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The increasing global demand for rough materials forces almost every mine to look at the mechanisation in their processes. This will not onlyimprove performance but with safety issues becoming more and more prevalent, the need for the introduction of mechanisation technologies to mining applications is essential. Ongoing developments are occurring in almost every field, ranging from basic developments to specialised mining. Mechanical tunnelling and shaft sinking have set the standards regarding safety, profitability and environmental protection. Different machine types and working principles have been developed to suit the geological and hydrological requirements of tunnelling projects worldwide. Continuous activity in research and development leads to constant optimisation of tunnelling performance.

Jan 1, 2008

THE exceptional rainfall characteristic of the West Coast of Tasmania, in conjunction with the rugged topography of the district, has always suggested the utilization of water-power, and from the earliest days of the Mount Lyell Company theeventual installation of a hydro-electric power scheme, making use of some near-lying lake, has constantly been kept in view. At the period of the inception of the company, however, the time was not ripe for such an undertaking, and it is only oflate that the various important considerations involved have sanctioned incun;ing the heavy expenditure necessary, with the positive assurance of permanently reaping the benefits expected. The West Coast of Tasmania contains many lakes of varioussites; situated at high levels, and, although the catchments of these lakes are not very extensive, still, the excessive rainfall is so constant over long periods that its regularity may be relied on as offsetting the limited catchments. The explanation of the abnormal rainfall is simply the circumstance that the West Coast Range forms the first high land barrier which is met by the moisture-laden westerly and north-westerly winds blowing off the Southern Ocean. By the time the clouds strike the mountains they ride very low, consequently the elevation of the range, the peaks of which do not exceed 3000 to 4000 ft. above the sea, is sufficient to cause a copious precipitation. Lake Margaret, which is situated five miles north of the reduction works, was first recognized as a possible source of waterpower by Mr. Hugh Ohrisp, a surveyor, who visited it about 1893-4. Earlyl in 1895, while the preliminary work on the erection of the first furnaces of the Mount Lyell Co.'s reduction...

Jan 1, 1915

By J Kinal, P Steinier

A considerable volume of work exists in the literature examining the electrochemical interactions between grinding media and sulfide minerals. Broadly, most sulfide minerals are more noble than forged steel grinding media used during comminution, therefore a galvanic couple between the media and the sulfide mineral(s) exists, which increases the corrosion rate of the grinding media. The corrosion products of the grinding media, iron oxy-hydroxide species, invariably precipitate on to the surfaces of the sulfide minerals thereby affecting their floatability. This paper explores the science behind these corrosion reactions, and provides an explanation of their impact on the pulp chemistry of sulfide mineral slurries and subsequent flotation behaviour. A number of laboratory and plant case studies are used to illustrate the benefits of changing to a more inert grinding media.

Jan 1, 2005

By K J. Davey, J T. Woodcock

Australian steelmakers produce up to 30 000 t/yr of electric arc furnace (EAF) dust. Current disposal techniques include sending EAF dust to landfill, stockpiling, and paying zinc smelters or registered waste removalists/processors to take the dust. Many of the complex overseas pyrometallurgical and hydrometallurgical treatment routes cited in the literature are not considered economic. Governmental, environmental and social pressures on producers to consider more sustainable disposal options are mounting, and there is now a strong push to consider recovering potentially valuable or recyclable components, such as zinc and iron units, from EAF dust. As well, there remain strong economic drivers for producers to find lower cost disposal solutions. Characterisation studies undertaken at CSIRO Minerals have revealed important physical differences in the nature of the zinc- and iron-bearing phases contained in domestic EAF dusts. These differences have been exploited using simple and cheap mineral processing techniques such as water washing, wet cycloning and wet magnetic separation. This has allowed a significant upgrade in the zinc content of EAF dust to be achieved, together with a reduction in the levels of key smelter penalty elements, such as chlorides and fluorides. The zinc-rich portion of the dust is now a more attractive smelter feed while the iron-rich part of the dust could potentially be briquetted or pelletised with a reductant and recycled to recover iron, and thus close the loop on dust processing. The basis of the separations tested together with laboratory results from several Australian dust samples are presented and discussed in this paper.

