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By E. G. King

Heats of formation of three crystalline oxides of rhenium (Re02, ReO3 and Re207) have been determined by the method of solution calorimetry, using an aqueous perchloric acid--ceric perchlorate solvent. Copper metal and cupric oxide were utilized as auxiliary substances. Heats were determined at 298' K for the reactions Re + 2CuO = Re02 + 2Cu, Re + 3CuO = ReO3 + 3Cu, and 2Re + 7CuO = Re207 + 7Cu. Standard heats of formation were derived using the value of -37.23 ±0,15 kcal/mole as the heat of formation of CuO. The standard molal heats of formation of the rhenium oxides were determined: Re02, -107.3 ±0.8 kcal; ReO3, -140.8 ±0.9 kcal; and Re207, -301.9 ±1.8 kcal.

Jan 1, 1969

By Raja V. Rarnani, Robert L. Frantz

"Co-Directors, Generic Mineral Technology Center for Respirable DustEarly in the 1980s, the U.S. Bureau of Mines initiated the concept of the Generic Center, incorporating it into its mining research program, and in 1983, the Generic Mineral Technology Center for Respirable Dust was established. The Generic Center concept was first envisioned by the U.S. Bureau of Mines as a way to bring together the various different scientific, engineering and medical research interests in the respirable dust area to effect a coordinated and efficient organization for advancing knowledge in that field. The result was a combination of the collective talents and skills of more than 100 scientists, engineers, medical personnel and graduate students, through the formation of a consortium of five major research universities, including medical facilities, to perform respirable dust research. The Generic Mineral Technology Center for Respirable Dust consortium comprises The Pennsylvania State University (with its Hershey Medical Center) and West Virginia University (with its Medical Center) as the lead universities and the University of Minnesota, Massachusetts Institute of Technology and Michigan Technological University as affiliates.Although respirable dust-related disease remains the nation's worst industrial hazard, the fundamental understanding of all aspects of respirable dust associated with the mining and milling industries, including the interaction of dust and lungs, has grown significantly over the past near-decade toward the larger effort to reduce the incidence and severity of disease caused by respirable dust. Continued progress toward making the mine work environment cleaner and healthier remains the immediate objective of the Respirable Dust Center.The Respirable Dust Center's research program and technology transfer activities, described in this paper, exemplify the Generic Center concept first envisioned by the U.S. Bureau of Mines. Interdisciplinary and interactive studies continue to result in significant progress toward making mine atmospheres cleaner and healthier."

Jan 1, 1995

Continuously monitor air-borne radon daughters that are a hazard to underground miners. Approach A beta detector continuously counts beta activity collected on a filter paper to allow calculation of exposure in working level units. How It Works At each Site a constant flow pump draws mine air through a fiberglass filter located in front of a beta detector (pancake type Geiger Mueller tube), Radioactive particles (products of the radon 222 gas emanating from the mine walls) collect on the filter and decay, releasing alpha and beta particles as well as gamma rays. A portion of the beta particles penetrate the Geiger tube window and create electrical pulses in the tube. These pulses are then amplified and sent by a coaxial type or shielded electrical cable to a central monitor located some distance from a working level detector. At the central monitor incoming Signals are amplified and fed into two channels, (See the block

Jan 1, 1979

By E. Morrice

Gadolinium, dysprosium, and yttrium are difficult to electrowin as high-purity liquid metals because of their high melting points (>1,300° C). Samarium metal is difficult to prepare directly by electrolysis because the metal reacts with the electrolyte. In this Bureau of Mines study, the rare-earth metal was electrodeposited on a solid manganese, chromium, or iron cathode to form a low-melting alloy. The alloy was then vacuum distilled to separate the rare-earth metal from the ferrous metal. A typical samarium metal product, obtained as the distillate from vacuum distillation of a samarium-iron alloy, contained 150 ppm oxygen, 80 ppm carbon, and 50 ppm iron as impurities, Gadolinium metal, obtained as a residue from the distillation of a gadolinium-chromium alloy, contained 300 ppm oxygen, 200 ppm carbon, and 100 ppm chromium.

Jan 1, 1969

By Oleg Terichow

Electrophoretic mobility measurements were made on samples of Florida phosphate slimes to determine the optimum conditions of coagulation and precipitation in aluminum sulfate solutions. The addition of silica sand and other selected materials as mutual coagulants has demonstrated the practicability of coagulating two dissimilar particle systems by elimination of the repulsive double layers. By proper selection of the solution and its concentration, the reduction of the double layer to a zero point of charge causes coagulation and rapid precipitation of both particle systems. Confirmation was found in filtration tests and sedimentation tests.

