic In(OH)3 particles with a short rod morphology. In the hydrothermal process, the structure, morphology and size of the particles changes through the mechanisms of Ostwald ripening and phase transition, respectively. When the hydrothermal temperature was less than 280 ?, the Ostwald ripening process took place, which changed the morphology of the particles from short rods to cuboids through dissolution-recrystallization. When the hydrothermal temperature was higher than 280 ?, the processes of Ostwald ripening and phase transition took place successively. Firstly, the morphology of the particles changed from short rods to cuboids through Ostwald ripening, and then, the phase transition from cubic In(OH)3 to orthorhombic InOOH occurred and the morphology of the particles changed from cuboids to polyhedron. INTRODUCTIONDue to its excellent electrical conductivity and optical transparency, indium tin oxide (ITO) film has been wildly used in flat-panel display, solar cell, antistatic coating and EMI shielding (Medvedovski et al., 2008). Indium oxide powder is one of the fundamental materials for preparing ITO film. Along with the development of ITO targets of both high density and large size, high quality indium oxide powders, such as single phase, nano-size, spherical morphology and mono-disperse, have been in high demand (Nakashima and Kumahara, 2002; Betz et al., 2006; Kim et al., 2007). The main preparation methods for indium tin oxide or indium oxide powders include chemical precipitation (Nam et al., 2001; Xu and Yu, 2007), melt atomizing-combustion (Chen et al., 2000) and spray pyrolysis (Ogi et al., 2009). Among them, chemical precipitation has been preferred, since it is simple, easy to control and suitable for industrial scale-up. In chemical precipitation method, indium oxide powders were prepared through the following steps: firstly, indium hydrate precursor was precipitated from an indium salt solution by neutralization using an alkali, such as ammonia; and then, indium oxide (In2O3) powders can be obtained from the precursor through calcination (Li et al., 2006), or solvothermal method (Lee and Choi, 2005), or hydrothermal processing/roasting (Xu et al., 2005; Chen and Li, 2007), respectively. However, the indium oxide powders obtained by direct roasting are polycrystalline, dispersable with a wide size distribution (Liao, 2006). The disadvantages of the solvothermal method are high cost, complicated after-treatment processes, as well as bad performances of the powders (Udawatte and Yanagisawa, 2000). Therefore, among three methods of obtaining indium oxide from the hydrolysis precursor, the hydrothermal process/roasting method is the most feasible to synthesize high quality In2O3 powder with uniform crystallinity and size (Kim et al., 2002; Zhu et al., 2004; Xu et al., 2005; Xu et al., 2005; Chen and Li, 2007; Seetha et al., 2009). However, current research on hydrothermal process-roasting method has been limited to the synthesis of a certain ITO or In2O3 powders under specific conditions. A systematic study on the phase transition, as well as the change of the morphology and size of the particles in the hydrothermal process is still missing. In this paper, the effects of hydrothermal processing on the mineralogy, morphology and size of products were investigated. The results showed that the evolution of crystal structure, morphology and size in the hydrothermal process was affected through the mechanisms of Ostwald ripening and phase transition successively. These results are novel and have guidance for improving the hydrothermal process for In2O3"

Jan 1, 2012

By E. Haccuria

Due to the growing share of electrical cars, the use of lithium ion batteries significantly increased. Recycling of these batteries is essential to safely dispose hazardous materials as well as to recover valuables (Cu, Ni, Co, etc.). In order to optimise the recycling process, accurate information is required on the slag phase equilibria for battery smelting. The slag is a multi-component system containing alumina from the battery cases, silica and lime from fluxes, and manganese and lithium from the electrode materials. The present study accurately determined the phase equilibria in the "MnO"-Al2O3-SiO2 sub-ternary system at metal alloy saturation. Particular attention was given to the accuracy and reliability of the final results by highlighting the different reaction pathways, mass transfer- and reaction mechanisms taking place in the system during experiments. This attention enabled improved experimental methodology and measurements. Based on the present study, further measurements will be undertaken in the quaternary "MnO"-Al2O3-CaO-SiO2 system at low "MnO" concentrations, which closely represents the future recycling industrial slags.

