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By V. G. Papangelakis, I. Guzman, S. J. Thorpe

Pressure oxidation (POX) leaching has been commercially applied to refractory gold ores since the 1980s. In the process, sulphide material is oxidized and dissolved in order to release the gold encapsulated in the sulphide matrix, making the gold available for further recovery. Redox potential is a significant parameter during POX, however it is only measured ex-situ at atmospheric conditions. In-situ redox potential measurement would provide instant information that allowing adjusting the process parameters accordingly. In the present study, redox potential measurements were performed during POX of sulphide material at high temperatures and high pressures. The working electrode was an Ir electrode combined with a flow-through reference electrode in a novel and robust configuration. Experiments were performed in a 2 L titanium autoclave, at 200–220°C, 50–110 psi oxygen overpressure, and 10–30% solids mass fraction. Temperature and oxygen pressure conditions were selected in order to reflect POX of refractory gold ores. Results show that the Ir electrode is consistent with theory and is able to perform well under these conditions, showing promise as a new in-situ sensor.

Jan 1, 2017

By Denis Yaychuk, Gary Billingsley

The economic eva luation of a mineral property or mining venture should include the quantification of ri k as part of the analy is. The re ults of such an analysis provide the decision-makers not only with the most likely financial outcome and the probability of achieving that or any other outcome. but al o with a ranki ng of the relative impact of all the ri sk factors. These type of resu lts offer more complete information for investment and technical deci ions than the traditional cash flow/ ensitivity analysis. In addi tion. by attempting to quantify ri sk. the personnel providing the va ri able input are forced to take a much clo e r look at the data involved, and are fo rced to work together. the reby increa ing substantially the awa reness of the impact their work and others· work has on th e outcome of the analysis.

Jan 1, 1986

By C. G. Harris, R. Sluyter

The purpose of an undercut is to undermine a block of ore which will then proceed to cave into draw holes just below the undercut. Undercut-ting is the final and most vital phase in the development of an ore block. Since its purpose is to undermine and induce caving into a block of ore, great care must be exercised to avoid premature caving by removing only enough rock to permit undercut development to proceed. Several undercutting methods, used over a twenty-year period, are re-viewed and their suitability is com-pared with ideal requirements.

Jan 1, 1960

By K. Parameswaran

This paper builds on presentations made at the Conference of Metallurgists (COM) 2015, COM 2017 and Extraction 2018 and associated papers published in the respective conference proceedings. Based on the classic Brundtland Commission definition of sustainable development as “development that meets the needs of the present without compromising the ability of future generations to meet their own needs,” the paper describes how metal mining can be compatible with sustainable development and how sustainability considerations have been applied in the primary copper industry, using several examples of sustainable mining practices from ASARCO LLC operations. Finally, the paper discusses how these considerations might be used in the future by discussing the need for developing a sustainable development strategy and how this strategy can be aligned with the United Nations Sustainable Development Goals. INTRODUCTION The primary copper industry comprises: mining (also referred to as “extraction”); mineral processing (also referred to as “beneficiation, “milling” or “concentration,”) which includes leaching, solvent extraction (SX), crushing, grinding, froth and flotation operations; and metallurgical processing which includes smelting and converting; refining, which includes fire-refining or anode refining and electro-refining; and electrowinning (EW). There are two routes for producing refined copper: hydrometallurgical and pyrometallurgical. The hydrometallurgical route comprises mining (open-pit and underground), mineral processing (crushing and grinding — for heap leaching only; leaching and SX) and metallurgical processing (EW). The pyrometallurgical route involves mining, mineral processing (crushing, grinding and froth flotation) and metallurgical processing (smelting, fire refining and electro- refining). The primary copper industry is capital, water, resource and energy intensive with the potential for significant environmental impacts, if the environmental aspects are not properly managed. ASARCO LLC (Asarco) was organized in 1899 as the American Smelting And Refining Company. Originally a consolidation of several lead-silver smelting companies, it evolved over the years into an integrated producer of primary non-ferrous metals, including copper, lead and zinc and associated co-products. Grupo México, S.A.B. de C.V (Grupo México) acquired Asarco in 1999. Today, Asarco is a vertically integrated producer of primary refined copper and associated co-products such as gold, silver, selenium and tellurium. Asarco operates three open-pit mines and mills, two leach, SX-EW plants, a copper smelter in Arizona and a copper electrolytic refinery in Texas.

