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By Sharif Jahanshahi

Calcium ferrite slags are often associated with Professor Yazawa due to his pioneering work on the thermodynamics of this type of melts. Over the past years CSIRO has invested some effort in studying physico-chemical properties of such melts to fill in some gaps in our knowledge and explore opportunities for application of the understanding developed. These investigations cover thermodynamics, transport properties of calcium ferrite based slags, as well as the kinetics of reactions of such slags with refractories. The present paper provides an overview of some of these studies and highlights some of the interesting behavior of such melts, The oxidation state of copper and arsenic in calcium ferrite based slags are predominantly Cu+ and As3+, respectively, at oxygen potentials below 10-7 atm. The concentration of CU2+ in such slags becomes significant at oxygen potentials of greater than 10-7 atm at 1300 °C. The activities of CuO0.5 and AsO1.5 in calcium ferrite slags show strong deviations from the Raoultian Law, while that of CoO is very close to ideal behaviour with respect to pure solid CoO. Addition of SiO2 to calcium ferrite slags can have significant effects on the activities of FeO and Fe2O3 and hence the stability of magnetite phase. Transfer of oxygen in calcium ferrite slags is fast with diffusivity of 2x 103 cm2/s at 1350 °C and activation energy of 16 kcal/mol. Presence of solid phases, such as magnetite, has pronounced effect on the viscosity of calcium ferrite slags. The observed dependence on solid loading and shear rate indicates deviation from Newtonian behaviour. The interfacial tension between copper mattes and calcium ferrite slags is strongly dependent on the matte grade, with the determined values being much lower than the corresponding ones for interfacial tension between similar mattes and iron silicate slags. MgO, Cr2O3 and MgCr2O4 have low solubility in calcium ferrite slags and their solubility increases with increasing copper oxide content of the slag at 1300°C. The oxidation state of the slag has strong effects on phase transformation, dissolution rate and disintegration of refractories in calcium ferrite slags. Other key factors with major impact on slag-refractory interactions include viscosity and surface tension of slags as well as the contact angle between slag and refractory material,

Jan 1, 2003

In surface mining operations, ultra-heavy trucks operate on haul road networks which are typically from 10?40 km in length. These road networks are often not optimally designed and maintained and as a result, identifying and remediating road functional defects is problematic. Most surface mine operators agree good roads are desirable, but find it difficult to translate this into an effective road maintenance system. This paper presents a haul road maintenance management system which utilizes an assessment of rolling resistance based on a functional performance evaluation of a haul road, together with mine haul truck operating cost models to derive the optimal frequency of road maintenance. A typical application is presented which illustrates the potential of the technique to manage maintenance as and where needed with resultant reduction in total road user costs and an improvement in service provided for the road user. Keywords: Haul road, surface mining, road maintenance, transportation, pavement design

Jan 1, 2003

By Charles W. Kenney

Mercury contamination of soil at an old chemical plant surrounded by a residential community and adjacent to a river has provided unique challenges for the current owner. Inorganic and organic mercury compounds had accumulated over the past 50 years to levels that require remediation. Hazen Research, Inc. conducted a multi-phased program to characterize contaminants and their occurrences, evaluate various treatment technologies, and demonstrate the selected technology at bench and pilot scales. A combined physical cleaning and chemical treatment was demonstrated to meet treatment goals for the site. This paper discusses the methods of process selection and results of the bench-and pilot-scale testing.

