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By Lars Lövgren, Jörgen Jönsson

Heavy metals may be retained within deposits of sulfide minerals under oxidation and in the nearest recipients of drainage water by sorption to secondary iron precipitates. The extent of sorption is strongly influenced by solution pH and presence of complexing ligands, such as sulfate and natural organic acids. Desorption of metals and organidinorganic anions to recent secondary Fe precipitates, collected at the Kristineberg mine, Sweden, has been investigated under different geochemical conditions. Elemental composition and structural characterization (X-ray powder diffraction) indicate presence of schwertmannite. While metals such as Ni and Pb were fractionally desorbed from the precipitates under acidic conditions, oxyanions, e.g. arsenatdarsenite and sulfate were desorbed preferably under alkaline conditions. In a separate study the adsorption of NOM onto synthetic goethite was investigated. NOM adsorption showed a strong pH dependence, 95% was adsorbed at pH 3 and 40 % was adsorbed at pH 9. Addition of 2 mM of sulfate desorbed about 10 % of the adsorbed NOM.

Jan 1, 2000

By John G. Reid

Geologists, employed by the Australian Company, Metals Exploration Limited, discovered nickel laterite enrichment at Greenvale in 1967. A joint venture was arranged with the Freeport Minerals Company who had gained early experience with nickel laterite ores when building and operating the Nicaro and Moa Bay Treatment Plants in Cuba. A 5 tonne/day Pilot Plant at the Freeport research facilities at Belle Chasse, Louisiana, verified the amenability of the ore to treatment by the reduction and ammonia-ammonium carbonate leaching process used at Nicaro. A 5 800 tonne/day Treatment Plant was constructed on the coast at Yabulu, North Queensland. This paper describes the ore body, the mining operation and the stages of treatment required to produce nickel oxide products and a mixed nickel/cobalt sulphide product at Yabulu.

Jan 1, 1979

By John L. Bolles

The mineral processing engineer must have some knowledge of mineral identification, and the greater his knowledge in this field, the greater will be his potential to do his own specialty well. Most metal-bearing ores and industrial minerals require processing of some kind to produce a salable product or a material suitable for further processing. The types of treatment are many, but each one is aimed at separating a mineral or family of minerals from others. Obviously, then, it is basic to all mineral processing to identify the minerals present in the raw material and in intermediate and final products resulting from processing. Very often the mineral processing engineer will enter planning while exploration of a mineral prospect is going on. He will examine hand specimens, drill cores and cuttings, bulk samples, and materials in place. He must identify the valuable minerals, their occurrence and associations with other minerals, and the identity of diluents or host rock. An exact and detailed knowledge of the raw material will usually suggest the treatment processes that should be investigated in the development of the most suitable scheme for that particular raw material in that particular location. Physical properties of a mineral often lead directly to a process for separating that mineral from others. Some well-known examples of these are: magnetic separations for such minerals as magnetite, rutile, ilmenite; gravity separations for gold, silver, galena. cassiterite; flotation separation for most sulfides; distillation of mercury from cinnabar; and selective dissolution in specific solvents such as halite or sylvite in water, gold and silver in cyanide solutions, copper oxides, carbonates, sulfates and silicates in dilute sulfuric acid. These processes and many others are described in detail elsewhere in the Hand¬book and so it is not appropriate to give details here, except to emphasize that processing is aided greatly by complete mineral identi¬fication. Developing a treatment scheme for a new mineral discovery is an exciting assignment fag the mineral processing engineer, but much more of the usual work relates to quality control in existing plants. Here too, mineral identification is important. Some processing is aimed toward producing an end product which will meet exacting specifica¬tions regarding purity or allowable diluents. In this situation it is vital that contaminants be identified so that the process can be adjusted

