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By H. E. Perlee

Mathematical expressions are derived for the histories of the pressure, flame radius, mass fraction burned, and burned and unburned gas temperatures associated with a spherical flame propagating concentrically in a spherical vessel. The equations are solved numerically for a 9.5 pct CH4/air mixture using the best available information for the burning velocity, expansion ratio, and specific heat ratio. Calculated histories are in complete accord with experimental measurements. The accuracy of calculated histories is determined relative to errors in the system parameters, and it is found that 10 pct errors in either the burning velocity or the expansion ratio results in a 40-pct error in the pressure history. A 10-pct error in either burned or unburned specific heat ratio results in a 22-pct error &apos;in the pressure history. It was further established that the usual assumption of constant specific heat ratio is unacceptable, but equating the burned and unburned specific heat ratios result in no apparent error in the histories. The cubic law (P = Kt3 + Po) is derived and discussed, and it is found that the law is valid only during the early period (P<2 atm) of flame growth.

Jan 1, 1974

By George S. Koch

Several methods of calculating ore grades by diamond-drill sampling in the Homestake mine, Lead, S. Dak., have been evaluated by statistical analyses of assay data. The natural distribution of gold particles, partly masked through sampling and assaying procedures, is probably lognormal. As a consequence of the gold particles being clustered rather than randomly distributed within the ore bodies, (1) more mine samples are needed to obtain a specified precision of mean grade than the number predicted by the standard-error-of-the-mean law; (2) the variance of gold values is not inversely proportional to sample volume, and, therefore, small-diameter drill core yields samples nearly as good as larger diameter core; and (3) sampling at 5-foot intervals provides nearly as good results as sampling at shorter intervals.

Jan 1, 1971

By J. P. McGee

As part of a joint U.S. Atomic Energy Commission-Federal Bureau of Mines program for using nuclear energy to supply process heat, a simulated nuclear loop has been constructed to test components. This loop has been operated for more than 1,800 hours at 100 p.s.i.g. Of this period, 23 hours were at 2,500° F. and higher; 540 at 2,000° to 2,500° F.; 840 at 1,500° to 2,000° F.; 200 at 1,000° to 1,500° F.; and 260 below 1,000° F. Leakage at flanges and welds was not a serious problem. A helium-recycle system with gas temperatures of 2,300° to 2,500° F. and a static pressure of 250 p.s.i.g. appears feasible. Difficulties were encountered with the recycle compressor due to thermal distortion of the impeller and shaft. The use of sealed bearings limits compressor operation to the life of the bearings.

Jan 1, 1960

By R. E. Thill

The ultrasonic pulse measurement system described measures velocities of longitudinal (compressional) and shear waves in rock to give values that can be used with density values to determine the dynamic elastic constants of rock. A special feature of this pulse measurement system is its unique acoustical bench that minimizes errors in pulse transit times that are commonly associated with coupling, sample alinement, and sample orientation. Some special features of the acoustical bench are its highly versatile transducer cartridges, a pneumatic ram coupling device, an orientation mechanism, and a vacuum chuck sample holder. The lathe-bed-like construction of the acoustical bench assures automatic alinement of samples and versatility in accommodating samples of various shapes and sizes.

Jan 1, 1968

By Andrew Cecala, John Organiscak, William Heitbrink

Many types of heavy equipment used in the mining and construction industries use enclosed cabs to protect equipment operators from dust and noise exposure. Normally, when the equip- [ ] ment is new, manufacturers&apos; deigned controls are effective at keeping the operator&apos;s exposure at acceptable level. However, as equipment becomes older and many components of the enclosure deteriorate, such as gaskets and seals, the effectiveness of the enclosed cab can be greatly reduced. This can cause excessive and dangerous exposures to respirable dust, especially when the ore or overburden contains crystalline silica.

