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By Mario Terceros H, Bengt H. Fellenius

"ABSTRACTThe city of Santa Cruz, Bolivia, is historically dominated by houses and three to five storey buildings.The geology in and around the city is such that even very light buildings need to be supported onpiles. The recent increase of the Bolivian economy, notably that of Santa Cruz, has created a demandfor new residential as well as office and industrial buildings, which mostly consist of multi-storey orhigh-rise buildings with significantly larger foundation loads. Foundation piles have become largerand longer, and the load on individual piles is increased. The development has resulted in an increasein the demand for more sophisticated design and construction methods and stricter approach toverifying the quality of the construction processes and results.This paper describes to geology of the Santa Cruz region and how the geotechnical conditions areconsidered in the design and construction of piled foundations. The improvement of past constructionand design techniques, based mostly on bored piles constructed with bentonite slurry, is beingreplaced with new methods of constructing bored piles, e.g. the Full Displacement Pile (FDP) andincorporation of techniques such as enlarging the pile toe, e.g., with the Expander Body. This paperpresents the results of several full-scale tests and discusses the incorporation of the test results indesign and construction.1 GEOLOGY OF THE REGIONSanta Cruz de la Sierra is located in the eastern lowlands and sub-Andean zone of Bolivia, SouthAmerica. The area lies at an elevation of about +400 m and the geology is a Paleozoic (250 millionyears old) sedimentary basin. The soils of interest to civil engineering construction are quaternarywith the dominant minerals being calcite, silica and feldspar. The main agent is the Piray River and itstributaries. Their past meandering over the area has resulted in a sedimentation-erosionsedimentationprocess and a profile dominated by fine to medium sands with intermittent layers ofclay or clayey sand. With increasing distance from the river, the clay-containing layers are thicker.Fig.1.- View of Bolivia with location of Santa Cruz and map of Santa CruzThe upper about 15 to 18 m thick part of the profile consists of normally consolidated layers of clays,silts, sands, in various combination and thickness. Below, the soil is more homogeneous and consistsmostly of sand and gravel. The groundwater table lies typically at a depth of about 6 m in the highestpart of the city and at about 1 to 3 m depth in the lowest part of the city."

Jan 1, 2014

By David Stephenson, Hugo Granados, Steven Klohn

"HudBay’s Constancia project is a copper molybdenum concentrator located in southern Peru. In 2010 Ausenco was contracted to perform a feasibility study optimization review which resulted in an improved design with significantly increased throughput capacity at a minimal increase in capital cost. Construction began in 2012 with commercial operation commencing in May 2015. This paper outlines the process plant design as well as describing the plant’s major equipment selections, start-up and early operations experiences.IntroductionHudBay Mineral’s Constancia project is located at 4200 meters above sea level (masl) in southern Peru, approximately 630 km south-east of Lima, Peru. The property can be accessed by road from Cusco, Peru, (approximately 110 km to the north), or from Arequipa, Peru (approximately 215 km to the south). Matarani, accessed via Arequipa, is the closest port.Constancia is located within the Yauri-Andahuaylas metallogenic belt. The region contains several large copper-gold-molybdenum porphyry deposits such as Antapaccay (by Glencore) and Los Chancas (by Grupo Mexico), and copper skarn deposits such as Tintaya (by Glencore) and Las Bambas (by MMG). Constancia’s ore reserves contain copper and molybdenum with trace amounts of gold and silver.Ore is mined by an open-pit operation. The process plant recovers copper and molybdenum concentrates, storing tailings in a conventional tailings management facility. Infrastructure at the site includes a grid power supply (via a 70 km overhead transmission line from Tintaya), water supply, workshops and an accommodation camp. Mine life is 22 years.Site construction works began in 2012 with first copper concentrate produced in late 2014. The project was executed for approximately 1.75B$USD.Ausenco’s design approach focussed on developing a capital efficient copper molybdenum concentrator. This paper outlines key features incorporated in the concentrator design, plant layout and equipment selection, as well as start-up experiences and early operational results."