Jan 1, 2003

By Aly M. Mohammad

The design of large diameter drilled shafts in weathered rock has always presented a challenge to the foundation engineers. Degree of weathering and load transfer mechanism through the rock are essential elements required for the design. From the Contractor's perspective specifying the right equipment and estimating the rate of drilling in the weathered rock are key elements for successful construction. The Delaware River Tramway Project has provided an opportunity to address the design and construction of drilled shafts in weathered rock. The Tramway, supported by twin 300-foot towers, will shuttle eight-person gondolas across the Delaware River in about four minutes. Each tower, founded on four high capacity drilled shafts, is designed to resist large axial and lateral loads. At the New Jersey tower, each 7-foot diameter shaft extends 145 feet deep and terminates in weathered Mica Schist. The shafts are situated in the Delaware River where the mud line is approximately 20 feet below Mean Low Water. Below the mud line, there exists a very soft, 20-foot thick layer of organic silt, followed by a 40-foot thick dense sand stratum. Below these sand and silt strata, a 70-foot thick layer of weathered Mica Schist underlies the entire site. Both skin friction and end bearing in the weathered rock stratum were utilized in the analysis to compute the axial capacity. AASHTO and the PennDOT design methodologies were utilized independently during design of the drilled shafts to verify the design. The drilling of large diameter drilled shafts embedded into weathered rock and situated in a marine environment provided a unique challenge in the construction. A permanent steel casing was installed for a specified depth and proper equipment was used to drill and keep the shaft open through the weathered rock. In addition, a 5000 kip Osterberg load test was performed on one shaft to verify design assumptions and confirm the shaft capacity. The results of the test were utilized to establish load transfer characteristics within the weathered rock and to develop foundation design parameters to be used for the remaining shafts.

Jan 1, 2003

By Naoki Hiroyoshi, Hajime Miki, Tsuyoshi Hirajima, Masami Tsunekawa

Acidic solutions for chalcopyrite leaching contain cupric, ferrous and ferric ions, and the oxidizing power of the solutions is indicated by a redox potential, determined by the concentration ratio of ferric to ferrous ions. This paper reviews our previous studies on the redox potential dependence of chalcopyrite leaching in sulfuric acid solutions. Leaching and anodic-polarization experiments showed that coexistence of cupric and ferrous ions activate anodic dissolution of chalcopyrite, causing faster copper extraction at the potentials below a certain value (critical potential). The analysis of the AC impedance spectra for chalcopyrite electrode indicated that a high-resistance passive layer grows on the chalcopyrite surface without cupric and/or ferrous ions, and that coexistence of these ions causes a formation of another product layer and inhibits the passive layer growth at low potentials. These results are explained by a reaction model assuming the formation of intermediate Cu2S due to chalcopyrite reduction and the subsequent oxidation of the Cu2S. The critical potential corresponds to the redox potential of the Cu2S formation and the predicted values matched with the experimental results. Catalytic effect of silver ions on chalcopyrite leaching was also discussed based on experimental results and the above model.

Jan 1, 2003

By Arthur E. Morris

Fifty years ago when Professor Yazawa began his career, the field of process simulation and modeling was in its infancy. Since then, tremendous progress has been made in our ability to model metal production flowsheets from mine to refined metal. This progress has come about by parallel developments in basic understanding of process chemistry and in computational techniques, This paper will review the progress made in process understanding and modeling in lead, zinc, and copper metallurgy from its inception to the present, and the role of Professor Yazawa's work in furthering this progress. Specific examples will be given for the sintering of lead concentrates, slag fuming, zinc concentrate roasting, flash smelting of copper, and pyro-extraction of zinc. Factors limiting further progress will be described.

Jan 1, 2003

By Tim O’Neil

Tire companies have historically used the mining industry as a platform to launch new technologies. And the mining industry has been receptive to that. So, while developing its Two Piece Assembly, Goodyear noted a number of trends in the mining industry: •The global market sophistication of equipment and operations requires the packaging of products and services to provide the best return on investment. •Industry consolidation and growth have resulted in fewer, more powerful mining houses, leveraging purchasing power in the marketplace. •User productivity demands continue to drive original equipment manufacturers to develop higher pay-load equipment. •Technology needs include improved ergonomics, to reduce fatigue and increase operator productivity. •Increased laws and environmental regulation prohibit on-site whole tire disposal practices.