Jan 1, 2019

By Elizabeth Edwards, Radhakrishnan Mahadevan, Vladimiros G. Papangelakis, Srinath Garg, Kurtis Judd

Mineralogical characterization of the tailings showed the deportment of Ni to be similar in the Vale and Glencore tailings, with 60% of the total Ni locked in pyrrhotite, and the balance 40% associated with pentlandite. The overall Ni dissolution was correlated with the individual dissolution extents of pyrrhotite and pentlandite as functions of four leaching regimes: ‘anoxic acid’ (with and without pH control), ‘oxic acid’ (oxygen sparging), ‘oxic acid’ (air sparging), and ‘oxic ferric’ (air sparging). The results showed that the maximum Ni dissolution was obtained during the pH controlled oxic acid leach with oxygen sparging at pH 1.5, while the anoxic acid leach at pH 1.5 resulted in minimum Ni dissolution (10–15%) from pyrrhotite. An overall Ni mass balance showed that pyrrhotite and pentlandite dissolve simultaneously in the presence of Fe(III) and oxygen, in contrast to the preferential dissolution of pyrrhotite in the absence of Fe(III). Sulphur mass balances revealed that the yield of elemental sulphur is maximized (65%) during the oxic Fe(III) leach at pH 0.6. Furthermore, the kinetics of Ni leaching and elemental sulphur formation from pyrrhotite tailings leached with ferric sulphate between 55–80°C was investigated at constant oxidation-reduction potential. Elemental sulphur yield increased with increasing temperature, but no observable trend could be linked to ferric or ferrous ion concentration.

Jan 1, 2017

By Baseer Abdul, Edouard Asselin

Hydrometallurgical leaching of sulfide concentrates of copper and nickel at medium temperature (150°C) produces residues that contain sulfur and iron bearing minerals and phases. During leaching, and depending on various process parameters, iron may be precipitated as hematite, goethite, jarosite or other oxyhydroxides, which may be more or less crystalline. Hematite is the favored precipitate because it is the most environmentally stable and does not ad/absorb as much copper, nickel or other solution constituents during precipitation. However, the low solubility of iron during the medium temperature processing of sulfide ores can favour the formation of poorly crystalline, nano-scale iron oxide/oxyhydroxide phases. In some cases these phases have been positively identified as the metastable ferrihydrite, which transforms into iron oxides such as goethite, hematite and magnetite over time. A better understanding of what may help drive this transformation during leaching would ultimately result in lower valuable metal losses and more stable leach residues. Higher acid concentrations result in increased copper extractions and favor the formation of hematite during concentrate leaching, rather than other metastable phases. Furthermore, commercially available water displacement formula “WD40®” and other novel reagent(s) affect Fe precipitation and sulfur chemistry, leading to very different process outcomes such as improved extractions and larger, more easily separated, sulfur particles.

Jan 1, 2017

By N. Schreithofer, M. Aspiala, R. Serna

The novel attachment timer apparatus presented in this paper serves as a diagnostic tool that allows the detection of changes in bubble-particle attachment probability and therefore floatability caused by alterations in the chemical environment and particle properties. The apparatus consists of six identical capillaries where bubbles with defined size are produced simultaneously in a measurement chamber. The bubbles at the capillary tips are placed in contact with the submerged particle bed for specific time periods, controlled with the help of automatic actuators. The advantage of the instrument is that hundreds of bubble-particle contacts can be measured automatically within a short time period. Microscopic pictures of each measured bubble are taken while recording the movement of the bubble before, during and after contact with the solid particles. The recorded pictures can be used to determine the actual bubble size and its corresponding deviation, and to detect the attachment of particles. The attached particles are collected in a detachable chamber for subsequent characterization. Furthermore, the device is portable and can be taken to the mineral processing plants for quick evaluation of particle-bubble attachment efficiency with particles and process water sampled directly from real processes.