Jan 1, 2016

By Michael S. Wieland

This report focuses on the U.S. Bureau of Mines research regarding desensitization and malfunction of delay detonators and cap-sensitive explosives. Delay blasting in underground coal generates tremendous shock waves and rifting forces that fracture and heave coal. The shock waves from charge explosions radiate outward in all directions through the coal, impacting neighboring charges with later delays. The impact phenomena have debilitating effects, causing degrees of reduced charge performance ranging from misfires or weak detonations to out-of-sequence detonations. Impaired charges react poorly, fracture less coal, and produce fumes with higher toxicity. Coal-mine, underwater, and simulator tests were conducted to more thoroughly understand the shock damage mechanism. Recently the U.S. Bureau of Mines partially resolved the malfunction problem by demonstrating the feasibility of formulating a rugged explosive. This rugged cap-sensitive candidate passed the requisite tests for certifying an underground coal-mine explosive. With natural aging the formulation rapidly lost initiation sensitivity. The charge formulation had to be rebatched to finish the testing and therefore could not be certified.

Jan 1, 1992

By Lonie W. M

The rapid development of the Australian steel industry over the past twenty years has greatly increased the demand for coking coal from the collieries owned by the Broken Hill Proprietary Co. Ltd. and Australian Iron & Steel Ltd. This in turn has called for an intensive and continuous programme of colliery expansion and new colliery development, along with the reorganization and modernization of existing collieries.This paper presents a general description of the factors involved and the techniques used in planning modern colliery development for the steel industry.PRELIMINARY GEOLOGICAL INVESTIGATIONSIn any colliery development, preliminary geological investigations require a detailed and practical knowledge of the geology and characteristics of the coal-field as a whole. In the early stages of the investigations, probably the most valuable information is obtained from outside the particular area under review, rather than within it, and unless the geology of the coal-field is understood, the projection of the known information into the unknown area cannot be carried out with certainty.Because development of the coal seams from the outcrops has been an apparently simple matter and not subject to the risks involved in deep mine development, the geology of the New South Wales. coal-fields has not received the attention that major mineral resources warrant.Only the most accessible regions of the coal measures have been generally prospected, while the potential areas remain...

Jan 1, 1957

By J Wei, A Yo, R Levy

Waste water reuse from municipal and industrial effluents is becoming increasingly important in many areas around the world. Water scarcity, local regulation and environmental impact are driving many industries like coal and copper mines to reuse the large volume of waste water they produce. For example, the Chinese coal industry generated about 4.2 billion tons of mine waste water in 2005 of which only approximately 30 per cent was reused. Coal energy represents 76.6 per cent of the total energy generated in China in 2007 and most of the coal-fired power plants are located in north-west of China, which is a water stressed area.The selection of mine waste water treatment process is challenging as the effluents typically contains high levels of organic compounds and salinity and their composition can vary significantly. In recent years there has been a growing interest in the integration of ultrafiltration (UF) and reverse osmosis (RO) membrane technologies for mine waste water treatment and reuse.In this paper, an overview of the design and performance of ultrafiltration and RO membranes applied for reuse of mine waste water are discussed. A study was carried out in two effluents treatment plants treating copper and coal mine waste water, which are located in Chile and China respectively. The following topics will be discussed to demonstrate the performance of an integrated membrane system in mine waste water reuse: The main challenges from copper mine waste water treatment: high level of chemical oxygen demand (COD); high level of total suspended solids (TSS); high salinity; high concentration of silica, sulfate, iron and other contaminants; and fluctuation of raw water quality. The main challenges from coal mine waste water treatment: high level of total dissolved solids, and waste water quality fluctuation. Design parameters for waste water treatment systems: Selection of pretreatment for dual-membrane system in the copper mine: Clarifier with coagulation and flocculation to remove high TSS; Dissolved Air Flotation (DAF) to remove non-settling solids; Media filtration to handle fine solids and particulate organics; Activated Carbon filters (ACF) to remove dissolved organics, colour and odours. Selection of UF and RO membranes and specific design of their recovery, flux, chemical dosage and cleaning regimes. Finally, the performance of UF and RO, including the main fouling factors and efficient cleaning procedures, will be presented and compared to the design parameters to demonstrate the efficiency and performance of the selected integrated membrane systems in each case.

