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By Hillary Williams, Ronghao Li, Christopher Marion, Kristian E. Waters, Devin Hundt

"Zircon is an important mineral for ceramic, foundry, casting, and refractory applications; and it is the worlds primary source for zirconium. Zircon can also contain large and valuable proportions of other valuable metals, such as rare earth elements and hafnium. The Nechalcho deposit (Northwest Territories, Canad), is a hard rock REE deposit, which looks to recover zircon for its Zr and REE content. In this deposit, zircon is finely disseminated and associated with predominately silicate gangue minerals. Most of the work to date has focused on the beneficiation of mineral sand deposit, which typically remove silicate gangue minerals through physical separation steps. Therefore, the separation of zircon from silicate gangue, such as quartz, by flotation, has received little attention. This work used zeta potential measurements and microflotation experiments to understand the interaction between zircon and six different collectors (sodium oleate, sodium dodecyl sulphate, dodecylamine, SM 15, K-octyl hydroxamate and Florrea 7510). The results were compared with those of quartz. This study indicated that selective separation of zircon from quartz without the use of selective depressants or activators is likely challenging. The findings suggested sodium oleate and SM 15 only offered selective flotation of zircon in highly acidic conditions. Separation by the flotation of quartz is possible using sodium dodecyl sulphate, dodecylamine and K-octylhydroxamate. However, selective separation is highly dependant on collector dosage, for dodecylamine, and the selective activation of quartz, for sodium dodecyl sulphate and K-octyl hydroximate. Florrea 7510 offered poor recoveries for both zircon and quartz.INTRODUCTIONZircon (ZrSiO2) is a nesosilicate mineral which has a wide variety of applications, due to its hardness, opaqueness and resistance to heat and corrosion. Its major end uses are in ceramic, foundry, casting, and refractory applications (Bedinger, 2017). Zircon is also the most abundant zirconium (Zr) bearing mineral in the earths crust and is the principal economic source of Zr (primarily used in alloys for heat and corrosion resistance) and zirconia (ZrO2) (primarily used in ceramics) (Bedinger, 2017; Milnes and Fitzpatrick, 1989). Zircon forms in silicate melts and can often contain large proportions of other valuable metals such as rare earth elements (REE), and hafnium (zircon is the primary source of hafnium) (Bedinger, 2017; Belousova et al., 2002; Orlova, 2007). A common chemical formula showing the range of substitution in zircon is (Zr,Hf,Th,U,REE,Ca,Fe,Nb,Ta)(Si,P)O4 (Orlova, 2007)."

Jan 1, 2018

By Richard A. Williams

The mineral processing community have been amongst the pioneer developers and early adopters of key platform technologies in analytical methods, chemistry, physical separation and advanced modelling. Fundamental research will continue to have a significant impact driven by the continued development of sustainable practices. Major drivers and challenges for change in our industry in the next two decades include: reduction in energy uses in processing; discovery of new energy materials; adoption of green chemistry routes; safeguarding of water resources; and demonstration of adherence to best practice at all times. With increasingly global mining enterprises, the provision of internationally accepted benchmarks for performance will continue to drive the creative process. This lecture highlights major opportunities around a new paradigm of Multi-scale Measurement coupled with Multi-scale Modelling, based on advanced sensors, communications and computing. Connecting real-time measurement sensors with dynamic simulation models opens up new horizons for visualising the process behaviour from an experimental and theoretical basis. Examples are given of the potential of this methodology and its implications for better design.

Jan 1, 2003

By Fengnian Shi

In the current energy-sensitive world, sustainable development in the mineral industry will require new, better and more efficient processes. Novel comminution methods, which offer the prospect of achieving the required outcomes of size reduction and mineral liberation at lower energy consumption, are continually being sought. In the past five years, extensive research using high voltage pulse electrical comminution technology has been carried out at the Julius Kruttschnitt Mineral Research Centre (JKMRC), in collaboration with selFrag AG. The major outcome of this research is the development of the concept of pre-weakening ore particles by electrical comminution procedures to reduce the energy consumption in the downstream grinding circuit. The research has also verified the preferential liberation of valuable minerals by electrical comminution. Given the advantages, several potential applications of electrical comminution in the mineral industry are proposed, including AG/SAG mill feed pre-weakening, pebble treatment, ball mill feed pre-weakening, early recovery of the liberated valuable minerals, crack/micro crack generation for improved leaching, and smelter slag treatment. For the mineral industry to utilize electrical comminution, two emerging issues identified from the research need to be address. They are the energy consumption by electrical comminution in the locked cycle treatment and the facilities scale up necessary to move this technology from the laboratory to the plant. Keywords: high voltage pulses, electrical comminution, energy efficiency, mineral liberation