Jan 1, 2017

By T. Newton, G. A. Bezuidenhout, P. J. Tauetsile, F. Trask

The technology to selectively leach gold, silver and base metals from ores, concentrates, and wastes, using an alkaline glycine solution, has initiated significant interest in using the new technology in various environments such as in-situ, in-place, dump, heap, and vat and agitated tank leaching. It has been shown that glycine acts synergistically with a number of other lixiviants to lower the net consumption of the other lixiviants while allowing low cost glycine solution recovery. Glycine is a non-toxic, stable, environmentally benign reagent that is available in bulk industrial quantities. It has the ability to dissolve most copper oxide and sulfide minerals, as well as native copper, whilst not interacting with acid consuming gangue nor dissolving iron and various or ubiquitous gangue elements. It acts synergistically with small amounts of cyanide to leach gold-copper ores at leach rates higher than either glycine or cyanide on their own, while significantly reducing cyanide consumption and eliminating detoxification requirements. The leaching behaviour of various glycine based systems will be reviewed, followed by the evaluation of the adsorption of gold onto activated carbon. Where the economics merit it, copper can be easily recovered using solvent extraction or sulfide precipitation.

Jan 1, 2017

By C. Feng, D. W. M. Arrigan

Arsenic is often associated with gold mining operations and poses a significant health and environmental hazard. While a number of technologies are available for removing arsenic, none of them is effective under all conditions. Although adsorption is a promising approach, most methods focus on the purification of water under neutral or acidic conditions and tend to be less effective in gold mining process waters, operating under alkaline conditions. In this study, the removal of As (III) and As (V) from both arsenic-only solutions and simulated process waters using composite magnetic nanoparticles was investigated. The nanoparticles consisted of magnetite (Fe3O4) or maghemite (?-Fe2O3) cores covered by various metal oxides with Langmuir adsorption capacities of As (III) and As (V) ranging from 31.4 to 79.1 mg/g and 10.2 to 25.5 mg/g, respectively, in arsenic-only solutions at pH 9. Their adsorption capacities were further recognised by the adsorption tests conducted in simulated process waters. The ability to remove As (III) is of particular importance as it is harder to remove it from alkaline solutions. The magnetic cores allow simple and efficient magnetic recovery of the As-loaded nanoparticles.

Jan 1, 2017

By M. van de Vijfeijken

This paper will first give a short overview of the Copper Mountain project in British Columbia, which just has started commercial operation earlier this year. The grinding process with one 34' x 20' SAG mill and two 24' x 39.5' ball mills will be briefly discussed. All three mills are gear driven by a ring gear, dual pinion and two low speed synchronous motors. Copper Mountain has installed on all three mills, the new state-of-the art dual pinion mill drives. All the inherent operation and maintenance features of this drive technology will be discussed, as well as the advantage of having variable speed control also on the ball mills. The installation and commissioning of the mills and drives at Copper Mountain will be briefly reviewed. Finally the first field measurements on these low speed mill drives will be presented, with the main focus on the low mechanical stress impact of these mill drives on the pinion and ring gear, as well as the accuracy of the load sharing between the two motors.