Jan 1, 2009

By W. A. Tiller, J. D. Harrison

HOT pressing of powder particles has gained importance recently, since it affords a method in which high densities are rapidly attained. In a recent study on hot pressing of alumina powders, Mangsen, Lam-bertson, and Best1 have shown within the limits of their experiment, the validity the rate equation for densification in hot pressing, originally proposed by Murray, Livey, and Williams.2 i.e., where D = fraction of theoretical density, t = time, P = pressure and 77 is the viscosity, all in appropriate units. This equation was derived from earlier work of Shuttleworth and Mackenzie3 which is based on the closing of spherical pores under the action of surface tension. The integrated form of this equation yields a straight-line relation between log (1 - D) and t. Such conditions were found by Felten4 to be true only after extended periods of pressing. In an endeavor to quantitatively evaluate the exactitude of this equation in the initial sintering stage, i.e., prior to sealing of the pores, spherical anti-

Jan 1, 1962

By W. A. Wood, H. M. Bendler

Cylindrical fatigue specimens of OFHC* copper were subjected to alternating torsion while under axial tension. The superimposed tension strongly influenced the fatigue life of the specimens as well as causing characteristic changes in the structure of the fissures that form and develop throughout the life of the specimen. A further effect of the superimposed tension is a continuous extension of the specimen throughout its life in a manner formally similar to creep at elevated temperatures. RECENTLY, studies of the structural changes leading to fracture of metals by fatigue have been made by a technique which reveals, in section, the lattice distortion arising from slip movements inside the metal and the disturbances built up by these slip movements at the metal surface.1'2 According to this approach, fatigue develops as follows: a) fine slip movements concentrate in bands, producing little strain-hardening and thus permitting abnormal totals of plastic strain before fracture and, therefore, abnormal amounts of lattice distortion along each slip band; b) both forward and backward slip movements occur in each band which, according to their distribution across the band, may build up surface disturbances that include sharp notches; c) these notches early in the life of a specimen penetrate the distorted slip zones and transform them into deep, fine fissures; d) the fissures on continued cycling locally saturate the metal and cause local collapse in the form of a microcrack. Thus, the significant consequence of fatigue or cyclic

Jan 1, 1962

By Jesse A. Pfeiffer

CPAR, the Construction Productivity Advancement Research Program, is a new initiative of the Corps of Engineers to enhance U.S. construction industry productivity through the development and application of joint-funded research. CPAR seeks to balance the requirements of both the private sector and the Corps of Engineers construction program, to identify research needs that are common to both parties in a partnership for conducting research, and to achieve practical real-world products which will enhance productivity in the construction industry. Increasing costs of doing business has had a major negative impact on much of the nation's industrial base, and research and development (R&D) is among the areas hardest hit. The Congressional Budget Office estimates that since 1984 inflation adjusted R&D outlays in private U.S. firms have risen at an average annual rate of three percent, or about half the rate of gain of the preceding decade. And, despite a significant increase in foreign competition, the portion of gross national product (GNP) devoted to R&D is lower today than 20 years ago. For the case of the U.S. construction industry, the numbers are even more dramatic.