Jan 1, 2006

By H Fukaya T Miki, J Gamutan

Molybdenum disilicide (MoSi2) is a promising material for thermal applications due to its excellent heat and oxidation resistance. It can operate at temperatures of up to 1800°C as furnace heating elements and protect refractory metals such as molybdenum from rapidly reacting with air to form volatile molybdenum oxides at elevated temperature. In this work, the feasibility of forming MoSi2 on a molybdenum substrate by hot dipping in a silicon-saturated molten metal bath was investigated. This method is simple, predictable and can be used to coat large components and complex parts. It was found that tetragonal MoSi2 can be successfully synthesised on the surface of the substrate after dipping for 15 mins at 1000°C using molten tin (Sn), bismuth (Bi) and copper (Cu) baths. The growth of the MoSi2 layer was fast within the first 15 mins and then gradually slowed down with time. After dipping for 60 mins at 1000°C, the thickness of the MoSi2 layer were measured as 441.5, 19.5 and 13.1 μm for the copper, tin, and bismuth baths, respectively. The MoSi2 coating synthesised in this study provided oxidation resistance at 1150°C by forming a protective SiO2 layer on the surface. The SiO2 layer prevented the sample from rapidly oxidising by inhibiting direct contact between the molybdenum substrate and oxygen in the atmosphere. Compared to conventional methods, the proposed hot dipping method produces a MoSi2 layer more rapidly and at much lower operating temperatures. This makes it a more attractive option for coating large and complex components, with the potential to enable the use of MoSi2 in a wider range of applications.

Jun 19, 2024

Various methods and software have been trialled for simulation of Au grades at Boddington Mine. This covers in-house and public software as well as sequential and turning bands methods. The diversity of options was further expanded with comparison of point and direct block simulation. Some difficulties were encountered in incorporating high-grade restrictions. Altering parameters or software can make very significant differences and give results varying from estimations. This paper details a new simulation run with validation and tests for local calibration (or progressive correction) of the simulations to the estimations, focusing on reproduction of statistics. This approach brings to the forefront the question æwhat is the purpose of the simulations?Æ Results and some ideas for future applications at Boddington are summarised.

Sep 26, 2011

By S J. Henderson

Pumped co-disposal of coal processing waste was promoted in the 1990-2000s as a low-cost highperformance alternative to tailings dams. In particular it would avoid high up-front capital for rejects trucks and dam embankments, and would produce a combined waste deposit with better geotechnical properties than either coarse rejects or tailings. Overall, the promise was not delivered; in particular, upon discharge the waste segregated by size, and operators responded by moving the coarser waste to contain the finer waste. In consequence, not only did design analysis lag behind construction, but some of the initial expectations persisted with the result that analyses did not fully represent what was occurring on the ground. After more than twenty years inspecting, designing and tending Co-Disposal Areas (CDAs), it is apparent that they are essentially upstream constructed tailings dams with some more favourable aspects but also a few unique quirks. Although waste management technology has moved on somewhat, the high cost of changing CHPP waste circuits means that most mines with pumped codisposal will continue to discharge mixed waste slurry into CDAs. It is therefore worthwhile to share some lessons in the hope of promoting sounder design, operation and rehabilitation. These include: • Discharged waste does not form a homogeneous wholly competent deposit but instead comprises materials ranging from sandy gravel to silty clay with the distribution determined by movement of the discharge and decant structures; • CDAs circulate and contain a lot of water; • As a result of the first two points, some areas of the CDA comprise saturated fine waste that is no different from tailings and, like tailings, often behaves in an undrained manner; • Seepage is inevitable and desirable because strength improves as water is removed. However, stability is strongly impacted by pore pressures and in design these need to be rationally rather than optimistically considered; • As CDAs are built to about 40m or higher, strength-deformation characteristics of the foundation become more important; • Even if geomechanically stable, CDAs will need covers to prevent salts and acids from reaching the surface; and • Erosional stability of the cover material(s) will probably dictate maximum slopes for rehabilitation.