Jan 1, 2014

By S. Konetschnik, Lux Degel, R. Degel, T. Haslinger

UrbanGold and its partners from Mettop and SMS group have developed a novel technology for the recovery of valuables from all non-ferrous metals’ fractions of WEEE (Waste Electrical and Electronic Equipment), with a special focus on low qualities which are commonly landfilled or incinerated. The technology is marketed under the brand name “UrbanGold Flex” to illustrate the high flexibility in respect of plant design and raw material portfolio, allowing also the processing of low grade material and materials with high caloric values. The process of the technology’s centrepiece, a modified and enhanced bath smelting furnace called “HENRI”, was investigated in numerous pyrometallurgical trials as basis for a scale-up towards a capacity of up to 100,000 tons of WEEE-concentrates per year. All relevant facility components have been evaluated in respect of references, fall-back options, as well as exit strategies (alternatives) to minimize risks when establishing a novel technology. A spin-off within the development is the “UrbanGold Compact” technology which can be seen as optimization of state-of-the-art smelters by using an optimized TBRC as primary processing unit. As an UrbanGold Compact plant will be the first industrial scale reference of UrbanGold’s technologies, it is also explained in the publication. As precious metals recovery is of major (economical) importance when recycling WEEE, major attention has been given to minimize the losses of these valuables. These measures, as well as a sophisticated way of utilizing waste heat as far as possible, result in interesting business cases with gross profits of up to 20% or even more. INTRODUCTION Over the past years, the demand of electrical and electronic equipment has increased dramatically with technological progress. Innovations on the technology of electronic devices led to a shorter usage and lifespan and thus boosted the generation of Waste Electrical and Electronic Equipment (WEEE). WEEE is one of the fastest growing waste streams, growing at 3 to 4% per year worldwide and is expected to reach more than 52 million tons per year by 2021. Currently, about 45 Mt of these wastes are estimated to arise worldwide, and the trend is rising (Baldé et al., 2017).

Jan 1, 2019

Since 2008 rapid advances have been made in technologies for the sensing and sorting of ores, particularly copper, and copper-related ores. Advances include significant increases in the sensitivity and throughput, specifically in the area of bulk sorting. Such advances were not possible without contemporaneous advances in the understanding of copper orebodies, in particular the understanding and quantification of the heterogeneity required within an orebody to support an effective sort, regardless of the technology deployed to do this. This paper covers fundamental knowledge in the characterization of orebodies and their ores for sorting; relationships between measures of heterogeneity and sorting response; the design of bulk sorting systems that can exploit this heterogeneity to add value to copper operations; and, a quantification of the value that can be generated from bulk sorting at a case study mine. INTRODUCTION Society currently puts increasing pressure on industries to move towards cleaner and more efficient means of production, and the mining industry is no exception. Mining additionally faces other factors increasing the pressure to be more efficient: high-grade and easily accessible reserves have become largely depleted, therefore the mined grade at operations across most commodities, including and in particular copper, is decreasing. Additionally, the grade of new discoveries in the sector continues to decrease (Schodde, 2011). Factor in the high capital cost of processing facilities and the low levels of efficiency of current grinding circuits, and the situation for such mines becomes dire. Sorting, by maximizing the amount of ore extracted while simultaneously reducing the waste content in ore delivered to downstream processes (whether simply transport and crushing, or more sophisticated circuits such as grinding and flotation or leaching) has long been of interest to mining operations and projects struggling with low margins (Bamber, 2012). However, until recently sorting technologies that are both cost effective and effective at such high throughputs have not been commercially available.

Jan 1, 2019

By S. Pauly, U. Kühn, J. Eckert, I. Kaban, G. Wiehl, F. Silze

In the present work, the effect of Ga on the wetting behavior of the Cu-rich braze filler CuGa10 (wt.%) on the steel 304L was investigated. For this, the macroscopic and microscopic effects governing the wetting of pure Ga, pure Cu and CuGa10 alloy (wt.%) on the austenitic steel were analyzed and compared. Contact angle and surface tension measurements were carried out by means of the sessile drop technique and, in addition, the phase formation at the interface was determined. Pure liquid Ga spreads on 304L, which supposedly is related to the formation of intermetallic Fe-Ga phases growing into the liquid Ga. Depending on the annealing time, FeGa3 and Fe14.5Ga12 were identified. In contrast, CuGa10 as well as pure Cu show secondary wetting on the steel surface. Especially, liquid Cu prefers to spread laterally and vertically along the grain boundaries of the steel substrate. In spite of rather similar mechanisms, CuGa10 wets 304L steel at lower rate than pure Cu above the liquidus temperature.