Jan 1, 1989

By Fred D. Fox

Introduction Abandoned mill tailings deposits can be found throughout the northern Black Hills of South Dakota, indicative of mining activities that originated during the great gold rush days of 1875. The Refuse Act of 1899 attempted to regulate the deposit of debris from mines and stamp works. But, in most cases, huge volumes of mine and milling wastes were disposed of in ways no longer considered environmentally acceptable. Restoration of gold mill tailings deposits is a relatively new practice to the Black Hills area. This discussion will present an overview of the environmental setting, environmental problems associated with past tailings disposal practices, practices being implemented to solve these problems, and prospects related to present the future tailings disposal practices. Environmental Setting An understanding of climatic characteristics, geology, surface and ground water hydrology conditions, and the physical and chemical characteristics of selected mill tailings deposits will aid in understanding environmental problems associated with tailings disposal and restoration. Climate The Black Hills region is in the middle latitudes, which have a

Jan 11, 1984

By R. G. Votteler, A. C. Brent

"The business performance of mining corporations in South Africa is adversely affected by the constantly increasing electricity costs. The most commonly used power sources are the national utility supplier via a grid connection, and on-site diesel generators. Previous research has identified the renewable sources of solar photovoltaic (PV), onshore wind, and geothermal energy in hybrid versions with current sources as possible opportunities to counteract rising electricity costs. To provide a clear understanding of the new, developing market of renewable energy sources, this research is divided into two papers. This first paper investigates the internal business structure of mining corporations in order to evaluate electricity generating sources. The multi-criteria decision analysis (MCDA) method is selected as the most suitable approach for this. The paper identifies the criteria used by mining corporations to evaluate possible electricity generation sources for self-generation by means of the corporations’ own investment. Four mining corporations with several mining locations were interviewed. The interviews revealed both new and identical evaluation criteria when the findings were compared to earlier MCDA adaptations analysed in the literature review. The second paper (Part 2) combines current knowledge about the external macroeconomic environment with the findings about the internal environment described here. MCDA is adapted in Part 2 and implemented to analyse and compare current to hybrid renewable sources from the perspective of mines. IntroductionMining corporations in South Africa are currently adversely affected by increasing electricity prices. Electricity is supplied mainly by Eskom1 and, especially in remote locations, by on-site diesel generators (Boyse et al., 2014). Electricity price increases, emanating from diesel price hikes and Eskom, have escalated the total operational expenditure on electricity by the largest mining corporations from 8% to 20% of total operating costs in the past seven years (EIUG, 2015). The reliability of electricity supplied by Eskom has decreased drastically (Govender, 2008), and the prices will increase annually by at least 13% until 2018 (Numbi et al., 2014; Eskom, 2015b). In addition, the South African government plans to introduce a carbon tax on greenhouse gas emissions (Alton et al., 2014)."

Jan 1, 2017

Neutralization with lime is a simple, cheap, and effective means of treating acid raffinates from uranium processing to' raise the pH, reduce the concentrations of dissolved salts (including heavy metal impurities), and remove amine by adsorption. Two-stage neutralization, using limestone in the first stage at approximately pH 4 and lime in the second, lIlay be advantageous.Lime neutralization of mffinates in the pH range 7 to 8· 5 generally reduced the radium ·concentration to 10 to 200 pCi 1-1, but ·there was considerable scatter in the experimental data. The radium concentration was further reduced to less than 3 pCi 1-1 by co-precipitation of barium (radium) sulphate with 10 mg Ba (as barium chloride) per litre of raffinate. Adsorption of radium on barytes was -also effective in reducing the radium concentration in neutralized raffinate to less than 3 pCi 1-1.The radium concentration of pit water was readily reduced to less than 3 pCi 1-1 when pit water containing 0·01 M sulphate as ammonium, calcium, or sodium sulphate was treated with 20 mg Ba per litre of pit water.Adsorption on barytes was also effective in removing radium from pit water containing 0·03 M sulphate.