Jul 1, 2021

By D S. Clarke, W M. Prebble

Potential waste rock products from the mining of epithermal deposits in the Hauraki Goldfield are characterised to facilitate their management. Hydrothermally altered andesites and their weathered near surface equivalents have been examined from the Golden Cross, Karangahake and Monawai gold deposits. These materials vary in both their clay content (smectite, illite, kaolinite and chlorite) and the degree of silicification resulting from alteration and weathering. The simulated degradation (slaking tests) of waste materials cannot be explained purely by consideration of clay content, siliciflcation, or the resultant variations in porosity.   Microstructure is considered to be essential in predicting the physical degradation of waste rock. The scanning electron microscope is an effective tool in such an investigation. Increasing alteration results in clay particles becoming more randomly orientated (matrix microstructure); this causes a reduction in the surface area of contacts between components resulting in increased potential for degradation. The extent of skeletal microstructure (commonly characteristic of weathering) is an important control on effective porosity and the long term potential for degradation. Management requirements for these materials include the minimisation of moisture content variations (with the prevention of initial drying being of primary importance) and the containment of sediments produced.

Jan 1, 1991

By M M. Hilden, M S. Powell, B Foggiatto

In an environment of decreasing ore grade, increasing costs and uncertainty with respect to commodity prices, the industry could benefit from evaluating alternative technologies and innovative circuit configurations. The flexible circuit approach suggests that the design of grinding circuits can be adapted to changes in feed properties and economic conditions. Advances in modelling and simulation are enabling metallurgists to predict the performance of more complex circuit configurations with increased confidence. Ore variability information and processing costs may be used as modelling inputs to determine the optimum processing conditions at a given time. A case study has been completed demonstrating the value of combining a flexible circuit with a model-based optimisation of the process. Ore properties and equipment performance data obtained in operating plants have been used to model and simulate flexible circuit configurations.This paper explores strategies to introduce flexibility to existing circuit configurations when processing ores with high variability. Multicomponent models incorporated in the model developers’ kit (MDK) allow the simulation of more complex and flexible circuits. This capability enables demonstration of the potential to enhance metal production through adapting processing routes according to the ore type being processed. The simulation of different flow sheet configurations allowed the definition of the best option for maintaining the metal production when treating lower grade ores, highlighting the advantages of flexible circuit configurations compared with a one-process-fits-all approach.CITATION:Foggiatto, B, Hilden, M M and Powell, M S, 2014. Advances in the simulation of flexible circuits, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 391–398 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

A new lead refinery with a. capacity of 230,000 tons per year com-menced operation at*Port'Plsie in October, 1959. This plant' superseded the refinery which had operated from 1933 with the advent of thecontinuous lead refining process. The incorporation of new equipment following local metallurgical developments, together with the overseas demand for lead of extremely low antimony content, created difficulties in operating the original plant. The new refinery project was under-taken to cover this disability and to gain the full advantage of the new processes.Desilverising and softening are carried out in units identical in size to those used previously. Metallic'zinc is now recovered from the entire output of desilverised bullion by vacuum distillation. Final refining is then carried out by batch'treatinent with caustic soda yield-ing lead of purity previously unattainable at Port Pirie.These two processes have replaced continuous dezincing by oxidation, a high temperature process which caused large quantities of lead and antimony to be recirculated. As the final stage is a .batch process the product composition can be.checked before casting. Individual batches can be adjusted to produce special alloys to,consumer's specification.Improved casting equipment has allowed the quantity production of pigs of good physical characteristics either as 56 lb bars or 2000 lb pigs. This, together with the high purity of the lead, has assured the B.H.A.S. position in world markets.Automatic control systems have been extensively employed particularly on the vacuum dezincing unit.The anticipated financial benefits have been achieved mainly by a reduction in the tonnage of recirculated materials, a smaller labour force, and reduced maintenance requirements.

Jan 1, 1963

By T Raynlyn, S Hapugoda, V Nunna

The predominant phase in most Marra Mamba, channel iron deposits and detrital iron ore deposits is goethite. Goethite abundant iron ore fines tend to have complex mineralogical associations and fine dissemination of gangue material. These ores are typically challenging to process using conventional beneficiation methods. With declining ore grades, there is a need to develop new processing routes for low-grade goethitic ores/fines.Comparative process amenability studies were carried out using two different processing options to recover iron with low alumina and silica content from a low-grade goethite-abundant iron ore fines (-2 mm) sample from the Pilbara region of Western Australia. The first option involved dehydroxylation at 350°C and 400°C, followed by grinding dehydroxylated samples to 100 per cent passing 106 µm and magnetic separation. The second option was processing raw sample by gravity separation using a Floatex density separator. The performances of the two processes are discussed in terms of the iron grade-recovery responses, and an optimal processing route is proposed based on the findings from these tests.CITATION:Nunna, V, Hapugoda, S and Raynlyn, T, 2015. Process amenability studies on goethite-abundant iron ore fines, in Proceedings Iron Ore 2015, pp 165–174 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By C G. Ryan, D R. Cooke

