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By Kung-Lee Wang

This Bureau of Mines study illustrates the economic significance of the Florida phosphate industry to the State and to the Nation. Environmental considerations related to phosphate industry activity are discussed briefly. Based on forecasts of Florida phosphate production in 1975, and using 1972 dollars, regional and national output value, income, and employment created by the phosphate industry were estimated for 1975. State and Federal government tax revenues generated by the phosphate industry, are also measured. Further, the concentrated impact of the phosphate industry on certain Florida areas and on regional industries is examined. Finally, the phosphate industry's importance to the U.S. balance of payments, U.S. agricultural production, and the Frasch sulfur industry is considered, in addition to byproduct fluorine, and potential byproduct uranium from fertilizer manufacturing.

Jan 1, 1974

By R. D. Leitch

[The accepted theory of acid formation in coal mines with the subsequent appearance of the acid in coal-mine drainage, is oxidation of iron pyrite and subsequent solution and hydrolysis of the iron sulphate formed. It has also been found that 5 gobbed sections and worked-out areas, where there is usually an abundance of iron pyrite-bearing, materials in contact with air, are the sections that make the most important contribution to the quantity of acid drainage. It would thus seem obvious that if oxygen can be kept out of contact with tae acid-forming materials in tie- sections mentioned the amount of acid in coal-mine drainage could be reduced markedly and corrosion problems with mine pumping equipment and general stream pollution mitigated thereby. Although the efficiency of the suggested remedy as been borne out by laboratory experiments6, it has appeared desirable to substantiate the laboratory work by field observations in so far as pertinent data are available. It has been difficult to learn of mines or sections of mines about to be sealed, whereby an actual comparison of the drainage before and after sealing can be made. In view of that difficulty it has been necessary to devote attention to a comparison of the character of the water from areas already sealed with that from open but otherwise comparable sections of the sane mine. Previous cork has shown that the acidity of drainage in different parts of the same mine may vary, but if it can be shown also that the water from sealed areas is with but fen exceptions less acid than the otherwise similar open sections of tae same mine, the laboratory finding will be supported in a practical gray. This report presents some of the evidence that has been obtained.]

Jan 1, 1930

By Maurice J. Peterson

THE VISUAL-ARC spectroscopic method of rapid qualitative analysis of complex inorganic compounds has been popularized in the past few years and is being employed by an increasing number of laboratories. The mineralogy and chemistry departments of several universities recently have added visual spectroscopy to their laboratory curricula. This revival of interest in a somewhat dormant analytical method has been stimulated through the publication of three papers 4 by members of the College Park staff of the Bureau of Mines. These virtually are the only recent sources of information on visual-arc spectroscopic analysis. They include data on the spectroscopic assembly, the analytical procedure, and the practical application of the method to determinative mineralogy and related fields. Requests for reprints of these papers continue to be received; at present only a limited number of copies are available for distribution. In order that these requests may be adequately answered, material from the three papers has been combined and, with some additional data, is presented in this bulletin. Numerous specific inquiries have been received regarding types of equipment available, problems in instrumentation, and information on the approximate sensitivity limits of the elements that can be detected by this method. Some of this material was not included in the original papers. Accordingly, the table of wavelengths has been revised to include the approximate visual-arc spectroscopic sensitivities, and a section on commercially available equipment has been added.

Jan 1, 1953

By W. W. Culter

"This paper is the outcome of thorough investigation into the value of the previous methods used for deriving production decline curves. It is highly important that methods be employed that are fundamentally sound and also practicably applicable. Six methods commonly used were studied. Some of these were found to be fundamentally in error; some save reliable curves but involved much work and time in the preparation; others gave reliable curves with less time and effort.It was found that of the methods previously employed the ""family curve"" method described in Bull. 134 Amer. Inst. Feb. 1918, pp. 499-500 by Lewis and Beal, was probably the most satisfactory. The now method given in this paper ploys the same principles as the ""family curve"" method, but is mathematical instead of graphical,The engineer and the oil man should carefully boar in mind both the use and the limitations of the average production curve such as is derived by the ""family curve"" method or other methods mentioned. Estimations of future productions or of underground oil reserves of a particular tract or well should be made from the production records of the tract or the well itself wherever such records are satisfactory. The use of the average curve of a district or field should be applied only to those properties or wells where there are not sufficient data to construct individual or tract production records, or where the productive life so short that a satisfactory individual record can not be obtained."

