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By F. L. D. Cloete, A. K. Haines, T. D. Sampson, T. H. Tunley, W. A. M. te Riele

The recovery of zinc from pickle liquors by ion exchange A. K. HAINES. Ph.D. (Visitor) T. H. TUNLEY. B.Sc;.(Chem.Eng.)(Visitor), W. A. M. TE RIELE. pr, Eng.. Ph. D. (Visitor), F. L. D. CLOETE. M.Sc. (Chem..Eng.)(Visitor), and T. P. SAMPSON. Pr. Eng.. BSc, (Chem.Eng,). B. Econ. (Visitor) Picklers and galvanizers in and around Johannesburg are encountering an ever-increasing problem in disposing of spent liquors from their hydrochloric acid pickling baths. Particularly troublesome is the zinc-contaminated liquor that is produced as a result of the clean-up of rejects from the galvanizing operation. Because of the volatility of zinc chloride. this liquor presents difficulties when processed in a conventional pyrohydrolysis acid-recovery unit. The paper describes the Metsep Process. developed by the National Institute for Metallurgy and Woodall-Duckham S.A. (Pty) Ltd. which involves the use of continuous ion exchange for the separation of the zinc from the pickle liquor. and the use of liquid-liquid extraction for the conversion of zinc chloride eluate to salable zinc sulphate. A description of laboratory and pilot-plant tests is given. and the approach used in the design of a full-scale continuous- ionexchange plant is outlined.

Jan 11, 1973

By H. S. Sichel, Kleingeld

A frequency distribution model plays a fundamental role in ore evaluation, especially for the feasibility study of new deep gold mines. The geological complexity of the reefs being mined at present in the Witwatersrand basin poses some difficulties regarding the modeling of the underlying ore-value distribution. This geological complexity has given rise to a need for more applicable distributional models. This paper places the geology of the Witwatersrand basin in perspective and draws some important conclusions from the genesis of the deposition. In addition to the three-parameter lognormal model, two more-general distributional models are proposed. These are the compound lognormal (CLD) and log-generalized inverse Gaussian (LN-GIG) distributions. A detailed, although preliminary, comparative study of these two more-general models with the three-parameter lognormal model is described, and the efficiencies of the estimates and modeling are analysed. It is found that the broad assumption that gold grades follow a three-parameter lognormal law is not always the case, and the need to test for departures from log normality should be emphasized so as to ensure the use of appropriate models.

Jan 1, 1992

Council for 1998/99 President R.P. Mohring President Elect J.R. Dixon Vice Presidents Senior M.H. Rogers Junior Dr L.A. Cramer Immediate Past President Dr N.A. Barcza Honorary Treasure J.A. Cruise Members of Council J.P.W. Bennie E.G. de Villiers A.A.B. Douglas F.M.G. Egerton R. Graham Dr R.G. Gürtunca Dr R.V.R. Handfield-Jones P.J. Knottenbelt R.G.B. Pickering* P.S. Piper Prof. R.F. Sandenbergh Dr T.R. Stacey D.J. van Niekerk P.J. Venter J.C. Viljoen

Jan 1, 1998

The results of small-scale resin-in-pulp pilot-plant investigations at Grootvlei Proprietary Mines Ltd, President Brand Gold Mining Co. Ltd, and Western Areas Gold Mine Co. Ltd are reported. At each mine, a pulp was fed simultaneously to a carbon-in-pulp plant, allowing a direct comparison of the metallurgical performance of the two processes. With the Grootvlei pulp, gold was extracted more efficiently by resin than by carbon owing to the Iow concentration of competing base-metal cyanide complexes in solution. With the Western Areas pulp, the reverse was true because of the high concentrations of copper and nickel in solution. Finally, with the President Brand pulp, resin-inpulp was significantly superior to carbon-in-pulp owing mainly to the inherently slow rate of gold extraction from calcine by activated carbon. Results are presented that show the efficiency of the elution of gold and other elements with a variety of reagents from the loaded resins arising from these three campaigns. At Western Areas, a detailed investigation enabled a preliminary cost evaluation to be made of three techniques for the elution of strong-base resins.

