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By G. A. Kordosky

The control of pH in solvent extraction circuits is an old technique (1,2) but one which has a large potential for future use. The equilibrium position of any reaction which has hydrogen or hydroxide ions, either as products or as reactants, can be controlled by pH adjustment. Several examples of reaction types which are important in solvent extraction systems and which also show a pH dependence are shown in Figure 1. The examples were chosen to show the wide variety of reactions which fit the above criteria, but it is not meant to be a complete listing of all the possible reaction types, Some of the reactions are presented in a simplified form. It is the intent of this paper to discuss pH controlled solvent extraction reactions for some relatively simple systems through more complex ones.

Jan 1, 1979

By Michael J. Humenick

A laboratory experimental research project was conducted to evaluate the use of chlorine for the oxidative destruction of residual ammonia which may remain in ground water after in-situ uranium solution mining operations. The work tested the idea of the injection of high strength calcium hypochlorite solution into the mining zone to convert ammonia to nitrogen gas as a final clean-up process for ammonia removal from the ground water system. The paper details ammonia removal efficiency as a function of chlorine dose, reactant and product material balances, and how the concept may be used as a final ground water restoration process.

Jan 1, 1982

By Dermot M. Ross-Brown

The more important factors controlling the design of pit slopes are related to the local geology over which the designer has little or no control. Nevertheless, there are some factors over which the designer does exert some control and these concern the say in which the rock is excavated and supported. They include blasting, face cleaning, water control, and the use of rock improvement techniques. The paper discusses these factors and relates the extra costs incurred to the steeper slope angles that can usually be obtained. It is demonstrated that even a modest increase in bench angle of 5° through improved excavation techniques can pay off in a single push-back.

Jan 1, 1975

By Steven T. Mitchell

The introduction of Vertical Crater Retreat (VCR) Stoping at the Homestake Mine in Lead, SD, constitutes a major advance in Homes take Mining Company's efforts to improve productivity and reduce costs through underground mine mechanization. The work to date indicates that Vertical Crater Retreat Stoping is one of the safest methods of underground hardrock mining today, and is competitive with all other forms of stoping in terms of cost and productivity. Homes take anticipates that VCR stoping rill account for approximately 30% of the total mine production in 1980.

Jan 1, 1980

By Harold L. Lovell

The extensive heterogeneity of coal is a fact long recognized by scientists and engineers. However, until recent years the practical implications of such heterogeneity have more often been realized from an undesirable experience than from knowledge or forethought. Variations in the properties of coal, even within the same seam, eventually lead to procedural modifications in mining, handling, preparation and utilization. The concepts considered here propose an enhanced application of information, detailing these properties, realizing the uniqueness of any given coal seam but the practicality of a common approach. Coal preparation practice has been designed primarily for the control of ash and sulfur content to meet market specifications which are similarly specified, Other physical characteristics of size and friability are also commonly employed and, to a lesser extent, properties which are implications of rank. The consideration of petrographic data as indicators of origin, thus total physical and chemical properties, has generally been overlooked as a realistic tool in-the exploitation of coal as a resource. The evolution of descriptive techniques, whether petrographic, physical, or chemical, capable of universal application with any rank of coal, is still beset with problems.

Jan 1, 1968

By Ronald C. Severson

Crystals of native gold occur in placer-type deposits. Gold, as a pure metal, is the most malleable metal known; therefore, delicate gold crystal forms should not survive mechanical transport and concentration processes involved in placer formation. To test the hypothesis that the crystalline gold is currently forming in place, two active gold-placer operations and an unmineralized background area in Alaska were examined. At these sites, rock outcrops, soil profiles, and native vegetation were sampled. At one sampling site, the soil was panned and yielded crystalline gold, as well as the more common rounded nuggets. The plants and soils were analyzed for their major, minor, and trace-element contents, especially gold. Two procedures, one a simple demineralized water leach and the other a partial digestion with acetic acid and hydrogen peroxide, were also used to extract gold and various anions from soils. The water-extractable gold ranged from <0.02 to 15.0 ppb Au in the extracting solution. This represents as much as a 104 enrichment in gold over average river water. This extractable gold is probably available to the native vegetation. Gold concentrations in the unashed dry plants from the two placer sites ranged between 0.4 and 106 ppb compared to a background range of <1 to <4 ppb Au. The presence of dissolved organic matter in the soils is thought to be responsible for the dissolution, transportation, and precipitation of gold in these placer soils, and this process is presently active in these soil profiles.

Jan 1, 2013

By Carl G. Schwenk

Rusk County is located in the northwestern portion of the state of Wisconsin, roughly 130 miles east of Minneapolis (Figure 1). The topography is generally flat with dairy farming the principal activity. Forest and swamp lands are common, as well as pasture and cultivated ground. Rusk County falls near the southern terminus of the Precambrian Shield and is covered by a thick layer of glacial drift. Outcrops are quite rare, but the few available exposures indicate that the subsurface is comprised of steeply dipping metamorphosed volcanics and sediments of Early Proterozoic age. A thin section of flatlying Cambrian sandstone is sometimes found directly under the glacial till. The depth to Precambrian basement has been recorded to be as great as 150 feet beneath the surface.

