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By M. J. Nicol, R. P. Colborn

An investigation into the kinetics and mechanism of the oxidation of iron (11) by oxygen in aqueous chloride solutions By R. P. COLBORN Pr. Eng., Ph.D. (Natal) and M. J. NICOLt B.Sc. Hons., Ph.D. (Rand) A reaction mechanism for the oxidation of ferrous chloride by molecular oxygen is developed. and the appropriate constants are evaluated. The effect of a number of cations and anions on the rate of oxidation has been tested.

By C Smit

SYNOPSIS A prototype collimated radiometric face scanner was tested in the Harmony Gold Mine. The results obtained during the pilot study indicate that in situ radiometric uranium assays are statistically indistinguishable from those obtained conventionally from channel chip samples. In addition, the study demonstrated that reasonably reliable gold estimates can be deduced from the radiometric measurements, by use of the ratio of gold to uranium within a mine. The instrumentation, calibration procedures, and background determination are described briefly.

Jan 1, 1985

By F. H. Guise-Brown

Raise-boring experiences in the gold mines of the Anglo American Corporation Group by J. W. WILSON and P. C. GRAHAM Published in the Journal, October, 1972. Discussion by F. H. Guise-Brown., B.Sc. (Min. Eng.) (Member) INTRODUCTION Messrs J. W. Wilson and P. C. Graham are to be congratulated on an excellent paper containing several thought-provoking remarks. The concept of allocating a machine and equipment valued initially at some R300 000 on an experimental basis is courageous, and the results obtained could be of interest to the mining industry as a whole. The Gold Fields of S.A. Group approached this problem differently. In pioneering the start of this work in South African gold mines, they considered that expenditure of this magnitude would be warranted only if the proposition was viable right from the start. To this end, a Robbins R41 was purchased expressly to assist in the duplication of part of the No. 1 shaft system of the Doomfontein Gold Mine. Mr M. J. Koortsl has summed up the initial results of this work and given some preliminary costing, but inflation since that period has made these figures somewhat out of date.

Jan 10, 1972

By P. A. Laxen, P. J. van Staden

In situ leaching tests with thiourea as the lixiviant were caried out in two worked-out stopes at the No. 6 shaft at Rand Leases Gold Mining Company. Dissolution rates of 0,9 and 0,7 9 of gold per week per 100 m2 of footwal area were achieved. A major disadvantage of the method seems to be the slow rate of dissolution of the gold, which is probably caused by poor contact and slow mass transfer between the lixiviant and the gold surfaces. Under full-scale application, the loss of lixiviant by leakage could also be a very important factor. Furthermore, the oxidation products of thiourea may 'poison' the activated carbon that is used for the recovery of the gold. The method may therefore be economically viable only in stopes that contain high values of residual gold.

Jan 1, 1989

By L. A. Balzan, M. Kalicinski, F. Nieuwenhuys

GEOSCANs on belt analysers have been widely utilised in iron ore for nearly two decades. Since the first installations in 2003, the availability of accurate and reliable grade data has become standardised across iron ore mines in the Northern Cape, where various streams are monitored continuously to ensure the optimal functioning of plants. Assmang Khumani has been at the forefront of technology adoption and has implemented 19 GEOSCANs at various locations throughout the plant, monitoring run-of-mine, stockyard feed, beneficiation plant feeds, and products. Over the years, collaborative advances in the technology have allowed for numerous benefits and gains to be made. In recent times, there has been a concerted effort on the development of analysis for phosphorus in the material flows, and based on Scantech's experience in the phosphate industry, this element has now been calibrated to achieve statistically acceptable and repeatable accuracies for real time analysis of this element on many of Khumani's GEOSCAN analysers. This paper provides an overview of GEOSCAN use at Khumani, while focusing on the development of phosphorus analysis. A case study of analysis results is presented for a range of analysers that have been calibrated for this element, as well as a discussion on the benefits obtained as a result of this analysis. Keywords: Online analysis, real-time, process control

