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By J. Sjöberg, P. Lundman, E. Nordlund, C. Quinteiro

Abstract In the Kiirunavaara underground mine, crude ore is transported through ore passes from the production levels to the main haulage level. Failure and stability problems have occurred in some of these ore passes, with increasing frequency as mining depths increase. In this paper, selected results are presented from a research project run by LKAB. The presentation focuses specifically on stability analysis. Numerical models were used to identify failure mechanisms, in conjunction with empirical data and engineering judgment. The most important controlling factors governing failure and damage in ore passes were quantified. A causative model was established in which failure mechanisms and failure development were described. This model was used to formulate a prognosis of future ore pass stability, and for recommending remedial measures. Résumé Le transport du minerai entre les niveaux de production et le niveau principal de transport, à la mine de fer de Kiruna, se fait par des passes à minerai. Avec la profondeur d'extraction grandissante, les problèmes de stabilité au niveau de ces passes à minerai se sont multipliés. Les résultats d'un programme de recherche sur la stabilité des passes à minerai à la mine de fer de Kiruna sont présentés dans cet article. Les mécanismes de rupture ont été identifiés à l'aide de modèles numériques, de données de terrain et du jugement empirique des ingénieurs. Les facteurs principaux controllant l'instabilité des passes à minerai ont aussi été quantifiés. Un modèle a été établi dans lequel les mécanismes de rupture et le développement des dommages ont été décrits. Ce modèle a été utilisé à fins prédictives et remédiatives. Zusammenfassung In der Grube Kiirunavaara wird das gewonnene Erz über Sturzschächte von den Abbauebenen zu der Hauptförderebene gefördert. Mit zunehmender Tiefe des Abbaus sind vermehrt Standsicherheitsprobleme in den Sturzschächten aufgetreten, die teilweise zu Verbrüchen geführt haben. In dem vorliegenden Beitrag werden ausgewählte Ergebnisse einer Forschungsarbeit des LKAB präsentiert. Dabei wird der Schwerpunkt auf die Standsicherheitsuntersuchungen gelegt. Zur Ermittlung der Bruchmechanismen wurden numerische Modelle in Verbindung mit empirischen Daten angewendet. Die wichtigsten Einflußfaktoren für das Versagen der Sturzschächte wurden ermittelt. Es wurde ein Modell zur Beschreibung der Bruchmechanismen und des Versagensablaufs aufgestellt. Dieses Modell wurde verwendet, um die Standsicherheit zukünftiger Sturzschächte zu prognostizieren und um Sanierungsmaßnahmen zu erarbeiten.

Jan 1, 2003

By B. Zlender

ABSTRACT: The paper presents investigation of carboniferous slates from the Trojane hilly area performed on series of samples of equal material. The results of static loading tests show that carboniferous slate is heterogeneous and yields on slate layers. Where that kind of heterogeneity is distinctive the strength results are essentially lower of commonly tests results. The results of dynamical loading tests show that the slate surfaces have the essential meaning for the stability of the material. When those surfaces are moistened the material become unstable. RÉSUMÉ: L'article présente une épreuve des ardoises carbonifères de la région montagneuse de Trojane sur une série des échantillons des matériaux identiques. Les résultats des tests de charge statique montrent que l'ardoise carbonifère est hétérogène et qu'elle cède sur les couches d'ardoise. Quand l'hétérogénéité est distinctive, les résultats de stabilité sont essentiellement plus bas que les résultats obtenus par des tests ordinaires. Les résultats des tests de charge cyclique montrent que les surfaces d'ardoise sont très importantes pour la stabilité du matériel. Quand ces surfaces sont mouillés, le matériel devient instabile. ZUSAMMENFASSUNG: Der Artikel präsentiert die Forschung von Karbonschiefersteinen im Bereich des Bergland Trojane, ausgeführt durch Serien von Proben aus den gleichen Erdmaterial. Die Resultate der statischen Belastungsprüfungen zeigen, das die Karbonschiefersteine heterogen sind und die Schieferflächen nachlassen. Wo bei dieser Art der Heterogenität die Festigkeitsergebnisse wesentlich niedriger sind als bei gewöhnlichen Testergebnissen. Die Ergebnisse der zyklischen Belastungsprüfungen zeigen das die Schieferflächen eine wesentliche Bedeutung für die Stabilität des Erdmaterials haben. Wen diese Schieferflächen befeuchtet sind, wird das Erdmaterial unstabil.