By N. N. Moebs

The Bureau of Mines air-sealed a 77-acre) above-drainage coal mine to evaluate sealing as a means of reducing the acid and metallic salt contents in drainage from abandoned mines. An approximate reduction in acidity of 150 ppm (equivalent to 193 pounds per day) and in iron of 98 ppm were directly attributed to sealing. The topographical, hydrological, and other factors involved in air-sealing are discussed, and the construction used to seal the mine is described.

Jan 1, 1970

By George A. Morgan

Mineral production was confined to out-put of cement and gravel. However, exploration was being conducted by the U.S.S.R. and the United Nations Development Program. Development of a domestic limestone deposit and crude oil from an offshore oilfield was underway. Benin&apos;s currency remained fixed to the French franc. The gross domestic product (GDP) was $977 million in 1981, the latest year for which information was available. 2 COMMODITY REVIEW Cement.-Construction of a cement plant with 500,000 tons per year capacity neared completion at Pobé. The operator of the plant, using locally produced limestone, was the Societe des Ciments d&apos;Onigbolo, a joint venture between Benin and Nigeria. Nigeria was expected to utilize most of the cement produced. Equipment for the plant included a 1,600-ton-per-day, oil-fired pre-heater.

Jan 1, 1984

By David C. Peters, Robert S. Crosson

A method of error analysis has been applied to the location technique of non-linear least squares iterative inversion in order to evaluate the resolving power of several seismic array configurations with various assumed earth models and errors and inaccuracies in arrival times. The results obtained demonstrate that lateral accuracies of location are improved significantly when the depth of the miner is known. Lateral location to within 100 feet appears achievable in many instances. If it is possible to refine earth models significantly beyond what has normally been assumed in this work by the use of on-site data, or if the mine is shallow (300 feet or less), accuracies of-about 30 feet or so may be attainable. Inaccuracies in earth models of about 5% are found to contribute much more heavily to these location inaccuracies than errors of a few milliseconds in picking arrival times; however, arrival time errors of 15-20 ms or above will dominate these model inaccuracies. The expected accuracy of location is found to fall off very rapidly as the miner moves outside the array. The strength of this effect depends markedly upon the geometry of the array configuration and can be reduced by careful design. Also, as the size of the array is increased, expected location errors within the array are not altered much, but continue to match the error associated with the smaller array over a larger area (assuming that all stations can still pick up the miner&apos;s signals). Better location accuracy, especially with respect to depth control is achievable in an earth where the velocity is depth-dependent (increasing with depth) than in one which is homogeneous. This is an advantage since the

Jan 1, 1974

By R. S. James, E. J. Gleim

Not long after electrically driven equipment was introduced into coal mines it became apparent that the spark-producing parts, such as controllers and motors, required safeguards to prevent the ignition of mine gas that might come into their vicinity. Many of the early designs attempted to provide protective enclosures having ventila¬tion and relief for pressures if ignition should occur within. The principal feature of the Davy safety lamp, namely, the wire gauze, was employed widely for this purpose. Other devices were developed to reduce the temperature of products of combustion escaping through the protected openings to a value below that which would cause ignition of surrounding explosive atmospheres. Although many such devices performed their intended function satisfactorily under laboratory conditions they were not so satisfac¬tory when subjected to the rigorous conditions encountered under¬ground. Corrosion, mishandling, and accumulations of grease and dirt reduced or destroyed their protective qualities after a period of service in the mines. In the United States this has led to abandon¬ment of special devices in favor of what is called " total enclosure " which means that no regular provision is made for ventilation and release of pressure but rather that the housings or enclosures are built strong enough to withstand the explosion pressures without rupture. As a further protection the joints usually are made of broad, closely fitting surfaces. It is impractical to make such joints absolutely gastight in ordinary machine practice when provision must be made for partial or complete disassembly to facilitate ad¬justments and repairs. Therefore, when an explosion occurs within such enclosures flames may escape through the joints. If the latter are broad enough and not separated too widely, however, the flames will be cooled by contact with the metal surfaces (flanges) of the joints, by rapid expansion, or by both cooling and expansion, with the result that an explosive atmosphere surrounding the enclosure will not be ignited. This is termed " flange protection." In testing parts of cutting machines and other equipment for coal mines, with the ultimate object of approving the equipment for use

