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By P. R. Khangaonkar

The variety of intermediates, middlings, complex materials and wastes produced in the conventional processing of tin ores as experienced in the tin industry in South East Asia is reviewed. The problems associated with the treatment of these materials so as to produce useful products by hydrometallurgical or pyro-cum-bydrometallurgical approaches are discussed. Results of treatment of amang middlings consisting of cassiterite, struverite, ilmenite, zircon, monazite etc by chlorination with carbon tetra chloride are presented. The efforts to leach tin without letting iron coming in, by alkali leaching of certain wastes of tin processing are also briefly indicated. It is felt that pyro-cum-hydrometallurgical approach can help a viable treatment of these materials so as to obtain usable or value added products.

Jan 1, 1994

By Yuanbo Zhang, Zhixiong You, Li Qin, Guanghui Li, Tao Jiang

Low-grade manganese oxide ore is generally characterized by high iron content. In this work, sulfidation roasting of an iron-rich manganese oxide ore with elemental sulfur was characterized. The experimental results indicated that manganese dioxide can be selectively reduced over iron oxide by using elemental sulfur. The manganese phases in roasted product included low-valence manganese oxide, manganese sulfide and manganese sulfate, while those of iron mainly depended on the sulfur addition. Iron oxide would only be reduced or sulfidized at larger sulfur additions. The effect of roasting temperature and S/Mn mole ratio on the phase transformations was also investigated; extractions of Mn/Fe by sulfuric acid were evaluated. An extraction of Mn greater than 95% was obtained while that of Fe was controlled less than 10% under the optimal conditions.

Jan 1, 2016

By B. Q. Li, R. A. Mirshams

"A numerical algorithm is described for the simultaneous prediction of the thermomechanical behavior of the materials and microstructure evolption during metal forging. The numerical development is based on the finite element solution of the thermoviscoplastic deformation of metals coupled with the internal state variable model describing the microstructure evolution involving work hardening, recovery, recrystallization and grain size distribution. The finite element code for rigid viscoplastic deformation is developed based on the modification of the existing code for the thermal and fluid flow calculations. The code is tested against and compares well with the results reported in literature. The procedures for the integration of the · rnicrostructure model into the macro finite element model are described. Results are presented showing the characteristics of materials dynamics and mechanical deformation during simple metal forging processes.IntroductionIn industrial deformation processes such as hot rolling and forging, the workpiece undergoes both macroscopic plastic deformations and microstructural evolution. A computer model that allows to predict both materials dynamics and macroscopic deformation is obviously more useful for both fundamental understanding and deformation process optimization. For some industrial applications, especially those involving novel, light and high strength materials, such an integrated model is critical in that both materials and thermomechanical 'behavior during forging must be carefully controlled to obtain the products that meet the desired strength requirement [I]."

Jan 1, 2000

By S. Z. El-Tawil, K. A. El-Barawy, M. B. Morsi, M. M. Nasr, Z. I. Zaki

"Tue sulphatization of zinc concentrate produced from heated zinc concentrate of Um Ghieg area, eastern desert by ammonium sulphate as sulphatizing agent is carried out at different conditions to achieve the appreciable formation of soluble sulphates. The maximum zinc recovery as soluble sulphate equfils to 95% upon using 1.5 stoichiometry ammonium sulphate at 600 °C for one hour. Tue obtained leached zinc sulphate solution is subjected· to purification process to prepare high pure zinc metal and zmc compounds such as pure zinc sulphate, zinc caibonate and zinc oxide. The products obtained are analyzed chemically and identified by X-ray analysisTue mechanism and kinetics of the sulphatization process of zinc concentrate are considered where the activation energy is calculated and equals to 33.3 K.J.mol""1 A process flowsheet for the overall sulphatization process of zinc concentrate by ammonium sulphate is proposed.IntroductionConsiderable reserves of zinc ores are present in Um Ghieg area eastern desert, Egypt. The possibility of extraction zinc from these ores and preparing its valuable compounds by choosing a more feasible technology become of vital importance. An attention is focused on the sulphatizing roasting processes (1-9) to achieve the appreciable formation of soluble sulphates. Previous publications are reported in our division by El. Tawil and others (10-16) using ammonium sulphate as sulphatizing agent for the successful treatment of nonferrous bearing materials.Therefore, the present work aims to study the different factors affecting the sulphatizing roasting process of local zinc coocentrate by anunonium sulphate to extract completely zinc and preparing its main compounds. Tue mechanism and kinetics of the different chemical reactloos that 1ake place in the process are considered."

