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By George S. Rice, W. L. EGY, H. P. Greenwald, L. M. JONES

CHAPTER I. INTRODUCTION AND SUMMARY. BY GEORGE S. RICE. PREFATORY STATEMENT. This bulletin describes the second series of coal-dust explosion tests conducted by the Bureau of Mines in the experimental mine near Bruceton, Pa. It covers a period from 1913 to 1918, inclusive, of more or less consecutive testing, during which many important conclusions were drawn regarding the way a coal-dust explosion may originate, the mechanism of an explosion, and the methods of pre- venting explosions and of limiting incipient explosions. The manuscript was prepared in 1918, but its publication had to be put aside during the World War for more pressing publications and it was not until this fiscal year 1922 that funds could be allotted for its printing. Meantime the general facts concerning methods of preventing explosions have been made known to the mining industry, with great advantage, it is believed, as explosions of coal dust in mines in the United States have become infrequent. This fact, however, must not lull the consciousness of mining men to the terrible potential danger that lurks in untreated coal dust. The experiments described in this volume should be of aid to them in planning to keep the ever present coal dust in an innocuous condition. The first series-reported in Bulletin 56, "First Series of Coal-Dust Explosion Tests in the Experimental Mine"-included only pre- liminary tests of the ability to start explosions of coal dust under the conditions in the experimental mine. After this fact had been determined and several violent dust explosions had been demon- strated before large audiences of mining men, the work had to be suspended in order that necessary repairs and extensions might be made in the fall and winter of 1911-12. Although the question of the possibility of coal dust causing explo- sions had been considered for more than a century, and much testing in laboratory apparatus and in small surface galleries had been done, coal-mining men generally did not believe that coal dust was explo- sive and considered that fire damp or gases of unknown composition were responsible for the mine explosions that had cost thousands of lives in the various coal-mining countries during the last century. As coal mines increased in number, size, and depth, explosions became alarming in their frequency. Finally came the Courriéres disaster in northern France, 1906, by which 1,100 lives were lost, and the following year in this country, the Monongah mine explosion, in West Virginia, which killed 361 men, and the Darr explosion, in Pennsylvania, which killed 239 men. These two disasters, both in December, 1907, led Congress to make an appropriation for an in- vestigation of the causes of mine explosions. The funds became available July 1, 1908, and the work was placed under the United States Geological Survey's technologic branch, with the late Dr. Joseph A. Holmes in charge. Before undertaking the investigations Dr. Holmes visited Europe, accompanied by the senior author of this bulletin, to study the methods foreign countries used to prevent mine explosions, to obtain details regarding tests being made in several countries, to procure safer explosives and better safety lamps for use in gaseous and dusty mines, and to study the methods used in coal-dust explo- sion tests in the recently completed galleries at Altofts, England, and Liévin, France, and in the older galleries at Gelsenkirchen, Germany, and Frameries, Belgium. At all of these stations the explosions tests were made in surface galleries. The Austrian gallery at Segengottes, near Brünn, Moravia, visited by the writer in 1911, is an underground gallery, but the testing done in it was limited, dealing with ignition of coal dust rather than with propagation. Although the results obtained in the foreign galleries had indicated that coal dust was explosive, mining men in the respective countries were of the opinion that the dust would not explode under mine con- ditions. This situation led Dr. Holmes to the conclusion that testing must be done in a real mine, to make certain that the conclusion would be reliable and would be accepted by the mining public as decisive.

Jan 1, 1922

1. In 2002, a total of 2,065 coal mining operations reported employment to the Mine Safety and Health Administration (MSHA). Coal mines comprised 14.2% of all mining operations. • Bituminous mines comprised 92.5% (n = 1,910) and anthracite mines 7.5% (n = 155) of coal mining operations. • More than 70% of all coal mines were located in three states: Kentucky (28.7%), West Virginia (21.7%), and Pennsylvania (20.1%).

Jan 1, 2004

By E. P. Youngman

Ethiopia is generally conceded to be rich in minerals. The lack of mineral development in that country is attributable not so much to the in- accessibility of the deposits as to political conditions. Ethiopia is the only country in the Continent of Africa that has maintained its political independence; and now that it has a progressive and enlightened ruler, Ras Taffari, hope is entertained in many quarters that through foreign partici- pation the Ethiopian mining industry will develop rapidly.

