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Removal of Dilute Toxic Anions in Wastewater Using Aluminum Hydroxides Co-Precipitation Method

Sep 13, 2010

By J Loimi, P Minkkinen, T Korpela

The head loss caused by metallurgical sampling for slurry streams can be reduced by metallurgical sampler design. When the process volumetric flow rate is reduced by vertical static cutters before the sampling by an equal number of moving cutters to the static cutters, the installation requires less installation head space than other sampling arrangements and is easy to accommodate at suitable locations in the process. Low head loss reduces building costs for the processing plant and operational costs during the lifetime of the plant.The presence of a possible systematic bias in the particle size distribution, solids density and elemental composition between an Outotec MSA 2/50 metallurgical slurry sampler sample and MSA 2/50 manually sampled reject have been studied by a customer. The paired samples were taken as simultaneously as possible. The customer evaluated the possible bias using a paired t-test and provided the assay results to Outotec for further evaluation.The results of the paired t-test showed no systematic bias in particle size distribution, solid density or assayed analytes, except in one analyte with low content and a high relative error. The high relative error in one analyte may have been caused by the same calibration model used in a X-ray fluorescence analyser for both high elemental-content concentrate and very low elemental-content tailings samples. The sampled stream is the tailings of a previous process stage.The results of the t-test were studied further using analysis of variance to reveal the error sources in samples. The results showed no bias between the samples collected from the MSA 2/50 reject and composite samples collected of the MSA 2/50 sample stream. The courier online analyser data was also available for evaluation of representativeness to the process stream.The analysis results of the courier online analysis reveals no bias between the MSA 2/50 reject samples, MSA 2/50 sample stream composite samples and online analysis results during the comparative sample collection period.CITATION:Loimi, J, Minkkinen, P and Korpela, T, 2017. Comparative evaluation of manual sampling and Outotec MSA 2/50 metallurgical slurry sampler, in Proceedings Eighth World Conference on Sampling and Blending , pp 167–172 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2017

By R Young, D OÆSullivan

When Centaur Mining and Exploration produced nickel metal fromlaterite ore at its Cawse nickel project in January 1999, a new era in the nickel industry was heralded in. One of three new laterite projects commissioned that year, new technology and a unique process design has been combined at Cawse to launch what will be amongst the worldÆs cheapest nickel production. However, the road to success has proven to be long and challenging. This paper explores CentaurÆs approach to the Cawse start-up and discusses a number of issues that have been confronted and overcome. * Originally published in the Proceedings of the Seventh MillOperatorsÆ Conference, published by The AusIMM.

Jan 1, 2001

By L A. Maslov

We have considered the following characteristics of the crust and upper mantle of the Pacific Belt: seismic wave velocity anomalies, mechanical stress and shear deformation rate fields, heat flow and the pattern of metallogenic provinces of the Belt. It has been noted that there exist certain .regularities in distribution of the above mentioned geophysical characteristics and metallogenic zones within the Belt, displayed by prevalence of the lithophile elements in the Asia-Australian part of the Belt, and of the chalcophile ones within the American part.

Jan 1, 1995

Laboratory and pilot plant investigations aimed at recovering gold as an electroformed sheet from gold eluate and gold leach solutions and slurries are discussed. The electrolytic test work undertaken makes use of high surface area electrodes, in particular nickel-chrome foam metal and activated carbon, as well as ultrasonic activation. The process involves initial gold electrowinning (or adsorption onto activated carbon), followed by gold electroforming, both operations being carried out in a specially designed reactor. The pilot plant work mainly involved the treatment of gold eluate solutions from a South African gold mine containing 600 mg/L Au: some tests were also carried out on gold leach solutions containing 6 mg/L Au. In the former case, very efficient gold extraction onto the foam metal cathode was achieved using electrolysis combined with ultrasonics. The polarity of the gold-loaded cathode was then reversed and, using a replacement electroforming electrolyte, gold was electroformed in situ onto a polished stainless steel mandrel, from which gold sheet was subsequently removed. In the case of leach solutions, pilot plant tests confirmed laboratory findings that in the presence of calcium (resulting from the lime used during the leaching process) no electrowinning is possible. Laboratory tests showed, however, that when sodium (in the form of NaOH or Na2CO3) is added to the leach solution, electrowinning can indeed take place. Alternatively, if a special activated carbon electrode is used (without current), the non-ionic calcium aurocyanide complex is adsorbed on to the activated carbon. When a gold-loaded activated carbon electrode is made anodic in a gold electroforming electrolyte, gold electroforming is feasible, although the efficiency is very low. The possible implications of these developments for gold recovery are further examined.