Jan 1, 1935

By Steven J. Schatzel, Gerrit V. R. Goodman, Robert B. Krog, C. Özgen Karacan, Gabriel S. Esterhuizen

Although longwall mining productivity can far exceed that of room-and-pillar mining, the total methane emissions per extracted volume associated with longwall sections are generally higher than those for continuous miner or pillar removal sections. Increased face advance rates, increased productivities, increased panel sizes, and more extensive gate road developments have challenged existing designs for controlling methane on longwalls. Methane control research by the National Institute for Occupational Safety and Health (NIOSH) recently examined a number of practices designed to maintain concentrations in mine air within statutory limits and consistently below the lower explosive limit. These included a reservoir modeling approach to predict methane inflows in gate road entries. The outputs sug­gested that emission rates in the gate roads decreased with the use of shielding boreholes and increased degasification time. Also, mining perpendicular to the face cleats liberated more gas into the mine workings, emissions were almost a linear function of Langmuir pressure and volume, and emissions were inversely related to sorption time constant. Subsequent simulations predicted changes in methane drainage using in-seam boreholes. The results showed that longer degasification times resulted in lower face emission rates. Premining degasification produced more methane than that produced during panel extraction, a fact attributed to the already decreased methane content of the coalbed. This work concluded that longer premining degasification periods would be more advantageous to the operator. The industry trend toward increasing longwall face width can produce increased methane emissions from the face due to a higher volume of cut coal on the face conveyor. Two methods were used to estimate face methane levels on longer faces. In the first method, segmented methane data were extrapolated for greater face widths. The second method estimated emissions contributions from the shearer, face conveyor, panel belt, longwall face, and ribs, and summed these for wider panels. Permeability changes in the gob behind the longwall shields were estimated using a NIOSH-developed numerical model. The results showed that permeability was highest near the edges and corners of the gob.

Jan 3, 2008

By K. K. Kershner

This report describes an investigation by the Bureau of Mines designed to provide background data for extending and improving the applications of chlorine metallurgy in extracting metals from ores. Optimum conditions are given tor chloridizing galena, sphalerite, and chalcocite by contact with chlorine gas. Petrographic and chemical analyses of the sulfides used in the experiments are listed. Graphs are furnished showing the extent of chloridization of each metal sulfide over the temperature range of the observations. In each case, the first tests were made with the reaction chamber at room temperature. This temperature was increased by regular increments in succeeding tests until the temperature was reached at which quantitative conversion of the sulfide to chloride was observed. The data are also plotted for screen-size fractions of the sulfide minerals investigated. Data show that the extent of metal chloride formation was affected by chloridization time, particle size of the sample, and usually, the temperature of the reaction chamber. At 300° to 400° C. an anomaly was noted for both galena and sphalerite. The temperature at which this anomaly was observed varied according to the particle size of the mineral. Comparisons are made between the chloridizing characteristics of the mineral sulfides and their chemically prepared counterparts.