Jan 1, 1985

By Gemei Yang, Pierre Mousset-Jones, Felipe Calizaya, Malcolm J. McPherson

Laboratory tests on controlled airflow recirculation have shown the development of transient states in response to changes in system prevailing conditions such as those generated by a sudden start-up and stoppage of fans. Researchers in many European countries have developed various models to explain these phenomena. However, these models failed to consider some important factors such as diffusion and dispersion of gas in turbulent flows. For both in-line and cross-cut recirculation, tests have shown that after the start- up of a booster fan, the gas concentration in the system fluctuates, reaching high levels at the initial states and slowly dying out with time. These fluctuations cannot be represented adequately by simple step-wise functions but rather by smooth, albeit complex equations. In this paper, the phenomena are explained by the convection-dispersion theory, and represented by a mathematical model. Based on a few simplifications and applying Fourier's Transform Method to the differential equations of the flow recirculation model, an integral form of gas concentration function was derived. The Simpson Integration Method was used to compute numerical results for two laboratory tests. The paper also discusses the range of the dispersion coefficient to improve the accuracy of the model.

Jan 1, 1989

By Gerald J. J. Aleva

Lateritization is a surface and near-surface process enhanced by a humid and warm climate and by good drainage. It closely follows the development of the regional landscape. The cyclic landscape development on the Guiana Shield is accompanied by a progressively thicker and more evolved laterite mantle the older, and hence in most instances the higher the planation level. The known, economically interesting bauxite and aluminous laterite eposits of the Shield are restricted to the remnants of the oldest of the Cainozoic planation levels (level I1 and 111).

Jan 1, 1984

By Mehmet Maral

Various types of Tertiary (Miocene) lignite occurrences had been formed and alternated with volcano-sedimentary Bigadiç Formation in the field of study, which resides in the middle and eastern parts of Biga Peninsula. The focus of the study is to identify the geochemical and petrologic properties of coal occurrences and the formation mechanism of the deposits. A comparative study of the deposits will also be studied. Biga Peninsula is a very rich zone in terms of both metallic ores and industrial minerals. Most of the metallic deposits and industrial occurrences in the region have been known and mined throughout the history. This richness of the region is related to the volcanic and tectonic activities that have developed during different geological periods. These activities are the main reasons of weathering and alteration phenomenon.

Jan 1, 2005

By Chris Chmura, Ketut Karmawan, Ian J. Duckworth

P.T. Freeport Indonesia operates a mining complex located in the highlands of West Papua, Indonesia. Present production from PTFI’s DOZ Underground Block Cave Mine is approximately 40 thousand tonnes per day (ktpd). This paper describes the design process and recommended ventilation infrastructure necessary to expand the DOZ Mine reserves and to increase sustained daily production above 50 ktpd. The enlarged footprint will feature longer production panels of up to 650 m in length, more active draw points, a second large gyratory crusher, and additional men and mobile equipment. The increased ventilation capacity will be achieved through the development of new, dedicated ventilation drifts, and primary Underground exhaust fans.

Jan 1, 2005

By R. L. McNearny, K. A. Barker

Four numerical models written with the "PFC2D " program were compared against four similar physical models. The numerical models were constrained numerically to closely follow the caving behavior of the physical models. Results from the numerical analyses closely simulated both the granular and blocky behaviors of the physical models, including bridging and interlocking of the simulated orebody during draw. The drawdown patterns and the rate of draw developed during numerical modeling also closely simulated the physical models. The same assumptions and governing parameters used in analyzing the first four models were applied to an additional model. The fifth model employed a completely different, uneven, draw sequence than the other four models, allowing the material to flow in a more granular manner with a demonstrated instability of the undercut sections between each drawpoint opening. Drawdown patterns and behavior of the numerical material of the first four models progressed at uneven and inconsistent rates, similar to those seen in the physical models. By inspection, the overall shape and flow lines of both the numerical and physical models were close in the area removed and in the flow characteristics. The fifth model proved to be the most unstable of all the models tested, with poor correlation to the physical models. The uneven draw sequence, coupled with an additional frictionless wall condition and an added drawpoint, caused the material to flow in a very granular manner. Information generated by this study can be used as a first approach in determining the proper draw rate, drawpoint spacing and undercut thickness for a block-caving operation. Numerical models are often difficult to predict and interpret. However, this study should increase the confidence level for use of the PFC2D program in the future.

