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By B. H. Eccleston

The Bureau of Mines, in cooperation with the American Petroleum Institute, studied the effect of fuel volatility and front-end fuel composition on the amount and photochemical reactivity of automobile exhaust and fuel-system evaporative emissions. The study involved six gasolines--the base fuel, three fuels of varied volatility, and two fuels differing from the base and from each other in front-end olefin content. Data were obtained from 16 vehicles operated on a chassis dynamometer using a speed-load-time cycle that approximated a typical urban trip. Tests were made at ambient temperatures of 20°; 45°, 70°, and 95° F, using a climate-controlled dynamometer room. The amount of hydrocarbon emission and its probable photochemical effect, a potential contribution to pollution, is expressed as weight (reactivity equivalent) of a moderately reactive material, ethylene. Emissions of oxides of nitrogen, car-bon monoxide, and aldehydes were also observed. Results showed that reduction of volatility from currently typical levels serves to reduce both the amount and the reactivity equivalent of evaporative losses with a slight penalty by way of higher exhaust emissions. Alternatively, reducing the amount of light (low boiling) olefin in the fuel had no effect on the amount of hydrocarbon pollutant but did significantly reduce the reactivity equivalent of the emissions. Neither volatility change nor chemical changes to the fuel significantly affected the nonhydrocarbon emissions.

Jan 1, 1970

By John Henderson

If you missed this year?s Texas State Holmes Safety Association meeting, you missed a great one. On January 23 & 24, 2009, we held the meeting that was rescheduled when Hurricane Ike threatened Corpus Christi in September 2008. Sixty-five persons from across the state attended the meeting held at the Holiday Inn Emerald Beach. The weather was 82 degrees, and the sky was clear and perfect for a safety meeting. Evaluations submitted by the attendees gave the presentations, the networking, and even the food top marks. There were eight councils represented; Big Country, Central Texas, Costal Bend, Heart of Texas, Hill Country, North Texas and North Central. Presentations included Workplace Examinations, Emergency Preparedness, Screen Safety, Contractor Responsibilities, Powered Haulage, Supervising for Safety, and Basic Inspections of Slings and Rigging. Mr. Edward Lopez, SC MSHA District Manager, gave the State of the District Address.

Jan 1, 2009

By P. W. Jeran, C. M. McCulloch, Maurice Deul

The natural vertical fracture sys tem in bituminous coalbeds is called cleat. Cleat orientation commonly controls the direction of mining with major development paralleling the face cleat. Previous researchers have categorized the origin of cleat as endogenetic, relating the origin of cleat to compaction and coalification, and exogenetic, relating the origin of cleat to tectonic forces. In the coalbeds studied for this report it was found that tectonic forces were the controlling factor of cleat formation. Face cleats were formed as extension fractures during structural deformation, and butt cleats, as release fractures during erosion and uplift. The face cleat of the Pittsburgh coalbed rotates from N 80° W in north- western West Virginia to N 57° W in southwestern Pennsylvania ; the face cleat maintains a perpendicular orientation to the shifting axial trend of local structures . Cleat orientation in other bituminous coalbeds in Virginia, Utah, Oklahoma, and Central Pennsylvania showed a similar relationship to local structure. Directional permeability of coal is directly related to cleat. Holes drilled perpendicular to the face cleat yield from 2.5 to 10 times the amount of gas released as compared with holes drilled perpendicular to the butt cleat.

Jan 1, 1974

By G. L. Cook

The design of a dual-inlet system for a Consolidated model 21-103C mass spectrometer is described in detail. The system permits both high-mass and low-mass samples to be run by using a single instrument. The difficulties of using a single instrument for both purposes are given and a method of minimizing these difficulties through the use of the present design is discussed, After examining the experience of five years of use, the conclusions are that the bimodal operation is practical and the low-mass analyses had nearly the same precision as before the modifications to the instrument were made. In 1951, O'Neal and Wier.5/ published the first description of the modifications made to a mass spectrometer so that the spectra of hydrocarbons with molecular weights up to 600 could be obtained. Further discussion of the equipment of O'Neal appeared in 1953.6/ Also, Brown, Melpolder, and Young7/ described a parallel inlet system designed to reduce sorption effects at room temperature.