Jan 1, 1973

By Forrest T. Moyer

THIS CHAPTER of the Minerals Yearbook contains injury experience and related employment information for the coal-mining, coking, oil and gas, peat, and native asphalt industries in the United States for 1962. Injury experience is measured by the number of injuries sustained per million man-hours of exposure in each industry. No attempt has been made to combine these data and present rates reflecting the mineral-fuel industries because the hazards of the separate industries are not comparable. Tabulations showing the trend of injuries and employment for all mineral industries are presented in volume III of the Minerals Yearbook. COAL The injury-frequency rate for the coal-mining industry of the United States increased less than 2 percent, according to reports received by the Bureau of Mines. The number of fatal and nonfatal injuries per million man-hours in 1962 was 45.86, based on final data for anthracite mines and preliminary data for bituminous coal and lignite mines.

Jan 1, 1963

To enhance safety and efficiency when moving large mining equipment under energized trolley lines, and to assist in compliance with Section 75.1003.2, 30 CFR. Approach A system was designed, using established technology, that permits a remotely located circuit breaker to be controlled from the cab of a mine locomotive moving large mining equipment under energized trolley lines. This control consists of setting the desired trip current, automatic or manual tripping, resetting, and voice communications between the locomotive and a remote Circuit breaker location. How It Works According to 75.1003.2, 30 CFR, whenever a piece of off-track equipment (such as a longwall chock or a continuous miner) is moved by rail under energized trolley or feeder lines, power for the locomotive that is moving the equipment must come from only one' circuit breaker. This circuit breaker must be adjusted to permit no more than one-half its rated short-circuit current to flow. The intent is to lessen the danger if an accident should occur, and if the equipment contacts the trolley line. Even so, the danger is great. This half setting can still represent many hundreds or even thousands of amperes, enough to endanger personnel, the equipment, or the mine. The Remote Control System reduces this danger substantially by giving the personnel associated with the move total control over the associated circuit breaker. The system as designed, is intended to be used with portable circuit breakers that are pulled on a small flat car by a mine jeep, and either precede or follow the equipment, depending on the direction of the power. This portable circuit breaker is equipped with a commercially available solid state overcurrent relay and associated shunt. This circuit breaker is connected via heavy duty clamps around an open trolley line tie breaker such that the current through the shunt is also the current in the trolley line. A receiver, interfaced with the overcurrent relay and shunt, completes the remote system.

Jan 1, 1981

By W. L. Staker

Alternatives were developed to the conventional ammoniacal carbonate leaching-steam stripping procedure for recovering copper as an oxide from contaminated scrap metal. By entraining air bubbles in the leach solution, the copper dissolution rate was increased to 1.5 g/in2 of copper surface per hour, compared to 0.5 g/in2/hr produced by conventional agitation in stirred tanks. Using entrained nitrogen gas bubbles for agitation in conjunction with powdered sulfur not only resulted in rapid dissolution but also simultaneous precipitation of the copper from solution as a high-grade cuprous sulfide.

Jan 1, 1971

By D. H. Chambers

The Bureau of Mines developed a process for producing high-purity zinc and tin by electrorefining from liquid amalgams. Commercial grade metals were dissolved in mercury to produce saturated amalgams at room temperature. Amalgams were also prepared by electrolytic transfer from soluble anodes of the metals to a mercury cathode. Amalgams formed by both methods were used as anodes in electrorefining cells to produce high-purity cathodes. Metal impurities, excluding mercury, were at levels of less than 5 ppm in zinc and 9 ppm in tin. Mercury content was about 2 to 10 ppm in zinc products, and this was effectively removed by heating the cathodes in a vacuum. Mercury was excluded from tin cathodes by pumping the tin electrolyte through tin turnings and controlling the cell temperature.