Jan 1, 2012

By C. Lapointe

"IntroductionTen years ago, when nuclear fission became practical, the element uranium, until then a not very desirable by-.product of the radium industry, became overnight the strategic material par excellence. One of the several important problems that had to be solved at that time was the rapid and precise determination of uranium in ores and concentrates.GeneralThe chemical analysis of uranium ores is a long and difficult business and is complicated by the presence in most ores of a large number of interfering elements. True, much progress has been made, during the past few years, toward simplification of the analytical methods, but the chemical determination still remains the job of a skilled operator. For this reason, the chemical method has been replaced, whenever possible, by a physical determination based on the measurement of the radiations emitted by the elements of the uranium family. There are several types of instruments suitable for these measurements, but of all the radiation detectors known to the physicist, such as ionization chambers, crystal detectors, scintillation, proportional counters, and the like, the Geiger-Mueller counters have proved to be the most satisfactory for routine determinations, because of their simplicity.The Geiger-Mueller counter is a very versatile instrument; it can be constructed to detect any type of radiation, corpuscular -0r electromagnetic. Here, however, we are interested in these counters because of their ability to detect the beta and the gamma radiations, both emitted by some members of the uranium family. The beta radiation is corpuscular, and is composed of fast electrons, while the gamma radiation is electromagnetic."

Jan 1, 1950

By John E. Udd

I N Part I of this paper, Professor Morrison suggested that our technique of causing cracks to develop around openings in a sheet of photoe1ashc plastic is, in effect, a laboratory-scale rockburst. Our investigations have indicated that the location and direction of these cracks are predictable, and that their growth can be controlled. On several occasions, we have been able to cause these cracks to propagate sufficiently slowly to be followed, with the naked eye. In practice, the rate of growth, gradual or sudden, would depend upon rock properties. This part of the paper presents an analysis of the stresses surrounding the openings before and after failure and also this author's views on the causes and after-effects of cracking. An attempt is made to correlate the stress patterns with those deter-mined from pure mathematics. Considering that the openings, except for the central enlargement, are long apertures with somewhat rounded corners, they might be compared with elongated ellipses having axes ratios of about 20:1 or with

Jan 1, 1963

By D. Moronkeji, R. Maharidge, D. A. Curry, B. J. Davis, U. Prasad, J. Franquet

"Proper shale characterization is crucial in shale gas drilling, exploration, completion and production. Unlike porous sandstone and carbonate reservoirs, the challenge with shales comes from their micro- to nano-darcy permeability ranges and the anisotropy of their mechanical and hydraulic properties. Most porosity-dependent logs are not sensitive enough to capture the true behavior of shales. Consequently, mineralogy and other strength and stiffness-related properties must be determined to characterize magnitudes and variances in shale mechanical and flow properties. In addition, these properties must pass quality assurance/quality control (QA/QC) practices to give confidence in their use in subsequent log calibrations, during geomechanical modeling, or in fracture design models. This paper presents a technique to integrate shale properties that are measured by various methods, and a methodology to perform QA/QC on the data before application.Shale properties originate from various sources, including downhole and laboratory measurements. Physical samples for laboratory testing are usually limited to a few depths. Lab tests are often costly, and replicating in-situ conditions can be difficult or impossible. In addition, results frequently show wide scatter, reflecting inherent depth variability and lateral heterogeneity. Wireline logs provide nearcontinuous data, but rarely yield direct measurements of rock strength properties. Although geomechanical and fracture models use log data, calibrating it with reliable and previously verified lab-measured properties is important. This paper presents a process to perform QA/QC on lab-measured data using various crossplots.Ten mechanical, microstructural and physical properties are graphically displayed to visually characterize shale strength behavior in ambient and in-situ conditions, whether measured or modeled statically or dynamically. These properties are often sourced from different departments. The properties are integrated but are individually subject to the previously mentioned uncertainties. Pairs of property values are crossplotted and compared with correlations from the literature or previously established with qualified data from related formations. Conformance with these correlations gives confidence in the data, whereas outliers are flagged as questionable. Repeating the process with questionable data crossplotted against other parameters for the same depth highlights the property with the greatest uncertainty. The determination of its value is investigated to locate the source of the inconsistency and establish a more reliable value. Where this is not possible, the user has a rational basis for rejecting that property value."