Jan 1, 2007

By A J. Eggers

With gold first discovered at Carrick in 1864, exploration and mining on the Carrick Goldfield in Central Otago, New Zealand, has now been ongoing for more than 130 years. Recorded historical hard rock production from up to 52 different mining claims from 1864 to about 1921 is 24,047 ounces (oz) of gold.   Since 1980 Amoco Minerals New Zealand Limited, CRA Exploration Pty. Limited, Amax Gold Mines New Zealand Limited and Summit Gold (New Zealand) Limited have conducted modem systematic exploration campaigns targeted at locating shear controlled gold bearing quartz lodes and stockwork deposits. More than NZ $1million has been spent by these companies on aerial photography, geological mapping, stream sediment surveys, soil and rock chip geochemistry as well as reverse circulation (RC) percussion and diamond drilling.   RC drilling by Summit Resources in 1997 has identified a 1,500 m long zone of low-grade gold mineralisation at Lower Carrick, with an average grade of 1.00 g/t Au over a 14 m average thickness. This gold mineralisation, hosted within a low angle shear zone, has analogies with the Hyde-Macraes Shear Zone in eastern Otago. Recent exploration and drilling at Carrick has revealed the potential to discover large (>0.5 million ounce (Moz)) low-grade bulk shear controlled quartz vein and stockwork gold deposits similar to those now being mined at Macraes.

Jan 1, 1997

By C De-Vitry

"The large Yandi channel iron deposit (CID) is located in the north-west of Western Australia and is currently mined via open pit methods. Drilling at Yandi is widely spaced and current estimates are mostly linear averages of the surrounding local samples. Linear estimates such as ordinary kriging (OK) based on block sizes that are significantly smaller than the dimensions of the drilling grid are less variable than the unknown reality (Armstrong and Champigny, 1989).Conditional simulation (CS) provides a series of plausible realisations that represent the actual grade variability at a small scale (eg 1 m + 1 m + 1 m). These simulations are very useful for a number of purposes, eg: optimising grade control, stockpiling and blending selection of optimal drill hole spacing assessing resource risk on contained tonnage and metal.At Yandi the major constituents of the ore (Fe, P2O5, SiO2, Al2O3 and LOI) are correlated to varying degrees. Independent CS of each assay variable will not reproduce these correlations. Reproducing the correlations (and the shape of scatterplots) is important if the simulations are used for the abovementioned purposes. This paper examines and compares various methods of CS that aim to reproduce the correlations between the assay variables.The CS methods evaluated in this paper are conditional co-simulation (CCS) using the linear model of co-regionalisation and two other, alternative multivariate simulation methods, which use min/max autocorrelation factors (MAF) or the stepwise conditional transform (SCT) to de-correlate assay variables before performing independent CS. It was found that CCS best reproduced the characteristics (histograms, variogram, scatterplots, etc) of the declustered drill hole data (Figure 1). Whilst simulation using MAF generally produced acceptable results, the method did not adequately reproduce the variance of the assay variables. The univariate statistics, histograms and experimental variograms were acceptable for simulations generated from the SCT. Bivariate statistics, cross-variograms and scatterplot reproduction for the SCT were unacceptable. The latter method produced inferior results because there were insufficient samples to obtain a reliable transform of the third assay variable in the transformation sequence.None of the abovementioned simulation methods provides good reproduction of all the scatterplots. This is due to the presence of clay pods, which cause some scatterplots to display two trends. These clay pods contain higher percentages of SiO2 and Al2O3 than the surrounding CID. The clay pods are generally smaller than the drill-grid dimensions. Thus their locations are typically unknown and they cannot be defined by manual interpretation, eg via wireframes. The locations of the clay pods were simulated via indicator CS. CCS was then performed separately for the clay pods and the CID. This significantly improved the reproduction of the correlation coefficients, the scatterplots and visually the simulation was more geologically realistic. Simulating the location of clay pods followed by CCS of assay variables is the recommended approach for simulation at the Yandi CID.CITATION:De-Vitry, C, 2013. Simulation of correlated assay variables - a case study from the Yandi Channel iron deposit, in Proceedings Iron Ore 2013, pp 137-148 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 12, 2013

It is no longer satisfactory to assess the value of a coking coal on its intrinsic properties alone; its value depends upon its behaviour as a component in a blend. No single test can be used to make this assessment, it can only be made by carrying out a suite of tests. The quality parameters which are considered desirable, and which have widespread acceptance, have been discussed and their application to the blending of coals from New South Wales and New Zealand has been reported and discussed. Blending can be utilised to offset deficiencies, or capitalise on advantages, of the individual coals making up a blend. Coals can be blended, which alone are poorly, Coking, but which have compensating features. Blending also allows better exploitation of coking coal reserves. Several applications of blending have been reviewed with regard to coal producers and exporters, as well as coal users. The possibility of extracting a coking coal fraction from fuel coals is discussed. Blending systems and the coking of coal are also briefly reviewed.