Jan 1, 2000

By F. Shahbazian

attempt to systematize the knowledge on slag viscosities, the present work was carried out. The Among the physical properties of slags, viscosity is very important in understanding the mass out in the temperature range 1438-1762 Q The rotating cylinder method was used in the viscosity measurements. Crucibles and spindles made out of pure iron were employed. The transfer phenomena in metallurgical processes. The viscosities of fayalitic slags are of great interest in the non-ferrous metal industry, with special reference to copper production. In an slags were prefused before the measurements. In order to take into account the vaporization reactions involving CaF2, pre- and post measurement samples of the slags were chemically analysed and the compositions were ascertained. The results show that in the case of the CaO-SiO2 system, CaF2 additions tend to decrease the viscosity, in accordance with the expectations. In the case of the "FeO"-SiO2 system, at higher "FeO" / SiO2 ratios in the slags, a reverse trend was observed. The results are discussed on the basis of a viscosity model for silicate melts developed in the present laboratory as well as the structural considerations of silicates.

Jan 1, 2000

By R. P. King

The essential features of an image analysis system for the measurement of mineral liberation are described. Good procedures for image acquisition and image processing prior to image analysis are defined. The basic stereological methods for the measurement of volume fraction, surface area per unit volume, particle size distribution and liberation spectra are given. The appropriate methods for fractal correction when measuring perimeters of irregular features and for frame correction when measuring linear intercepts are developed. Practically useful and accurate procedures for the stereological correction of particle size and liberation distribution methods are given.

Jan 1, 1995

By Lori Bassman, Cassandra George, Cullen McMahon, Md. Zakaria Quadir, Michael Ferry

"Complete and accurate analysis of subgrain microstructural features must include three-dimensional information. Three-dimensional electron backscatter diffraction (EBSD) data can be used to characterize these features; however their boundaries first must be determined. This cannot be accomplished simply with pixel-to-pixel misorientation thresholding because many of the boundaries are gradual transitions in crystallographic orientation. Fast Multiscale Clustering (FMC) is an established image processing technique that we have combined with quaternion representation of orientation to segment this kind of data. Segmentation algorithms often have issues handling images with both distinct and subtle boundaries. Our implementation of FMC addresses this by using a novel distance function and statistical analysis to take into account the variance in orientation of each feature. Although FMC was originally a twodimensional image processing algorithm it can be generalized to analyze threedimensional data sets. As an example, a segmentation of microbands in cold-rolled aluminum is presented.IntroductionThree-dimensional electron backscatter diffraction (3D-EBSD) is a method for mapping the local crystallographic orientations of points in a volume. The technique uses a dual beam platform consisting of a focused ion beam (FIB) and SEM with EBSD, where FIB is used for serial sectioning and EBSD for orientation mapping of 2D slices. These 2D slices may then be stacked to create a 3D volumetric data set.Typical uses of such a data set include characterizing the geometries and crystallographic orientations of surfaces between structures in 3D [1-5]. This involves identifying boundaries accurately, either in 2D slices with subsequent 3D reconstruction (as illustrated in Figure 1) or in the 3D data set. All such data sets present the challenges of i) aligning data slices to correct for instrument drift, ii) identifying relevant boundaries, and iii) implementing appropriate smoothing or interpolation algorithms. The focus of this paper is boundary identification."