Jan 1, 1960

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

B 2 Program Use Instructions necessary to execute the program, after the card deck has been prepared, are summarized in the following. B 2. 1 Input Data Format Input data is supplied to the program in two ways a. By data cards that are read in after program compilation. b. By data specifications that are included within the program.

Jan 1, 1976

By William P. Diamonds, David C. Oyler

Stimulated vertical boreholes are an effective means of removing gas from coalbeds in advance of mining. This Bureau of Mines report examines the coal mine roof damage potential of stimulation treatments. Twenty-two Government-sponsored stimulation treatments have been mined through to determine the effects on the coalbed and roof strata. Vertical fractures in the coalbed were discernible for most treatments and horizontal fractures were present for about half of the stimulations. Sand-propped vertical fractures were usually short in lateral extent. Evidence of stimulation fluid movement could generally be traced beyond the maximum extent of sand-filled fractures when fluorescent paint was added to the treatment fluids. The maximum lateral extent for a sand-filled vertical fracture was 416 ft and a paint-coated vertical fracture extended 630 ft. Horizontal fractures were generally found within bedding planes, most commonly on top of the coalbed. The maximum lateral extent for a horizontal fracture was 265 ft at a coalbed depth of 630 ft. Horizontal fractures have been found to occur as deep as 1,145 ft. Penetration of strata overlying coalbeds was observed in nearly half of the treatments intercepted. Most of these occurrences have been interpreted to be penetrations into preexisting joints. No roof falls or adverse mining conditions were encountered that could be attributed to the stimulations.

Jan 1, 1987

By Alexis M. Herman

It?s school vacation time again, and kid?s thoughts turn from textbooks and term papers to fun and play, includ­ing outdoor adventures. Old quarries can become swimming holes on hot summer days; sand and gravel piles look like interesting playgrounds; aban­doned mine shafts beckon explorers. But, for the unaware, all three mean danger. Already this year we have seen two stark reminders that mines and minors don?t mix. In Oklahoma, a 13-year-old girl drowned while swimming with friends in an inactive strip mine. In Maryland, a six-year-old boy playing on a quarry site, plunged more than 100 feet to the bottom of the quarry. Playing at such sites may seem like harmless fun, but every year dozens of children and adults are seriously hurt or fatally injured while playing on active and abandoned mine property. These accidents sometimes happen in traditional mining areas like the coal fields of Appalachia and the remote areas of the west. But the threat is anywhere there are active or abandoned quarries, sand and gravel pits, underground mines, or other mining operations.

Aug 1, 1999

By Joseph S. Coffman

The Bureau of Mines investigated the availability of barite (BaSO4) from 35 U.S. and 41 non-U.S. mines and deposits in 17 market economy countries (MEC's). This evaluation assesses the availability of mud-grade barite, and concentrates consumed by the chemicals and fillers industries. The demonstrated resources defined in this analysis totaled 130 million metric tons (Mmt) of barite (contained BaSO4), yielding a potential 115 Mmt of recoverable barite concentrates. At the 1984 MEC production rate, the evaluated resources would last about 30 yr; however, this would include production costs of up to $100/mt concentrate. An average price needed to cover all costs of production over the life of each operation was determined for both mud-grade and chemical- and filler-grade barite products. Including a 0-pct discounted-cash-flow rate of return (DCFROR), regional weighted- average total production cost ranged from $38/mt for barite concentrates in Asia to $71/mt for U.S. operations. Transportation costs have the greatest impact, contributing up to 60 pct of the total cost of production. Rail transportation costs from the mines to U.S. markets are generally significantly higher than ocean shipping rates on imports.