Jan 1, 2015

By Fazel G. Jahromi, Ahmad Ghahremaninezhad

Enargite (Cu3AsS4) is a major complex copper mineral and often is a carrier of invisible gold particles. Pyrometallurgical treatment of enargite is challenging due to the arsenic release to the environment. Hydrometallurgical treatment, on the other hand, appears to be a promising alternative for enargite processing. In an atmospheric enargite leaching process both the copper and arsenic from the mineral can be leached into a sulphuric acid solution and the arsenic can be simultaneously precipitated as ferric arsenate. The unlocked gold in the residue then can be recovered in a subsequent cyanidation circuit. The downside of the atmospheric enargite leaching in sulphate solutions is the slow leaching kinetics. In this study the effective parameters of the atmospheric enargite leaching process in ferric chloride media were investigated. All the experiments were carried out at temperatures below 100 °C. The process parameters that were investigated in this study included ferric, chloride, sulphate and cuprous concentrations, temperature, mixing rate and leaching slurry pulp density. It was found that the copper recovery rate increases with the addition of cupric chloride and also with raising the temperature. The highest leaching kinetics and the highest overall copper recoveries were achieved when cupric was initially added to the leach solution and at 90 ºC.

Jan 1, 2015

By G. Grassmück

The question of whether the air curtain principle could be used under conditions prevailing in Canadian metal mines was investigated. A vertical, portable BERRY air curtain was tested, at first in a wind tunnel built at Ecole Polytechnique at full scale (8-by 8-ft cross section) to simulate a drift and its lateral connections, and then in the haulage ways of a metal mine under actual conditions. The results permit us to predict under what conditions this type of air curtain is capable of acting as an air stopping or flow regulator and how it could be further developed.

Jan 1, 1969

By K. Sun

The exothermic behavior of the intermetallic reactions inside an Al-Mn metallic powder compact and its assimilation fundamentals in molten aluminum were examined. In this study cylindrical compacts were manufactured and tested. The experimental work involved simultaneous temperature measurements of three thermocouples as well as detection of the apparent weight of the cylindrical specimen during its assimilation in liquid aluminum. The details of the intermetallic reactions prior to the compact complete disintegration were investigated by microscopically studying the morphology and local composition in a partially reacted compact. The variation of manganese concentration in the melt was determined by chemically analyzing the samples taken from the molten aluminum at specific time intervals. The exothermic reaction increases the compact's temperature above that of the liquid aluminum. In tandem with this exothermic reaction, the compact is suffering a swelling action. This swelling action disintegrates the cylindrical specimen, which is assimilated into the liquid aluminum. The intermetallic reactions proceed in a stepwise manner. Both the bath temperature and the compact composition impact on the exothermicity of the intermetallic reactions. However, when the amount of Mn in the compact is greater than 75-wt%, the maximum centerline temperature rise is slightly reduced as Mn amount increases.

Jan 1, 2004

By Frank Lemy

This paper presents an application of digital face mapping in an underground mine. Based on photographs it was possible to construct discontinuity maps, which were used to characterise the rock mass. The results were compared favourably with values obtained through scanline and area sampling mapping for the same site. The case is made for digital mapping as a safe, fast, and efficient way to characterise rock mass structure for engineering purposes.