Jan 1, 1975

By Leonardo Salas, Denys Parra, Kellwi Tejada, Selene Quispe

La técnica de exploración por tomografía de resistividad eléctrica (ERT o electrical resistivity tomography) es un método eficaz, rápido, de bajo costo y no invasivo, que permite modelar y visualizar la estructura interna de los materiales del subsuelo. El presente trabajo se ha enfocado principalmente en mostrar las últimas aplicaciones del ensayo de tomografía eléctrica en el diseño y evaluación de diferentes proyectos de ingeniería en minería en el Perú, tales como pads de lixiviación, presas de relaves, botaderos, entre otros, donde esta tecnología ha demostrado exitosamente su aplicabilidad, detectando fugas en presas de relave, zonas de deslizamiento, detección de cavidades, etc. y previniendo a largo plazo impactos ambientales, remediación de estructuras mineras y potenciales problemas legales.

Sep 20, 2019

By J. Allaire, P. N. Muteb

The Meadowbank mine is operated by Agnico-Eagle Mines Ltd. and is located in the Kivalliq District of Nunavut in northern Canada. The process plant operates presently at a throughput of 11,500 tpd with gold grade varying between 2.9 and 3.6 g/t. The ore supplied to the process plant come from two different open pits and it expected to come from a new open pit early 2014. The ore is mid-hard materials so the feed size ore have a bigger impact on the throughput. The average gold recovery is 94.0% with about 15-30% of gold recover from the gravity circuit. The Meadowbank mine commissioning started in February 2010 utilizing a flowsheet consisting of one stage of crushing followed by primary and secondary grinding. The commercial production began in March 2010. During the commissioning several difficulties were observed to reach the designed throughput of 8,500 tpd. It was evaluated to insert a second stage of crushing. The insertion of the secondary crushing have two objectives, first to reach easily the process plant design throughput as well as to evaluated the mill capacity increasing. The process plant team evaluated various expansion alternatives eventually deciding to install a secondary crusher, increased the SAG and Ball mills motors capacities and maintain the rest of the process unchanged. Early 2011, with the improvement in the gold markets, decision was made to install the secondary crusher between the primary crusher and the primary grinding. The process plant continued to operate on the initial design until early June 2011. This paper presents the SAG mill throughput increasing from the designed tonnage of 8,500 tpd to 2012 targeted tonnage of 11,500 tpd, secondary crusher commissioning and the difficulties to operate in Canada Artic (Nunavut).

Jan 1, 2013

By Daniel P. Lathrop, Leslie C. Taylor, William L. Fourney

Except when the target is on the surface, e.g. a tank track, the most important loading mechanism from a buried charge on a target above it is the impact of soil propelled at the target by the expanding gas from the explosion. Detonation of a shallow buried explosive generally yields an unstable interface between the rising soil and the air which appears to be the result of Richtmyer-Meshkov instability. Irregular “fingers” of saturated sand extend into the air above a more generalized dome of soil. These fingers move at a much higher velocity than the material between them at smaller stand off distances. As a result, the local load on the target at positions on the target at the same distance from the charge may vary by 50% or more from shot to shot or even within a single shot. This variation requires a large design safety factor to assure the integrity of design of mine-resistant vehicles.

Jan 1, 2009

By M. Gous

Keywords: Pyrometallurgy, Namakwa Sands, ilmenite, DC arc furnace, titania slag, pig iron Namakwa Sands is a heavy minerals mining and beneficiation business in the Anglo Base Metals Division, and operates along the West Coast of South Africa. The business encompasses mining, mineral concentration, separation, and smelting operations. The smelting process comprises the carbonaceous reduction of ilmenite to produce titania slag with a TiO2 content of 86%, and iron with a carbon content of 2.5%. The Namakwa Sands smelter, situated near the Saldanha Bay harbour, commenced smelting operations in 1994, when a 25 MW DC arc furnace was commissioned. The smelting operations were expanded in 1999, with the commissioning of a second 35 MW DC arc furnace. Despite the fact that ilmenite smelting poses a technical challenge in terms of the high temperatures required, the physical characteristics of the slag, the constraints placed on the feedstock, and the tight product specifications, Namakwa Sands has continually increased slag production since 1995. High furnace feed-on utilisation and furnace stability, complemented by continuous improvement drives, will be the vehicle to drive performance in the short term, with longer-term performance enhancements due to strategic process development.