Jan 1, 2014

By Robert B. Parsons

"1984 was an eventful year in the courthouse f or observers 0/ the mining tax scene in Canada. For the first time in a number of years, the Federal Court heard several important tax cases which pertain directly to the resource industries. Tax Notes discusses/our cases that could affect the taxation 0/ operations and investment in the mining sector.Capital Gain or Income?Ever since tax reform, risk-takers in the exploration business have maintained that the taxation of capital gain s is a significant impediment to raising risk capital. It must be akin to rubbing salt in the wound, then, when an entrepreneur sells shares and the Court upholds Revenue Ca nada taxing the gain as ordinary income instead of capital gain. But, this is precisely what happened in the case of The Estate of Murray Watts, et al. v. The Queen.The issue that had to be decided by the Federal Court, Tri al Division, in this case was whether or not the profit from the sale of shares in Hearne Coppermine Exploration s Limited in 1968 was a capital gain, or income subject to tax.Hearne was incorporated in July, 1967. At that time, the three plaintiff s, together with seven other individuals, subscribed for 400,000 shares at 10 a share. The plaintiff subsequently subscribed for an additional 500,000 shares at $1.A pooling agreement was entered into by all ten shareholders regulating the disposition of any o f their shares; any sale required approval of seven of the ten initial sub scribers. It also provided for the sale of their shares 30 days after any public offering."

Jan 1, 1985

By S. Mohammadnejad, M. Olizadeh, B. Mehrabi

A new method using a combination of comprehensive mineralogical and analytical approach which includes optical and electrical microscopy and several analytical techniques with diagnostic leaching has been used to characterize the associations and distribution of gold in a variety of minerals from the Zarshuran refractory gold ore, NW Iran. Zarshuran ore with an average of 7.9 g/t Au-grade and about 8% arsenic with gold recovery less than 20% in direct cyanidation is considered as high arsenic, high au-grade refractory gold ore. In most of the refractory ores, gold is associated with arsenopyrite and co-para genetic ore minerals, while in Zarshuran ore; gold is associated with orpiment, realgar and arsenian-pyrite. Considering its mineralogy and As content, it can be considered as the most difficult refractory ore for characterization and processing. Results from the mineralogical examination and diagnostic leaches indicate that there is only a small amount of free gold (17-19%) that is present in cyanide-soluble sulfo-arsenides compounds, predominantly orpiment and realgar. Diagnostic leaches also indicate that little gold is occluded within the silicate structure (14%). Overall, the gold is mostly included in sulfides, arsenic sulfides and sulfo-arsenides (50%). The results also have shown how the technique can be used to gain a good initial understanding of potential metallurgical problems for a refractory gold ore.

Jan 1, 2005

By F. H. Samuel, J. E. Gruzleski, S. Valtierra, H. W. Doty, N. Andrade

In this work, the age-hardening behavior of cast Al-Si base alloys was investigated. It was found that multiple aging peaks are present in the age-hardening curves of Al-Si-Cu-Mg alloys. TEM observations reveal that the age-hardening behavior is related to the precipitation sequence of the alloy. For the Al-Si-Cu-Mg alloy, the first aging peak is the result from the high-density GP zones, while the subsequent are from metastable phases. The transition from GP zones to metastable phases may be the main reason of the formation of multiple aging peaks.