Jan 1, 2003

By J. P. Beukes

South Africa holds approximately three-quarters of the world?s viable chromite ore resources and dominates the global production of ferrochrome. Albeit completely unintended, small amounts of Cr(VI) are formed during ferrochrome production. Certain Cr(VI)species are regarded as carcinogenic, hence making the treatment of some ferrochrome waste materials necessary. In this paper, the Cr(VI) treatment strategies currently employed by the South African ferrochrome producers are investigated by means of a literature review and a questionnaire survey. From the discussion, it is evident that various treatment strategies are available to deal with Cr(VI)-containing waste in the ferrochrome industry. However, by far the most commonly applied treatment strategy remains the aqueous reduction of Cr(VI) with ferrous iron. The advantages and the correct application of this strategy, together with the disadvantages and pitfalls, are argued. Innovative improvements on historic practices are also discussed

Jan 1, 2012

By G. J. McTeer, D. J. Rioux

Teck Metals Ltd operates an integrated zinc-lead complex at Trail, British Columbia, Canada. Since 1997, KIVCETTM flash smelting technology has been utilized for the treatment of zinc plant residues and lead concentrates. Trail Operations’ furnace uses four water-cooled jackets for bullion tapping. This paper provides an overview of KIVCET bullion tapping for the past 16 years, and discusses successes and challenges encountered with respect to operations, training, and monitoring.

Jan 1, 2014

By Q. Li, B. Ricks

Over the last several decades mineral concentrate long distance slurry pipelines have been installed and successfully operated. Nearly all were installed via the buried construction method. Their record of depend ability and economy has been well proven. However, these systems operate in regions where seasonal soil frost penetration is shallow or non-existent. In recent years interest in long distance mineral concentrate pipelines in northern cold regions has been increasing. For cold regions one must consider seasonal temperatures and soil frost penetration in order to ensure reliable operations through the year. Herein a case study is developed where heat balance and temperatures for small and large diameter long distance slurry pipelines are compared. The study development is as follows: ?Rheological properties are analysed over range of temperatures from near freezing (4ºC; 39ºF) to relatively very warm (40ºC; 104ºF). ?Then assuming similar climatic conditions, soil properties, and pipeline length, a study is carried out for two pipeline diameters, namely: a small diameter (nominal8 inch; 219.1 mm) and a large diameter (22 inch; 558.8 mm). ?The study focus is on maintaining slurry temperature above freezing throughout the pipeline length by illustrating a decision based on burial depth versus coating the pipeline with insulation.

Jan 1, 2007

By D. Saramak, T. Gawenda, A. Stempkowska, Z. Naziemiec

The aim of the paper is to discuss the possibility of producing aggregates with an increased content of regular particles, as well as to present a method of aggregate production which has not previously been used in the industry. Traditional aggregate production circuits require the application of three or four grinding stages (depending on the particle size of the feed), but for fine particle fractions of aggregates, irregular grains occur on average with a content of 10%. The innovative technological circuit can produce the aggregates with the content below 3%, even in a single- or two-stage crushing circuit. Downstream jig beneficiation of such prepared material results in higher separation sharpness, lower probable error index (Ep) and imperfection (I). Keywords: Aggregate production, jig beneficiation, mineral processing, raw materials

Jan 1, 2020

By T. Mützea, L. Schützenmeister, G. Kacheb

High-Pressure Grinding Rolls (HPGR) are employed in cement plants worldwide. Although the technology has been mastered in the majority of applications, design-, scale-up- and operationalchallenges still exist today. In addition to modelling throughput, energy requirement and comminution success, the prediction and avoidance of malfunctions is of great importance in current research. The performance of the mill is highly influenced by the roll speed and the fineness of the feed material. Another parameter influencing the composition of mill feed is the circulating load, which is determined by the grinding circuit configuration, the target fineness and the separation efficiency of the classifier. In order to meet this circumstance and simultaneously maintain a reasonable level of material input and testing effort, a complete grinding circuit on a small technical scale was set up in the research centre of Thyssenkrupp Industrial Solutions AG. The present study varied the roll speed (0.5-2 m/s) and the proportion of fines in the feed (0-75 %) in order to investigate the influence of both parameters on the finish grinding of a Portland cement with a target fineness of 4000 cm²/g according to Blain. The experimental results are compared with model concepts and critically examined with regard to their transferability to industrial plants. Keywords: Cement grinding, grinding circuit, HPGR