Jan 1, 1984

By Zdenek Kunicky

Kovohute Pribram is a plant recycling lead wastes, lead acid batteries in particular. Relevant new recycling technologies are being gradually developed. Outdated technology of smelting lead plates has been replaced by a new technology based on processing of entire batteries in a blast furnace according to the process developed by know-how of German Varta company. The classical Harris refining has been substituted by the oxygen refining. New technologies aimed at utilization of related wastes arising from refining lead bullion in Kovohute Pribram are being developed in house. At present, a new technology of utilization of spent battery acid for extracting zinc from various wastes has been developed. Zinc oxide dross from alkaline refining of lead bullion, during which residual zinc from the preceding vacuum de-zincing is removed as well as waste zinc galvanic sludges (a product of neutralizing precipitation of metals from industrial wastewaters with lime) were treated. In this study, the new developed technology yielding basic zinc carbonate - a valuable raw material for zinc electrowinning, is described together with the first experience of applying the developed method to processing zinc wastes on a pilot scale. Most of the equipment used in the past to regenerate alkali solutions originating from Harris refinery was utilized in the practical realization of this new technology.

Jan 1, 2008

By D. Duncanson, R. J. Davidson

The elution of gold from activated carbon using deionized water by R. J. DAVIDSON, M.Sc., Ph.D. (Rhodes) (Visitor) and D. DUNCANSON, H.N.C., B.Sc. Hons. (Strathclyde) (Visitor) The pretreatment of gold-loaded activated carbon with a relatively strong sodium cyanide solution prior to elution with deionized water at 90 to 125°Chas been shown to have a most beneficial effect on the elution of gold. The findings emphasize the important role played by the calcium cation and the hydroxyl anion in effecting efficient elution of gold. The elution of the relatively unstable complexes of silver and base metals with cyanide was also significantly affected by the ratio of the sodium cyanide to sodium hydroxide in the reagents used in the pretreatment stage. It was demonstrated that the use of 0,5 bed volume of a pretreatment reagent comprising 10 per cent sodium cyanide stabilized with I per cent sodium hydroxide for safety reasons resulted in a virtually 100 per cent recovery of adsorbed gold, silver, and base metals on subsequent elution with deionized water. The elution procedure takes a relatively short time, about 14 hours at 90°C (7 bed volumes) or 3 hours if pressure elution at 125°C (4 to 5 bed volumes) is used. Because the mechanism of elution after pretreatment entails the shifting of a physical rather than a chemical equilibrium, the higher the gold loading on the activated carbon, the more efficient is the elution procedure. When compared with other elution procedures, the proposed method appears to have several economic advantages.

Jan 7, 1977

By M. C. Harris

Float-sink analysis has wide application in the coal laboratory. This paper evaluates the established methods used for the float-sink analysis of fine coal, and then describes a new method and apparatus that can be used for material down to a few micrometres in size. The method is rapid and accurate, and requires only a small amount of sample. The results presented show close agreement with the float-sink analyses obtained by the more classical technique using separating columns. The new centrifugal method reduces the time required for the analysis by a factor of ten.

Jan 1, 1986

By G. H. Morton

The tenth international symposium on the application of computer methods in the mineral industry (APCOM) was held in Johannesburg in April; the first time it had taken place outside North America. In the technical sessions fifty-seven papers were presented, providing a review of current work and including some important original contributions. These papers and a full account of the discussion at the symposium will soon be published in a single volume. The Technical Programme The first session of the symposium included an opening address given by Mr J. W. Shilling, President of the Chamber of Mines of South Africa, and a keynote address by Mr K. F. Lane of the Rio Tinto Corporation Limited. Mr Shilling spoke about the history of the South African mining industry and about some of the work of the Chamber of Mines. He stressed the importance of the symposium in familiarising those in mining with computer applications, and expressed his hope that it would stimulate and inspire scientists and engineers in the effort to develop safer and more economic methods of mining. Mr Lane, talking about economic and financial modelling, gave a fascinating account of the experience of RTZ over the last twelve years. In a very honest appraisal of the substantial progress that had been made, he confessed some disappointment not only in the cost and