Jan 1, 1971

Study on Flotation Experiment of Complex Copper-Lead-Zinc Polymetallic Sulfide Ore in High Altitude Area and its Industrial Application

Sep 13, 2010

By J R. Lang, J K. Mortensen

The Canadian Cordillera contains numerous classic porphyry deposits and several unusual subtypes, including the alkaline suite of porphyry Cu-Au deposits and the Tombstone magmatic suite and associated Au¦W deposits. The alkaline suite formed in collisional settings in island arcs whereas the Tombstone suite was emplaced in an active fold and thrust belt in a continental arc. In addition to different regional settings, these suites differ in the type of underlying basement, metallogeny, and the styles of mineralization. Both magmatic suites were emplaced over short intervals, probably in response to specific tectonic events. In the case of the alkaline suite, the tectonic event promoted magmatic processes suitable for the formation of porphyry Cu-Au deposits. The tectonic environment is less well constrained for the Tombstone suite, but the result was the formation of distinctive porphyry and intrusion-related Au¦W deposits.

Jan 1, 1995

By M P. Simpson

Forty one whole rock samples from the Gold Cross low-sulfidation epithermal Au-Ag deposit have d18O values that range from 4.4 to 9.3 per mil, with an average value of 7.0 per mil. Unaltered and weakly altered rocks have d18O values greater than eight per mil, and the orebody is surrounded by samples that are depleted in 18O. A strongly silicified sample adjacent to the Empire Vein System has a d18O value of 9.0 per mil, similar to previously reported analyses of vein quartz (7.0 to 11.7ë, average 9.4ë). This suggests that, in detail, Golden Cross may have a zone of 18O-enriched wall rocks in the core of the deposit, adjacent to the main underground veins. Although some workers have suggested that stable isotope geochemistry may provide useful information for epithermal mineral deposit exploration, at Golden Cross this is not the case. Alteration minerals, major elements and trace elements all define larger, less ambiguous halos than the zone of 18O-depleted wall rocks.

Jan 1, 2001

By R Mann, R Prasad, S Vink, V Nanjappa

The level of salinity that various aquatic organisms can tolerate without incurring any adverse effects is dependent on several environmental and evolutionary factors. These factors include the relative concentrations of different types of dissolved salts in the water that makes up their habitat, the regimes to which organisms are exposed to waters of differing salinity levels (including naturally derived variations), the degree to which an organismÆs life history stages have adapted to salinity, an organismÆs ability or behaviour to avoid adverse levels of salinity and an organismÆs capacity for osmoregulation.Release of saline water into rivers of the Fitzroy catchment has created concern about the impact on aquatic organisms. Not only is salinity itself a stressor on organisms but different ionic compositions will moderate the effects. Ecotoxicology experiments were conducted using artificial saline water based on mine water chemistry using sensitive macroinvertebrates collected from the catchment, as well as a range of laboratory organisms in accordance with the ANZECC and ARMCANZ (2000) guidelines. The 95 per cent ecosystem protection value calculated from species sensitivity distribution derived from the commercial tests was estimated to be ~2.0 mS/cm. For the protection of 99 per cent of the species the salinity has to be reduced by more than 50 per cent to 0.91 mS/cm. The electrical conductivity (EC) values, derived by commercial testing and species sensitivity distribution in this study suggests that salinity contaminant trigger values previously developed using a referential approach for protection of aquatic ecosystems from saline mine water releases in the Fitzroy may be conservative.CITATION:Vink, S, Mann, R, Nanjappa, V and Prasad, R, 2013. Determining the impacts of salinity on freshwater organisms, in Proceedings Water in Mining 2013 , pp 149-154 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

This paper reviews the development and operation of a small underground tin mine in NE Tasmania. Tin mineralisation was discovered in the Lottah area in the 1880s with early alluvial and eluvial workings leading to the development of large low grade open pit operations. Apart from short lived activities operations ceased in 1915. Intensive exploration in 1978 - 1981 outlined substantial tonnages of low grade tin mineralisation (0.2% Sn) of open pit material. An underground ore body was also located (800 000 tonnes 0.6 per cent Sn). Spectrum Resources Australia Pty Limited acquired a 98 per cent interest in the property in 1988. Mine and mill development began in early 1989 based on an underground mine utilising trackless mining using room and pillar with fill stoping. The milling circuit involves primary jaw crushing, Barmac secondary crushing to 1 mm, Mogensen and DSM screens with jigs and tables to make a wet concentrate. Final tin concentrates are produced by high tension and magnetic separation. Planned production rates are 500 t/day with a mine life of six to seven years.