Jan 1, 2011

By Andre L. De Vegt

Hydrogen sulfide is an expensive chemical used in nickel, zinc and copper mining and metallurgical operations for selective recovery and concentration of metals, from leach water streams, acid plant blow down streams, refinery electrolyte bleeds and precious metal, plant bleeds. Hydrogen sulfide is either produced on site by catalytic reduction of elemental sulfur or transported to the site as liquefied hydrogen sulfide (H2S) or as a sodium sulfide solution (NaHS) Biologically produced hydrogen sulfide has economically very interesting, application possibilities in the mining and metallurgical industry. Converting sulfates from waste streams into usable hydrogen sulfide by biological reduction results in operational cost savings in existing lime treatment systems. H2S can be produced biologically for less-than $500/ton S. For the past ten years Paques has been engaged in the development and installation of treatment systems based on biotechnological processes to remove sulfur compounds from water, air and gaseous streams. Paques has designed and installed a groundwater treatment system for the Budelco zinc refinery in the Netherlands to remove sulfate and heavy metals. The hydrogen sulfide produced is used for recovery of metals,, mainly zinc, from the ground water stream. The system has been operating since May 1992 treating a flow of 5000 m3/d. At Kennecott's Bingham Canyon Utah copper mine, a pilot plant started operation in November 1995 to develop the process for selective recovery of copper from leach water using biologically produced hydrogen sulfide from sulfate containing groundwater. Other pilot plants are operated at DOE's Pittsburgh Research Center and at Cominco Research focusing on selective recovery of metals.

Jan 1, 1998

By M. Kobashi, T. Choh, N. Kanetake

"A new processing route, which enables the cost-effective and energy- saving fabrication of metal matrix composites, have been proposed. The pressureless infiltration of the reactive powder blend with molten aluminum was investigated in this work. The molten aluminum infiltrated into the [Ti + C] powder blend spontaneously, whereas the spontaneous infiltration into the TIC powder phase did not occur under the same experimental condition. The processing time was shortened and· the processing temperature was .lowered by adding the aluminum powder in the [Ti + C] powder. The differential thermal analysis revealed that the aluminum powder in the powder blend melted at 933K and then ignited the reaction between titanium and ·carbon. However there was an .optimum additional amount of aluminum in the powder blend. The TiC formed in situ had three-dimensionally continuous morphologyIntroductionThe squeeze casting process has been used as one of the processing routes for aluminum matrix composites. [1, 2]. Non-reactive metal-ceramic systems have been, generally, used in this technique in order to prevent the degradation of the ceramic phase. Materials obtained by this process basically consist of a continuous metal matrix and discontinuously dispersed ceramic particles. Reactive systems have begun to be introduced into the infiltration process· recently [3A]. Since the ceramics are synthesized in-situ, this process can provide a continuous ceramic matrix [5]. This is one of the outstanding features of this technique in that a bulk ceramic-can be synthesized at relatively lower temperatures in a short time. Another advantage is that the highly reactive combination of a ceramic with a molten metal is in many cases wettable [6], which enables a spontaneous infiltration."

Jan 1, 2000

By A. W. Worcester

The plant is designed to produce 60,000+ tons of refined lead per year from a nominal feed consisting of 110,000 tons of SLI and industrial batteries, and 10,000 tons of lead contained in drosses and scrap. The plant will also produce as by-products polypropylene chips and detergent grade sodium sulfate, using the Engitec Impianti CX Technology. The battery separation circuit will consist of a battery breaking hammermill and a vibrating screen with water sprays to separate the battery paste from the grid metal and other battery components. The battery components, consisting of ebonite, and separator materials, will be separated' from the grid metal and classified with the use of hydrodynamic water separators. The battery paste will be treated with sodium carbonate to produce a lead carbonate paste for smelting in a reverberatory furnace. The slag from the reverberatory furnace will be campaigned through a traditional primary blast furnace to produce hard lead. The sodium sulfate liquor from the lead carbonate filtration step will be crystallized to produce anhydrous sodium sulfate. The metallic grid metal will be treated through a small rotary smelter of the Engitec design to produce a hard antimonial lead. The plant's scheduled to be commissioned 12 months after receipt of all of the Federal and state permits. The plant will be integrated into the Buick Primary Lead Smelter, located in the center of Missouri's New Lead Belt, at Boss, Missouri. This will allow The Doe Run company to fully utilize all of its existing assets.

Jan 1, 1990

By S. Eckert, G. Gerbeth, K. Timmel, B. Willers, T. Wondrak, N. Shevchenko, M. Röder

The quality of the produced steel in the continuous casting process is significantly governed by the melt flow in the mold. However, direct flow measurements in liquid metals are still rather scarce. In order to investigate these flow phenomena, three experimental facilities operating with low melting liquid metals were installed at Helmholtz-Zentrum Dresden-Rossendorf (HZDR). The melt flow in the models is measured by the Ultrasonic Doppler Velocimetry (UDV) or the Contactless Inductive Flow Tomography (CIFT), multi-phase flows can be visualized by X-ray imaging. The obtained measurement results are primarily used for validation of numerical models. In this paper we will investigate the fluid flow in the mold and the behavior of the surface of the liquid metal using flow measurements by UDV and surface profile measurement by a laser scanner, respectively. Strong fluctuations and deviations of the free surface were observed in case of a static magnetic field

