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By C. J. Thompson

Two sulfur compounds--the 2,2,5-trimethyl- and the 2,2,5,5-tetramethyl derivatives of thiacyclopentane--were identified in Wilmington, Calif., crude oil, using microdesulfurization and gas-liquid chromtography techniques.

Jan 1, 1963

By C. B. Daellenbach

A prototype particulate size analyzer system was developed that would rapidly determine size distributions of homogeneous and two-mineral materials in the 74-micrometer (200-mesh) to 7-micrometer size range. The system sizes particles in a series of hydrocyclone elutriation steps and senses the weight of the five sized fractions by nuclear attenuation techniques. Size distribution of materials was determined from experimentally developed mathematical relationships that existed between particulate weight and the measured transmittance of gamma rays from an Americium-241 source. In the developmental phases, size distributions of three minerals (quartz, magnetite, and hematite) and a laboratory prepared two-mineral mixture of quartz and magnetite were accurately determined by the prototype system. In later stages of the investigation, semiconcentrates, an intermediate magnetic product from a taconite plant, were evaluated. Using 25-gram feed samples of this industrial material, the analyzer system was found to predict weight percentages for individual size fractions with an accuracy of ±0.85 percent or better at a 95-percent confidence level.

Jan 1, 1974

By Joe H. Skidmore

This paper, describing mining and milling methods and costs at the Gold Hill mine, is one of a series being published by the Bureau of Mines. Boise Basin, in which the geld Hill mine is located, is in the central part of Boise County, Idaho, about 30 miles by air line northeast of Boise. The mine, owned and operated by Talache Mines, Inc., is at the southern end of the town of Quartzburg. About 115 to 125 tons daily is mind by square-setting and is treated in an amalgamation plant.

Jan 1, 1938

By E. A. Anundsen

The prevention of accidents is considered a necessity at all branches and divisions of the Phelps Dodge Corporation copper-producing operations, and since there is a continual exchange of data on safety accomplishments between the various units, their safety programs are fundamentally similar. Variations in accident-prevention methods result from a difference in emphasis rather than from a difference in the elements themselves. The main copper-producing operations of the corporation ore conducted in Arizona and distributed as follows: Copper Queen Branch, mines division, Fisbee, and smelter division, Douglas, Aria.; Morenci Branch, mines division, Morenci, and smelter division, Clifton, Ariz.; New Cornelia Branch, Ajo, Ariz.; and United Verde Branch, mines division, Jerome, and smelter division, Clarkdale Ariz. As it is not feasible to describe here the safety programs of all branches and divisions, the program at the Clarkdale smelter has been selected for discussion. The United Verde Brach includes the mine and smelter purchased by the Phelps Dodge Corporation in February 1935 from the United Verde Copper Co. The mine at Jerome and the reduction works at Clarkdale are designated, respectively, as the mine and smelter divisions.

Jan 1, 1939

By Thomas M. Barczak

This Bureau of Mines report describes research on developing technology to utilize shields as roof load monitors. Three-dimensional equations of static quilibrium are presented for a generic two-legged long-wall shield. The equations are presented in the most general form, assuming a force and moment vector at each reaction by rigid-body analysis of the shield mechanics. The resulting system of equations was found to be indeterminate to a very high degree. A three-dimensional solution to measurement of the resultant reaction on the canopy by the strata activity and shield response required the elimination of several forces or moments that were thought to be nonparticipating or to not significantly affect overall shield mechanics. Required measurements for solution of the equilibrium equations were leg, canopy capsule, and lemniscate link forces. Two-dimensional analysis, which considered forces acting only in the roof-to-floor and face-to-waste plane, was also provided by reduction of the three-dimensional equations~

Jan 1, 1987

By R. G. Nelson

The mechanical properties of low-hafnium, arc-melted, Kroll-process zirconium are presented. The effect of temperature on the ultimate strength, yield strength, proportional limit, elongation, hardness, Young's modulus, electrical resistivity, and impact strength are shown, The effects of cold work and annealing on the tensile properties, bend radius, and formability, as determined by cupping tests, are also given, Tensile properties are compared, in part, to those obtained on earlier graphite-melted zirconium and on crystal-bar zirconium. INTRODUCTION The commercial production of high-purity, low-hafnium bearing zirconium has been achieved, and this metal is becoming available for industrial use. However, there is little published information regarding the physical and mechanical properties of this product; and, since there have been many improvements in the production and arc-melting techniques of zirconium in the past 3 years, it was considered advisable to present the properties of the vastly improved zirconium representative of current production.