Jan 1, 1961

By L. A. Stewart

"SUMMARYThis paper describes most of the chrysotile-asbestos deposits of Arizona. Mining methods are discussed briefly and asbestos-mill flowsheets are incorporated. Arizona asbestos mines are the only sources on the American continents of naturally iron-free chrysotile spinning fiber that is so urgently needed for electric-cable coverings, especially on warships.Asbestos was first recorded and recognized in Arizona in 1872, and a minor amount was produced from a deposit in the Grand Canyon in 1900. The discovery of a deposit in the Salt River district in 1912 initiated intensive prospecting, and deposits soon were developed. The total Arizona production of all grades of asbestos through 1953 is estimated at 30,000 to 35,000 tons.The deposits of the Central Arizona region, which are discussed in this paper, are scattered over nearly 2,000 square miles. The annual output is relatively small, because the asbestos occurs in thin, discontinuous veins and only in areas where intrusions of diabase are adjacent to or crosscut certain favorable units of the pre-Cambrian Mescal limestone. This stratigraphic limitation, combined with other essential geologic conditions, tends to restrict the size of the deposits.Virtually all of the deposits are in rugged, mountainous country, and many of the mines are on steep canyon walls. In the average mine, production of 1 ton of commercial asbestos requires removal of 30 to 40 tons of waste rock. Mining and transportation costs consequently are high.Several deposits of chrysotile that is somewhat harsh and of moderate tensile strength have been known for years but were not worked because of the former exacting demands of industry for high-strength, soft asbestos. However, improve¬ments in asbestos fiberization and spinning technique, combined with the urgent need for asbestos, have made this so-called semisoft fiber desirable, and deposits of this type now are being exploited."

Jan 1, 1955

By Neil B. Young

Carbonate minerals constitute a major fraction of the oil shale in Colorado&apos;s Green River Formation. Quantification of carbonate minerals is important for the characterization of oil shale, particularly because of their thermal activity in production of oil from shale. The carbonate minerals found in this oil shale are nahcolite (NaHCO3), dawsonite [NaA1(OH)2CO3], dolomite [(Mg1-xFx)Ca(CO3)2], calcite (CaCO3), and ferroan [(Mg1-xFex)CO3]. Although carbonate minerals can be removed by acid extraction from the balance of the oil shale, direct determination of carbonate minerals is complicated by the occurrence of the same cations in more than one mineral. A method for assigning the acid-soluble cations to the individual carbonate minerals was developed from two assumptions based on oil shale geochemistry: (1) Calcite and ferroan do not occur together, and (2) the ratio of iron and magnesium is the same in dolomite and ferroan. These assumptions were tested by the Bureau of Mines by applying the technique for assigning cations to 219 samples from the saline section of the formation. The reported carbonate mineral amounts were compared statistically with X-ray diffraction peak heights, verifying the cation assignment method.

Jan 1, 1975

By Steven J. Schatzel

Gas drainage through surface bore-holes has been the conventional means of methane control for U.S. longwall gobs. However, these vertical boreholes are becoming so costly, and the surface rights so difficult to obtain, that the Bureau of Mines is developing underground gob gas drainage as an alternate means of methane control for U.S. longwalls. Holes are drilled into the roof over the panel and on retreating longwalls, towards the working face from a location inby the face. As the longwall retreats, an increasing portion of the hole intercepts the fracture system over the caved gob. A surface exhauster maintains a vacuum on a pipeline parelleling the panel and draws the methane mixture out of the mine. Auxiliary systems of gob gas drain-age during longwall mining will be essential for an increasing number of coal mines. Deep and gassy mines often find ventilation insufficient for adequate dilution of methane in bleeder entries. Although this cross-measure method of degasification has been used successfully in Europe, some of the European techniques cannot be directly applied to U.S. mines. This is the first study of its kind in this country.

Jan 1, 1982

By Robert J. Willard

This chapter includes tables from 1983 that were not available in time for publication of the 1983 Minerals Yearbook, but does not include corresponding tables for 1984. The value of raw nonfuel minerals produced in the United States during 1984 was estimated at $23.2 billion, an increase of $2.1 billion over the value for 1983. This is the second consecutive year that the value has increased, and except for a decrease in 1982, the value for each year has increased since 1971, or 12 out of 13 years. In 1984, 16 out of 21 metal commodities increased in output while 5 metals decreased; 14 metals increased in value and 7 decreased. Of 46 nonmetal commodities. 37 increased in output while 7 decreased and 2 remained unchanged; 35 nonmetals increased in value and 11 decreased. These statistics are grounds for continuing the cautious economic optimism expressed in 1983. Despite the note of optimism, however, numerous problems plague the mining industry, weakening its stability and inhibiting its growth potential. The problems are a complex mix of international and domestic factors that have been building in the recent past, but have become even more troublesome in 1984.