Jan 1, 2016

By H. Kaffash

Ferromanganese is a ferroalloy with high manganese content which finds many uses for example as deoxidizer in steelmaking industry. However, there is very little data on the dissolution rate of carbonaceous materials in Mn containing metals. In this paper, the kinetic analysis of carburization reactions is investigated for Mn–Fe alloys. Dissolution rate of graphite in pure iron and four different alloys with 10 wt%, 40 wt%, 60 wt% and 85 wt% manganese at 1823 K was studied. Results showed that the dissolution rate of carbon from graphite increased with increasing time for all alloys. The dissolution rate constant increased with the increasing manganese content from 6.5 × 10−3 cm/s for 0%Mn to 23.6 × 10−3 cm/s for 85%Mn.

By Kumar M. Lyer

The channel reactor for ferrous and nonferrous processing has been modeled as a combination of ideal reactors. Cold model studies simulated the counter-current flow of slag and matte (or metal) with high-strength submerged gas injection. A composite model has been developed which describes the mass transfer between the two liquid phases, including the transfer of minor elements. The residence time for the matte droplets in the matte/slag emulsion is compared with the settling rates for the matte droplets in the slag to determine their relative importance in the mass transfer between matte and slag. The governing equations for mass transfer have been developed using correlations for the mass-transfer coefficients in the continuous and dispersed phases. An application of this scheme to a typical copper smelting system is presented.

Jan 1, 1993

By Hector Henao

To provide thermodynamic data for converting the nickel matte to liquid nickel, an experimental study was conducted in the phase equilibrium between the Ni-S alloy and the CaO-Ah03 based slag melted in a MgO crucible at 1873 K under controlled Pso2 of 10.1 kPa and pO;, in a range between 2.5x,IO,2 and 10.1 Pa by using CO-C02-S0Z gas mixtures. The content of nickel in the slag at POz of 10.1 Pa, above which solid NiO is expected to precipitate in the equilibrium state, was found to be 4.1 mass% and the contents of sulfur and oxygen in the nickel melt were 0.4 and 0.2 mass%, respectively. It was clarified that increase in the temperature reduces the solubility of nickel in the slag and the contents of sulfur and oxygen in the alloy. The distribution of minor elements such as gold, silver, copper, cobalt, iron, arsenic and antimony between the Ni-S alloy and the CaO-AI20) based slag was also studied. The distribution ratios of iron and cobalt, defined by (%X in slag)/[%X in alloy] where X is the minor element, are larger values than that of nickel, while those of copper, silver and antimony are similar to that of nickel. The distribution ratios of arsenic and gold are lower than that of nickel in the higher range of oxygen partial' pressure.

Jan 1, 2003

By Anna Wasilkowska

The study concentrates on the effects exerted by microstructure, deformation history and uniaxial stress conditions (temperature, stress state, strain rate) on the mechanical properties offerritic TRIP-aided steels for automotive applications. In low-alloyed TRIP-steels it is quite difficult to separate the effect of the austenite to martensite phase transformation from the influence of the ferritic matrix contributing to the yield stress and uniform elongation. Investigation of transformation kinetics of retained austenite as a function of the deformation temperature show that using the parameter k to characterize the retained austenite stability allows to identify regious of different temperature sensitivity separated by a transition temperature of 10±5°C. The observed low strain-rate sensitivity of the flow stress is an intrinsic property of the ferritix matrix and points to defomtation governed by slip. The ultimate tensile strength is much stronger affected by temperature than the yield stress. The influence of the temperature on the elongation is complex, because of the heating of the specimens by 60-l20°C at moderate and high strain rates. The increase of the total strain can be understood in terms of thermal softening of the ferrite. On the other hand, the steep increase of the stress during dynamic testing is an effect of accommodated elastic and plastic strains in the matrix. The strain- hardening exponent is dependent on the conditions imposed during testing. The martensite transfomtation rate is lower and the critical stress for martensite nucleation is much higher under compression compared to tensile loading. In secondary tensile tests, the yield stress increases steeply, and the ultimate tensile strength and the total elongation depend linearly on the amount of pre-straining. The results confirm that in the range of 8=10-4 s-l the TRIP-effect governs room temperature plasticity. Keywords: TRIP-steels, mechanical properties, strain rate sensitivity, temperature sensitivity, austenite stability