Jan 1, 1990

By G Metzner, R Rodriguez, C Savage

OK Tedi Mining Ltd. (OTML) is in the process of optimising the concentrator performance. One aspect that has been recently implemented is an upgrade of the existing expert control philosophy on the grinding circuit and this will be the topic of this paper. Ore grinding in SAG mills is a multi-input multi-output (MIMO) process subject to several disturbances, most typical being quick acting disturbances such as changes in ore characteristics like hardness and particle size and slow acting disturbances such as ball charge variations and liner wear. The OTML SAG mills treat ore from diverse ore bodies and receive fresh feed subject to large changes in particle size. These circumstances make these mills particularly challenging to control. In this paper, a comparative analysis is presented between the performance of the OTML SAG mill #2 before and after the commissioning of a hybrid control strategy. The strategy uses Expert Knowledge combined with advanced disturbance rejection to reduce the variability of the main process variables, especially pressure and power. It further optimises the overall operation by driving the SAG mill #2 against process constraints (e.g. high power, high motor temperature and high scats recycle rate) and maintaining the operation at or near this point. This strategy is implemented by a combination of the manipulated variables (i.e. fresh feed tonnage and % solids) at any given time.The paper will present trends and a statistical analysis of the comparative results of the mill operation over a period of months, showing a 30% reduction in mill power / pressure variability and a 12% improvement in average power drawn. An increase in throughput was also observed, but cannot be conclusively attributed to the change in mill control due to other changes that were made to the SAG mill #2 during the period of comparison. An additional benefit includes better acceptance from the operators with improved consistency of the SAG mill #2 operation across shifts.The paper will also discuss further improvements envisaged in the continued optimisation of the grinding control circuit.CITATION:Savage, C, Rodriguez, R and Metzner, G, 2013. Hybrid process control strategy for the Ok Tedi Mining Ltd semi-autogenous grinding mill #2 - A comparative analysis, in Proceedings MetPlant 2013 , pp 202-214 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

The structure and tectonic setting has had a strong influence on gold mineralisation at the Porgera gold deposit. Here, the structural controls on the mineralisation at Porgera are discussed and placed in a regional tectonic context. The Porgera gold deposit is related to the emplacement of the Porgera Intrusive Complex. Prior to intrusive emplacement at Porgera,Papua New Guinea was affected by a major fold and thrust episode which occurred in response to arc-continent collision in the Late Miocene. After crustal shortening the region experienced a relaxation of compression which is expressed in the deformation accompanying mineralisation at Porgera. The first stage of mineralisation (stage I) is hosted by extension fractures, and is spatially associated with exposed intrusive stocks. A later episode of mineralisation (stage II) is hosted by the faults and fractures of the Roamane Fault Zone, which was active as a dip-slip normal fault during stage II mineralisation. Therefore a change in the tectonic environment from shortening to extensional tectonics can be seen at Porgera before and during mineralisation. Rapid fault-slip during stage II mineralisation may have aided high-grade gold mineralisation by subjecting hydrothermal fluids to changes in pressure, temperature, fluid-fluid and fluid-rock interaction. Uplift to form the highlands of Papua New Guinea occurred after mineralisation and was largely complete by 4.0 Ma.

Jan 1, 1995

The Mount Angelo prospect outcrops as two copper rich gossans, the larger of which is 250 ft long and 70 ftwide. The mineralization is epigenetic and replaces part of a brecciated and disturbed lime tone and calcareou sediment sequence.Magnetic and self potential survey indicated a substantial body of sulphide mineralization, the top of which was approximately 100 ft below the surface.Diamond drilling confirmed this and established the presence of a mineral body of at least 500,000 tons, extending to a depth of 300 ft. Of the 500,000 tons, 200,000 ton are primary copper ore which a ays 2 per cent copper.This mineral body is not economic at present, but could become economic if copper mining is established elsewhere in the district...

Jan 1, 1966

By R WOODS

The interaction of, flotation collectors with sulphide mmerals takes place at the solid-solution interface. The electrochemistry of the processes which affect this interface are discussed. The interaction of xanthates with sulphides is an electrochemical process, xanthates being electro-oxidized to chemisorbed xanthate and dixanthogen.The role of oxygen is to provide a cathodic process to allow the anodic oxidation to occur. The hydrophobic condition of the mineral surface is brought about by the presence of the oxidized xanthate species. The action of reagents which can activate or depress the flotation of sulphides is discussed briefly.