Jan 1, 2003

By V. Labiouse, B. Heidenreich

The rebound phenomenon, which occurs during rockfalls when a rock block impacts with a slope surface, is influenced by several parameters related not only to the slope material but also to the block and the kinematics. The paper presents a small-scale testing campaign undertaken at the LMR (EPFL) to better understand and quantify the bouncing of blocks on granular slopes. The influence of some factors related to the ground material, the block and the kinematics is examined. Bei Steinschlägen wird die Flugbahn eines stürzenden Felsbrockens maßgeblich durch den Abprall vom Hang bestimmt. Der Rückprall hängt von verschiedenen Parametern ab, wobei nicht nur das Hangmaterial sondern auch Blockeigenschaften und Kinematik eine große Rolle spielen. Zum besseren Verständnis dieses Phänomens und seiner Quantifizierung werden am LMR (EPFL) kleinmaßstäbliche Versuchskampagnen auf granulären Materialien durchgeführt. Der vorliegende Artikel stellt die Versuche vor und untersucht den Einfluss verschiedener Boden-, Block- und kinematischer Parameter. Le phénomène de rebond qui se présente lors de l’impact d’un bloc rocheux sur la surface d’un versant dépend non seulement des caractéristiques du terrain, mais aussi de facteurs relatifs au bloc et à la cinématique. L’article présente une campagne d’essais sur modèle réduit entreprise au LMR (EPFL) afin de mieux comprendre et quantifier l’impact de blocs sur des matériaux granulaires. L’influence de divers paramètres relatifs au sol, au bloc et à la cinématique est mise en évidence.

Jan 1, 2003

By N. Kumar, A. K. Dhawan, A. Varughese, S. K. Khullar

Abstract The in-situ stress field is one of the primary parameters influencing the performance of underground structures particularly in the Himalayas where there is strong influence of topography and geology on in-situ stresses. It is always advisable to measure the in-situ stresses, in whatever best way possible. Hydrofracturing is one of the methods by which in-situ stress can be measured. This paper briefly describes details of the concept of Hydrofracturing in arriving at the in-situ stresses of the rock mass at Pancheswar Project. The data obtained from the tests has been analysed, interpreted and the results are presented in this paper. Kurzfassung Das Spannungsfeld an Ort und Stelle ist einer der wichtigsten Parameter, die das Verhalten der Untergrund-Struktur beeinflussen, insbesondere in den Himalayas, wo die Topografie und die Geologie einen grossen Einfluss auf die oertlichen Spannungen ausueben. Es empfiehlt sich stets die Spannungen an Ort und Stelle so gut wie moeglich zu erfassen. Die Hydrofraktur bzw hydrografisches Zerstueckeln ist eine der Methoden, die bei den Messungen der oertlichen Spannungen verwendet werden koennen. Diese Abhandlung beschreibt kurz Einzelheiten ueber das Konzept von Hydrofraktur bei der Bestimmung der Spannungen an Ort und Stelle von der Felsmasse bezueglich des Projekts Pancheshwar. Die gewonnenen Daten aus den Messungen wurden analysieret und ausgewertet. Die Ergebnisse werden dabei vorgelegt. Sommaire Le champ de contraintes in-situ est un des paramèters principaux influencant l’exécution des structures souterraines particulierèment en Himalaya où les forces in-situ sont fortement influencées par les caractéristiques topographiques et géologiques de la région. La fracturation hydraulique est une technique qui permet de mesurer des forces in-situ des massifs rocheux. Cet article décrit brièvement le mécanisme de fracturation hydraulique et présente les résultats de mesure des forces in-situ des roches au site du projet hydroélectrique de Pancheswar.

Jan 1, 2003

By H. G. Denkhaus

Please allow me the temerity to reply to your reply to my contribution as follows: A fracture is brittle if plastic deformation is absent or, conversely a fracture is ductile if plastic deformation is present. Consequently, brittleness is specified by the degree of plastic deformation at fracture. This is the generally accepted definition. If other material properties (e.g. the quorient or the product of the uniaxial compressive and tensile strengths) under certain conditions are influenced by brittleness, or brittleness by them, these should not be called brittleness. If the one or the other author does that, he simply uses imprecise language. Even your remark, that ?Inyang and Pitt (1990) stated that the ratio of the compressive strength (sc/st) is directly proportional to brittleness?, confirms that the two quantities are not considered the same. For example:? The well known definition that a material is linear?elastic if the strain is directly proportional to the stress?does not mean that stress (measured in MPa) and strain (measured in %) are the same thing.