Jan 1, 1954

By P. E. Churchward

Rhenium sources and recovery methods were investigated by the Bureau of Mines to delineate potential resources of the metal. The only significant rhenium resource appears to be about 28,000 lb of rhenium contained in the domestic annual output of approximately 20,000 tons of byproduct molybdenite concentrates from porphyry copper operations. An estimated 70 to 80 pct of this rhenium is potentially recoverable by processing the rhenium-bearing fumes and dusts obtained during conventional roasting of molybdenite concentrate. At 70 pct recovery this would amount to 19,600 lb of rhenium. A more conservative estimate by the Committee on Refractory Metals of the National Research Council (1513 is that 12,000 lb of rhenium metal could be produced annually from current production of molybdenite from porphyry copper operations in the United States. A procedure was developed in the laboratory for recovering rhenium in the form of electrolytic flake by electrowinning the metal from a solvent extraction strip solution. The procedure included (1) water leaching of molybdenite roaster flue dust, (2) selective extraction of rhenium from the leach liquor by contacting it with a kerosine solution of a quaternary amine, (3) stripping of rhenium from the loaded organic solution by a perchloric acid solution, and (4) electrodeposition of rhenium from the loaded strip liquor. Raw material for the studies was flue dust containing 0.48 pct Re, 35 pct Mo, and 23 pct S in sulfide and sulfate form, and small amounts of numerous metallic impurities. Water leaching dissolved 85 pct of the Re and yielded a solution that was 13 in sulfuric acid and contained, 1 g/l Re and 16 g/l Mo. The solvent extraction strip solution that was electrolyzed for rhenium deposition was 1 molar in perchloric acid and 1 molar in ammonium sulfate and contained 13 g/l Re and 0.01 g/l Mo.

Jan 1, 1963

By J. K. Whyatt

The U.S. Bureau of Mines has been conducting a series of rock mechanics investigations at the Lucky Friday Mine in the Coeur d'Alene Mining District of northern Idaho. In the present study, the energy release rate (ERR) index was used to evaluate three underhand stope backfill parameters-cement content, density, and placement gap-to determine their influence on rock bursts. This index provides a relative measure of the likelihood of rock bursting for a given rock mass. It is known that the elastic idealization of the rock mass inherent in this method causes underestimation of stope closure and hence underestimation of the influence of backfill on rock bursting. However, this evaluation still showed that (1) changing from present practice to one in which backfill was omitted altogether would increase the ERR by 42 pct and (2) perfect placement of backfill would reduce the ERR below present practice levels by 28 pct. The easiest step toward perfect placement would be elimination of the placement gap, which accounted for half of the difference in ERR between present practice and ideal placement conditions. There was no indication that increasing initial fill strength through increased cement content would affect the ERR.

Jan 1, 2010

By D. B. Gawthrop

"One of the properties of an explosive, of interest to the user, is its ability to transfer detonation across an air gap to another explosive charge. This Property is of particular importance with permissible explosives used in coal mines, since they are relatively insensitive to detonation when compared to many of the commercial dynamites used in metal mining.An essential characteristic of an explosive is that it shall always be sufficiently sensitive to propagate detonation completely. An insensitive explosive constitutes a hazard because of (1) the danger of drilling into unexploded portions of charges of explosives which have partially misfired, and (2) the likelihood of a low order of detonation, or the burning, of all or part of the charge in a hole prepared for blasting. The latter condition not only usually produces large volumes of poisonous gases, but it is particularly hazardous in gassy or dusty coal mines where explosions may result.The Bureau of Mines and manufacturers of explosives determine the sensitivity of explosives to detonation over an air gap by means of a [(halved-cartridge gap test,"" for which the ends of the cartridges of explosive exposed to one another, are cut off. Since in blasting, the crimped ends remain on the cartridges used, this investigation has been made to ascertain the effect of the crimped paper ends on the distance detonation is propagated over an air gap as compared with the propagation distances obtained when the crimped-paper ends are removed."