Jan 1, 2000

By Stephen W. Kline

Rock suitable for crushed-stone aggregate is almost entirely restricted to the Highlands region of Arkansas, mostly from Paleozoic sedimentary units, but also from a few Cretaceous igneous plutons. Reserves in the state are sufficient for local needs, and Arkansas is geographically well situated for export markets to the south, where resources for crushed-stone aggregate are lacking. A study of 423 quarries, test pits, and exploration sites in Arkansas has been completed to evaluate the relative quality of bedrock units for producing crushed aggregate. Of these, 274 sites have records of engineering tests for stone evaluation done by the U.S. Army Corps of Engineers and/or the Arkansas State Highway and Transportation Department (AHTD). Of the 1,775 sample records from these sites, the most commonly reported parameters are the LA abrasion test and the Na-sulfate soundness test. Many records also have absorption and specific-gravity data, and, for some, petrographic information helps identify the potential for alkali-silica reactivity in portland-cement concrete. By determining the bedrock sources of the tested samples, comparison is made between the various geologic mapping units as to their relative quality for crushed stone.

Jan 1, 1999

By R. Larry Davis

Over the past decade there has been a continual decrease in domestic oil reserves accompanied by a sharp increase in the demand for energy. Even with increased imports of foreign oil, the energy demand has not been met. This has forced many users to turn to substitute fuels. Of the many substitute fuels available most users are turning to and creating an increased demand for low sulfur coal. Because of the increased demand for low sulfur coal as well as the inherent problems in producing eastern coal, many producers have turned their attention to the large deposits of low sulfur coal in the western United States. Western coal mining is, however, not without its problems such as high moisture content, high ash content, highly variable sulfur content, multiple seams, and/or pitching seams. It is to aid in the solution of these problems that this chapter is directed.

Jan 1, 1979

By R. R. Oder, R. J. Gray

We report measurements of the effects of rank, type, and grade of coal on grinding energy and grinding media consumption in a Pitt Mill. The rank of coal has a greater effect on grinding energy than does coal type. The effect of coal grade on grinding energy depends upon the relative grindability of the mineral matter and of the hydrocarbon components of the coal. The mineral matter is primarily responsible for abrasive media wear in a Pitt Mill. The widely recognized HGI test for coal breakage may yield misleading results, particularly for multiple-banded bright and dull coal where the screening procedure used in sample preparation favors the testing of the hardest coal fraction. The work reported here indicates that the Pitt Mill, which grinds the whole coal in a single stage and which yields easily interpreted results, is an excellent candidate for testing coal pulverization characteristics including energy requirements and equipment wear. The measurements of the effects of coal characteristics on grinding energy and on media consumption have been used to estimate the cost of fine grinding in a Pitt Mill. The results, based on a conceptual level evaluation of grinding at the rate of 1 TPH, show that there are trade-offs possible between the cost of energy and cost of media consumption which involve choice of grinding media size. The use of fine-size grinding media to lower grinding energy and to increase throughput can be deceptive because the total cost of grinding must consider both energy and media consumption.

Jan 1, 1992

By C. B. Manula

The total systems model for underground coal mine planning and design (Master Design Simulator) is a set of computer programs which encompasses a realistic reproduction of the interaction among the geological, environmental, equipment, methods, and the health and safety aspects of the mining plan (Manula, Rivell, and Ramani, 1975). The total system includes nine major subsystems: geology and reserves, methane generator, roof support, subsidence, production, rail haulage, cost, water generator, and ventilation (Fig. 1). The subsystems themselves are divided into two categories based on the frequency with which they are executed: (1) event-oriented subsystems are executed either independently or at discrete intervals when certain specific events occur; and (2) dynamic subsystems function interactively during the production cycle, transferring data to or requesting data from event-oriented subsystems only when specific events occur (Fig. 2). Each subsystem has been tested and validated independently (Ramani, White, and Sutton, 1974; Ramani and Owili-Eger, 1974; Manula, Mozumdar, and Jeng, 1974a; Manula, Mozumdar, and Jeng, 1974b; Manula, et al., 1974; Manula, Rivell, and Sanford, 1974; Ramani, McClay, and Burgos, 1975; Manula and Owili-Eger, 1975; and Ramani, Owili-Eger, and Manula, 1975).