Jan 1, 2006

By E. J. Sides

In this paper, the argument is put forth that the codes used for public reporting of mineral resources and mineral reserves have some significant limitations with regard to the information provided to investors on the short- to medium-term value of mining properties. Such limitations include a) failure to explicitly incorporate a time element and b) failure to state explicitly the quantity and quality of mineral product that will be produced for sale. A time-value framework for reporting mineral assets is proposed in order to overcome these limitations. The proposed system is based on two classification axes: a) an X-axis representing time in years during which the value of the asset is likely to be realized and b) a Y-axis representing the value identified by a mining or exploration company\u2019s activities. The potential benefits of this system are discussed, including the ability to incorporate factors, such as permitting and construction times, directly into the magnitude of the reported mineral assets. The proposed framework would assist in the standardization of mineral assets reporting in such a manner that they could eventually be more readily included in financial statements. Year of Publication: Not explicitly mentioned in the document.

Jan 1, 2010

By A. Sobhy

Froth flotation is a widely used, cost effective coal cleaning process. However, its high process efficiency is limited to a narrow particle size range between approximately 50 to 600 µm for coal and 10 to 100 µm for minerals. Beyond this range, the efficiency of froth flotation decreases sharply, especially for difficult-to-float coal fines of weak hydrophobicity (e.g., oxidized coal). This study was aimed at enhancing recovery of an Illinois fine coal sample using a flotation column featuring a hydrodynamic cavitation nanobubble generator. Nanobubbles that are mostly smaller than 1 µm can be formed selectively on hydrophobic coal particles from dissolved air in fine coal slurry. Results indicate that combustible recovery of a -150 µm coal was increased by 5-50% for different size fractions in presence of nanobubbles, depending on process operating conditions. Other major advantages of the nanobubble flotation process include lower collector dosage and air consumption since nanobubbles are produced from air naturally dissolved in water and they act as a secondary collector on particle surfaces, thereby resulting in considerably lower operating costs. Key words: Cavitation; coal; froth flotation; nanobubble.

Feb 27, 2013

By Eleanor Abshire

THIS PUBLICATION is the third to be prepared as a result of a cooperative project by the Bureau of Ships and the Bureau of Mines for accumulating literature published on zirconium and hafnium. The undertaking also resulted in the establishment of an information center on zirconium and hafnium at the Bureau of Mines station at Albany, Oreg., for the use of research organizations and others. The present bibliography consists of references (with abstracts) to pertinent literature on zirconium. The first publication in this series was Information Circular 7771, Bibliography of Zirconium, published in April 1957. It consists of 969 abstracted reports and 645 U.S. and foreign patents. The second publication, called a supplement to Information Circular 7771, is numbered Information Circular 7830 and consists of 844 abstracted reports and 62 U.S. and foreign patents. It was published in October 1958.

Jan 1, 1962

By James M. Riddle

A discussion of frequently asked questions may help individuals trying to interpret subsidence regulations or prepare permit applications. The subsidence permitting process involves just one part of the mass of Surface Mining Control and Reclamation Act regulations. But of the 18 main SMCRA sections, subsidence is critical to the permitting process for coal operators. It's an area in which applicants have had problems interpreting regulations and preparing permit applications. Of 22 western states, only Wyoming, Montana, Colorado, and Utah heave thus far received approval for their mining and reclamation plans. The other states are now involved in the permit application process and will be dealing with SMCRA regulations for the next year or so. Some state programs, when approved, may differ substantially from the federal SMCRA program. But, to be approved, the state programs must be deemed equal to or more stringent than the federal regulations. SMCRA regulations apply to any coal operation "that exhibits surface effects." Thus they apply to surface strip mines as well as underground coal operations. The regulations do not apply to hardrock mining operations. Since August 3, 1977, the government, industry, and the public have wrestled with SMCRA. They have struggled through an initial program with the US Geological Survey; a new agency, the Office of Surface Mining Reclamation and Enforcement (OSM); an interim program; and a "final" permanent regulatory program. Even now, OSM is reluctant to publish formal program guidelines because: •The regulations are still in the process of judicial review. • Some approvable state programs will supersede the federal regula¬tions. • The flexible regulations are open to interpretation, which is desir¬able to maintain. •Guidelines could be misleading until regulations and interpretations are revised and finalized.