Jan 1, 1972

Structurally- controlled deep leaching processes have removed vast quantities of carbonate from a substantial portion of the "silica-dolomite" enclosing the 500 copper orebody. Mine drainage subsequently allowed free access of air to the porous environment created and oxidation of sulphides commenced. During the mIne development stage the exothermic and temperature-dependent nature of these hydrolysis reactions resulted in a slow general elevation of ground temperatures. and levels of 90 - lOO°C were attained in restricted moist sulphide-rich areas.With the advent of production and extensive use of explosives, the oxidation processes were locally raised to new levels of activity. Direct interaction of explosives and sulphides in favourable conditions caused temperature rises to above 260 C. Above this point the dry oxidation of sulphides in air was initiated and rapid escalation to the vicinity of 800 C has been known to occur in isolated cases.Ground reactivity is a function of the complex interrelationship of several controlling factors and no simple index exists.Control techniques are presently aimed at prevention of temperature rises in the range 100 -260 C. Inhibition of the rapid dry oxidation processes above 260 C is difllcult and current efforts have met with only partial success.

Jan 1, 1968

The areas of concern lay in the processing of, and the subsequent hearing into, Waihi Gold's resource consent applications to extend Martha Mine. The proposed amendments to the Resource Management Act 1991 might see the introduction of contestability in the processing of applications - which would have assisted Waihi Gold; and the use of commissioners to hear the applications, with a right of appeal to the Environment Court on points of law only. It is also proposed to have major applications heard directly by the Environment Court. If Waihi Gold's applications had been heard at first instance by the Court, the delays in time and associated costs would have been reduced. However a hearing by commissioners only would not have been satisfactory, there being no right of appeal against the conditions of consent, which if implemented as granted by the Councils would have had a significant impact on the costs associated with the extended project.

Jan 1, 1998

The Nena high sulphidation-type copper-gold deposit is composed of andesitic pyroclastic units with minor interstratified lava flows. Epiclastic sandstone and conglomerate, and siliciclastic rocks consisting of mudstone, shale, lithic and bioclastic sandstone and conglomerate are locally present. Pre-mineral diorite intruded and domed the volcano-siliciclastic sequence. Economic copper-gold is hosted by vuggy quartz altered lapilli tuff and tuff breccia. The early hydrothermal alteration stage involved deposition of epithermal banded quartz and chalcedonic silica in localised environments. This alteration stage was locally superimposed by a hydrothermal breccia event. Following the breccia event, magmatically-derived volatiles were channelled through a NW striking dilational fault zone and generated the high sulphidation alteration. The high sulphidation alteration is zoned from a vuggy quartz core with local massive replacement silica through a broad pyritic quartz-alunite halo and finally to a thin illite-smectite zone. This is surrounded by regional chlorite-epidote-smectite alteration. A gangue mineral phase consisting of quartz, alunite and baryte overprinted the zoned high sulphidation alteration and preceded the main copper-gold-arsenic mineralisation. Early sulphide deposition is characterised by marcasite, arsenical pyrite and melnicovenite. Main-stage copper-gold mineralisation involved sequential deposition of hypogene bladed covellite+chalcocite, enargite-luzonite and luzonite+stibioluzonite respectively. The copper sulphides are zoned from bladed covellite-chalcocite in the north (cross-sections 5000 - 5600 N) through enargite-luzonite (cross-sections 4700 - 5000 N) and to luzonite????stibioluzonite in the south (cross-sections 4400 - 4700 N). A late phase of minor acicular covellite and enargite+luzonite overprinted the zoned copper sulphides and associated gold mineralisation. Gold mineralisation commenced at the transition from enargite to luzonite, and continued through the deposition of luzonite-stibioluzonite in both stages. Most gold was deposited during the main-stage mineralisation. Yellow native sulphur was deposited in the remaining vugs and defines the waning stage of the hydrothermal system. Post-mineral dioritic intrusives and feldspar porphyries intruded the volcano-siliciclastic sequence. Finally, supergene chemical processes with associated erosion and uplift generated a 40 - 50 m thick oxide-hosted gold cap. The oxide gold cap is underlain by a 35 - 45 m thick blanket of supergene chalcocite+covellite mineralisation which overlies and occurs throughout the main hypogene copper-gold zone. Supergene gold is related to the distribution of primary gold-bearing sulphides. Therefore, remobilisation and redeposition of gold are considered to be insignificant and very localised.

Jan 1, 1999