Jan 1, 2006

By Kenta Kusunose, Dadang Sundana, Ahmad Munib Fikry, Yosuke Unno

PT Smelting has operated the Mitsubishi Process in which feed materials are charged into the S- furnace through top lances using a pneumatic conveying system comprising 6 feeding tanks (S-Feeding Tanks). Each S-Feeding Tank was designed as a batch machine and had been operated in a batch mode so that feed materials are conveyed 70% of the operating time (conveying time). An S-Feeding Tank was revamped in August 2016 in order to attempt to achieve 100% conveying time during operation, aiming to reduce the furnace draft fluctuations and melt temperature fluctuations leading to reduced copper losses to slag and refractory wear on the sidewall in the melt zone. After two-year operation with some adjustments and modifications, it was concluded that the new system works as expected. During scheduled major shutdown in November 2018, the same modification was applied to all other 5 feeding tanks as the first one, while several modifications other than the S-Feeding system were also conducted for the purpose of expanding the capacity of the smelter. INTRODUCTION PT. Smelting (PTS) Gresik Copper Smelter and Refinery is located 30 kilometers north of the city of Surabaya, East Java major port. PT Smelting equity partners are Mitsubishi Materials with 60.5%, PT. Freeport Indonesia with 25%, Mitsubishi Corporation RtM Japan Ltd. with 9.5% and JX Nippon Mining and Metals corporation with 5.0%. PTS was established in February 1996 and started commercial operation of the Mitsubishi Process in 1999. The Mitsubishi Process is a unique technology which connects 3 stationary furnaces, namely the Smelting furnace (S-furnace), Slag-Cleaning furnace (CL-furnace) and Converting furnace (C-furnace) by covered launders. These features result in savings in manpower and energy, and make the process more environmentally friendly since there is no ladle transfer of melt. Figure 1 illustrates the outline of the Mitsubishi Process.

Jan 1, 2019

By Frank Condon

?Location ?Background ?Drilling Program ?Mineral Resources ?Geology ?Economic Assessment ?Strategic Partner ?Located in Nunavik, Québec ?160 km northwest of Schefferville ?240 km south of Kuujjuaq ?160 km northeast of Brisay ?Magnetic Anomaly ?Property Boundary ?Diamond Drill Holes

May 1, 2011

By A. L. Mackie

Mine water from base metal mines is generally characterized as having high concentrations of heavy metals and low pH, resulting in the need for treatment prior to discharge to receiving waters. In this study, two high-rate clarification processes were evaluated at bench-scale: the high density sludge (HDS) process and sand-ballasted flocculation. High-rate clarification processes generate larger, denser flocs which settle more quickly than those formed in conventional flocculation processes. The HDS process uses recirculated sludge in order to seed floc formation, whereas ballasted flocculation uses microsand. Both of these high-rate processes require the addition of quicklime or hydrated lime to increase pH and allow for the formation of insoluble metal hydroxides, which can then be removed in the clarification stage. Previous research has shown that cement kiln dust (CKD) can effectively replace quicklime in conventional sedimentation processes for metals and acidity reduction to meet discharge guidelines (Mackie & Walsh 2012). CKD is an alkaline by-product of cement manufacture that has fine particle sizes and varying free lime concentrations depending on the manufacturing process. The lower solubility (i.e., free lime content) of CKD requires larger doses of material to be added to reach treatment pH targets for metals precipitation. The purpose of this study was to evaluate the treatment efficacy of high-rate clarification processes for mine water treatment, compared with conventional sedimentation, at bench-scale with conventional (i.e., lime) and novel (i.e., CKD) pH adjustment additives. Results of the study showed that all treatment processes (i.e., HDS, ballasted flocculation, and conventional sedimentation) were able to reduce target metal concentrations to well below Canadian guidelines (i.e., total zinc and total nickel < 0.5 mg/L, total copper < 0.3 mg/L) using either CKD or lime. Additionally, mine water samples treated with CKD generated lower sludge volumes than those treated with lime (i.e., 50 versus 100 mL for conventional sedimentation and 100 versus 200 mL for HDS) even with increased concentrations of solids introduced during treatment. This is most likely due to slower neutralization rates when using CKD, due to its lower solubility, as well as finer particle size. The sand-ballasted flocculation process was able to reduce final turbidity in CKD-treated samples while the HDS process did not when compared to conventional sedimentation, making the ballasted flocculation process preferable for reducing final solids concentrations in CKD-treated mine water.

Aug 1, 2013

By H. M. Woodrooffe

IT IS WELL KNOWN that chrysotile asbestos from various occurrences exhibits varied physical properties and certain differences in chemical corn position, both of which conditions may have an important bearing on the industrial utilization of the fibre. The usefulness of a harsh fibre in the manufacture of asbestos cement products and of low-iron fibre for certain electrical uses are examples. It is also .possible to obtain a fibre with a texture too harsh and brittle to be of economic value. Much research into the structure of the mineral and to a lesser degree observations relating the water of combination to certain physical properties have ?been reported. This paper is an attempt to show that the pyrolysis of ?chrysotile takes place in three stages and that the conditions of pyrolysis are peculiar to the fibre and may afford some clue to the variations in physical properties of asbestos fibres which affect their utilization.

Jan 1, 1956