The Thames gold-silver deposits are part of the Hauraki goldfield, situated within the Miocene to Pliocene calc-alkaline Coromandel Volcanic Zone (CVZ). The Waitangi vein system is one of the mineralised ore shoots in the Thames district. The Thames gold deposits are characterised by shallow-level epithermal vein mineralisation with phyllic to advanced argillic alteration assemblages and abundant sulphide minerals including pyrite, arsenopyrite, chalcopyrite, galena and sphalerite. Gold occurs as electrum in association with sulphide minerals. Sulphur isotope analyses of mixed sphalerite-galena and sphalerite-galena-chalcopyrite samples yield a narrow range of δ34 SCDT values (-1.0 to 0.9 ë; n=5), whereas late spongy pyrite gives unusually light sulphur isotope values (-16.7 to -27.9 ë; n=4). Vein quartz from the mineralised zone at Waitangi yields δ18OSMOW values from 6.8 to 12.7 ë (n=23). Fluid inclusion studies indicate a homogenisation temperature range of 190¦ - 296¦C and salinity range of 0.2 - 3.0 wt per cent NaCl equivalent. Similar temperature and salinity ranges have been recorded for the other gold deposits in the Coromandel Peninsula. PIXE (Proton Induced X-ray Emission) analysis revealed that the Waitangi ore fluids have 1090 - 2700 ppm K (average 1600), 145 - 205 ppm Ca (average 180), 80 - 100 ppm Mn (average 90), and 80 - 200 ppm Fe (average 120) but no detectable Cu, Zn, Br, Rb, Sr, Pb and Bi (only one fluid inclusion contains 28 ppm Zn). The sulphur isotopic values of base metal sulphides from Waitangi suggest that the sulphur was derived from a magmatic source (either directly, or by leaching of igneous sulphides). The calculated oxygen isotopic composition of ore fluids is between -2.1 to 3.8 ë at 250¦C and -0.1 - 5.8 ë at 300¦C. Oxygen isotope analyses have revealed significant variations in δ18O values with elevation and gold grades. Zones of gold enrichment coincide with a zone of variable oxygen isotope values at the top of the vein system, where boiling and/or fluid mixing most likely occurred. Mixing of ore fluids with convective ground water is a likely mechanism for gold deposition in a shallow environment for the Waitangi vein system and there is also lack of fluid inclusion evidence (eg liquid-rich and vapour-rich inclusions in the same growth zone) for boiling of ore fluids. Oxygen isotope values varying with gold grades within the Waitangi conduits suggest that δ18O values may be useful in targeting bonanza grade gold mineralisation in epithermal vein systems.

Jan 1, 1999

Since I first enrolled to study Mining Engineering, the idea of working with big machinery and explosives has always appealed to me. After a few courses at uni, combined with vacation work and a number of presentations at the New LeadersÆ Conferences I had attended, I began to realise that the explosives side seemed to have more appeal than the others. As I look back on the past two and a half years that I have spent with Orica Australia Pty Ltd as part of their graduate program, I would have never imagined the dynamics of explosives in mining. This I put down to the ever changing and rapid development in technology converting blasting techniques into a defined predictable science. The opportunities I have been given have delivered all the appeals from when I first started my study. As a result of my entry into a profession that uses explosives to deliver broken rock in a range of mining and construction projects, through the use of advanced blasting technology and products, my experiences have been wide and varied. These experiences have included the use of OricaÆs i-konÖ detonator technology and blast design software to allow for blasting operations to occur in a range of environmentally sensitive quarrying and construction projects throughout New Zealand, to the implementation of various Orica blast based services aimed at improving dragline dig performance and reducing coal loss thus improve overall mine sustainability in the coal mines of Central Queensland, to the advanced utilisation of Orica explosive products and technology in a number of the worlds largest copper mines in Chile. I have witnessed first hand the blasting technology available within Orica Mining Services to both deliver fundamental changes in mining results and in turn kick off my career with a bang.