Jan 1, 1985

By Jack C. White

As part of an investigation of the production of alumina by the nitric acid leaching of kaolinitic clay, the Bureau of Mines designed, built, and tested a fluidized-bed system for the calcination of aluminum nitrate nonahydrate to alumina, while recovering nitric acid. The calciner consisted of an 8-in-square by 36-in-tall vessel containing 18 in of fluidized solids. Molten aluminum nitrate, sprayed directly into the fluidized solids, formed sandy, granular alumina by growth of successive layers on fluidized particles. Solids were fluidized in a dense bed at temperatures of 250° to 500° C with steam, air, or mixtures thereof. Decomposition of nitrate ranged from 4 to 10 pet during single-pass steam or air fluidization, respectively. Alumina dust losses and low throughput are significant unsolved problem areas.

Jan 1, 1982

Continuous remote sensing of methane concentration in underground mines. Approach A methane transducer, developed as a fixed point rib-or face-mounted operating device, measures ambient levels of methane and produces a signal that is proportional to the measured concentration. How It Works The methane transducer, developed under contract for the Bureau of Mines, uses a catalytic-type sensor which will detect methane concentration. The transducer is mounted vertically, as shown. This type of mounting minimizes dust accumulation on the sensing element, which might cause degraded operation. The unit must not be located in an area where water can continuously drip or run on It. The transducer generates an electrical signal proportional to methane concentration at the sensor. A sensor failure output indicates the status of the sensing element A circuit within the methane transducer detects whether the sensing element is shorted or open. A high signal (approximately 8 Vdc) on the failure output Indicates the sensor element is operating In Its normal range. A low output (less than 1 Vdc) indicates an element fault. The methane transducer, enclosed in a stainless steel

Jan 1, 1982

By Jr. Allan

"Although the advantages of large-capacity air receivers for underground mines are plainly evident from published information about various installations in the United States and abroad, details of their construction are not generally known in this country., Ordinary present-day air-compressor installations servicing mining machines are designed to supply air at a specified pressure in sufficient quantity to meet the peak demand of the mine,2/ although this demand may exist for only a few minutes out of 24 hours and, as usually happens, eventually exceeds the capacity of the compressor. Most of the receivers provided with these compressors (to a certain degree of standardi¬zation) are capable of storing a volume of air approximately equal to that compressed in 1 minute by the machine.3, 4/ As a result, during peak-load periods the compressor operates at full load capacity without maintaining kick-off pressure. At other periods of the work cycle, production of compressed air is intermittent.At least one large mine5/ has adopted large-capacity receivers to reduce wear on its air-compressing system caused by the sudden demand of peak loads. Under the old system, the compressors jumped suddenly from half speed to full speed; boilers furnishing steam to the compressors were taxed heavily to provide the increased requirements of power; and machines using the air, among which were four large hoists, were required to operate at 65 pounds per square inch rather than at the 90 pounds per square inch for which the compressors were regulated. Operation of air machines, especially drills, at pressures lower than those for which they were designed decreases their efficiency and increases maintenance costs. In addition, air that comes directly from the compressors has had little opportunity to cool and dry enroute.6./ As a result, quantities of compressor lubricant and water are carried into the machines that use the air. When expansion occurs in the cylinder or turbine of such engines, the temperature of the air drops, and this oil and water is precipitated. The water washes away lubricating oils in the machine, causing poor performance and high cost of maintenance; the compressor oil, in addition to being a poor lubricant for compresed-air engines, exerts a corrosive action on gaskets and rubber hoses.7/Reduction of peak demands on air compressors by large receivers lowers power costs by establishing more nearly constant load factors,8/ and in some cases by permitting the use of smaller compressor capacity.8,9/Load factor is the ratio of average demand to maximum demand; a low load factor costs money.10/Elimination of high-peak demands raises the load factor by making the average and the maximum demand more nearly equal. Further savings may be made possible by large receivers where their use permits charging to be done at night in regions having lower power rates during that period.11/Where ordinary receivers are used, compressor breakdowns cause immediate work stoppages in the mine owing to lack of air. Similarly, the capacity of a large receiver has been known to permit uninterrupted work in the mine until the compressors have been returned to service.9/Large-capacity receivers, either steel-tank or underground rock-chamber, offer a practical solution of many existing problems by providing a sufficient reserve of compressed air within the pressure range required for efficient operation of machines to level off peak demands on the compressor. The com¬pressors operate when the demand has reduced the pressure in the receiver below the regulating pressure and until all air used from the receiver has been replaced. It has been found possible in at least two mines,8.9/ one of which the author has visited, to entirely eliminate one compressor and to obtain more efficient performance from the remaining one by the construction of an underground coal-chamber receiver.8/"