Jan 12, 1980

By R. Greenwood

The advent of the space age and its promise of interplanetary flight has prompted new ideas for propulsion systems that will allow maximum energy with minimum fuel weight. The use of cesium as the source of energy for such rocket flights has been found desirable. Theoretical efficiency of a rocket fuel is measured in terms of specific impulse, defined as the number of pounds of thrust per pound of propellant consumed per second. Specific impulse is usually expressed in seconds (the number of seconds for which one pound of fuel would produce one pound of thrust) although it is really a measure of total energy, not of power. The most sophisticated chemical fuels have a specific impulse of 300 to 400 sec; liquid hydrogen heated by nuclear reactor has a specific impulse of 1000 to 1200 sec. Specific impulses as high as 20,000 sec, however, are theoretically attainable with the ion rocket, in which free cesium ions are accelerated across a voltage drop and ejected at high velocity.' Characteristics of the system have been sketched by Boden.2 The desirable properties of an ion propellant are: 1) low ionization potential, 2) low boiling point, and 3) high atomic weight. Alkali metals best fulfill these requirements, and Table I indicates the superiority of cesium. The use of heavy complex ions such as UCl3 is ruled out by their instability and other disadvantages.' Despite its enormous superiority in specific impulse, the ion rocket is inherently low-powered, capable of very small acceleration. Application of ion propulsion will be limited to large rockets and spaceships on missions requiring powered flight for weeks or months and employing a separate chemical propulsion system for escape from the earth's atmosphere where power requirements are large but of brief duration. For example, Kraemer and Larson3 considered the case of an unmanned 25,000-lb pay-load placed in a 300-mile orbit by chemical rockets, proceeding thence by ion propulsion to the vicinity of Mars, where it would go into orbit once again. Calculations provide for 8500 lb of cesium for such a voyage. The question of whether such quantities of cesium will be readily available to the space program does not appear to have been considered by geologists and mining engineers. Present Production and Uses Literature on industrial applications of cesium is scanty. The metal is used in scintillation counters, photocells, infra-red detection devices, and as a "getter" in low-voltage vacuum tubes. Production is sporadic and total figures are not published, but the annual consumption is measured in pounds rather than in tons. The few pollucite deposits known, small as they are, can easily supply the present limited demand for gram or pound lots of cesium. Until recently the price of cesium was $2 to $4 per gram, but according to Chemical Engineering, cesium salts are now available at $13 to $27.50 per lb. Geochemical Distribution As a large alkali ion, the cesium ion accompanies potassium in geological processes and tends to be concentrated in the latest crystallizing fractions of potassium minerals in much the same manner as rubidium. Most of the cesium in igneous rocks, therefore, is in the micas and potash feldspars of granites, and especially in granitic pegmatites. The cesium content rises markedly in the micas of the late by-drothermal replacement stage in complex pegmatite~.' Typically, cesium is only 0.5 to 0.01 times as abundant as rubidium in potassium minerals. Rb', with a radius of 1.47 A, is close enough in size to K' (1.33 A) so that rubidium forms no minerals of its own. Cs+ is so large (1.67 A) that only small concentrations can be taken up in potassium minerals; when cesium is present in solution in larger concentration it forms the mineral pollucite, Cs3-Na2A17Si17O48.3H2O, which is known only in pegmatites. In the weathering of igneous rocks, cesium is dissolved, carried to the ocean, and apparently in-

Jan 1, 1961