Jan 1, 2020

By G. Sánchez, S. Seiler, B. Klein, T. Cebeci, P. Bradshaw

The Decar Nickel District is a greenfield discovery by FPX Nickel Corp., of nickel mineralisation located in central British Columbia (BC), Canada. The Baptiste deposit is part of the Decar Nickel District and is a unique deposit containing a nickel-iron alloy mineral called awaruite, with over 2-billion tonnes of inferred resource grading 0.12% Davis Tube Recoverable (DTR) nickel. This deposit represents a significant nickel resource. Awaruite is a high density and ferromagnetic mineral, which could be recovered, along with magnetite that is also present in the samples, using magnetic separation. However, there is still a lack of understanding of the properties of the awaruite and its metallurgical response. This information is imperative for the set-up of the variables involved in its concentration. The aim of this paper is to show and discuss the effect of magnetic field strength for the recovery of nickel from Baptiste deposit samples. Magnetic separation at bench and pilot scale with different magnetic field strengths is evaluated as a concentration method for awaruite. Mineralogical information is provided to support the results and also to briefly assess the variability of DTR nickel within the deposit. The Baptiste deposit is unique and will benefit from a sound scientific understanding of the process solution as well as other ongoing work. If successful, the outcome will lead to the development of a mine. With greater than 2-billion tonnes of inferred resource, the mine would represent a significant new source of nickel globally. Keywords: Nickel ore processing, magnetic separation , awaruite, magnetite

Jan 1, 2020

By P. de A. Barbosa, M. G. Bergerman, E. da Fonseca

Located in the state of Pará, Brazil, the Sossego copper and gold mine consists of a heterogeneous geological deposit. Its complexity derives from the hydrothermal alteration, the ore-forming event, which modified the host rocks, such as granite, and metamorphosed volcanic rocks into several mineral assemblages. Different mineral assemblages have led to differences in abrasiveness. A few Bond abrasion tests conducted during the mine feasibility study did not provide a robust abrasiveness database, thus the variation of physical properties for some mineralisation host rocks was not possible. Although several test methods may be used to determine ore abrasiveness, the Bond method is the one most commonly used in the mining industry. Despite being simple to carry out, this test method has certain limitations as to particle size and the amount of ore sample required, which often makes it difficult or even impossible to apply in the early stages of a project and in geometallurgical studies. The Laboratoire Central des Ponts et Chaussées (LCPC) test may provide an alternative, as it requires a smaller amount of fine-grained material. This study aimed to provide data on wear properties of various ore types from Sossego mine using the LCPC method. It included validation for 40 different ore samples using the Bond test as a benchmark. The results showed good correlation, indicating it may be possible to use the LCPC test as an alternative to the Bond abrasion test. A high abrasiveness index was found for acid metavolcanic rock, confirming the results observed in Sossego mill’s operating database, pointing to a mineralogical drive to amorphous quartz. Keywords: Abrasiveness, geometallurgy, copper ore, Bond abrasion test, LCPC

Jan 1, 2020

Commissioning of the Cannington processing plant began in October 1997. The nameplate capacity (of 1.55 million tonnes of ore per annum) was achieved relatively quickly. Since then (like many mines) the operation has strived to increase throughput and improve valuable metal recoveries, to offset declining head grades and lift the value of the operation. The processing plant now has the capability of treating over 3.2 million tonnes of ore per annum and in financial year 2005/06 the combined concentrate production exceeded 600 000 wet tonnes, approximately 80 per cent above concentrate output in the first full year of operation (at the design feed rate). This improved performance was achieved by making changes and additions to each of the major unit processes - primary grinding, flotation, leaching, filtering and paste fill preparation. The changes have included: adding a fines flotation circuit, expanding the grinding circuit, adding a pebble crusher, switching from continuous to batch leaching, building paste conveyors and decommissioning the column flotation cleaning circuits. This paper reviews these changes, outlines the current operating practices and discusses the challenges or opportunities that remain.