Jan 1, 1950

By James E. Hill

In the course of exploratory drilling during World War II by the Bureau of Mines under the Strategic and Critical Minerals investigations Program, a problem arose as to the ultimate disposal of the drill core resulting from that program. The difficulties experienced in obtaining factual information to evaluate mineral deposits examined (during that program) influenced the Bureau in a decision to catalog and store the drill cores for future reference. Initially, the drill cores were stored at the nearest Bureau of Mines station that had space available for the purpose. Recently the Bureau stations at Minneapolis, Minn., and Denver, Colo., were designated as the locations of permanent drill-core storage facilities. Drill cores that are retained from Bureau of Mines mineral-exploration projects are stored at these two locations and are given preference in selecting cores for storage. Drill cores are accepted also for storage from other Government agencies, State agencies, private companies, or individuals on the basis of available facilities and consistent with the significance of the core in relation to Bureau of Mines objectives and national interest. Selection and acceptance of such drill core are determined by the Bureau of Mines. The drill cores stored at the two locations are available for inspection by any person having a legitimate interest in the mineral deposits represented by the cores. Approximately 1,850,000 feet of drill core can be stared in the facilities now available to the Bureau of Mines. Approximately 475,000 feet of drill care is stored or scheduled for storage at Minneapolis, Minn., and 240,000 feet of core stored or scheduled for storage at Denver, Colo. A list of drill core now in storage at the Bureau of Mines core-storage facilities at Denver and Minneapolis is included as appendix A.

Jan 1, 1957

By David W. Houseknecht

Probabilities of encountering coalbed discontinuities during vertical or horizontal drilling in a specific coalbed can be estimated based on analysis of mined-out areas of the coalbed where the size, shape, orientation, and distribution of discontinuities are known. The result-ant probability estimates can be applied to cost-risk evaluations of drilling programs proposed for exploratory, developmental, or methane drainage purposes in undeveloped areas of that coalbed. Data compiled from mine maps of the Beckley Coalbed in southern West Virginia were used to estimate the probabilities that discontinuities would be encountered in two illustrative hypothetical drilling programs--one for drilling vertical boreholes and the other for drilling horizontal boreholes. Analysis based on a mined-out area of the Beckley Coal bed indicated that vertical methane drainage boreholes spaced 1,000 feet apart in a square grid pattern would each have a 29 percent probability of encountering a discontinuity in a geologically unexplored area of the coalbed. It was also determined that exploratory vertical drilling could locate most of the discontinuities if a borehole spacing of 2,500 feet were used. For horizontal drainage boreholes in the Beckley Coalbed, the analysis indicated a linear relationship between hole length and the probability of encountering a discontinuity.

Jan 1, 1982