By L. A. Vermeulen, D. D. Howat

A study was made of the performance of a rod mil operating without liter bars and with different arrangements of liter bars in the lining. . The results show that striking improvements in performance, increased throughput, and reduced consumption of liner metal and electrical energy can be obtained by a change in the geometry of the liter-bar arrangements within a mil. Rod mils of equal size fitted with the same arrangement of liter bars but operating at different speeds presented apparent anomalies in the relative consumption efficiency of electrical energy for the production of material smaller than 75 µ m. Marked savings in the consumption of liner metal were achieved by the use of an arrangement of alternating lines of higher and lower liter bars. A study of the relative performances of two large tube mils showed that the use of liter bars in one of the mils resulted in a marked reduction in the consumption of liner metal and electrical energy per ton of material smaller than 75 µ m in the product.

Jan 1, 1986

By B. Litt, D. L. Van Coller

Job evaluation and the changing wage pattern by D. L. VAN COLLER, B.A.(Cape Town), M.A., B.Litt.{Oxon.) (Visitor) This paper sets out to show how changing forces are affecting the techniques that have been used in the evaluation of Black jobs on gold mines in the Anglo American Group since the introduction of job evaluation in 1961. Initially, job evaluation was essentially a management tool designed to differentiate jobs in a limited skill spectrum and thereby permit the establishment of a 'many stepped' job ladder for Black employees to climb. With the changing wage pattern, job evaluation is becoming an industrialrelations tool aimed at recognizing the skill and effort contributed by the worker so that the pay relationships between jobs are seen to be equitable by the employees.

Jan 8, 1974

By C. L. E. Swartz, I. J. Barker, J. H. Schubert

A dynamic simulator of the leaching and adsorption cascades of a gold plant was developed and used to compare the effect of various disturbances on the overall efficiency of the plant. These comparisons show which disturbances most critically need to be controlled to optimize plant performance. The simulator was based on an existing gold plant. Dynamic and steady-state data were collected on the plant and were used in the modeling of the process. Simple dual-rate models are used to describe the leaching and adsorption processes. Mole-balances of various species take into account the changes of concentrations in the leach, and also the movement of pulp and carbon up and down the adsorption cascade. Fluctuations in the flow rate, density, and cyanide concentration of the feed to the leach have a negative effect on the efficiency of the leach, while carbon attrition was found to be an important factor in decreasing the efficiency of the carbon-in-pulp (GIP) section. Badly regulated transfers contribute towards the decreased efficiency of the GIP section, but overflows and carbon leakage have only a limited long-term effect. Various carbon profiles and transfer schemes were studied, and the results indicated that a slightly heavier loading at the bottom of the cascade is beneficial, while the type of transfer is relatively unimportant.

Jan 1, 1993

By NONEn NA

1. Book reviews . Rudiments of mining practice, oy C.E. Gregory.Clausthal-Zellerfeld (West Germany), Trans Tech Publications.OS$24.Reviewer: A.N. BrownProfessor Gregory has had a wide experience of hardrockmetalliferous mining throughout the world, beinga well-known academic who has taught at many universitiesin the Western World. His basic training was obtainedin his native land of Australia. In this publication he identified the need for a basic, simple book on miningpractice to provide new students of mining with a backgroundto their studies. He also designed the book to providea background to persons operating on the fringesof the industry such as students of economics and journalists.The text extends to only some 120 pages, and containsa sufficient number of monochrome sketches, diagrams,and photographs. It is written in a straight-forward, easyto-read style. The book contains an index and elementarytable of conversion from imperial to SI (metric) units,and there is also a glossary of mining terms that mostreaders would find useful.The author has succeeded in keeping the contentssimple, as indicated by the title. However, after each chapter, there are references to further recommendedreading. The book could be useful in the South African context, although the coverage of coal and opencast mining operations is slender.