Jan 1, 1979

By H. D. Freeman

The Pacific Northwest Laboratory (PNL) is developing cover technology for uranium mill tailings that will inhibit the diffusion of radon to the atmosphere. As part of this cover program, an improved radon flux measurement system has been developed. The radon measurement system is a recirculating, pressure-balanced, flow-through system that uses activated carbon at ambient temperatures to collect the radon. With the system, an area of 0.93 m2 is sampled for periods ranging from 1 to 12 h. The activated carbon is removed from the radon trap and the collected radon is determined by counting the 214Bi daughter product. Development of the system included studies to determine the efficiency of activated carbon, relative calibration measurements and field measurements made during 1980 at the inactive tailings pile in Grand Junction, Colorado. Results of these studies are presented.

Jan 1, 1981

By Maurice C. Fuerstenau

INTRODUCTION The term, chelate, from the Greek for 'claw,' has its origin in the pincer-like representation of more than one atom of a single ligand bonded to the same metal atom, forming a ring-like structure. Depending on how many attachments exist on the sphere of coordination around the metal ion, ligands are referred to as bidentate, tridentate, tetradentate, pentadentate and hexadentate According to Calvin and Martell (1952) and Somasundaran and Nagaraj (1984), chelating agents must contain suitable functional groups, and their location within the ligand molecule must enable ring formation that is sterically possible. Typical structures that meet these requirements have been given by Fuerstenau and Herrera-Urbina (1988) and are listed in Figure 1. As noted, the functional groups of these reagents contain electron donor atoms such as oxygen, nitrogen and sulfur. Basic groups, such as amino (-NH,), are those that contain an atom with a lone pair of electrons. Acid groups are those, such as carboxylic (-COOH) which lose a hydrogen ion and coordinate with the metal atom. Examples of each of these types chelating reagents are given in Tables 1-4. The specificity of chelating agents for various metal ions has long been known and was utilized early in the search for new flotation collectors. In 1927, Vivian used ammonium nitrosophenylhydroxylamine as a collector for cassiterite. Holman (1929) tested dimethylglyoxime as a collector for nickel oxide. He also suggested taurin as a collector for oxidized lead ores. DeWitt and von Batchelder (1939) suggested the use of oximes as flotation collectors. Gutzeit (1946) conducted an extensive investigation on the use of chelating agents as collectors and as depressants for gangue minerals. The depressants are those reagents that form soluble chelates with metal ions that could function as

Jan 1, 2005

By A. Cordonnier, Ch. Obry, R. Evrard

In spite of the large annual expenditures and the vast field of activity covered, it cannot be said that many new grinding machines have actually come to light and modified the existing market for more than half a century. Manufacturers have mainly made advances in increasing machine sizes, efficiency and reliability, and in machine automation. The relatively recent emergence of roller presses is the only exception to this homogenisation of machine ranges. The development of roller presses in pregrinding has shown the advantages of compression grinding over the ball mill from the power consumption point of view. But classical roller presses still have maintenance problems due to the high grinding pressure. The FCB Research Centre has carried out much work in this field and in particular has studied the advantages of this process in pregrinding and integral grinding. These researches lead to the development of two new compression grinding machines. The first one, HOROMILL®, presented for the first time on the 8th European symposium on comminution at Stockholm, finds its application in the field of fine to very fine grinding in dry process. The second one, RHODAX®, presented at INTERMAT in Paris, covers the field of secondary and tertiary crushing and the first stage of grinding for most of the minerals in dry or wet process. Its high reduction factor permits to do with only one machine the work realised today with two or three crushing/milling stages. These two complementary machines offer a wide range of combination summarised on [Figure 1].