Sep 1, 2012

By Lj. D. Andric

Development of modern devices for mechanical and mechanochemical materials activation has been dated since the beginning of last century. Rapid development of high-energy mills that are different in type, size, design and performances, has been occurred during the last four decades. Because of complete understanding of mechanical processing, entire knowledge of theoretical principles of high-energy mills is necessary. These principles are main causales of process that are happened in materials during the mechanical activation. This paper is occupied by theoretical principles of operation of high-energy mills. Conventional high energy mills with balls, high-energy planetary mills and high-energy vibrational mills are particularly considered in the paper.

Jan 1, 2014

By H. J. Schulze

From a colloidal science point of view (Schulze 1984, Nguyen & Schulze, 2004) five micro-processes are responsible for successful particle-bubble formation: the approaching of the particle to the liquid-air interface, the thinning and rupture of the intervening liquid film, the expansion of the three phase contact perimeter, the generation of sufficient large capillary force to stabilise the aggregates and the transport process of particles into and within the froth layer. Flotation reagents influence mainly the thinning and rupture of the intervening liquid film between particles and air bubbles, the expansion of the three phase contact after the rupture of the liquid film and the stability of the aggregates against external destruction forces in the flow field. But it exist also a non-negligible influence on the approaching of particles to the bubble surface during the encounter process and on their passing over into the froth layer and the froth stability.

Jan 1, 2003

Froth flotation is an industrial process commonly used for the separation of mineral particles. Bubbles sparged in a pulp collect and carry hydrophobic particles to the top layer of a flotation cell, the froth zone. There is a strong correlation between the stability of the froth phase and the flux of solids. However, flotation units placed in series operate, as a whole, in a non-steady state regime with the concentration of particle decreasing from one cell to the next resulting in a decrease in froth stability, which can compromise the recovery of valuables. Organic chemical reagents, frothers, are generally added to prevent fine bubbles from coalescing and to increase the stability of the froth phase. Frothers represent the second largest group of mining chemicals. It is crucial to understand the resulting properties of the frother on the froth phase in order to select the most suitable reagent for a particular operation. The bubble coalescence dynamic of three different surfactants, 1-pentanol, poly (propylene glycol), and tri (propylene glycol) methyl ether, were investigated in this study. In the first stage, the stabilisation mechanism of bubbles in a solution of surfactant was investigated using a specifically designed experimental setup. The coalescence behaviour of bubble pairs was recorded using high-speed video imaging in which information such as the coalescence time and the deformation of the resultant bubble upon coalescence could be extracted. The results were then compared between the different surfactants for several concentrations. It is shown in a study that the coalescence time increases with surfactant concentration until the Gibbs-Marangoni effect is suppressed by bulk diffusion. Conversely, the oscillation of the resultant bubble was found to be affected only at concentrations at which the film is saturated. The implications of the effects of surfactant type and concentration on the coalescence time and bubble oscillation in froth flotation are discussed. Keywords: froth flotation, frother, bubble coalescence

Sep 1, 2012

By S. Narra

Converting biomass into valuable fuel requires various preprocessing of the raw materials. Biomass densification is one of the conversion processes for its utilization. The aim of densification is to produce biomass pellets, which can withstand regular handling stresses and exhibit high densities with uniform size and shape. Physical properties, such as the particle size distribution after comminution is of highest importance for the binding mechanisms in the pelletisation process. Durability and strength of the pellets play an important role indicating the ability to withstand handling stresses. Particle size distributions of the cereal straws (Rye and Wheat) after specific comminution and liberation processes have been carried out with the help of three different image analysis (Microscope, Camsizer and Fibreshape). The durability of the pellets have been investigated as specified in the standards (ASAE standard S269.4) with a quadratic crate and the strength of the pellets with compression and tension testing machine (Zwick Roell type: ZMART.PRO). The particles size results showed differences in both length and width after different comminution processing. An exact comparison between the particle size analyses with the three different image analyses was not possible. The particle size distribution and the different comminution processes displayed influences on the durability and strength of the produced pellets. The particle size distribution displayed approximately 40 % of fines and 60 % of fibers. The particle size distribution displayed a direct relation to the durability of the pellets. Further durability and strength of the pellets displayed a good correlation.