Nov 1, 1931

By Van H. Manning

PETROLEUM INVESTIGATIONS. The work of the petroleum division of the Bureau of Mines during the period of the war was under the supervision of Chester Naramore, chief petroleum technologist. In its petroleum investigations the bureau cooperated freely with other Government bureaus and acted as a source of information on petroleum matters. COOPERATIVE WORK ON INTERALLIED PETROLEUM COMMISSION. On July 15, 1918, Mr. Naramore and W. E. Perdew, chemical en- gineer of the bureau, left for London to act as representatives of the United States Fuel Administration and the United States Shipping Board on the Inter-allied Petroleum Commission. Numerous con- ferences were held with representatives from France, England, and Italy on specifications and requirements of the various allied Govern- ments for petroleum products, and for this purpose meetings were held in London, Paris, and Rome. EXAMINATION OF PETROLEUM FACILITIES IN FRANCE. The storage facilities and the transportation system in France were studied, and recommendations based on the information gained were made to the director of the oil division of the Fuel Administra- tion and to the chairman of the Shipping Board. Refinery plants in France were inspected, as well as filling stations and shipping facilities from ports in France and Italy to the various fronts and the petroleum base of the American Expeditionary Force at Romorantin. France. At the request of Ambassador Sharp, a re- port was prepared on the advisability of developing the petroleum resources in France.

Jun 1, 1919

By Ira E. Sproat

The question "Why can not American kaolins be substituted for English china clay?" has been asked time and time again, and more often since the beginning of the present war in Europe, which has threatened to cut off the supply of European clays imported from abroad. The answer to this question has invariably been, that the domestic kaolins are not as pure and uniform in composition as the imported clays. This demand for white-burning American clays is of such economic importance that it was considered advisable to determine whether some of our vast deposits of impure white clays could not be refined sufficiently to permit their being substituted for the foreign materials. Up to the present time mechanical principles only have been applied in the refining of kaolins, but in order to keep pace with the increasing requirements for better quality and uniformity of product, the application of the principles of colloidal chemistry is necessary. The investigation described in this report was carried on to deter- mine the practicability of applying technical control of clay disperse systems to the refining of kaolins and the utilization of the prepared clay in the manufacture of vitreous china and wall tile. It is hoped that this report will prove a stimulus to the clay- washing industry; will point out a method of refining certain Amer- ican clays, and will lead to the substitution of domestic kaolins for imported china clays by manufacturers of high-grade ceramic wares.

Jan 1, 1916

By Isaac A. Zlochower

A number of ignition incidents involving mining and farm equipment have illustrated the surprising danger of drilling, cutting, or otherwise penetrating sealed compartments or frames that are filled with metal scrap for ballast. The presence of chemically-reactive metals (or electrochemically-active pairs), such as zinc in galvanized steel, can produce hydrogen from moisture in the steel scrap, and the resulting pressure, due to the internally-generated hydrogen, can produce an easily-ignited gas jet when the sealed component is penetrated.

By Kris Chatrathi, John E. Going, Kenneth L. Cashdollar

Two types of flammability limits have been measured for various dusts in the Fike 1-m3 (1000-L) chamber and in the Pittsburgh Research Laboratory (PRL) 20-L chamber. The first limit is the minimum explosible concentration (MEC), which was measured at several ignition energies. In addition to the three dusts studied previously (bituminous coal, anthracite coal, and gilsonite), this work continues the effort by adding three additional dusts: RoRo93, lycopodium, and iron powder. These materials were chosen to extend the testing to non-coal materials as well as to a metallic dust. The new MEC data corroborate the previous observations that very strong ignitors can overdrive the ignition in the smaller 20-L chamber. Recommendations are given in regard to appropriate ignition energies to be used in the two chambers. The study also considered the other limiting component, oxygen. Limiting oxygen concentration (LOC) testing was performed in the same 20-L and 1-m3 vessels for gilsonite, bituminous coal, RoRo93, and aluminum dusts. The objective was to establish the protocol for testing at different volumes. A limited investigation was made into overdriving in the 20-L vessel. The LOC results tended to show slightly lower results for the smaller test volume. The results indicated that overdriving could occur and that ignition energies of 2.5 kJ in the 20-L vessel would yield comparable results to those in the 1- m3 vessel using 10.0 kJ. The studies also illustrate the importance of dust concentration on LOC determinations.