Jan 1, 1986

By Bryan F. Ulrich

If resin-grouted roof bolts are not installed correctly, mine roof reinforcement can be affected, and roof falls can result. A bolt installation variable that is readily controlled by the mine operator is annulus thickness. The objective of this U. S. Bureau of Mines investigation was to study the effect of annulus thickness variations on the integrity of 3/4-in-diam resin-grouted bolts. Forged-head test bolts, 2 and 1 ft long, were installed in concrete blocks that had been drilled with 1-, 1-1/8-, 1-1/4-, 1-3/8-, and 1-1/2-in-diam bits. Standard pull tests were performed; then the concrete was broken away from the bolts so that grout mix quality could be inspected. It was found that the optimum annulus thickness is 1/8-in (l-in-diam drill hole), and as annulus thickness increases from the optimum, there is a corresponding decrease in grout mix quality, effective grout ratio, and axial stiffness.

Jan 1, 1989

By R. L. Montgomery

The literature has been surveyed and values recalculated for the heats and free energies of formation of solid rare-earth compounds at 298° K. In most instances it was necessary to estimate the entropies. Thermodynamic properties of aqueous rare-earth ions have also been calculated. INTRODUCTION The accumulation of thermochemical data on rare-earth compounds in recent years makes it possible to review the subject and to obtain more consistent and more reliable information than was available previously.

Jan 1, 1959

By R. Pakalnis, Richard P. Curtin, Lewis A. Martin

Instrumented cable bolts developed at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health were used in conjunction with existing ground control to monitor rock mass loads at various field sites (FMC Granger, Getchell, Meikle, SSX, K-2, and Stillwater). Axial and shear loads were determined by strain gauges to levels of instrument accuracy of ±5 N or ±5 microstrain as these loads were transferred to the instrumented cable bolts. These gauges were 12.5 mm long and embedded into are manufactured king wire that replaced the conventional king wire. Cable bolt performance, quality of grout, and installation techniques were also assessed. By using instrumented cables, a mine operator can determine axial load along the cable at predefined gauge locations. By monitoring load on and displacement of the rock mass, more effective ground support can be selected and installed, which will lead to safer working conditions for miners.

By Ivette E. Torres

Bulk carriers, freighters, and tankers are the three classes of seagoing vessels engaged in transporting mineral commodities. However, vessels in these classes are not exclusively devoted to mineral commodity transport. Bulk carriers move considerable tonnages of agricultural products as well as crude minerals, their concentrates, mineral fertilizers, and the like. Freighters, owing to their great variety, can be devoted wholly to hauling mineral products or wholly to nonmineral goods, as well as carrying mixed mineral commodities and nonmineral commodities. They include general cargo ships, full container ships, partial container ships, roll-on/roll-offships, and barge carriers. Tankers, although largely engaged in moving crude oil and refinery products, also transport liquid chemicals, molasses, wine, liquefied natural gas, and other fluids. Although physical characteristics of vessels such as size, draft, crew requirements, type of propulsion system, ratio of gross tonnage to cargo tonnage, and fuel costs have undeniable influences on shipping industry performance, problems of and changes in the quantity and types of materials moved also significantly affect the shipping sector of the world economy, and thus have a bearing on the minerals sector of that aggregate. Unfortunately, comprehensive global data reflecting changes in these critical variables are not published.

Jan 1, 1994

By D. H. Baker

This report, one of a series prepared by the Federal Bureau of Mines on the technology of titanium, describes the development of an electrorefining cell from which cathode deposits up to 30 inches long can be produced. Data show individual deposits to be homogeneous, comparable from top to bottom, and not varied in quantity or quality of metal over the entire length of the deposit. Investigations concerned with various diameter cathodes showed that cathode current efficiencies were materially reduced with cathodes less than 2 inches in diameter. Deposits produced on 1/2-inch-diameter cathodes showed cathode current efficiencies of 19 percent and on 1-inch cathodes, just over 22 percent, whereas deposits produced on 2- and 4-inch-diameter cathodes showed about 70-percent current efficiencies. A series of 20 deposits on 4-inch-diameter cathodes was produced under simulated production operation. The average current efficiency, based upon a divalent ion, was 72 percent with 11 1/2 pounds of metal produced per cycle of operation - 98.8 percent of which had a Brinell hardness number (B.h.n.) of 80 or less.