Sep 1, 2012

Goethite ore are the third most abundant source of iron. The overwhelming part of these ore is represented by low-grade varieties which cannot be used in iron and steel industry without preliminary beneficiation. Biomass is a renewable solid fuel, which is feasible for the substitution of coke and coal in the manufacturing due to its lower contents of harmful elements and abundant raw material sources. Utilization of biomass in iron ore sintering process as heating agent and reducing agent contributes to energy conservation and emission reduction. The biomass was mixed together with goethite ore for roasting process to investigate the effects of reduction roasting. The results show that the goethite ore is dramatically reduced and magnetized into maghemite by biomass with the biomass dosage less than 20% and the roasting temperature below 650 oC. When the goethite ore roasted with biomass, the magnetization values could be enhanced more than two orders of magnitude, meets the standard of magnetic separation, which could significantly reduce the iron beneficiation cost. Keywords: biomass, goethite, reduction, magnetization, roasting

Sep 1, 2012

By Vasile Murariu, William Pate, John Herbst, Dilek Alkac

"Multiphysics models are essentially first principles models capable of providing very accurate micro scale predictions. The computational requirements for Multiphysics Models are extensive, precluding their direct use for flowsheet simulations. Population balance models get their form from theory but the model parameters have to be provided from experiments. The prediction errors for the population balance models are typically significantly higher than those for the Multiphysics Models but the computational effort for Population Balance Models is typically much less than that for the Multiphysics models. The hybrid model described here takes advantage of the strengths of each of the two primary model types and minimizing the weaknesses of each. The Multiphysics Model is used to perform high accuracy "experiments" that are difficult or impossible to conduct in laboratories or plants. The results of these experiments are combined with standard laboratory or plant data to parameterize and further enhance the Population Balance portion of the hybrid model. The creation of a useful Hybrid Model is demonstrated for a MP1000 secondary crusher. The validation of the hybrid crusher model is also presented. Finally the use of the Hybrid Model is illustrated in a full comminution flowsheet simulator."

Jan 1, 2014

By S. Fiore, M. C. Zanetti, C. Clerici

The processes and fluxes of a cast iron foundry plant located in the North of Italy were analyzed in order to determine the amount and kind of wastes produced from the different activities. The main fractions are the molding sands, furnace muds and powders coming from the dust abatement plant, the exhaust lime, the furnace refractory, the metallic shotting and the sludges and powders coming from the dust abatement plant of molding lines for a total production equal to 800 t/d. All wastes were sampled and particle-size and chemically characterized to evaluate the best recycling or reuse solutions. Wastes were sieved and divided in three categories according to the particle-size dimensions: below 0.1 mm, between 0.1 and 0.6 mm and above 0.6 mm. The fraction above 0.6 mm dimension underwent magnetic separation to recover and quantify the potentially available iron fraction. The fraction between 0.1 mm and 0.6 mm was chemically characterized in order to understand if it could be fed to the sand regeneration plant. The below 0.1 mm fraction was characterized to evaluate the following recycling and reuse solutions: additive for molding sands and/or raw material for the concrete industry.