By W. H. Ode, F. H. Gibson, W. A. Selvig

The great expansion of production of aluminum for war purposes has aroused some concern regarding the available supply of carbon suitable for making carbon electrodes required in the electrolytic aluminum process. Approximately three-quarters of a pound of carbon electrode is consumed for each pound of aluminum produced. 5 Because of its small amount of impurities and its suitable physical characteristics, calcined petroleum coke is the standard material used by the aluminum industry for making electrodes As it may be necessary to use some substitute materials, the possibility of using coke made from coal has been considered. Besides this possible use, information concerning the source of low-ash coals is of general interest. Specifications of the aluminum industry for calcined petroleum coke suitable for the manufacture of electrodes are very stringent in regard to allowable impurities. In one such specification the maximum allowable ash is 1.0 percent; the maximum allowable content of iron (as Fe) is 0.06 percent and that of silicon (as Si) is 0.08 percent; the maximum for cal- cium (as Ca) and for sodium (as Na) is 0.12 percent for each, but the two combined may not exceed 0.12 percent; maximum allowable sulfur is 2.0 per- cent. The presence of barium, nickel, chromium, manganese, cobalt, or vanadium is objectionable, and only extremely small amounts are allowed. In regard to physical properties, the coke is required to be so thoroughly calcined that it has a real density of at least 2.02.

Nov 1, 1943

By Hans M. Cassel

The specific objective of research presented in this report was clarifi- cation of physicochemical fundamentals of the mechanism of dust explosions. The equipment, techniques (chiefly photographic), and dusts (chiefly graphite and light metals) employed are described. From behavior of individual par- ticles, conclusions are drawn as to their cooperative function in ignition and combustion of dust clouds. Results are interpreted using thermal theory as accepted for combustible gas mixtures. Radiative transfer across the flame front, as a characteristic of dust flames, is given particular atten- tion. Related studies by other investigators are discussed.

Jan 1, 1964

By N. S. Dalal, W. Irr, X. Shi, V. Vallyathan

"Inhalation of crystalline silica is associated with a biphasic biologic response of acute cell injury and chronic pulmonary fibrosis. Dust induced cell membrane injury leading to the release of lysosomal enzymes and cell death has been implicated as the initial important biologic event triggering the fibrosis. However, it ls also possible other biologic reactions could alternatively, or in addition to these enzyme related cytotoxicity reactions, alter the normal functioning of cells. It is well known that phagocytic activation results in the production of oxygen radicals which are highly cytotoxic to cells. In healthy - lung, protection against the toxic effects of the normal balanced ·biologic reactions are provided by a number of defen1e systems including antioxidants. In disease or condition of overproduction of oxygen radicals, biochemical protection may be overwhelmed with resultant cellular injury.Our recent observations have shown that reactive oxygen radicals (ROR) are generated during grinding of crystalline silica. We hypothesized that these newly generated RORs may cause cell injury, lipid peroxidation, or even damage to macromolecules such as DHA. Biochemical aberrations caused by the inhalation of crystalline silica with ROR at occupational settings might overwhelm cellular and antioxidant defense systems of the lung leading to injury and subsequent fibrosis.To test this hypothesis, we have investigated the generation and decay of ROR produced by crystalline silica using electron spin resonance (ESR) and investigated its toxicity with conventional biologic tests at various time intervals after grinding. We also studied the decay of these newly generated RORs in buffer and the effect of antioxidants and scavengers in the abolition of cellular damages."