Nov 1, 1932

By T. H. Jeffers

The Bureau of Mines conducted laboratory tests to devise a procedure for extracting copper from low-grade discarded mill tailings. A solid extractant consisting of an organic solvent extraction reagent adsorbed on granular activated carbon was investigated and proved to be satisfactory for extracting copper directly from leach pulps. When this material was used in a cyclic leaching, stripping, and electrowinning pro-cess, 95 pct of the acid-soluble copper was recovered from oxidized mill tailings. The weathered tailings contained 0.24 pct Cu (total) and 0.20 pct acid-soluble Cu. The copper was recovered as cathodes containing, in parts per million, 1.6 Pb, 3.6 Fe, 0.5 Sb, 1.5 AI, 1.9 Mn, and <1 Mg.

Jan 1, 1985

By C. W. Schultz

The vapor pressure of manganese in equilibrium with a series of liquid iron-manganese alloys was determined by the carrier gas method over a broad range of alloy composition. From these data the activities of manganese in the iron-manganese system were calculated. The system appears to be ideal.

Jan 1, 1966

By J. R. Ross

The extraction and recovery of nitrate from waste solutions generated in the production of titanium were investigated using solvent extraction techniques. Laboratory studies and continuous tests in a small solvent-extraction system showed that up to 98 percent of the nitrate can be selectively extracted by a solution of tributyl phosphate in kerosine. The extracted nitrate can be recovered as nitric acid, at concentrations suitable for reuse, by stripping the loaded organic with water.

Jan 1, 1973

By W. D. Riley

The Bureau of Mines is conducting research on methods for the rapid identification and sorting of mixed scrap metals and alloys so that domestic scrap resources can be fully utilized. One method, spark testing, is the examination of the pattern of sparks that results when a metal or alloy is ground on an abrasive wheel. This technique requires experienced sorters. Bureau researchers have shown that spectrophotometric methods can be used in lieu of the highly skilled sorter. The spectra of a mild steel, an HSLA steel, several stainless steels, and four nickel-base alloys have been measured. Differences in the spectra that are sufficient for identification are apparent.

Jan 1, 1985

By Albert J. Rambosek

The results obtained in a study of the stress conditions existing in a drill bit-point area and in the underlying rock, when the bit was in full but nonpenetrative contact with the rock, are presented. This investigation by the Bureau of Mines was the preliminary exploratory phase of a long-range program of research on rock drilling to establish criteria for the maximum economically feasible rate of rock penetration. The photoelastic technique of experimental stress analysis was the principal method used to obtain the data. Transparent models and transmitted light were employed to investigate patterns in drill-bit models and isotropic materials under the bit when subjected to a concentrated static load. Comparative stress data for anisotropic rock were obtained by the reflective photoelastic technique. Brittle lacquer and an extensometer were used obtain supplementary information wherever substantiating data were desired to check photoelastic results. The zone of maximum shear occurs along an arc near the contact face of the bit. The stress distribution pattern in an isotropic model rock near the area contacted by the bit was nearly a mirror image of that exhibited within a similar areal zone of the bit. The stress pattern in granodiorite specimens was similar, though not symmetric, to the pattern in the isotropic model rock. The asymmetry of the stress pattern in the granodiorite was attributed to the anisotropic characteristics of the constituent minerals of various sizes.

Jan 1, 1963

By R. R. Sayers

Mine operators and managers for a number of years have known that the maintenance of health among the workers has an appreciable financial value, In order to maintain the health, it has been found ne cessery to imow; 1. The health hazards existing in the industry as a whole and the specific hazard in the individual mine. 2. The physical condition of applicants for employment as well as that of the old employees. This can be determined only by systematic physical examination of all applicants and of regular employees at intervals of at least once a year thereafter. 3. All cases of sickness that occur among the workers. No operator or manager, or personnel, medical, or safety organization can control or prevent sickness without knowing where, when, and under what conditions the sickness actually occurs. In order to obtain information as to the hazards of industry, investigations have been and are being made of the effects of the condi- tions both in the field under usual working practices and in the laboratory. In the field several factors are generally present which affect the health. The effect of these factors may be determined by studying each of them separately in the laboratory. However, both the field and the laboratory studies are limited in value in that such studies usually have been made over a comparatively short period. While we have some information as to their immediate effect, we do not know to what extent extreme heat, humidity, the presence of dust or other health hazards are the cause of disability. Mortality statistics are probably the most easily available indices as to the hazards of industry. As an example, a study of such statistics among coal miners of Indiana shows a marked increase in the death rate in 1918.