May 1, 2001

By S. Bozorgi, K. Anders

"The automotive applications of heat treatable AlCu cast alloys are designed for performance at high temperature, which can be improved using specially alloying element as well as different heat treatment. In this research work an effect of alloying element such as Cu, Ni and heat treatment on microstructures and mechanical properties of AlCu alloy were investigated using optical microscope (LIMI), scanning electronic microscope (SEM) equipped with energy dispersive X-ray detection (EDS), Differential scanning calorimetry (DSC) and mechanical testing. It was found that during solidification most of the elements Cu, Mg and Ni segregated at the grain boundaries in the form of Al2CuMg or Al7Cu4Ni and a very small part of Cu and Ni element dissolved in the FCC-Al matrix. The latter is not completely reclaimable for strengthening mechanisms in FCC-Al matrix in its as-cast state. The results of mechanical test show that yield strength and ultimate tensile strength increases after heat treatment significantly compared with the as-cast state. Furthermore the mechanical properties at elevates temperature (240°C) is higher with higher Cu+Ni+Si containing alloys compared with the less Cu+Ni+Si containing alloy.INTRODUCTION Due to the high strength-to-weight ratio, high strength and ductility at room- and elevated temperature, AlCuSi cast alloys are widely applied in the automotive industries specially for producing cylinder head and engine block, where modified alloys with enhanced metallurgical properties are always needed to satisfy the ever increasing demands for the applications. The AlCu based cast alloys can be strengthened by age hardening. The precipitation processes from which this hardening is derived can be attributed to the presence of selected trace element additions or micro alloying, which can change the process or kinetics of precipitation in age hardenable AlCu cast alloys (Polmear, 1998; Morris, 1991). Furthermore their strength is mainly controlled by the aging process through the precipitation and growth of very fine precipitates of the ?'-phase (a semi-coherent, metastable form of the equilibrium Al2Cu phase) from the Al and Cu Guinier-Preston (GP) zones. Several studies have shown that solute clustering occurs prior to the precipitation of GP zones, and this modifies both the nature and kinetics of the precipitation process. The typical size of GP zones is in the order of tens of nanometers, and the chemical composition of these precipitates is not easily measured, even with a typically analytical electron microscope (Polmear, 1989)."

Jan 1, 2018

By A. Putz, F. Vincent, A. R. Laplante

"This paper briefly reviews some of the gravity research done at McGill University and current Canadian operating practices, with emphasis on results of interest for operators. The following topics are addressed: security, economics, predicting recovery, circuit optimization, unit selection and final upgrading. Emphasis is placed on the Knelson Concentrator.The topic of security and economics are addressed jointly, in terms of the place of the gravity circuit in the mill flowsheet. Actual plant experience is drawn upon to identify potential problems and actual solutions.Predicting primary recovery is linked with a characterization of the ore, the choice of a circuit, and the fraction of the bleed used. Factors such as feed preparation, preliminary upgrading, fraction of recycle treated, ability to recover fines and location of the bleed are discussed.Final upgrading is achieved almost only by tabling and smelting. This can lead to fine gold recovery problems when more effective units are used upstream. Alternatives are discussed.IntroductionResearch on gold recovery by gravity over the past eight years has associated McGill University with a number of gold producers. This paper attempts to review the information gathered from a practical perspective. Some of the information was generated in McGill University's labs, some gathered at plant site, and some was shared by operators."

Jan 1, 1994

By A. M. L. Cushing, S. Kelebek, A. Ghahreman

Iron sulfides are part of many ore deposits affecting flotation separation of non-ferrous base metals from them. Open-circuit potential (OCP), potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) measurements were carried out with pyrite and pyrrhotite electrodes to investigate their reactivity under various flotation conditions, which involved the use of TETA, SMBS, and their combination. TETA was found to adsorb on the electrode surfaces causing a significant increase in charge transfer resistance of the product formed, which was most significant at OCP. This effect is much less with SMBS, indicating its greater surface reactivity compared to TETA. The combined use of these reagents decreases charge transfer resistance to a greater degree than that experienced with their individual uses. Addition of Cu2+ as a potential activator to this system nearly eliminates the action of TETA on the electrode surface, which can be attributed to sequestration/chelate formation in liquid phase. The relative effects of these reagents on pyrrhotite electrode are similar to that of pyrite. The main difference between the pyrite and pyrrhotite electrodes is that the observed charge transfer resistance on the pyrrhotite surface with each reagent case is significantly lower by 3 to 4 fold. This is compatible with its anodic nature and ease of oxidation since the OCP value of pyrrhotite is lower than that of pyrite. Results are discussed in relation to flotation/depression behavior of these iron sulfide minerals in mineral separation processes.

Jan 1, 2017