Jan 1, 1987

By H. M. Wells

The investment decision under uncertainty by H. M. WELLS, Pr. Eng., M.Se. (Fellow) The future outcome of a proposed investment is uncertain at the time the decision must be made to accept it or reject it. This uncertainty can be expressed in the form of a probability distribution. An attempt is made to rationalize the investment decision under these circumstances, especially when the range of possible outcomes extends into both the acceptable and unacceptable domains. A rigorous definition of risk is proposed, and a criterion of risk aversion is developed that forms the boundary between acceptable risk and unacceptable risk (called the loss limitation line). It is shown that this decision criterion can also serve as a quantitative yardstick in the evaluation of various possibilities for 'tailoring' the proposal to mlke it more compatible with the particular financial circumstances of the company concerned.

Jan 4, 1976

By A. McCracken

Probabilistic methods for assessing the reliability of engineering systems in mining are the way of the future. So agreed the delegates of a recent short course on the subject, entitled 'Reliability-based Approach in Mining engineering Design'. This was a very successful five-day technical course sponsored by The South African Institute of Mining and Metallurgy and held at Mintek from 7th to 11th March, 1988. The main lecturer for the course was Milton E. Har, Professor of Geotechnical Engineering at the School for Civil Engineering of Purdue University, Indiana, USA. Professor Har was ably assisted by Dr Dirk van Zyl, a former student. Science quiz Teams of pupils from 37 schools within a radius of 12 kilometres of the Council for Mineral Technology (Mintek) competed in a science quiz held by Mintek at its headquarters in Randburg on Tuesday, June 7th, 1988.

Jan 1, 1988

The kinetics of cyanide loss were found to be first order under any given set of conditions, allowing rate constants to be easily determined. At room temperature and in the absence of activated carbon, some cyanide is lost by hydrolysis to hydrogen cyanide, but this does not occur to any significant extent at pH values higher than about 10. A higher rate of hydrolysis occurs when air agitation is used. When activated carbon is present, an additional carbon-catalysed oxidation reaction is responsible for a fairly high loss of cyanide. The evidence indicates a reaction mechanism that consumes oxygen and produces cyanate ion. Some of the cyanate thus produced decomposes to form a mixture of ammonia, carbonate, and urea, depending on the solution conditions. Additional cyanide is lost as a result of the adsorption of sodium cyanide by the activated carbon. At high temperatures, an additional hydrolysis reaction, which involves the formation of ammonium formate as an intermediate, occurs an/j is responsible for. a high loss of cyanide, leading ultimately to the formation of ammonia, hydrogen, and carbon dioxide. The presence of activated carbon has no effect on the rate of this reaction.

Jan 1, 1990

By H. M. Friede

A study was made of the smelting process in two experimental furnaces patterned on Iron Age furnaces excavated at Melville Koppies Nature Reserve, Johannesburg. In a number of smelting experiments, the influences of air supply, temperature, time of operation, fuel consumption, and other operational factors were investigated. Metallurgical and metallographic aspects of the furnace operation and smelting products are discussed, and the experiments are compared with similar research work conducted in Europe and Africa.