Jan 1, 2020

By D. Das, B. K. Nandi

The present study focuses on utilising the electrocoagulation (EC) process for the treatment of process water generated in an iron ore beneficiation plant for safe discharge and reuse. Removal of heavy metals like Fe, Cr, Cu, Zn, Mn and Pb which was found in higher concentration along with some other impurities exceeding the permissible and discharge limit were attempted. The influence of different electrode material, current density, inter-electrode distance, and solution conductivity was explored for effective removal of the metal ions. Experimental results infer that almost 99.95% Fe, 97.77% Cr, 73.44% Cu, 99.34% Pb and 88.69% Mn was removed using aluminum electrodes at monopolar mode at a current density of 68.50 A/m2, inter-electrode distance of 1 cm and solution conductivity of 1.033mS after 60 min of EC. In addition, removal of other toxins like TDS, turbidity, salinity and conductivity etc. was also assessed during the process. Removal of such heavy metal ions by EC was found to follow 1st order kinetics with electric energy consumption of 3.93 kWh/m3, electrode consumption of 0.1191 kg/m3 and operating cost of 0.6115 US$/m3 respectively. Keywords: Fe removal, electrocoagulation, Al electrode, turbidity

Jan 1, 2020

By L. Kühnel, H. Lieberwirth

Confined bed comminution in High Pressure Grinding Rollers (HPGR) and Vertical Roller Mills (VRM) is gaining substantial attention in many applications. Previously used mainly for milling coal or construction materials, HPGR and VRM have started to complement or even replace tumbling mills in ore beneficiation. Materials like coal or clinker are relatively homogenous, however, in comparison to metal ores and wall rocks. This characteristic poses a new challenge to the confined bed comminution but also an opportunity. Fuerstenau and Abouzeid have investigated the selectivity in comminution of a mixture of particles of different strength in a particle bed. The median particle size and particle size distribution (PSD) of the two constituents used were kept constant. Only the proportion of the two constituents was modified. The competence of a material is, however, also a function of particle size. Smaller particles tend to be more competent than larger ones of the same material. If selective comminution is applied on ores, this size influence has to be understood. The paper presents research results on this topic based on experimental investigations with model materials as well as with natural particles, which were stressed in a piston-die press. It appeared that the comminution result depends substantially on the material characteristics and the composition of the mixture. Conclusions will be drawn for the application in future applications of selective comminution in mineral processing. Keywords: Confined bed comminution, HPGR, VRM, piston die press, particle size

Jan 1, 2020

By L. Prosch

"The word 'sustainability' has gotten such a work out lately that the whole concept is in danger of floating away on a sea of inoffensiveness" Michael Pollon. It is estimated that approximately 65% of the roughly 130 million carats of diamonds mined globally per annum originate in Africa and has an annual value of US$ 8.4 billion', Many of these mines are located in remote areas of the continent where the directly affected project community's income is often well below the poverty line. Often associated with these communities are occurrences of localized over exploitation of natural resources, environmental destruction and the abundance of social ills.

Jan 1, 2010

By K. Naidoo, M. Pelser, J. Hagemann, K. C. Sole

The copper tankhouse at Rustenburg Base Metals Refinery is an essential component of the Anglo American Platinum value chain. The tankhouse uses starter-sheet technology that was adopted in the 1980s, so dependence on manually intensive labour and overall operational excellence has a significant impact on process performance. An efficient, stable, and sustainable electrowinning process contributes to minimising energy consumption and reducing operational costs, and enables improved product quality and increased throughput. Historic performance of this tankhouse has often been suboptimum over prolonged periods. An in-depth operational review of performance from 2018–2024 was carried out to understand challenges, risks, and high-impact factors that contribute to poor performance. Implementation of adherence to fundamental operational basics identified from global best practice, such as the frequency and quality of cell cleaning and maintenance, preventing backlogged harvesting or maintenance, preserving cell-top furniture conditions and integrity of electrodes, preventing short circuits and poor current distribution, and maintaining a high level of operational discipline, has since contributed to an era of exceptional performance. Root-cause analysis fault trees pertaining to poor current efficiency and high scrap rate are summarised. Current efficiency has significantly improved since 2021, now consistently exceeding 88%. The copper scrap rate, previously believed to be limited to a minimum of 4%, achieved a historic monthly low record of 2.06% in 2023. Chemical and physical quality has considerably improved, and cathodes exhibit minimal morphological defects.