Jan 1, 2007

By S. Langea, H. Lieberwirth

Impact crushers are common machines in comminution plants. Their high size-reduction ratio and relatively simple design, make them a preferred tool even when subjected to harsh wear, and producing a large quantity of fines in some applications. Until now the alignment of the operational parameters was an operator’s responsibility. Due to the random process characteristic this is mostly done based on empirical values and sensor data, such as power consumption. This paper describes a new approach for online process monitoring of the horizontal-shaft-impact crusher. The application of robust, low-cost acceleration sensors enables the permanent observation of the process characteristics. The operational and evaluation methods are determined on the basis of experiments. Subsequently the recorded measurements are analysed in regards of throughput, rotational speed and product particle size distribution. Occurring signal characteristics are described based on physical and technical principles. The measured data of the acceleration sensors at varying operation conditions provide insight in the course of process. The accurate utilisation yields the determination of the preferential process conditions providing the best balance between the pros and cons of an impact crusher. Both the experimental method and the data processing is discussed from a scientific perspective, displaying a completely new approach for the operation of impact crushers. Keywords: Impact crusher, acceleration sensors, data processing, particle size

Jan 1, 2020

By L. Gutierrez, R. Yepsena

Enargite in porphyry copper deposits is an important mineral as it displays good floatability under the presence of the collectors usually used in the flotation of copper sulfides. As a result, copper concentrates grades are reduced. As scarcity of water resources is a problem relevant to Chilean mining, the use of seawater is a feasible solution. The behaviour of copper sulfides and molybdenite in the process of flotation in seawater was previously studied but not for enargite. The objective of this research is to study the behaviour of the enargite in different conditions of electrochemical potential during the process of flotation using seawater. The study was carried through micro-flotation tests using pure samples of enargite, at Eh values ranging from -300 to 500 mV(SHE), both in seawater and aqueous solutions containing calcium and magnesium. The results show that at pH 10.5 in seawater, the enargite and chalcopyrite recoveries are reduced throughout the whole range of Eh studied. At pH 9 in seawater, enargite and chalcopyrite are depressed under reducing and slightly oxidising conditions. The recovery of both minerals drastically decreases at Eh values lower than -100 mV and greater than 400 mV. The behaviour of enargite in seawater flotation differs from that observed in conventional water, since in the latter case the recovery of enargite decreases at higher potentials close to 500 mV. Keywords: Enargite, flotation, seawater, redox potential

Jan 1, 2020

By S. M. Spottiswoode

Rock mechanics benefits of stope support in deep-level mining originate principally from the ability of the support to resist relative movements between the hangingwall and the footwall. While the role of stabilizing pillars and backfill on reducing the energy release rate (ERR) at the face is well understood on the basis of elastic behaviour of the rock mass, the effect of support on controlling movement of fractured ground around deep-level stopes has not yet been thoroughly studied. As part of a programme of studying the behaviour of this fractured ground, geophones were placed 10 m from the face on the roof and floor of a longwall stope in which packs were used as supports. It was found that differential movement between the roof and floor generally exceeds average stope movement during a seismic event. Conventional support therefore transmits very little seismic energy; this is expected to remain true until complete convergence occurs. In backfilled stopes, backfill can become at least as stiff as the fractured wall rock. This will have the effect of reducing the length of the hanging- wall beam. Amongst other rock mechanics considerations, a shorter hanging- wall beam should: (i) increase the resonance frequency of the hangingwall and thereby decrease the levels of vibration for seismic events with M > 1,0; (ii) reduce absolute vibration levels by increasing the mass of rock immediately adjacent to the stope which is shaken by seismic waves; and (iii) reduce differential movement between the roof and floor and thereby reduce cyclic strain on the backfill and on gully support.