Jan 1, 1989

By Eric G. Zahl, John P. Dunford, Hamid Maleki

Coal bumps are influenced by geologic conditions, the geometric design of coal mine excavations, and the sequence and rate of extraction. Researchers from private industry and government agencies around the world have studied mechanisms of violent failure and have identified individual factors that contribute to coal bumps. To develop predictive tools for assessing coal bump potential, the authors initiated a comprehensive study using information from 25 case studies undertaken in U.S. mines. Multiple linear regression and numerical modeling analyses of geological and mining conditions were used to identify the most significant factors contributing to stress bumps in coal mines. Twenty-five factors were considered initially, including mechanical properties of strata, stress fields, face and pillar factors of safety, joint spacings, mining methods, and stress gradients. In situ strength was estimated in 12 coal seams where uniaxial compressive strength exceeded 2,000 psi. Allowances were made for favorable local yielding characteristics of mine roof and floor in reducing damage severity. Pillar and face factors of safety were calculated using displacement-discontinuity methods for specific geometries. This work identified the most important variables contributing to coal bumps. These are (1) mechanical properties of strata, including local yield characteristics of a mine roof and floor, (2) gate pillar factors of safety, (3) roof beam thickness, joint spacing, and stiffness characteristics, which influence released energy,(4) stress gradients associated with the approach of mining to areas of higher stress concentrations, and (5) the mining method. By combining the strength of both analytical and statistical methods, new capabilities were developed for predicting coal bump potential and for building confidence intervals on expected damage.

Jan 5, 1999

By Barbara Fotta, Lynn Rethi

Within the Mine Safety and Health Administration's (MSHA's) classification of metallnonmetal (MAM) mining, the number of independent contractor' employees has increased significantly in recent years. In 1985 independent contractor employee hours reported to MSHA accounted for 4.5% of all M/NM mining employee hours (excluding office workers); by 1994 that proportion had doubled to 9.0%. As a result, these workers now account for an increasingly significant proportion of fatal and nonfatal mining accidents. According to MSHA's statistics, annually computed fatality incidence rates (the number of fatalities per 200,000 employee hours) for independent contractors working in M/NM mining are consistently higher than those for operator employees. Over the five-year period from 1990 through 1994, 53 independent contractor employees were fatally injured while working on M/NM mine property (See Table 1). More than one third of these fatalities (36%) were due to accidents involving powered haulage; 21% were machinery accidents; and 11% percent were falling material accidents. Combined, these three accident classifications accounted for 68% of all independent contractor fatalities occurring on M/NM mine property during these years. Clearly, current efforts to increase the safety of the mining workforce must also address the safety of the independent contractor employee. This report is a preliminary attempt to identify trends in the employment and safety of independent contractor workers by identifying which segments of M/NM mining are experiencing the greatest increases in the number of independent contractor employees and by examining changes in the rates and types of accidents in which these employees are involved. The employment and accident data used in this report were obtained from the MSHA database. [ ]

By Harold M. Smith

The production of oil during the early development of new oil fields is usually accompanied by large quantities of natural gas. Since In most fields gas under pressure is the main source of the energy causing the oil to move throug the sands into the wells and thence to the surface, this coincident production of natural gas will contime as long as present day producing methods are used. Generally the use of this gas is restricted, and markets are not readily available Consequently, a large portion of the gas produced at such times is often wasted by being blown into the air.

Dec 1, 1930

By J. S. Peterson, G. P. Cole

The National Institute for Occupational Safety and Health (NIOSH), Pittsburgh Research Center (PRC), has conducted research to improve electrical fault detection on coal mine direct current (dc) trolley systems. Present circuit breaker protection systems are current-magnitude-based and cannot discern between normal traffic and high resistance electrical faults. Tests were conducted at cooperating mines to assist in developing a neural-network-based detection algorithm for distinguishing between electrical faults and normal operation. The Fast Fourier Transform of the trolley rectifier current signature served as baseline data for the neural network. During field tests, the algorithm performed with greater than 90% accuracy.

By R. V. Ramani, A. S. C. Owili-eger

The Federal Coal Mine Health and Safety Act of 1969 (sec. 303 (b)) stipulates that no working section of the mine shall contain more than 0.5 percent carbon dioxide and no harmful quantities of other noxious or poisonous gases such as the oxides of nitrogen. The concentration of methane should at all times be maintained below one percent. A split of air returning from any working section shall contain no more than 1.5 percent of methane (sec. 303 (i) (2)) and air that has passed by an opening of any abandoned area shall not be used to ventilate any working place in the coal mine if such air contains more than 0.25 percent of methane (sec. 303 (j)). Methane concentration in the returns from the bleeder entries should not exceed 2.0 percent (sec. 303 (i) (3)), and no air that has passed through an opening which is inaccessible for examination shall be used to ventilate any active areas. While the air quantity requirements alone can easily be met, the governing condition in most mines is the dilution requirements for quality control. A sufficient quantity of air is required to render harmless and carry away noxious and respirable pollutants. In recent years, changes in coal extraction methods, rates of advance, location of available reserves, position of prominent methane sources and horizons, and geological sequences have contributed sig¬nificantly to alterations in rates, patterns and character of numerous methane emissions. Gas production of 10 to 15 million standard cubic feet per day is not uncommon from deep mines (Cervik, 1969). Thus, because of the large capital outlay involved in the instal¬lation and subsequent remedial actions of methane drainage systems, knowledge of gaseous flow patterns and storage characteristics of the