Jun 27, 2025

By L. D. Robbins, M. L. Murphy, A. C. Campbell, L. Murphy

This paper reports on what appears to be the first discovery of prehistoric mica-schist mining in southern 4frica. The mine concerned was found in a location very rich in rock art that is one of the most important archaeological sites in the Kalahari. The authors conclude that the oval pieces of mica schist that were found at the mine site were used by Khoisan peoples to scrape fatty tissue from hides that were to be cured. Radiocarbon datings seem to indicate that such ovals were used for at least 20 000 years.

Jan 1, 1994

Review Mining annual review June 1979. London, Mining Journal, 1979. 624 pp. Available as part of the subscription to the Mining Journal or at £12,50 per copy. This annual review is recognized internationally as the world leader in reporting on metals and minerals, and is eagerly awaited each year for its authoritative content, which is compiled by well-respected experts throughout the world.

Jan 1, 1979

By B. J. Madden

The formula developed by Salamon and Munro in 1967 has been used for the past 22 years in the design of bord-and-pillar workings in South African collieries. This paper re-assesses the formula In the light of Its past performance and examines the effect of mining method on coal-pillar strength. An account is given of the extension of the formula so that it can be applied beyond the empirical range for which it was derived, and the advantages of the extended formula (the squat-pillar formula) are described.

Jan 1, 1991

By L. Tartibu, S. Assuli, P. Nkul, A. Kabimba, W. Elongo, N. Makhotla, D. F. Verwey, F. G. Ndiitwani, J. Bilali, T. Mukongo

The presence of colloidal silica negatively impacts various hydrometallurgy processes. This paper details the nature of colloidal silica, operational issues caused by colloidal silica, as well as various mitigation measures. MMG Kinsevere observed severe phase-continuity instability, increased crud formation, and reagent consumption, and reduced current efficiency in electrowinning with a deterioration in copper quality. Historical mitigation measures were initially implemented but failed to solve the problem. MMG Kinsevere successfully achieved efficient silica removal without adverse effect on the solvent extraction with the use of DEHSCOFIX® SC12 coagulant. A week into the coagulant trial, silica concentration had dropped from > 1500 mg/L to within 500 mg/L. The solventextraction plant recovered its stability and again operated at maximum capacity. Additionally, improvement was observed on current efficiency and copper cathodes quality with use of the coagulant.

Jan 1, 2023

By P. V. Scheers

A rotating-cylinder electrode (RCE) was used to simulate the effect of flow velocity on pipe corrosion. A comparison is made between the electrochemical measurements obtained and those measured with a laboratory-scale flow loop. There is good general agreement if the speed of rotation of the RCE is adjusted to give the same value of mass transfer Coefficient as in the other system. Hence, it appears that the RCE is well suited to simulate actual flow conditions in pipes. The simultaneous effect of flow velocity and pH value on the corrosion rate of mild steel in a synthetic mine water was investigated. The i1nrease of corrosion rate was found to be more pronounced at lower pH values and, apart from a sharp increase below pH 4, the initial corrosion rate also increased at pH 7 and 6.

Jan 1, 1992

By J. H. van Dalen, P. J. Brandt, F. W. Wessels

A maximum of ten process streams (Merrill barren solutions) can be monitored sequentially with this on-line analyser, and gold concentrations as Iow as 0,005 mg/I can be determined. The design is a further development of the Tell-tale analyser constructed by the Corner House Laboratories during the period 1965-69. The barren solution is preconcentrated automatically by solvent extraction, the solvent being a solution of I per cent Aliquat 336 in di-isobutyl ketone. An aqueous-to-solvent ratio of 40: I is maintained. The extracted gold in the organic phase is determined by flame atomic absorption, each analysis taking approximately II minutes. The long-term reproducibility of the absorbance readings over a 24-hour period of repetitive sampling of four simulated process streams varied from 6,9 to 4,1 per cent relative standard deviation for gold concentrations of 0,0 I to 0,05 mg/I.