Jul 1, 1920

By R. H. King

A very simple cold-bend test was devised and tested for evaluating thermoplastic jackets used on mine-power-feeder cables. A test sample is bent into a semi-circle whose radius is equal to the minimum bend radius recommended by IPCEA and then cooled to the, desired test temperature (-35°C). While at temperature, the sample is straightened by pulling the cable ends with a winch arrangement. The results show that of the jackets tested, those which cannot withstand the test literally burst when the sample is straightened.

Jan 1, 1978

By E. E. Donath, L. L. Hirst, L. C. Skinner

Two processes are available for the production of synthetic fuels from coal high-pressure hydrogenation and the carbon monoxide-hydrogen synthe- sis. This paper presents some ideas and new developments in coal hydrogen- ation that have been incorporated in an estimate for the production of 30,000 barrels per day of liquid fuels, mainly gasoline. A few comparisons of the processes will be helpful before discussion of the details of pro- posed improvements in the hydrogenation process. The principle of the high-pressure hydrogenation process ie the addi- tion of hydrogen at pressurea in the range of 3,000 to 10,000 p.s.i. to coal at elevated temperature and with the help of catalysts. On the other hand, the principle in the Fischer-Tropsch synthesis is the complete break-down of coal into a mixture of carbon monoxide and hydrogen, followed by the catalytic combination of these two gasse into hydrocarbons or suitable catalysts. For the synthesis, moderately elevated pressures of about 350 p.8.1. will bo used in the immediate future, although it can be carried on at atmosphoric pressure with certain catalysts. The products of these two processes using coal as raw material are almost as differont as hydrocarbons can be. The products of the high-pres- sure hydrogenation of coal reflect the original constitution of the coal. They are, therefore, rich in ring compounds, both aromatic and naphthenic, but, due to the action of highly comprcesed hydrogen and catalyst, are satu- rated and very stable. These constituents give the gasoline a high octane number and excellent rich-mixture performance, combined with good gum and storage stability. Therefore, this gasoline is suitable for aviation gaso- line or base stock. The Diesel fuel can be hydrogenated to a centane number of 45 or higher, which is entirely satisfactory for operating normal Diesel

Dec 1, 1948

By C. E. Jordan

The fundamental properties of dielectric separation were studied to provide insight into the design and operating characteristics of a dielectric separator. Force equations on mineral particles were derived and evaluated experimentally. Responses to variations in the electrical voltage and frequency, feed rate, particle size, dielectric fluid, and dielectric constant were tested theoretically and experimentally, using a 5-cm-diam dielectric separator. High-dielectric mineral recovery was proportional to the calculated effective dielectric force volume (EDFV) that surrounded each drum-electrode wire. Electrode spacing was the most sensitive design parameter; spacing of less than 0.4 cm was required for a good separation. Dielectric separation was effective for separating minerals with dielectric constants that differed by approximately 2 or more.

Jan 1, 1985

By F. V. Meriwether

The Bureau of Mines, in cooperation with the Federal, State, and local health services, and the mining companies, and miners? organizations, has for several years been carrying on sanitary surveys of mining districts in various states, with the purpose of collecting information on good and poor practices in mine sanitation, construction of approved wash-houses and change houses, the measures being taken to combat preventable diseases, the essential features of good houses for mining towns, and other conditions affecting the health and efficiency of miners and their families. The knowledge thus gained is disseminated for the common benefit of the mining industry. The sanitary conditions in the coal-mining districts of Alabama, as found by a recent survey made by the writer, are presented in this report. In addition to the towns on which this report is chiefly based, at least twice as many were visited where no details :were taken, but their general conditions are taken into consideration in summing conditions in the coal districts.

Jan 1, 1926

By Lloyd M. Kniffin

[This paper is one of series being prepared by the United States Bureau of Mines on mining methods, practices, and costs in the various mining districts of the United States. It describes the mine of the Hanover Bessemer Iron & Copper Co. at Fierro, Grant County, N. M., which is the only operating iron mine in the southwestern part of the United States. This mine is in a district noted for the great variety of ores that it produces. Within a small area, as shown is Figure 1, there are noteworthy deposits of nearly all the common metals. The ore occurs in lenticular masses dipping at about 50°. An underhand stoping method has been developed that requires but a very small amount of handling of ore. As the ore is very irregular in iron content and also in the distribution of the impurities--chiefly sulphur, silica, and magnesia--a method has to be used that will permit selective mining and will also allow ore and waste to be taken out separately as conditions change. A magnetic cobbing plant raises the grade of the ore shipped about 10 per cent.]