Jan 1, 1974

By Charles L. Kimbell

The estimated value of world crude mineral production in 1989 was nearly $1,420 billion in terms of current dollars or more than $1,168 billion in terms of constant 1983 dollars. This latter figure was almost 4.7% above the 1988 level but did not attain the historic high of $1,207.1 billion 1983 dollars set in 1980. The accompanying tabulation provides the latest available revised time series for the value of world crude mineral production in terms of both constant 1983 dollars and current dollars. It also provides one of the two statistical bases for the estimation, this being the data on the value of production of a group of key commodities that was compiled for and published in the authoritative French language mineral industry periodical Annales des Mines for years up to 1983.l It should be stressed that the values just discussed and those presented in the tabulation are for crude minerals only and by no means reflect adequately the role of the entire mineral industry in the world economy. These figures represent only the value of mineral materials as they are mined or otherwise extracted from the earth. They do not reflect the value added to these materials through downstream processing within the facilities commonly accepted as mineral industry plants. That is, value added through beneficiation of ores, smelting, refining, and similar processing is not included in these figures. Comprehensive world data on the value added by such processing are not available; however, a conservative estimate of [ ] the total value of processed output from mineral industry plants derived wholly from primary (newly mined) materials would be on the order of about $2,800 billion constant 1983 dollars or $3,400 billion in terms of 1989 dollars.

Jan 1, 1992

The Bureau of Mines believes that all coal mines are potentially gassy; for the purpose of administration in the prevention of explosions and fires, the Bureau recommends: That any coal mine wherein methane or other combustible gas can be detected in amounts as much as 0.27 of 1 percent or more by frequent systematic searches shall be classified as a gassy mine. Permissible methane-indicating detectors such as are given in I.C. 7110 or subsequent lists of Bureau approved methane-indicating detectors, or conventional methods of sampling and analysis of required accuracy may be used. The concentration referred to in the decision is percent by volume.

Jan 1, 1941

By D. J. Bauer

Liquid-liquid extraction techniques were investigated by the Federal Bureau of Mines for the fractionation of rare-earth solutions. Separatory funnel work using tri-n-butyl phosphate (TBP) for extracting ceric nitrate from solutions containing sulfate ion resulted in almost complete extraction. Similar tests using primary amines for splitting trivalent rare-earth pairs and fractions gave promising results. The ceric nitrate extraction procedure was scaled-up by use of pressure-bubbler equipment, a series of spray towers for extraction, washing, and stripping. In this case only 84 percent ceric nitrate extraction efficiency was achieved. This work was done using dilute sulfuric acid for stripping.

Jan 1, 1960

By Rudolf E. Greuer, Linneas W. Laage, Xinton Chang

The program MFIRE consists of four files MFIRE0 EXE, MFIRE1 EXE, MFIRE2 EXE, and MFIRE BAT The batch file, MFIRE BAT, controls the operation and cooperation of the three executable pro¬gram files and the output Networks of up to 500 air¬ways and 350 junctions can be modeled in the PC version of MFIRE Larger data sets can be accommodated by increasing array dimensions and compiling the program again. Input for MFIRE is in the form of a data file The data file contains fines of numerical data describing the physical mine, the ventilation parameters present, the fans, and the proposed thermal or mechanical disturbances

Jan 1, 1990

By T. Brady, R. Langston, J. C. Johnson, H. Kirsten

An experiment is described in which instrumented rock bolts were used to measure strain in the rock mass during drift development at the Stillwater Mine, Nye, Montana, USA. Two strain-gauged rock bolts were grouted into the middle of the rib next to the face. The drift was excavated in three advances, each one-half drift wide. Strains were recorded hourly by a data logger. Results show that the average change in axial bolt strain for the first and second advance was about the same and that there was almost no change in strain after the third advance. Bending strain was observed 19 cm from the head of the bolt.