Jan 1, 1959

By F. L. Klinger

CRUDE OIL refining continued to be the foremost industry of Bahrain in 1963. This island, the largest of a group 30 kilometers off the Saudi Arabian coast, is the site of the first petroleum discovery in the Persian Gulf and in the Arabian peninsular region. The island's only oilfield was discovered in 1932; exports of crude began in 1934 and the refinery was built in 1936. Although its crude oil has been less than 1 percent of annual Middle East output in recent years, Bahrain has been an important refining center for many years, processing a substantial portion of Saudi Arabian petroleum as well as all local production. The Bahrain refinery annually accounts for 17 percent 0 the petroleum products produced in the Middle East and 25 percent of the exports. Bahrain's mineral resources consist of oil, gas, and basic construction materials. Petroleum production and refining are the important mineral industries and contribute most of the national income by payments for taxes, wages, and local services including construction and material supply. The petroleum industry has supported a large share of local business and extensive indirect employment, and its early establishment also helped Bahrain to strengthen its position as a trading center in the Persian Gulf. The country's entrepôt trade produces about 20 percent of Government revenue, and Bahrain is somewhat less dependent on the petroleum industry than are the neighboring States to the west.

Jan 1, 1964

By John A. Breslin

Three scale models of coal mine entries and mining machines were constructed by the Bureau of Mines to study the effects of ventilation parameters on dust concentrations where mining personnel would be working. A one-fifth-scale model of a coal mine entry with a drum-type continuous-mining machine and a one-sixth-scale model of an entry with a twin-borer-type machine were used as well as a one-fifth-scale model of a longwall face with a double-drum shearer. Methane was used as a tracer gas to simulate respirable dust in the models. The distance of the end of the brattice or tubing from the face was found to be more important than the airflow rate for the drum-type machine. Dust reductions greater than 90 pct were shown to be possible with a secondary ventilation system used with the twin borer and a dust collector mounted on the longwall shearer. Cutting-head speed had a significant effect on concentrations at typical positions of miners with the drum-type machine and longwall shearer but not for the twin borer.

Jan 1, 1976

By D. B. Dow

The study of oil production methods with reference to the amount of oil originally pressent in the oil-bearing, formations has developed the fact that-ordinary methods-of production remove only a part of the oil actually present. In fact, it is generally realized that when a field is abandoned more oil remains in the sand than has ever been removed. As a consequence of this realization, the petroleum engineer has devoted considerable tine in recent years in devising methods for increasing the percentage of recovery. His studies have indicated that in most cases the total production of a field is dependent upon the available gas rather than upon the available oil. Mien the gas in the sand is exhausted, oil production ceases even though there may be enormous quantities of oil remaining unrecovered. Consequently, any method of conserving the gas or increasing the supply of gas will increase the ultimate recovery from a field. The practice of producing oil under vacuum increases the effectiveness of the gas remaining in the sand, as well as furnishing more gas by evaporating the light fractions of the crude. Pumping ' compressed gas or air down selected wells of a lease has been found to increase the production of oil from the surrounding wells. Studies of oil and gas ratios have indicated that much of the available gas has been wasted as far as its effectiveness on oil production is concerned. his has led to the development of "stop cocking"3 and the practice of producing under back pressure3, which methods aim, to obtain more effective work from the gas with reference to the amount of oil delivered to the well.