Jan 1, 1930

By Mayo D. Hersey

This problem was taken up by the Bureau of Mines as a result of the oxygen explosion at the Jefferson Physical Laboratory of Harvard University , and other similar explosions , in order to supply technical information which would serve as a basis for safety precautions in the future . At the Harvard inquiry the fact was emphasized by the Massachusetts State Chemist , Mr. Walter M. Wedger , that we do not know the limiting pressures and temperatures above which compressed oxygen and lubricating oil are capable of spontaneous explosion . The problem is also of importance to the Army and Navy and to the Bureau of Mines in connection with the hazards incurred in the use of compressed and liquified gases in the repurification of helium. In fact , the risk of fires and explosions due to traces of lubricating oil coming into contact with high pressure oxygen is of serious interest to all concerned with the manufacture and use of oxygen , a commodity which is now being produced and distributed on a rapidly increasing scale . Part of the money expended on this investigation was from Army and Navy funds . The problem was undertaken by the Bureau of Mines at the suggestion of Dr. Charles E. Munroe , Chairman of the Committee on Explosives Investigations of the National Research Council , and referred to the Pittsburgh experiment station of the bureau.

Jul 1, 1923

By Thomas E. Popplewell

This paper is one of a series being prepared for and published by the United States Bureau of Mines describing the mining and treatment methods and costs obtained in sand and gravel plants throughout the United States. These papers are designed to disseminate technical information regarding the methods used. The cost tabulations represent operating expenditures only and not total costs. It is recognized that publication of total costs might in many instances cause embarrassment to individual operators as well as to the industry as a whole. On the other hand operating costs are essential to the technical discussion and study of the methods employed. The attention of the reader is specifically called to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue.

Jan 1, 1932

By M. H. Kersten, G. A. Brady, Jerry W. Ramsey

Anthracite samples were oxidized with nitric acid to prepare products representing intermediate stages of oxidation . Similar oxidizing conditions affected different anthracites to varying degrees as characterized by peptization behavior with 0.1 N NaOH . Techniques used in attempts to separate and characterize the products included esterification , absorption spectrophotometry , sublimation , chromatography , electrophoresis , metal salt formation , and solvent extraction . Mellitic acid , either free or in the form of metallic salts , was identified in the acid- soluble products from 10 tests in which the anthracite was treated with nitric acid for periods varying from 24 to 1,000 hours . pentacarboxylic acid was also found in some products . Other benzene carboxylic acids were not present in amounts detectable by the methods used in this study . The acid- insoluble residue from nitric acid treatment varied significantly in solubility behavior toward different classes of solvents . The most effective ones tried included polar oxygenated solvents and pyridine . Infrared spectra of the extracted material indicated that similar compounds were extracted by the different solvents . Aliphatic amines and aniline peptized the residue and o- toluidine reacted with it . Organic material separated from the residue by peptization with dimethylformamide contained 1 percent ash , consisting of more than 50 percent zirconium .

Jan 1, 1964

By P. T. Brooks

Semipilot scale tests were made to demonstrate a newly developed electrorefining process which could be extrapolated to commercial scale in producing high-purity nickel and cobalt from crude nickel metal and high-grade ferronickel. The new process comprises application of solvent extraction techniques to remove and separate cobalt and iron from nickel and the electrodeposition in diaphragm cells of pure nickel and cobalt from chloride-based purified electrolyte. Using water insoluble organic amines, the solvent extraction operations enabled production of commercial-sized nickel and cobalt cathodes of higher purity than that of commercial electrolytic metals. The solvent extraction operation for separation of cobalt from nickel was made simpler than the conventional method. Furthermore, the solvent. extraction operation for iron removal made possible the electrorefining of ferronickel without the prohibitive loss of nickel resulting from the method ordinarily used for iron removal.

Jan 1, 1970

By M. J. Sapko

The U.S. Bureau of Mines has developed a portable meter for measuring the component concentrations in binary dust mixtures whose constituents have different optical reflectivities. The meter has been successfully tested with coal dust-rock dust mixtures taken from coal mines in Europe and the United States and fluorinated-carbon mixtures that change from carbon black to pure white during fluorination. Additional study has also substantiated the theoretical expressions used in the design of the meter.