Jan 1, 1995

By Jack M. Jodrey, Neil D. O’Donnell, R. A. Metz

Bituminous sands of the Lower Cretaceous McMurray Formation in northern Alberta constitute the ore for the surface mining operation at Syncrude Canada Ltd. These sediments represent a complex succession of fluvial, estuarine and marine depositional environments. Grade prediction is realized through a combination of geological interpretation, computer modeling, and reference to past mining experience. Accurate forecasts of feed grade permit reliable predictions of volumes for removal to meet budgeted synthetic crude oil production. This planning facilitates efficient allocation of mining equipment and resources. The feed grade to the Extraction Plant is monitored at various points along the delivery system.

Jan 1, 1992

By M. G. Rylatt

BHP Diamonds is developing Canada's first diamond mine, Ekati, located in the Northwest Territories (NWT). The mine is a joint venture between manager and operator BHP (51%), Dia Met Minerals (29%), Charles Fipke (10%) and Stuart Blusson (10%). BHP Diamonds is part of BHP Minerals: Production at Ekati began Oct. 14,1998. The mine is situated on a 3,450-km2 (853,000-acre) claim block located in the Lac de Gras region of the NWT (Fig. 1). It is about 300 km (185 miles) northeast of Yellowknife and 100 km (60 miles) south of the Arctic Circle. The seasonal winter ice road to Echo Bay's Lupin Mine passes along the eastern margin of the project area. This allows road access each year from mid-January to mid-April. For the remainder of the year, the project is accessible only by air.

Jan 1, 1999

By K. Norrena, E. Magri

An important problem in mine operations is the classification of material as waste, low-grade stockpile and ore. This classification must often be made with blasthole data that are widely spaced and that have sampling errors. Geostatistical-simulation techniques combined with basic economic principles allow a procedure for classification that maximizes the expected profit. Geostatistical-simulation methods (Gaussian, indicator or annealing-based) allow the integration of hard and soft data in the creation of alternative, equally probable realizations of the mineral grades. At each location, for each realization one calculates the "profit" if the block were to be classified as ore or waste. The optimal classification is the one that maximizes expected profit (a maximum profit selec¬tion or MPS procedure). In this paper, the authors discuss the theoretical justification of the method and implementation details. The use of blasthole data from different types of mineral deposits, that is, different levels of continuity, are considered. The authors also show the efficacy of the procedure with different levels of sampling error. The increased revenue due to the MPS procedure and improved sampling is shown. The paper shows the geostatistical-simulation procedure and the uncertainty in block grades that result from incomplete and imperfect sampling. The optimal classification is presented. Optimal block classifications are transferred to realizable dig limits by hand-drawing polygonal boundaries. The results of the proposed method are compared to classification based on kriging. Limitations and areas of future work are identified.

Jan 1, 2000

By M. R. Moon

The fire at Wilberg Mine in 1984 reached the surface resulting in the failure of the vertical ledge forming the roof and entrance for three main intake portals. The fallen material was covered with a concrete cap to seal the air from the mine. As the mine was recovered and ventilation pressure was placed on seals on the perimeter of the fire area, the concrete capped rubble proved ineffective. Due to the steep and rugged terrain and the inaccessibility to the portals from underground, horizontal holes were drilled into the portal entries and three seals were placed remotely. The seals, in conjunction with pressure balancing the seals around the perimeter of the fire area, resulted in the control of the mine fire.

Jan 1, 1994

By H. Lind

Mining in Estonian oil shale deposit mainly takes place in the Ordovician, Keila-Kukruse aquifer. The aquifer is affected by mining and is fully dried out around the working mine areas (Perens and Savitski, 2008). The groundwater level is decreased down to 30 m, to the mine floor elevation using about 30 pumping stations (Lind, 2005). The pumping rate is very high - depending on the season, ranging from 10 up to 40 m3 per ton of produced oil shale (Reinsalu et al., 2006). The Estonian oil Shale Company mined 15.5 million tons of oil shale in 2007 (Source: Estonian Oil Shale Company). In order to predict the effects, and avoid the social and environmental impacts, there is a need to continuously monitor the situation and run software simulations aiming at decreasing the pumping rate. This becomes even more important since the environmental taxes on usage of groundwater resources increase every year. Therefore, it is necessary to monitor groundwater level and quality, and develop a groundwater model for the overview of the situation during mine operations and also for a number of years after mine closure.

Jan 1, 2008