Jan 1, 2009

By M I. Pownceby, N Karimian, J R. Manuel, M J. Peterson

The CSIRO ore classification scheme for Pilbara ores was used as a reference frame to target recognisable ore types/textures with potentially elevated phosphorus content for detailed analysis. Particles of each individual ore texture were separated from a Brockman high-P ore and each class was characterised using methods including XRF, XRD, EPMA and synchrotron-based XAS. Results were then correlated with optical microscopy and hand specimen identification to establish any relevant associated mineralogical phases and/or textures. This represents a more systematic approach to identification of high-P ore components based on particle and goethite type and texture. The information can then provide the basis for more targeted P-removal strategies factoring in the relationship between particle/ore texture and phosphorus deportment

Sep 18, 2023

Froth flotation is widely used for the separation of particulate materials in the world. It is a complex process whose operational behaviour in process plants is difficult to predict. A comprehensive phenomenological dynamic flotation model was presented at the 1982 IMPC. This model uniquely linked the particle/bubble interactions and water transport phenomena to the flotation cell hydrodynamics. The model was used as a dynamic framework to analyse and develop process optimisation strategies. New developments in mineralogical characterisation, real time information management systems and data validation simplify the implementation of flotation technologies for mine to mill grade recovery optimisation. With recent developments in software programming, dynamic simulation enables process engineers to develop process alternatives interactively. This paper presents such an implementation of current process analysis tools and an updated froth flotation dynamic model. It demonstrates how this new environment can be used to improve our technological knowledge of flotation, eg alternative bubble/particle attachment and detachment microprocesses can be incorporated. The dynamic flotation model has several manipulated variables (such as feed flow rate, per cent solids, aeration, wash water flow rate, frother flow rate, specific power energy (impeller speed/delta pressure), cell geometry and tails flow rate) and evaluates the dynamic effects of these variables on grade and recovery.

Jan 1, 2005

By R Winterberg

Concrete is a well established and reliable construction material for the permanent lining of tunnels, but shows some weak performance characteristics, which can be overcome by the addition of specialised fibre reinforcement. This paper addresses the particular performance design requirements of segmental linings, discussing the improvements of fi bres on concrete properties. Focus is made on the beneficial effects of fibre reinforcement on the cracking behaviour and the toughness performance, providing a safe and durable tunnel lining.Not only the mechanical performance of fibre reinforced concrete (FRC) for segmental linings, but also the durability of the linings has gained growing attention among the designers and consultants. Especially tunnel linings with exposure to media with corrosion potential, such as wastewater sewer tunnels or desalination plant outfall tunnels, have high requirements on their durability. The design of these structures must provide a comprehensive study of durability aspects. Fibre reinforcement can substantially improve the durability of concrete.Research has been carried out on the cracking behaviour of concrete. The beneficial effects of steel fibres on the cracking behaviour reduce the permeability by reducing the flow paths within the concrete. Crack bridging steel fibres create necking effects in bending cracks, leading to earlier closure of the cracks. Further, steel fibres create particular crack formations, which lead to a substantial reduction of the fl ow rates through separation cracks. The results also show that considerable cost savings can be achieved using FRC, as the thickness of the linings can be reduced.The durability design issues will be addressed and underlined by a case history on the Hobson Bay sewer tunnel in Auckland, New Zealand.

Mar 8, 2011

By M Ahler

Future developments in the mining sector will be driven by the need to increase safety, ecological sustainability and efficiency. Autonomous systems represent a huge step towards achieving these goals. This paper describes the basic infrastructure of an autonomous system – essentially a network of distributed sensors. Although the sensors are distributed, the overarching communication network with its related middleware offers a transparent and uniform layer. This middleware acts as an abstraction layer which priorities information and provides information to other platforms on request. This permits higher-level autonomous functionality to utilise all information available in the system regardless of where data has been generated or via which physical communication link it has been processed.The Personnel Proximity Detection (PDD) system is described in detail as an example, with details not only of the system itself, but also of the essential full integration and how the abstraction layer allows this technology to be plugged in at any location of the network. The paper ends with a summary of the content and a conclusion.