Jan 1, 1980

By L. Makua, K. Langa, Ndlovu. S., C. Saguru

"Global demand for the three platinum group metals (PGMs) Pt, Pd, and Rh has been steadily growing due to their widespread use in emission control, industrial catalysis, and numerous other applications. The primary supply of PGMs is currently the mining industry. However, legislative, operational, and environmental challenges faced by many mining operations result in erratic supply patterns and deficits for these three metals. Naturally, recycling scrap material to recover Pt, Pd, and Rh has therefore aroused research interest in the scientific and engineering communities. Given that the majority of the global demand for these three metals is driven by emission control devices, autocatalytic converters are therefore a significant source of already processed and beneficiated PGMs for recycling.Although pyrometallurgical processes dominate the recycling industry, hydrometallurgical processes may offer certain advantages, chief among these being lower emissions and reduced energy consumption. In this investigation, scrap converter material was leached in acidic chloride media and the leach liquor subjected to solvent extraction and cloud point extraction (CPE) to recover the PGMs. The recoveries for Pt and Pd using Alamine 308® dissolved in kerosene with decanol as a modifier were 95% and 81%, respectively. The maximum recoveries using CPE after complexation with 2-mercaptobenzothiazole (2-MBT) in the presence of Triton X-100 and tin (II) chloride dihydrate as a reductant were 97% for Pd, 96% for Pt, and 91% for Rh. This demonstrates that CPE, although relatively new, may have some potential as a breakthrough PGM recovery technology. IntroductionPlatinum group metals (PGMs) have found a wide variety of applications in different industries due to their chemical, catalytic, and physical properties. PGMs are essential in automobile emission abatement, petroleum refining, and the pharmaceutical and electrical industries (Carabias-Martinez et al., 2000). However, the abundance of PGMs in the Earth’s crust is low and their primary sources are fast depleting (Crundwell et al., 2011).The high demand for PGMs, together with social, economic, environmental, and political aspects related to their production, has led to concerns about their future supply. This has resulted in renewed interest in recycling end-of-life material. PGM supply from recycling has doubled over the last decade, and currently contributes 22% to global supply (Johnson Matthey, 2016). This is in part due to the environmental, social, and operational challenges associated with mining of PGMs. For example, labour unrest, energy cuts, declining commodity prices, and declining ore grades have collectively made the mining landscape economically challenging (KPMG, 2015). On the other hand, the high content of PGMs in secondary sources makes their recovery from the increasing quantities of waste products important from a resource conservation viewpoint. Moreover, PGMs obtained through recycling have been demonstrated to have a 1% environmental cost from a life-cycle perspective, whereas PGMs obtained from mining contribute the remaining 99% of environmental cost (Bossi and Gediga, 2017). Sustainable resource recovery and the economic incentive of recycling have therefore been major drivers to justify investment in PGM recycling. The autocatalytic converter industry accounts for about 70% of the global consumption of these metals (Johnson Matthey, 2016) and therefore recycling spent converters has become a major source of Pt, Pd, and Rh (Figure 1)."

May 1, 2019

By H. Ramazi, A. Amini

"This article is devoted to the introduction of a new technique of electrical resistivity data processing called residual resistivity (RR). We define RR as measured resistivity minus background resistivity. To determine the background resistivity, the data acquired from electrical resistivity measurements along a given survey line is evaluated, and then an equation is fitted to the data corresponding to a chosen measurement station as a function of current electrode spacing (or array length). The RR technique was applied to several synthetic models to compare the conventional resistivity inversion of each model with its RR-based inversion. A case study was carried out in a karstic area in Zarrinabad, Lorestan Province, western Iran, to detect the location and geometry of probable cavities by conventional resistivity inversion and RR-based inversion. The results showed that the anomalous zones are better highlighted in the RR-based inversion images in comparison with the conventional inversion images. In some cases, anomalies detected by the RR-based images were hidden in the conventional method. IntroductionThe geoelectrical resistivity method has been widely used since the early 20th century, and plays an important role in several fields such as groundwater and subsurface mineral exploration, geotechnical and environmental investigations, and archeological studies (Bayrak and Senel, 2012; Candansayar and Basokur, 2001; Fehdi et al., 2011; Hee et al., 2010; Osella et al., 2003; Wilkinson et al., 2010). The goal of geoelectrical resistivity surveys is to determine the distribution of subsurface resistivity by measuring the current-potential difference on the ground surface (Aizebeokhai et al., 2010). In the electrical resistivity method, an electrical current is injected into the ground by two electrodes, called current electrodes (AB), and the potential difference is measured between another pair of electrodes, the potential electrodes (MN). Several methods of interpretation are available for application to electrical resistivity data, the simplest being the graphical interpretation of the apparent electrical resistivity pseudo-sections along each survey line. A second method, electrical resistivity inversion, has been developed to create relatively accurate two- and threedimensional computational resistivity models of subsurface sections (Loke and Barker, 1996; Niwas and Mehrotra, 1997; Nordiana et al., 2014; Oldenburg and Li, 1994; Papadopoulos et al., 2009; Yilmaz and Narman, 2014). In the inversion method, models of subsurface objectives are mathematically inverted to reach optimal solutions subject to prescribed objective functions, constrains, and convergence criteria. A common problem when using the electrical resistivity inversion method is that the inversion model of an electrical resistivity profile may be non-unique because different inhomogeneities in the investigation media can result in the same electrical response (Smith and Vozzof, 1984)."