Jan 1, 1988

By S. M. Rupprecht

"Artisanal mining is basic mining characterized by manually intensive work methods utilizing primitive or simple equipment and conducted by individuals or small groups exploiting deposits. Artisanal mining in Rwanda and Burundi is further complicated in that the techniques applied are often inadequate, resulting in low productivity and poor recoveries, and workers are paid low wages with owners reluctant to reinvest in the mining operations. A consequence of this vicious circle is often poor working conditions, with miners operating under unsafe and/or unhealthy working conditions. An additional problem is that mining is conducted in a manner that is detrimental to the environment.Artisanal mining is commonly more dangerous than large-scale modern mining operations. Artisanal operations are generally subsistence activities with the miners focusing more on immediate concerns than the long-term consequences of their activities. When miners have no other source of income, they will usually find ways to evade controls and carry on working. Machinery tends to be expensive and often far beyond the reach of most artisanal miners, and therefore there is a general tendency for workers to focus on labour intensive and riskier mining methods.This paper proposes the introduction of small-scale mechanization with labour-intensive manual mining utilizing a bench mining approach in artisanal mines operating in Central Africa. From the 1950s to the 1980s bench mining was successfully conducted in Burundi utilizing manual labour. In order to achieve a balance between job creation and project economics, the combination of manual and mechanized mining is proposed. Manual mining offers the benefit of local job creation while ensuring good mining techniques, such as minimizing mining loses and dilution. Through the introduction of mechanized loading and hauling activities, areas of high stripping ratios can be viably mined, thus increasing the amount of resources that can be exploited. The use of a loader and tractor-trailer arrangement is proposed, thereby improving throughput, productivity, and worker safety and, reducing the impact on the environment."

Jan 1, 2017

By A. F. Mulaba-Bafubiandi

Pseudomonas spp was isolated from mine water and tailings samples collected from mining effluents and mine dumps in the Gauteng and Northern provinces of South Africa respectively. Adsorption properties of Pseudomonas spp were then tested for the removal of Cu and Co initially from their synthetic sulphate solutions, subsequently from effluents derived from metallurgical operations. The effects of experimental conditions such as pH, temperature, time, volume and metal concentration on the efficiency of the biosorption process were studied. Absorption of 45% Cu (pH 6, 37°C, 24 hours) and 40% Co (pH 6, 37°C, 24 hours) was observed from solutions with low concentrations (0.07 M). A maximum of 73% and 65% of Cu and Corespectively were recovered from the mine water samples derived from effluents.

Jan 1, 2009

By S. Fazluddin, K. C. Sole, M. R. Serwale, T. Coetsee

The CSIR-Ti process employs lithiothermic reduction of titanium tetrachloride feedstock to produce titanium sponge. The product is therefore contaminated by a range of lithium and chloride species. In this study we examine the effects of particle size, temperature, and HCl concentration as input leaching variables on the removal of chlorides from the crude titanium sponge. A review of the aqueous chloride chemistry of Li and Ti provided initial conditions for leaching of impurity species from the sponge. Experimental results confirm that the effectiveness of leaching and removal of dissolved impurities from the sponge are dependent on leaching kinetics, which are influenced by temperature, particle size, and morphology. Of the variables tested, reaction temperature had the strongest influence on the oxygen content of the leached product. The HCl lixiviant concentration had a negligible effect under the conditions tested. Leaching of crude titanium sponge (−10 mm size fraction after crushing) at 14°C in either 1 M or 0.032 M HCl yielded a titanium sponge product that met the ASTM standard specification for commercially pure Grade 1 titanium, i.e., oxygen content < 0.18 mass% and chloride content < 0.15 mass%.

Dec 13, 2022

By S. T. L. Harrison, M. Smart, C. J. Edward

Biooxidation, a biohydrometallurgical process, utilizes a mixed microbial consortium to mediate the dissolution of refractory gold-bearing ores to enhance gold recovery during cyanidation. Recognition of water as a critical resource has prompted improved water management strategies within mining and minerals processing. Bioremediated wastewater from the cyanidation tailings provides a potential water source to supplement the water required for the biooxidation circuit, reducing freshwater extraction. Gold biomining operations have typically been reluctant to recycle this wastewater due to the potential inhibitory effects of cyanide and thiocyanate (SCN-) on the microbial population. Historical process upsets suggest that the microorganisms are sensitive to SCN- concentrations as low as 1 mg/L. However, effective bioremediation processes resulting in effluents with low or negligible SCN- concentrations may allow gold biomining plants the opportunity to recycle available water. Microbial activity as well as alteration in community structure were monitored as a function of increasing SCN- concentration over the range of 0 mg/L to 5 mg/L to investigate the response of the biooxidation community to potential SCN- spikes resulting from upsets in the remediation process. Appropriate microbial growth and ferrous iron oxidation activity with a nominal shift in community structure were observed at SCN- concentrations up to 1 mg/L. Thiocyanate concentrations above 1 mg/L resulted in the complete inhibition of ferrous iron oxidation activity. This was attributed to Leptospirillum ferriphilum’s sensitivity to SCN-. Exposure to a SCN- concentration of 5 mg/L resulted in a lower cell concentration and a significant increase in growth lag time, and the absence of L. ferriphilum from the microbial population. At. caldus and Ap. cupricumulans were still present at 5 mg/L SCN-, although Ap. cupricumulans was unable to oxidise ferrous iron at this SCN- concentration. It was concluded that recycling bioremediated cyanidation tailings wastewater within the biooxidation circuit is feasible; however, to retain process performance, SCN- concentrations should not exceed 1 mg/L. Keywords: Biooxidation, thiocyanate, water recycling, community structure