Jan 1, 2010

By M. G. Zabetakis

At ordinary temperatures and pressures methyl ethyl ketone (MEK)-air mixtures containing between 2.0 and 11 vol.-pct. MEK and methyl isobutyl ketone (MIBK)-air mixtures containing between 1.5 and 7.5 vol.-pct. MIBK are flammable. However, MEK-bromochloromethane (BCM)-air mixtures containing at least 6.2 vol.-pct. BCM and MIBK-BCM-air mixtures containing at least 7.0 vol.-pct. BCM are nonflammable. Also, MEK-BCM-air and MIBK-BCM-air mixtures containing less than 18.7 vol.-pct. oxygen are nonflammable. To assure the formation of nonflammable mixtures when mixed with air, MEK-BCM vapor mixtures must contain at least 1.6 vol. BCM per volume MEK, and MIBK-BCM vapor mixtures must contain at least 2.8 vol. BCM per volume of MIBK; these quantities of BCM would be produced by liquid mixtures containing 55 vol.-pct. BCM in the first case and 60 vol.-pct. in the second. An MIBK-BCM-trimethylene chlorobromide mixture containing equal volumes of each liquid forms nonflammable mixtures with air at ordinary temperatures and pressures. The same is true of a liquid mixture containing 34.6 pct. (liquid volume) BCM, 34.b pct. perchloroethylene, 15.4 pct. MIBK, 7.7 pct. toluene, 3.85 pct. ethyl amyl ketone, and 3.85 pct. trimethylene bromide.

Jan 1, 1960

By Lung Cheng

The Bureau of Mines conducted laboratory tests to investigate the ease of frictional ingition with frozen (nonrotating) conical bits cutting into sandstone. The number of strikes with a new bit to obtain ignition of a combustible methane-air environment was measured. Tests were made with bits tipped with both tungsten carbide and steel at several bit attack angles (angle between bit axis and sandstone surface) and initial tip angles (included angle at the tip of the new bit). Carbide-tipped bits required more strikes for ingition than steel-tipped bits, by a factor of 7 to 10. With a carbide-tipped bit, the number of strikes for ingition increased by a factor of about 3 if the bit attack angle increased by 10° or if the initial tip angle decreased by 10°. During use, abrasive wear of the frozen bit caused a flat surface to form at the tip of the bit, thereby decreasing the tip angle. As the attack angle increased, however, the new bit involved a smaller wear-flat area whereby, abrasive wear was decreased.

Jan 1, 1987

By Henry E. Perlee

Air compressor explosions that are caused by the ignition of combustible vapor mixtures cannot be explained by a single reaction mechanism or sequence of events. Explosions have been caused by the sudden release of large quantities of lubricating oil, by the rapid vaporization of oil that had accumulated slowly in high-pressure piping, and by the production of decomposition products from carbonaceous deposits. Ignitions can be caused by the heat produced in a catalytic reaction, in a compression process, or when a shock wave is propagated through a combustible vapor-air mixture. The frequency of these ignitions can be minimized by establishing proper maintenance and cleaning schedules. Further study is needed to satisfactorily correlate the various factors involved in compressor explosions.

Jan 1, 1963

By Noel N. Moebs

The coal wants at the Westland Mine in southwestern Pennsylvania consist chiefly of elongated, sandstone-filled channels with slickensided basal contacts. Tentatively identified as washouts, these channels are about 1,000 feet long and 300 feet wide, are erratic in occurrence and trend, and are difficult to delineate from the customary core drilling pattern. Roof conditions are hazardous adjacent to the washout contact, but roof stability is generally unaffected greater than 30 feet away.

Jan 1, 1981

By J. A. Organiscak

The Bureau of Mines recently investigated dust generation and methane liberation during half-and full-web cutting at a double-drum shearer longwall face. This study was conducted to ascertain the health and safety aspects of wider web shearing at longwalls. Results from these underground tests showed that deeper web cutting reduced dust generation and methane liberation per ton of coal mined, while significantly improving shearer production rates. When cutting with the airflow (head-to-tail cut pass) full-web cutting decreased dust generation per ton by 16 pct at the shearer and 6 pct at the tailgate, with an increase in shearer production rate of 72 pct. Methane liberation per short ton also deere~sed by 36 pet at the shearer and 22 pct at the tailgate. Full-web cutting against the airflow (tail-to-head cut pass) decreased dust generation per ton by 41 pct at the shearer and 37 pct at the tail-gate over half-web cutting, with an increase in shearer production rate of 61 pct. Methane liberation per ton also decreased by 35 pct at the shearer and 41 pct at the tailgate. These improvements for full-web cutting are a reflection of improved cutting efficiency (less dust and methane produced from cutting) and less new face area exposed per ton of coal mined (less methane liberated from face per short ton of coal mined).

Jan 1, 1988

This Bureau of Mines publication presents five papers given at a Technology Transfer Seminar on Metal Mine Fire Protection Research. Several seminars are held each year to bring the latest results of Bureau conducted and sponsored research to the attention of the mining industry as quickly as possible.

Jan 1, 1977