Jan 1, 2016

By M. -B. Kime

This study applies attainable region analysis to optimise cobalt recovery from oxidised ores via reductive leaching with sulphur dioxide and sulphuric acid. The attainable region framework enables systematic visualisation of trade-offs between cobalt yield and sulphur dioxide loss, guiding reactor network design beyond conventional mass balance modelling. Experimental column leaching trials, supported by validation runs, were conducted under controlled flow and reagent conditions. Kinetic parameters for cobalt dissolution and sulphur dioxide consumption were used to simulate reactor trajectories and construct attainable region envelopes. To ensure hydrodynamic realism, residence time distribution tests confirmed partial plug flow behaviour with dispersion effects, justifying the use of hybrid reactor models in the attainable region simulations. The results revealed that increasing recirculation ratios improves cobalt yield while reducing sulphur dioxide losses, with attainable efficiencies exceeding 90% cobalt recovery and < 20% sulphur dioxide loss. Importantly, the study proposes practical reactor network configurations for future implementation, including staged percolation columns with intermediate mixing zones, oscillatory flow reactors, and modular fluidised bed systems. These designs offer scalable pathways to translate attainable region-based optimisations into industrial practice. Compared to traditional modelling, attainable region analysis provides a geometric decision support tool that captures multi-objective trade-offs and reactor interactions, offering novel insights for continuous leaching system design. This work advances the application of attainable region methodology in minerals engineering by bridging theoretical optimisation with practical reactor design, supporting sustainable cobalt recovery from both primary ores and recycled feedstocks.

Mar 30, 2026

By T. Nghipulile, M. Moys, M. Bwalya, H. Simonsen

The quest for efficiency in comminution is an ongoing concern as comminution usually constitutes a major cost component in the metal production industry. Such improvements can be made by circuit optimization or development of more efficient equipment. A novel crusher, known as the rotary offset crusher (ROC), promises to deliver in this space. The ROC was invented in 2002 by Michael Hunt, Henry Simonsen, and Ian Sinclair, but failed to garner enough support to progress to production. The original design concept was recently rekindled, and a laboratory version of the crusher has been built and commissioned at the University of the Witwatersrand. The crusher is simple in design, with two cylindrical discs that are parallel to each other, and, as the name implies, there is an offset between the vertical axes of the discs. The top disc has a conical section on its lower face, and this creates a crushing zone between the opposite faces of the two spinning discs. Centrifugal motion transports particles through the crushing zone. Batch experiments have been conducted with quartz at various crusher settings (discs offset, rotational speed, and vertical exit gap) for various feed size distributions. The indications so far suggest that the disc speed is a key factor affecting the performance. Size reduction ratios as high as 11 were recorded from experiments with quartz at a speed of 830 r/min.

Jan 1, 2021

By P. A. J. Cabassi, B. K. Loveday, M. J. Wilkinson, P. H. Radcliffe

The recovery of gold, uranium, and pyrite from accumulated residues at mines in the Orange Free State is adversely affected by the presence of pyrophyllite, which is naturally floatable and must be prevented from floating with the desired constituents by the use of a mica depressant, and of thucholite (uraniferous kerogen), which contains significant quantities of uranium and gold but does not float readily in the presence of a mica depressant. In laboratory tests on these residues, the use of a mixture of MIBC (methyl isobutyl carbinol) and paraffin in addition to the suite of reagents normally used was found to increase the gold recovery substantially, but the sulphur grade was lower. The recovery of thucholite also increased considerably, but the proportion of uranium associated with this mineral was small. Plant trials, which are continuing, have been encouraging, indicating an increase in the gold recovery of 4,6 per cent.

Jan 1, 1983