Jan 1, 1926

By Robert M. Becker

A multistage probability model for assessing the reliability of mineral samples following any number of stages of sample reduction is presented. Sample reduction is the process of alternately crushing or grinding and sampling mineral particles prior to assaying. The final multistage model developed accurately describes the ideal sample reduction practice. This model is based on previously developed and experimentally tested models for a single stage of sampling. The problem is approached through the probability distributions for the various stages of sampling. The probability distribution, moments, and moment relationships for a single stage of sampling are first reviewed, and the useful concept of unit moments is defined. In presenting the models for two stages of sampling, emphasis is placed on the physical description of the sample reduction process which leads quite naturally to its mathematical representation. In this representation, crushing or particle-size reduction between the stages of sampling is viewed as a random process with respect to the number and proportion of particles of the various kinds produced. The physical and mathematical description is extended to more than two stages of sample reduction, and the first three moments for any number of stages are developed. In common sample reduction practice the effects of a finite population (finite amount of material) at each stage of sampling appear to be important in describing the variance contribution of each stage. This is also true for the third moment about the mean. An example is cited in which the skewness increases by more than an order of magnitude when several stages of sampling are considered. This is largely due to the dependence of the multistage third moment about the mean on the variance. In general the model and results should be useful in helping to understand, control, and reduce the random errors that arise in the sample reduction process.

Jan 1, 1968

By M. L. Odenbaugh

The viscosity reduction effect of varied concentrations of leonardite (a naturally oxidized form of lignite) and leonardite-caustic on the rheological properties of a standard bentonite drilling fluid was studied and evaluated. The minimum plastic viscosity was found to occur at application rates of 4 lb of leonardite and 1.33 lb of caustic per barrel of drilling fluid. Leonardite-caustic treatment was not beneficial in treatment of salt-contaminated drilling fluids. Although filter loss rate was reduced; both yield values and gel strength were increased. Compared with other viscosity control agents) including quebracho) ligno-sulfonate) humic acids extracted from leonardite) as well as other reaction products of lignite) leonardite is less effective at low application rates but is an effective treating agent at rates of 2 Ib/bbl or more. Considering the comparable merits of the substance tested) the major factor in determining which agent to use should be based on cost consideration.

Jan 1, 1967

By T. R. Jolley

An investigation was begun by the Bureau of Mines in 1948 to determine the preparation characteristics of American coals. Results of the investigation were planned to be reported on a county basis and, from the data developed, to determine: I. Which coals either as mined or after beneficiation by conventional preparation are chemically suitable under present standards for producing metallurgical coke. 2. Which coals require special and more intensive treatment in preparation than is now practiced. 3. Which coals cannot be considered potential sources of metallurgical coke, regardless of preparation by present-day methods. This report is one in the county series that describes the preparation characteristics of the coals of Bell County, Ky.

Jan 1, 1957

By John H. Hild

The topography of the Jamestown fluorspar area is rough and ranges from 6,400 to 8,000 feet in altitude. Some fluorspar was mined as early as 1870, but mining really did not begin in earnest until 1940, and up to July 1947 it is estimated that 272,500 tons of fluorite was mined and milled. In 1947 the General Chemical Co. was mining fluorite and milling it in a 200-ton-a-day mill at Valmont, 7 miles east of Boulder, and the Ozark-Mahoning Co. was milling ore in a 100-ton-a-day mill at Jamestown, using ore mined, by H. M. Williamson & Son. These fluorite deposits comprise veins in a granite country rock. The Bureau of Mines drilled eight holes, aggregating 2,579.1 feet, on the Blue Jay vein; four holes, aggregating 1,434 feet, on the Chancellor; and one 350-foot hole on the Nations Treasure. Fluorite of a minable grade and width was found in 10 of the holes drilled. In this report the location and accessibility, physical, features and climate are described and a brief history of the district is given. The deposits and character of the ore and sampling and analyses are described, mine workings are outlined, and work performed by the Bureau of Mines is summarized. Diamond drill logs are shown in appendix I, and 'Sample analyses are tabulated in appendix II.

Jan 1, 1949