Jan 1, 2020

By S. Maluadzi, D. Rocchi, S. Luyckx, S. S. Potgieter-Vermaak, C. Machio, J. H. Potgieter

The aim of this work was to compare the corrosion behaviour of thermal spray WC ? based coatings before and after annealing. X-ray diffraction (XRD) was used to determine the phases present in the coatings at various stages. The corrosion resistance of the coatings was measured using electrochemical and immersion corrosion tests. The results obtained from electrochemical corrosion (quantified by corrosion current density) and immersion corrosion tests showed that annealing appears to decrease the corrosion resistance of the coatings. From the XRD results it was determined that the phases that corroded preferentially were cobalt (Co), eta (Co6W6C) and W2C. Keywords: Corrosion, thermal spray, coatings, hardmetals.

Jan 1, 2006

By M. Matabane, T. Khati

"Accurate delineation of the contact between a kimberlite pipe and country rock at production level depths is a challenge due to limited geological data. Geological information is obtained from widely spaced diamond core boreholes which are drilled either from surface or from higher mining levels within the pipe. Kimberlite pipe/country rock contacts are notoriously irregular and variable, further reducing the confidence in contact positions defined by the drill-holes. At Finsch Diamond Mine (FDM), the opportunity arose to further improve the confidence in the contact positions relative to the planned slot (end) positions of each sublevel cave tunnel during the development stage of these tunnels. As a result, the accuracy of the 3D geological model has improved.The use of diamond drill core for this purpose is expensive due to site establishment requirements. The lengthy time taken during site establishment also delays the development of tunnels and support cycles, thereby extending the completion dates. FDM has reduced delays during development by adopting percussion drilling, in conjunction with gamma ray logging. The S36 drill rig is mounted on a moveable platform and does not require a costly and lengthy site establishment. The holes are generally drilled (0°/flat) on grade elevation, and these holes could also be drilled from the rim tunnels (developed in waste) into the kimberlite pipe. A single-boom production drill rig is normally used to drill holes about 20 m in length.On completion of the contact delineation drilling, gamma logging of the holes is conducted using the GeoVista geophysical sonde (or probe) to log the natural gamma signature of the dolomite/ kimberlite contact. The advantage of this tool is that the readings are continuous within centimetre intervals, and due to contrasting characteristics between kimberlite (rich in clay minerals) and dolomite, the contact position can be determined accurately. The better definition of contact positions also adds value to tunnel stopping distance in terms of developing the tunnel’s slot at the optimum distance from the contact (easier blasting of longhole rings, avoidance of contact overbreak and premature waste ingress, and other matters relating to extraction of ore from these tunnels). This method is highly successful and has reduced development costs (on-time completion), improved definition of the pipe’s contact position for geological modelling, improved blast design, and mitigated early waste ingress by maintaining the contact’s integrity."

Feb 1, 2019

By I. Mitov, A. Stoilova, D. Krastev, B. Yordanov

We present three technological scenarios for the recovery of valuable components from gangue, stored in the tailings dam at Kremikovtzi metallurgical plant in Bulgaria, into marketable iron-containing pellets. In the first approach the iron concentrate was recovered through a two-stage flotation process, desliming, and magnetic separation. In the second proposed process, the iron concentrate was subjected to four sequential stages of magnetic separation coupled with selective magnetic flocculation. The third route entails the not very common practice of magnetizing roasting, followed by selective magnetic flocculation, desliming, and magnetic separation. The iron concentrate was pelletized in a laboratoryscale pelletizer. Each technology has been assessed with regard to the mass yield of iron concentrate, the iron recovery. and the iron, lead, and zinc content in order to identify the most effective route.

May 1, 2021