Mar 1, 1923

By Alla D. Mah

The heats of combustion of three chromium carbides, Cr23C6, Cr7C3, and Cr3C2, were determined by combustion calorimetry. Heats of formation calculated from the results follow: ?Hf°298 (Cr23C6) = -94.7 ± 5.0 kcal/mole, ?Hf°298 (Cr7C3) = -43.3 ± 1.7 kcal/mole, and ?Hf°298 (Cr3C2) = -22.5 ± 0.8 kcal/mole.

Jan 1, 1969

By E. J. Lintner

This paper is one of a series being prepared by the United States Bureau of Mines describing gypsum mining and crushing methods and costs at various operations throughout the United States. These papers are designed to disseminate technical information regarding methods used. The cost tabulations represent local operating expenditures only and not total production costs. It is recognized that publication of total production costs may in many instances cause embarrassment to individual operators as well as to the industry as a whole. On the other hand, operating costs are essential to a technical discussion and study of the methods employed. The attention of the reader is called specifically to this differentiation so that there may be no misunderstanding of the scope of the cost tabulation. This paper deals specifically with the mining and crushing methods employed by Victor Plaster, Inc., Victor, Ontario County, N. Y. The maximum annual production capacity of this company is 150,000 tons of crushed gypsum. The methods and practices employed arc typical of those followed in the gypsum mines in western New York State. The shaft is, perhaps, the deepest and the thickness of the gypsum mined is above the average for the section.

Jan 1, 1937

By R. E. Perry

To develop new or improved flotation methods for beneficiating low-grade red iron ores, the Bureau made many bench scale and continuous anionic flotation tests on ferruginous sandstones and calcareous iron ores from the north-eastern part of the Birmingham, Ala., iron district. The ores contained about 21 to 36 percent iron, a to 11 percent lime, and 22 to 64 percent silica. Production of iron concentrates containing 48 to 52 percent iron was technically feasible in batch tests, and the iron recoveries ranged from 85 to 92 percent. In continuous tests 49 to 51 percent iron products were obtained with 80 to 90 percent recovery.

Jan 1, 1962

By Michael G. Zabetakis, Glenn H. Damon, Joseph A. Herickes

The flammability and explosibility of unsymmetrical dimethylhydrazine ( UDMH ) were investigated by the Federal Bureau of Mines to evaluate hazards associated with commercial application of this material as a missile fuel . This program included the following determinations : 1. Temperature limits of flammability in air at one atmosphere pressure ; 2. limits of flammability at selected elevated temperatures and pressures ; 3. 4 . 5. spontaneous ignition temperature in air at one atmosphere and at 200 pressure per square inch gage ( p.s.i.g. ) initial pressure ; spontaneous decomposition temperatures in nitrogen at one atmosphere and at 200 p.s.i.g .; shock sensitivity over a temperature range from about ( ca. ) 25 ° to 50 ° C .; 6. shock sensitivity of reference propellants ( hydrazine , nitromethane , methyl acetylene , etc. ) ; 7 . shock sensitivity of UDMH plus small amounts of selected metal catalysts . Part of the corresponding data was obtained for a mixture of unsymmetrical - dimethylhydrazine and diethylenetriamine ( U - DETA) .

Jul 1, 1960

By E. C. Tarpley, H. M. Cooper, R. F. Abernethy

"INTRODUCTION The float-and-sink test 5/6/ is generally the first test used in determining the washing characteristics of coal. The simplest form of the test is that of using one solution of such specific gravity that the test sample is separated into ""float"" and ""sink"" fractions. In practice, however, a series of solutions is used, and the sample is separated into a number of fractions of a definite specific-gravity range. Analyses of a series of fractions of this type are often referred to as the ""specific-gravity analysis,"" and are of great value in the selection, construction, and operation of commercial washing equipment.The test is rather simple to use, provided a number of conditions are recognized and as many as possible held constant, such as:1. In laboratory testing, two types of solution are available -Aqueous solutions of calcium and zinc chlorides.Mixtures of organic liquids such as carbon tetrachloride, benzene, gasoline, bromoform, etc.2. Absorption of the solution by the coal,3. Solvent action of the solution toward the coal.4. Constancy of specific gravity during the test is affected by temperature changes, dilution, and evaporation.5. Personal technique of the test, such as the time the coal is in the liquid, rate of adding the sample to the liquid, stirring, time of draining, etc.6. Moisture content of the coal as tested."

Dec 1, 1947