Jan 1, 1976

By Peter G. Sechiari

The Rio Tinto-Zinc Corporation Limited (RTZ), through it exploration company Riofinex, commenced exploration for bauxite in the Amazonia region of Brazil during 1970. Following&apos; encouraging indications, exploration licences were taken out and an exploration programme was initiated In February 1975, a preliminary &apos;feasibility report indicated that a project, based on the Miltonia plateau located close to the town of Paragominas in the State of Para, was viable and that barging might offer an economic solution to getting the product to an ocean-going port. A, decision was taken in April 1975 to proceed with a full feasibility study. In the latter stages of the study, an engineering consortium of Mendes Junior and Bechtel do Brasil was employed to review, and modify if necessary, the concepts that RTZ had developed for the project&apos;s operation. With these concepts agreed, the consortium was requested to make capital and operating cost estimates, and these became available during February 1978. The deposit is being developed by a Brazilian company Mineracao Vera Cruz S.A. (MVC) in which the present share-holding is owned 64 percent by RTZ and 36 percent by Companhia Vale do Rio Doce (CVRD). RTZ is a British based international group of mining and industrial companies with interests in almost every major metal and fuel. CVRD is a Brazilian mining company, 85 percent owned by the Brazilian Government, with a major interest in iron ore and also other non-ferrous metals. It is intended, in due course, that the company will become majority owned by Brazilian interests.

Jan 1, 1979

By A. A. Jonke

The combustion of fossil fuels in a fluidized bed of calcined limestone particles is a potentially efficient and economically attractive process for the generation of steam for electric power production and other uses. The process results in greatly reduced emissions of both sulfur oxide and nitrogen oxide pollutants. Development work, evaluations and design studies are being carried out by various organizations under contract with the U. S. Environmental Protection Agency and the Dept. of Interior (Office of Coal Research). The AEC&apos;s Argonne National Laboratory is one of the principal participants in the development program under interagency agreements with EPA and OCR. This paper covers the principal reasons for developing fluidized-bed combustion, its advantages and disadvantages over conventional combustion methods, and some of the potential applications of the process. The participants in the multi-organizational program, the sponsoring agencies, the general status of development of the overall project, and the chief program areas that still require resolution are discussed. The main features of the program of work at Argonne National Laboratory and the results achieved so far are also included.

Jan 1, 1974

The concept of "classification is expanded beyond the performance of the classifying equipment to include all aspects of the fines removal system of the grinding circuit. Design and operating parameters which affect fines removal are identified and discussed, and a quantitative index for circuit fines removal effectiveness is defined. This approach lends new interpretation to certain observed phenomena, and suggests useful guidelines for circuit design and operation.

Jan 1, 1985

By S. C. Termes

This paper discusses recent Federal Bureau of Mines research on the selective flocculation of various minerals with insoluble crosslinked starch xanthate (ISX). ISX is insoluble, has a shelf life of over a year when kept cold, and has a higher molecular weight due to cross linking than the soluble noncrosslinked starch xanthate used in previous flocculation studies on nonsulfide minerals. ISX readily flocculates a number of sulfide mineral fines but not silicious gangue. Floc formation, floc size, and settling rate are strongly dependent on pH, with the pH dependence differing for each mineral. Bornite has been selectively flocculated from bornite-quartz mixtures, and the bornite-containing flocs were separated from the unflocculated quartz using decantation and washing procedures.

Jan 1, 1982

By Douglas E. Hansen

A current trend in blasting of large volumes of rock is to use increasingly larger diameter shot holes. The use of large diameter holes meant; correspondingly large explosive charges will be loaded and detonated, and, if special efforts are not made, will result in more damage and vibration beyond the intended blast area. With the rising awareness of environmental factors, vibration control becomes increasingly important. Equally important is the preservation of intended lines and grades, and in some cases by blasting with care, slopes can be safely steepended. In the past, vibration control was established to prevent damage to man-made structures. The quarry or open pit itself can be regarded as a structure composed of rock. Far too little attention has been given to the effects of blasting on rock walls. The primary purpose of blasting is to break rock. If the integrity of the rock has been destroyed beyond intended lines and grades, the excavation will be more costly than originally anticipated. The increased cost will not only be from in¬creased excavation due to overbreak, but also increased maintenance due to blast induced wall instabilities

Jan 1, 1976

By A. K. Sinha

Inspite of the growing demands worldwide, thermal coal must compete in the market both in price and quality. The design and performance efficiency of coal preparation plants is thus crucial to the survival and profitability of a coal industry. While the coal recovery influences the cost of production, the quality produced by a preparation plant determines the selling price. Several coal preparation plant simulation models have been developed in recent years to help Improve the performance of coal preparation plants. A research project was recently conducted at Southern Illinois University to evaluate the practical applicability of such a model. The results of this study are presented and discussed.