Jan 1, 2003

By S. C. Brown

A number of studies have suggested that microscale asperities enhance bubble-particle attachment efficiency; however, in practice the roughening of particulate surfaces can also lead to a decrease in flotation. In the present investigation, it is proposed that nanoscale asperities may be partially responsible for this phenomenon. It is suggested that as inter-asperity separation distances are reduced capillary effects are enhanced leading to the formation of stable liquid domains, which adversely impact bubble-particle adhesion. In addition, obstruction of surfactant self-assembly may occur, further limiting flotation.

Jan 1, 2003

By Jan Svoboda, Toyohisa Fujita

The current status and history of innovation in magnetic methods of material treatment are reviewed. The milestones and key drivers of innovation in magnetic separation are identified, advantages of this technology in comparison to other physical methods of material manipulation are discussed and reasons for its failure to live up to its potential and expectations are indicated. Derailers that were responsible for the implementation failures are identified. The future focus in such diverse areas as mineral processing, waste treatment, recycling and biosciences is discussed and the research and development needs are outlined.

Jan 1, 2003

By Jim Steding

L.G. Barcus and Sons, Inc. recently completed a three-phase project for the expansion of Presbyterian Hospital in Albuquerque, New Mexico for McCarthy Construction Co., the Construction Manager for the project. It was a challenge that allowed Barcus to demonstrate many of it's strengths. Safety of people and property, restricted access, low headroom conditions, extensive planning to maintain hospital operations and a tight schedule were all key elements affecting the successful installation of the Augered Cast-In-Place Piles. Phase I began with installing and performing a 450-ton pile load test on an 18-inch diameter Augerpile 65 ft long. The load test was installed and performed directly in front of the Emergency Room entrance. Space was limited and the E.R. had to remain open with uninterrupted ambulance access. The results of the load test were outstanding. In fact the test pile performed so well that some of the job piles were shortened from 75 ft long to 65 ft long. [ ]

Jan 1, 2003

By L. Spiers

Motorized Conveyor Pulleys contain all the traditional conveyor belt drive components inside the pulley. Light duty airport check in, grocery stores and food processing conveyors; requiring compactness, elimination of guarding and component containment have been using them for years. Portable Aggregate Processing Equipment require these features but with higher belt pulls and severe duty beyond the capacity of traditional components in a limited space. New materials, design technologies and automation; converging with safety issues, higher energy and operating costs; have created a pressing need. The challenge is to integrate new technologies and traditional components into a reliable, compact, conveyor belt drive system.

Jan 1, 2003

By Claudio L. Schneider, Peter R. King, Reiner Neumann

"Predicting the liberation spectra that are produced from breakage of two-phase ores under the random fracture assumption can be accomplished by measuring the conditional, on length, linear grade distribution directly from images obtained from a representative sample of the unbroken texture. The technique tremendously simplifies the prediction problem by avoiding the multiple convolutions that arise from the traditional method based on a description of texture from a measurement of the chord length distributions associated with each phase in the unbroken texture. For a 3-phase system, the phase transition probabilities associated with the textural information make the traditional calculation an almost insurmountable mathematical problem. The direct measurement procedure on the other hand can be expanded to three phases comparatively easily.A coal sample is used here to demonstrate the procedure. It is concluded that the conditional, on length, linear grade distribution can be predicted in the same fashion for multi-phase systems. Accurate stereological conversion is the practical hurdle to be overcome for multi-phase systems, but it is already a reality for 3- phase systems."