Jan 1, 1984

By M. Keevy, K. Hackney

Centrifugal slurry pump station and deposition sites are a common feature of many mines and mineral processing plants. Yanacocha Mine has completed the design of a pump station consisting of two trains of four pumps each. A number of trade-off studies was conducted to optimize the pump station design. The most significant of these was determining the drive types for the slurry pumps. The pump station duty can vary considerably due to the number of deposition points round the disposal site. The standard solution to this problem on a multi-stage pump train is to install one pump with a variable speed drive to control the pump station output by varying the speed of this pump and stopping and starting other stages. However, there are a number of negative impacts associated with this approach. These include head losses through pumps that are stationary or ?wind-milling?, different wear life on pumps that are running and pumps that are stationary, and slower response to the control system with the possibility of hunting. The use of variable speed drives on all the pumps was considered as an alternative to the standard solution. The factors considered in comparing these options were the control and operational differences, the pump efficiencies and absorbed power, the expected pump wear life, the impact on pump maintenance and the cost of the drive options. For this project the option of using all variable speed drives was selected. The paper presents the following aspects of the study: ?Description of the various options investigated. This includes a discussion on the required duty and the drive options. ?Technical comparison between the options. ?Description of the factors influencing pump performance and life.

Jan 1, 2007

By M. Reuter

This paper gives an overview of some criteria for the selection of processes for the recovery of lead and zinc from various raw materials and/or intermediate products. A glossary of possible processes and process variants, is presented and discussed, as well as the way in which these are interlinked. Recent developments in metallurgical process synthesis are also discussed, and the results produced by an eco-techno-.economic synthesis procedure for process routes in zinc metallurgy are given briefly. The way in which such a synthesis can complement a life-cycle assessment (LCA) of zinc-producing technologies is also described.

Jan 1, 1997

By A. H. Mokken, G. K. I. Blendulf, G. J. C. Young

A study of the arrangements for pulp discharge on pebble mills, and their influence on mill performance by A. H. MOKKEN, B.Sc. (Eng.) (Rand) (Fellow), G. K. I. BLENDULF, M.Sc. (Stockholm) (Member), and G. J. C. YOUNG, B.Sc. (London) (Member) Although used for many years in the gold-mining industry, the conventional pan lifter at the discharge end of a pebble mill has hindered attempts at optimization of speed of rotation and pulp flow. A theoretical approach to flow patterns in pan lifters has pointed to limitations in the capacity of these lifters, with capacity decreasing as speed of rotation is increased. Complete elimination of the pan lifter by the adoption of peripheral or end discharge has resulted in a marked increase in pulp flow and an improvement in power utilization. Assays of the gold content of pulp discharged after a mill stoppage from mills fitted with pan lifters show values well in excess of the current milled grade, which indicates an accumulation of gold particles in the mill and, therefore, a longer retention period. The same could apply to other heavy minerals and metals present in the ore feed or worn off mill linings and metallic grinding media. Examples are osmiridium, fine iron and iron alloys, and copper and sulphide minerals. This phenomenon is attributed to the higher specific gravities of these metals and minerals, causing them to migrate towards the mill shell, from which position they are not readily removed by the lifters at the discharge end of the mill. The close association of gold particles with iron and sulphide minerals in the crevices of mill liners might be conducive to the formation of coatings on the gold. Assays of samples of milled pulp taken from a mill designed for end discharge show a lower accumulation of gold. The accumulation and nature of these gold particles are being studied at present. With increasing diameters of pebble (or autogenous) mills, peripheral or end discharge appears to be the preferred method of pulp removal.

Jan 5, 1975

By Peter Smith

The construction of one of the world's largest goldrecovery plants to treat run-of-mine ore is progressing on schedule at the President Brand Gold Mine in the Orange Free State. Designed to treat 390 kt per month, the plant will recover 96 per cent of the gold from the ore at a capital cost of 160 million rands in terms of January 1983 money. It will replace the existing gold-treatment installation, as well as provide a 30 per cent increase in capacity. Mintek reports Report M161 Improved recoveries of gold from auriferous calcines and pyrites by fine milling. Report M171 The development of a versatile computer programme for the evaluation of batchflotation results. Report M178 The reduction of chromite in a transferred-arc plasma furnace. Report M179 Optimization of an inductively coupled plasma by the simplex method.

Jan 1, 1985