Jan 1, 1969

Legislation and Government Programs.-On February 4, 1977, the Occupational Safety and Health Administration (OSHA) issued its final environmental impact statement on the occupational use of inorganic arsenic.2 The statement examined the ramifications of the original proposed standard published in the Draft Environmental Impact Statement (DEIS).3 The DEIS proposed to limit the exposure of employees to no more than 4 micrograms of arsenic per cubic meter of air as determined on an 8-hour-time-weighted average basis; or a ceiling limit of 10 micrograms of arsenic per cubic meter of air based on a 15 minute sampling period. The purpose of the proposed regulation is to reduce the risk of smelter workers developing lung and skin cancer as a result of exposure. A comprehensive study compiled by the Committee on Medical and Biologic Effects of Environmental Pollutants concluded that "there is strong epidemiologic evidence that inorganic arsenic is a skin and lung carcinogen in man."' In April 1977, the Environmental Protection Agency (EPA) served notice to ASARCO Incorporated that its Tacoma copper smelter and associated arsenic-producing facilities were in violation of State laws which limit sulfur dioxide and particulate matter emissions. This notice followed the Washington State Pollution Control Hearing Board overturning a prior ruling by the Puget Sound Air Pollution Control Agency (PSAPCA) which had permitted a 5-year variance from the State of Washington air quality standards. In December 1977, ASARCO appealed in court the decision of the Hearing Board.

Jan 1, 1980

By Harry W. Campbell

A mineral survey conducted by the U.S. Bureau of Mines in 1984 identified no mineral resources or prospects with mineral development potential in the Pit River Canyon Wilderness Study Area (WSA). Basalt suitable for aggregate and fill is in the WSA but rock of this nature is abundant in the region and closer to potential markets.

Jan 1, 1984

By Fred C. Turin, Kim M. Cornelius

Work in underground coal mines is repetitive and physically demanding. Workers commonly report a wide range of aches and pains. Management at one mine was concerned about increased reporting of aches and pains by roof bolting machine operators. An analysis of roof bolting tasks was conducted at this mine to identify early warning signs of cumulative trauma. Health and safety risk factors were identified and recommendations to reduce cumulative trauma exposure were provided. Recommendations addressed job procedures, equipment design, and worker awareness of risk factors.

By Wm. C. Dean

The location of trapped miners from their seismic signals will be in- accurate if we assume the P-wave propagation velocity is a constant. P- wave velocities are anything but constant in regions about mines, so some calibration is necessary to obtain more accurate seismic locations. The reference event method compares the time arrivals of signals generated by the miners with those previously recorded from a reference or calibration event in the vicinity of the miners. This method locates the miners' position relative to the calibration source. Hence, the location of the miners is absolute if the reference event position is known absolutely, usually from surveys and mine maps. Advantages resulting from the system, besides greater accuracy, are locations independent of the velocity model assumed, the same solution from the full array and from any subset of four or more seismometers in the array (three if the miners' depth is known), fewer seismometers required, and no complex computers required for analysis. VELA Uniform experience shows that the accuracy of locations of teleseismic explosions and earthquakes is improved by an order of magnitude over locations computed from average travel time curves. Each calibration event is applicable only over a limited range. We recommend a field test of the method at a mine to measure its location accuracy, the range of effectiveness for each calibration event, the number of seismometers needed, and the number of reference events required per mine. From these experiments we could decide whether the reference event method was useful and, if so, what form a practical rescue system would take.

Jan 1, 1974

Accurately measure time of detonation and explosive detonation velocity in a blasthole for analysis of explosive performance and delay intervals. Approach A blasthole-monitoring fiber optic probe was developed consisting of filer optic cable to carry the fight and a sensor to detect and convert the light signals into electrical signals. Events can then be recorded on an oscilloscope, tape recorder, digital computer, or start-and-stop timer. This method is simpler to use and more immune to electronic noise than existing resistance techniques. The fiber optic material,, are inexpensive and easy to obtain, and the recording devices, such as storage oscilloscopes, arc available or easy to obtain. The probe provides the mining industry, explosive manufacturers, and those studying blasting, with a practical alternative to complex and expensive coaxial cable reflectometry, resistor strings, or resistance wire methods for determining explosive and detonator performance. How It Works The fiber optic cable is a plastic light guide consisting of sixteen 0.01-inch-diameter optic strands having an overall outside diameter of 0.087 inch. The receiver module incorporates a photodiode to detect the signal and an integrated circuit receiver for signal amplification into one package about 1/2 by 5/8 by 7/8 inch.

Jan 1, 1989

By G. M. Wilemon

The Bureau of Mines conducted preliminary investigations on the use of an acid-alcohol leaching technique for recovering phosphate values from phosphate matrices. H2S04 and methanol were used as the leaching agents. Starting-matrix particle size and acid-apatite ratio were found to significantly affect the efficiency of phosphate leaching. Phosphate extractions of more than 80 pct were obtained when minus 200-mesh ore was used and the acid-apatite ratio was 8:1 or more. The iron and aluminum oxide impurities (R203) present in the crude acid products were monitored, and R203-P205 ratios are reported. Phosphate extractions in excess of 80 pct also were obtained when phosphatic clay wastes were leached. Typically, leach slurries filtered using test leaf filters ex-hibited filtration rates of 100 lb/(h·ft2) or more.