Jan 1, 2003

By Guojun Qi

This work relates to wafer bumping technologies for flip chip packaging applications in the electronics industry. Nickel and its alloys are alternative under bump metallization (UBM) materials because of their slower reaction rates with Sn-based solder as compared to Cu-based UBMs. In this study, we compared the morphologies of the intermetallic compounds (IMC) formed between Sn-bearing solders (Sn3.5Ag and eutectie Sn-Pb) and two types of nickel- based UBMs, electro less Ni-P (EN) and sputtered nickel. Both chunky-type and needle-type of intermetallics were observed between the EN UBM and the solders. In the case 'of sputtered Ni UBM, there is only a layer of scallop-type intermetallics formed, The morphology change and growth kinetics of the IMC in thermal aging process were analysed. Kirkendall voids were noticed from samples ofSn3.5Ag solder vs Ni-P UBM that have undergone prolonged thermal aging at high temperature.

Jan 1, 2003

Optimisation of mining projects is directly related to effective and efficient management of risks through the life cycle of mining projects. Effective and efficient management of risks must include explicitly all aspects of Occupational Health and Safety (OHS) through the life cycle of mining projects. This paper presents a different scale of OHS in the context of the optimisation of mining projects. Meaning of risk through the project life cycle is explained. Complex relationships between numerous risk, safety, knowledge, culture and change variables, and project life cycles are shown. The key element developed in this paper is a multi-disciplinary knowledge base that is necessary for constructive development of risk management and OHS models through the life cycle of mining projects.

Jan 1, 2003

By V. M. Paretsky

The basic work conducted by Prof. A.Yazawa has demonstrated that in order to ensure single-stage white metal production by autogenous smelting of copper sulfide raw materials, it is most favorable to use highly basic slags, in particular oxide systems CaO-FeO-Fe2O3-Sio2. he special studies have been conducted in the Gintsvetmet Institute to investigate the composition and structure of slags produced on a semi-commercial scale when testing the KFP and FBP processes for white metal smelting, as well as the slag obtained in a full-scale KFP furnace at the Almalyk copper smelter. The investigations conducted have demonstrated why production of high-grade matte or white metal is associated with lower loss of copper in slag in a series: silicate slag I silicate-calcium slag I ferrite-calcium slag.

Jan 1, 2003

By Malcolm Mudge

"One of the oldest mining areas in the World exist in Africa and the Middle East. This area is being exploited by foreign and local mining entities. Several large plants, both foreign and local as well as small operators, conduct their mining business on a scale which would be could be prohibited in any other part of the world. Relatively recent European disaster with tailing disposal and breakout has highlighted the problem.More important to the author is that the presence of foreign entities in zones which have not remedied the situation but has heightened the concern due to those entities using similar outrageous methods in treatment of waste. The abject misuse of technology cannot be permitted to continue and the lack of any metallurgical knowledge in the treatment of gold ores is considered deplorable for the majority of third world countries.The destruction of cyanide is simple and straightforward and requires no special skills. In South America, we developed a system that is modular, compact and can be operated in batch mode to cater for several clients, as required. Larger installations would require a separate module, as treatmentwould be on a continuous basis."

Jan 1, 2003

By J. P. Josien, Didier C.

ABSTRACT: France now faces the closure of most of its mining sites. Surface instability risk may sometimes remain, especially where large underground voids exist. This paper illustrates the importance of failure mechanisms identification in order to define properly how to manage the residual risk. RESUME: La France fait aujourd’hui face à la fermeture de ses exploitations minières. Des risques d’instabilités de surface peuvent persister, notamment lorsque des vides résiduels existent au sein des travaux souterrains. L’article illustre l’importance que présente la nature des mécanismes de rupture potentiels dans le choix des mesures compensatoires à adopter pour gérer le risque résiduel à long terme. ZUSAMMENFASSUNG: In Frankreich stellt sich derzeit das Problem der definitiven Schliessung des meisten Bergwerke. In manchen fällen ist die Stabilität der Oberfläche nicht garantiert, speziell wenn unter Tage nicht verfüllte Hohlräume verblieben sind. Dieser Bericht zeigt die Wichtigkeit, bei der Auswahl geeigneter Langzeit-Risikomanagementmethoden, der verschiedenen Mechanismen mit denen ein eventueller Bruch an die Tagesoberfläche geraten kann.

Jan 1, 2003