Jan 1, 2003

By J. F. White

An experimental study was undertaken to evaluate the feasibility of a selective chloridizing roasting pre?treatment process for the elimination of impurities from zinc feed?stocks prior to recovering zinc by conventional unit operations. In this investigation, a number of chemistries that might serve as a basis for such a pre? treatment process were examined. A variety of chloridizing agents were admixed with EAF dust to promote the selective removal of lead and cadmium by the formation of volatile metal chlorides, he results of the experimentation firmly establish that selective chloridizing roasting is a technically feasible means of eliminating lead and cadmium from EAF dust. Excellent extraction efficiencies were accomplished with a number of chloride additives; as high as 98 percent lead extraction and 88 percent cadmium extraction were attained with minimal zinc losses, Continuous pilot?scale tests reinforced the trends established by laboratory?scale experimentation, Attempts of chlorine elimination using pyrohydrolysis were less successful. The extent of chlorine elimination was found to be highly dependent upon EAF dust sample type and treatment temperature.

Jan 1, 1996

By C. -S. Jiang

In most copper refineries, addition agents are added at predetermined rates with no further monitoring of their activity or concentration in the electrolyte. Increasingly stringent cathode quality requirements, and a desire for better process control in tankhouse operations, have recently directed a number of refineries to search for a better addition agent control strategy. Extensive development work has been carried out at the Noranda Technology Centre for the monitor in of glue and thiourea in copper refinery electrolyte using cyclic voltammetry (cv~. Data from both synthetrc and commercial electrolytes are presented, showing the ability of CV to produce reliable and easily identifiable fingerprints of addition agent concentrations in copper refinery electrolyte.

Jan 1, 1991

By K. Krishnapisharody

The phenomenon of slag droplet formation under the action of gas-stirring in steel ladles has been analyzed with experiments conducted in a thin-slice room-temperature model using water and mineral oils as the working fluids. Visual and video investigations have been performed on the interface behaviour along with measurements of liquid velocities in both phases, using the Particle Image Velocimetry (PIV) technique. The measured velocity data and observations on the interface break-up establish that the droplet formation results primarily from an instability mechanism at the interface.

Jan 1, 2008

By Thomas R. Wildeman

Experimental methods for studying vapors over solid minerals are reviewed and an especially developed method using atomic absorption is described. The method is used to study vapor pressures over Te. Ag, Au, Ag2Te, and AuTe2 from 250°C through 10S0oe. Vapor pressures observed and, concurrently. sintering properties are significantly altered by the form of the solid. The vapor pressures of the tellurium compounds reveal complex processes occurring on the surfaces of the solids. The data given also point out a method of recovering precious metals from their telluride minerals w

Jan 1, 1987

By Ximeng Zhu

The electrochemical behavior of mineral and coal pyrites in stirred and quiescent alkaline boratelsulfate solutions @H 7.9-10.5) have been investigated using cyclic voltammetry. Significant differences in the electrochemical response of these pyrites were observed. At the mineral pyrite surface, three anodic peaks at about -0.8 V, -0.1 V and +0.5 V (SCE) have been detected along with their corresponding reduction peaks. The first two peaks correspond to FeIFeOI) and FeOI)lFe(III) oxidation. The third peak is present for quiescent conditions but disappears as a distinct peak when the electrolyte is stirred. In the upper voltage region +0.30V (SCE), the current increases markedly during stirring and the reactions correspond to the oxidation of pyrite with the formation FeOII) oxides plus elemental sulfur. Also there is evidence that Fe oxy-ions form. Coal pyrites, under rapid sweep conditions display only the first two anodic peaks, the associated reduction peaks and an additional reduction peak corresponding to one or more of the high voltage oxidation products. After prolonged exposure to high potentials, coal pyrite displays reactions similar to those of mineral pyrite but at much higher current densities demonstrating the much higher reactivity of the coal pyrite. The reactivity sequence was Upper Freeport coal pyrite > Pittsburgh coal pyrite > mineral pyrite.

Jan 1, 1991