Jan 1, 1987

By Willard L. Hunter

The separation of tantalum and columbium by solvent extraction was under-taken as part of the Bureau of Mines research program to improve methods for extracting, separating, and reducing these elements to metal. The diethyl ketone aqueous HCl-HF system was one of several systems studied to determine the effect of metal and acid concentrations in aqueous solutions upon the transfer of tantalum and columbium into selected ketones. The tantalum-columbium oxide mixture used in this investigation was obtained by chemical extraction from Geomines slag. The investigation showed that tantalum 99.4 percent pure and columbium 97.2 percent pure can be produced by the selective transfer of tantalum into diethyl ketone from a solution of 2-N HF and 1-N HC1. The relatively low acid concentration necessary for tantalum transfer and the excellent selectivity of the system recommend its use for the separation of tantalum and columbium.

Jan 1, 1961

By Ann G. Kim

Samples of gas were obtained directly from the coalbed during drilling of horizontal and vertical boreholes in six different formations. The samples were analyzed by gas chromatography for C1 to C5 hydrocarbons and for O2, N2, H2, He, and Co2. Methane in the gas varied from 63 to 99 percent; carbon dioxide from 0.1 to 15 percent. The CH4/CO2 ratio varied and showed no apparent correlation with age, rank, or bed. The majority of samples contained ethane, propane, and butane; hydrogen and helium were found in some samples. Oxygen and nitrogen were usually present, possibly as a result of air contamination. A more extensive sampling program would be necessary to establish relationship between the amount and composition of the gas in the coalbed and other factors.

Jan 1, 1973

By Edward D. Thimons, Jay F. Colinet

NIOSH conducted a strategic planning effort to identify those areas in mining with the greatest research needs. Data analysis and stakeholder input identified the need to reduce worker exposure to respirable crystalline silica dust as a high priority area. MSHA dust sampling data were analyzed to target the mining commodities and occupations with the greatest percentage of samples containing silica above compliance levels. In response, the Pittsburgh Research Laboratory (PRL) has implemented a multi-faceted research program to improve silica dust control for these problematic commodities and occupations. A review of silica compliance trends, PRL silica research programs, and recent control technology developments are provided here.

Provide a more efficient method of cooling hot working environments in deep mines than is possible with single stage spray coolers or cooling coil heat exchangers. Approach Pass warm mine air through several stages of horizontally oriented water sprays fed by the chilled water supply of the mine. How It Works This concept extends the capabilities and potential applications of the coolers described in Technology News nos. 71 and 93. In this multi-stage design, hot ventilation air is cooled while passing through horizontal water sprays. Air enters the cooler through a diffuser section which slows the airflow and distributes it evenly across the cooler with a minimum of pressure drop. This ensures uniform exposure of the warm air to the cool water and consequent high thermal efficiencies. In the three-stage cooler shown, cold mine service water is sprayed from the first water stage manifold on the downwind end of the cooler. Slightly warmed water from this spray stage is collected in a sump, pumped and then resprayed through the second stage manifold. The process is repeated again for the third-stage. An overall counterflow heat exchange effect is thus achieved by exposing the hottest incoming air to the warmer, third-stage water spray first and to the coldest, first-stage water spray last. Wave plate eliminators can be employed between stages of water sprays to increase thermal efficiency or at the outlet to minimize the water discharged into the mine ventilation air. Cooled air can then be ducted to hot work spaces or simply released

Jan 1, 1985

Minimize failures or inefficiency in the operation of in situ mining wells. Approach The proper design, construction and development of wells are important to any in situ leaching operation. To permit cost-effective production from an underground ore body by leaching it in place, many wells are normally installed. Construction and maintenance costs increase with the number of wells, and poor construction and maintenance procedures result in production losses and negative environmental impacts, To minimize these losses and impacts, the Bureau of Mines conducted an investigation to determine the optimum in situ well construction and operating procedures for the minerals industry. Factors considered during the investigation included drilling equipment and procedures; types of well casing and grouting; completion methods, e.g, screening or perforation; and system maintenance. The data collected were used to prepare a manual that offers guidelines

Jan 1, 1984