Jan 1, 1986

By H. Chu

Selective Agglomeration experiments carried out to clean ultra-fine coal are examined. Effect of feed size, pulp density, coalescing agent dosage, and mixing intensity and duration on the kinetics of agglomeration are principally evaluated. A computer coded population balance model governing agglomerate size distribution and composition utilizing coalescence and breakage mechanisms is developed. Model calibration, verification and extension are analyzed.

Jan 1, 1987

By Francisco A. Fonseca

The Carajás Hills are in Brazil&apos;s Eastern Amazon, between the Araguaia and Xingu rivers, and parallels 5° and 7° Latitude South. A location map is given in Fig. 1. It is an area of low mountains (maximum altitude 900 meters), covered by the Amazon rain forest. Annual average temperature is 25°C, ranging from 31°C (maximum) to 19°C (minimum). Annual rainfall averages 2,000mm. Although it rains throughout the whole year, heavy rains occur from December through March. At the beginning of the 20&apos;s, Brazilian explorationists made brief geological descriptions of the area. Due to the thick soil, scarce fresh rock outcrops and the tropical forest covering a completely unpopulated area, detailed geological studies were difficult and reconnaissance expeditions were limited to the river margins.

Jan 1, 1982

By D. R. Dixon

Since the critical role of oxygen in xanthate flotation of sulphides was established (1) subsequent studies have been concerned mainly with the galena-xanthate system. It is therefore surprising to find at the conclusion of a comprehensive review of the topic by Granville, Finkelstein and Allison (2) that it was not possible for them to draw unequivocable conclusions on the mechanism of xanthate adsorption. It was apparent that some new advances were likely if systems other than galena-xanthate (Pbs/x-) were examined. (2) Specifically a less reactive sulphide such as ZnS may interact with flotation reagents at a slower rate than PbS and more information per unit time gathered. Again ZnS is far less reactive electrochemically than PbS or stated equivalently, it is a poorer semiconductor than PbS. More importantly, the ability of ZnS to act as a semi-conductor can be controlled photochemically rather than by direct doping reactions for which it is difficult to assess the uniformity of doping. Thus the conductivity of ZnS can be made the same as that of PbS by irradiating the ZnS with ultraviolet light at circa 360 n.m. (3)

Jan 1, 1974

By Kenneth G. Colman

Even though wet processes were used in coal preparation plants prior to 1941, dewatering coal was not a problem then because the finer sizes were uneconomical to recover and were considered waste. However, during the war years the scarcity of raw materials necessitated the utilization of every pound of natural resources and coal plants began seeking an economical mans of recovering fine coal. Early efforts to this end concentrated primarily on centrifugal dewatering devices. Such equipment produced good results but was relatively expensive. In 1944, a method was devised utilizing a vibrating screen fitted with a profile wire deck rather than the standard woven wire cloth deck. This machine came to be referred to as a dewaterizer. Results obtained with the dewaterizer approached those of the centrifugal equipment, but at a lower capital cost, Their use reduced either the number of centrifugal units required to follow the dewaterizers or the required energy input to heat dryers, In some cases they eliminated the need for any further dewatering equipment.

Jan 1, 1970

By Dave D. Ferris

Today the coal industry is beginning to use some very fundamental economic evaluations to determine the most economical circuit to produce a specified saleable product. The fundamental economic methods used are standard return on investment and net present value calculations. By utilizing these economical evaluations, one can justify a larger capital expenditure and realize more return for an investment over the life of a coal property.

Jan 1, 1983

By E. L. Smith

The development of larger size flotation machines, which started in the 1950&apos;s and 1960&apos;s, is still proceeding. The largest mechanical flotation machines avail-able today have unit volumes in the range of 38.2 to 43.9 M3 (1,350 to 1,550 cft). Designs for mechanical flotation cells of unit volumes as large as 70.8 m3 (2500 cft) are available. The development of these "giant" flotation machines has been and continues to be motivated by the increasingly critical forces of higher energy and capital costs, decreasing ore grades, and lower (real) prices for the products. As an expansion of a previous publication, this paper reports the further development of an improved mechanism for these large flotation machines. The starting point in the develop¬ment of a new mechanism was the identification of design and performance features of existing machines where improvements were desirable. The result of this work was a mechanism which s is an improvement over existing designs. This new design is characterized by an efficient overhung stator and a vortex profile rotor. The overhung design of the stator removes unnecessary and undesirable baffling in the lowest parts of the tank, while maintaining a quiescent froth layer. This results in lower power consumption and better pulp circulation and solids suspension. The vortex profile rotor acts as an efficient pump, with higher pulp recirculation rates as evidenced by the increased air dispersion capabilities, good solids suspension, and low power consumption.

Jan 1, 1983

By Jack D. Melin

The commercial development of the Liwell Screen is a result of a thorough search for a non-blinding and highly efficient screening device capable of handling even the most difficult-to- screen feed materials. A proprietary development of Hein, Lehmann A.G. of Duesseldorf, West Germany, the Liwell Screen utilizes a unique flexible deck motion for sizing a variety of sticky, high surface moisture feed materials including raw coal and lignite at separations ranging from 3/4-inches (19mm) down to 10 mesh (1.5 mm).

Jan 1, 1983