Nov 22, 2011

By Toro HCH, Von Borries GH

A brief description of the semi-autogenous grinding (SAG;) facilities of Compania Minera Disputada de Las Condes is given. A data-logging and computer system was connected to the plant inter facing the existing analog control system in a supervisory s, control philosophy. The development of a control straiov,v t,) maintain maximum power of the SAG mill atsubjected to process restrictions is shownThe present control scheme is discussed inalgorithm was designed based on correlations onLween vartaoles. Associated with this, a direct level of control was developed be, on classical control algorithms, process inter-active tuning has been included. Also, an algorithm to prevent overloading of the is discussed. Control scheme tests are presented in comparison t manual operator control under the same conditions. It is shown t the control strategy gives a more stable operation and a higher plant throughput.

Jan 1, 1985

By Z U Bajwah

During the Palaeoproterozoic, a large number of granitic intrusions were emplaced in the various parts of the Pine Creek Geosyncline (PCG). In the central region, the granitic magmatism is represented either by the coalesced mass, eg the Cullen Batholith, or individual plutons such as the Mount Bundey Granite which together with the Mount Goyder Syenite intrude the metasedimentary strata, causing wide spread contact aureoles. Some of these granitic intrusions are temporally and genetically related to gold (and less commonly base-metals) mineralisation present in the adjacent metasediments. These plutons are characterised by the presence of biotite and homblende which appear late in the paragenetic sequence. Electron microprobe analyses of biotite and homblende show that these minerals are poorly to moderately zoned. Biotites are characterised by a decrease in Fe/(Fe + Mg) ratios when plotted against AIVI. Similarly a modest decrease in Ti from centre to the margins of the biotite crystals has also been observed. Furthermore, an increase in Mg/(Mg + EFe) ratios from centre to the margins as well as in mafic to felsic rocks is also apparent. On the other hand, homblendes from the granitic bodies display less well marked trends and are poorly zoned. However, they show systematic increases in Mg/(Mg + EFe) ratios, and decreases in Fe, Al"' and Fe/(Fe + Mg) ratios, when plotted against Si. Magnetic susceptibility measurements on powdered samples of the plutons give results characterised by high values ranging from 0.8 x 10-4 to 2.0 x 10-3 emu/g which place the granites in magnetite- series field. This indicates that the oxidation state of the magma was high during crystallisation. The range of chemical compositions of the mafic phases indicates a rise in the oxidation state of the magma as it progressively became saturated in H20-volatiles and other metals, not partitioned into the earlier crystallised phases in the final stages of magma consolidation. These variations in chemical compositions also indicate that initially fOz was high and became progressively higher during fractional crystallisation of magmas; this subsequently led to the emanation of hydrothermal fluids responsible for the mineralisation in the adjacent metasediments.

Jan 1, 1994

By Allnutt S. L, Radojkovic A. M

Century, a major shale hosted zinc deposit in the Riversleigh Fold Zone of northwest Queensland's Mount Isa Basin, was discovered by CRA Exploration in 1989. A total of 322 drill holes, completed by the end of 1992, define a resource of 118 Mt of mineralisation averaging 10.2 per cent zinc, 1.5 per cent lead and 36 grams per tonne silver. Mineralisation is developed in the upper portion of Lawn Hill Formation Unit 4 (Pmh4). The intersection of the Termite Range and Little Range Faults, major regional structures, may have been important in controlling mineralisation development. Three listric normal faults, and an unconformity between Proterozoic rocks hosting mineralisation and overlying Cambrian carbonates, divide the deposit into three distinct blocks. The deposit is essentially blind, outcropping in only two places. The deposit is characterised by an extremely simple sulphide mineral assemblage, sphalerite being the most common sulphide phase. Pyrite, the most common phase in many other shale-hosted zinc-lead deposits, accounts for only five per cent of all sulphides present. Siderite is the principal non-sulphide phase present. Both sphalerite and galena have near stoichiometric compositions. Sulphides are confined to carbonaceous shale horizons. Intervening siltstones are essentially barren. Shale and siltstone beds forming the mineralised sequence can be correlated across the entire deposit area. Systematic grade variation occurs within each mineralised shale bed. Although sulphide laminae parallel primary lithologic layering, the point of most intense mineralisation development transgresses stratigraphy. Bituminous material is intimately associated with sulphide mineralisation.

Jan 1, 1993