Jan 1, 2003

By P. Somasundaran, G. Anastassakis, Z. Pan, D. R. Nagaraj

Gums are often used as depressants for talceous gangue minerals in the flotation of nickel and platinum bearing ores. However, the mechanisms of gum adsorption on talc are not clearly established. In this work, adsorption of guar gum at the talc-solution interface is investigated using spectroscopic and allied techniques. Guar gum adsorption on talc is not affected significantly by changes in solution conditions such as pH and ionic strength. Electrokinetic studies showed that guar gum decreased the negative zeta potential of talc but did not reverse the charge. Fluorescence spectroscopy studies conducted to investigate the role of hydrophobic bonding using pyrene and dansyl probes showed no evidence of the formation of hydrophobic domains at talc-aqueous interface. Urea, a hydrogen bond breaker, reduced the adsorption of guar on talc to the same extent as that for guar/alumina system, in which hydrogen bond plays an important role. All of the above results suggest that one of the main driving forces for guar adsorption on talc is hydrogen bonding rather than electrostatic or hydrophobic force.

Jan 1, 2003

By A. Collings, A. Farmer

Power ultrasound may be used in the processing of mineral suspensions to clean the particle surfaces of oxidation products and fine coatings, mainly through the large, but very localised forces, produced by cavitation. This effect may be utilised in lowering the level of iron contamination in silica sand used for glass making, in improving the sharpness of electrostatic separation of heavy mineral concentrates, in shortening the time of leaching of minerals and in improving the selectivity and recovery of flotation processes. Parameters affecting the efficiency of these processes, such as input power and levels of reagent addition, are discussed. In particular, we present data showing the relationship between power input and the particle size of surface coatings removed, which can be explained by the Derjaguin approximation for the energy of interaction between a sphere and a flat surface. Pilot scale studies, using commercially available components, are currently being used to assess process viability and will be compared with laboratory scale results.

Jan 1, 2003

By Wei Sun, Xue-feng Cao, Lei Sun, Run-qing Liu

The flotation performance of kaolinite in laboratory micro-flotation was investigated with 3- (dodecyloxy) propan-1-amine (ON12) as the collector. Compared with dode cylamine (DDA), which is commonly used as the bauxite reverse flotation collector, ON12 shows stronger collecting ability for kaolinite than using the same amounts of DDA, when experimental pH value reaches more than 6. With the addition of ON12, the isoelectric point of kaolinite shifts to 6.1 from 3.6, which suggests a strong adsorption between kaolinite and ON12. Infrared spectra analysis indicates that the type of ON12 adsorbed on the kaolinite surface is mainly of electrostatic adsorption. Molecular dynamics simulation further indicate that electrostatic adsorption of ON12 cation on kaolinite (001) surface based on electrostatic interaction between NH4+ and O atoms. ON12 will be suitable for bauxite reverse flotation with the efficiency depressors of the diaspora.

Jan 1, 2014

By F. C. Yi

Discontinuous and consecutive process was applied to probe into the Kinetics and adsorption theory for Cs+ adsorbed by Zeolites under the conditions of temperature, time and fixed-bed dynamic adsorption. It indicated that the sorption kinetics behavior of zeolite?s sorption on Cs+ is ac-cord with pseudo-secondary velocity equation, velocity constant k2=0.0005213 g?mg min-1, and equilibrium adsorptive capacity is 147.0588 mg?g-1; The equation can be expressed as: Y=0.0068X+0.0887; From the analyzing of diffusion coefficients on different temperatures and times, the coefficient of diffusion is not only related with the fabric of mineral and the character of ions but also the temperature and time; When the ambient temperature hoisted, the diffusion velocity augmented rapidly; Cs+ would get over a certain energy barrier when it enters into structure of zeo-lite; This energy is expressed by activation energy, and its value is E=131.668818 kJ?mol-1; There are two dominating adsorption mechanisms in the system of zeolite absorb Cs+: ionic interchange and surface coordinate adsorption.

Jan 1, 2014

By Y. M. Zhu, G. C. Gong

"The influences of citric acid (CA) on the flotation behavior of cassiterite using styrene phosphonic acid (SPA) as the collector were studied via single mineral flotation tests, contact angle measurements, zeta potential determinations and solution chemistry calculations in this paper. The results of single mineral flotation tests revealed under the conditions that pH=4 and the dosage of SPA 100 mg/L, the recovery of cassiterite reached 76.78%. The addition of 20 mg/L AC decreased the recovery by 12.42% at pH=4. Contact angle measurements demonstrated the adsorption of CA prior to SPA made the cassiterite more hydrophilic. The results of zeta potential determinations and solution chemistry calculations indicated the chemisorption of C6H7O7- and C6H6O72- filled parts of the Sn site on cassiterite surface and prevented the SPA from getting adsorbed. The hydrophilic effect of AC was stronger than the hydrophobic effect of SPA and the flotation of cassiterite was crippled. INTRODUCTION Tin is an important metal which is widely used in medical instruments, marine engineering materials, electronic and electrical devices, welding, weapon manufacturing and organotin compounds industries (Angadi et al., 2015). Cassiterite is the only mineral from which the tin can be extracted, thus it is of great importance to efficiently exploit the cassiterite mineral. Flotation is an indispensable method for the recovery of cassiterite (Li et al., 2015). However, cassiterite is usually in association with many other gangue minerals which are of similar floatability, such as quartz, calcite, fluorite, iron oxide, wolframite, scheelite and tourmaline (Sreevinas, 1997). So some modifiers are necessary in the cassiterite flotation process. The amounts of the modifiers used in the flotation must be judicious and the overmuch modifiers may cripple the recovery of cassiterite (Parsonage et al., 1987). Nevertheless, the research about the effects of the modifiers on the flotation behavior of cassiterite has been rarely reported. In this paper, the influences of citric acid (CA) on the flotation of cassiterite using styrene phosphonic acid (SPA) as the collector were investigated by flotation tests, contact angle measurements, zeta potential determinations and solution chemistry calculations."

Jan 1, 2018

By H. U. R. Kattentidt, W. L. Dalmijn, T. P. R. de Jong

"Research at Delft University aims to develop systems for automatic inspection and sorting of bulk solids which can be applied in the mineral processing and recycling industry. A recent development includes an automatic sorter based on airport X-ray inspection technology. It is designed for continuous inspection and sorting of 5 - 150 mm solids and has as objective a cost effective and high capacity on-line inspection and sorting.Dual energy X-ray transmission imaging provides instantaneous data about particle dimensions and the atomic number distribution. The system provides particle thickness and average atomic number on a pixel level at scanning speeds between 250 and 500 lines / second. With existing X-ray components inspection speeds between 0.5 and 2 m/s at approximately 1-meter inspection width and between 1.5*1.5 and 5*5 mm2 sensor resolution can be achieved.Imaging algorithms that were developed by Delft University for applications in recycling, waste cleaning and other applications acquire shape, size distribution and composition data. Currently on-line processing of a product at a rate of around 200 particles per second is possible using a standard PC. Experiments with a demonstration X-ray unit indicated good potential for various applications in solids processing. They include continuous inspection of organic content, sulphur, chlorine, ash, and metal distribution. It is applicable for coal cleaning, ore sorting, industrial minerals, and various applications within waste cleaning and recycling. Dual energy X-ray transmission fundamentals and recent progress in system development and applications are presented."

Jan 1, 2003

By Y. E. Brylyakov, M. A. Kostrova

"The apatite staffelite ores (ASO) of Kovdor deposit are dominated by fine-grained aggregates containing both phosphate minerals and silicates — vermiculite, smectites, zeolites. These minerals exhibit ion-exchange properties. In this connection, the magnitude of cation exchange, along with the content of P2O5 and CO2, is an important property of apatite staffelite ore, which largely determines the performance of concentration processes. In the examined ASO samples, the magnitude of cation exchange measured in terms of Ca2+ is 2546-4790 g/ton. The conducted laboratory studies of apatite staffelite ores with various mineral composition showed that adding calcined soda improves the recovery of P2O5 into the flotation concentrate. Full-scale tests were conducted at the apatite staffelite ore processing plant at Kovdor Mining and Concentration Operation and demonstrated the high performance of the proposed agent treatment. The test results showed that in the flotation of apatite staffelite ores, the optimum calcined soda feed rates range from 3,500 to 5,000 g/ton of the flotation feed. With close flotation feed and concentrate grade parameters, the P2O5 recovery gain is 17%. The effect of adding soda is associated with the desorption of the hardness cations from the minerals, precipitation in the pulp and, accordingly, improvement in the ionic composition of the liquid phase of the flotation feed due to a reduced content of calcium ions. Based on the test results, the proposed agent treatment with an elevated feed rate of calcined soda was implemented at Kovdor Mining and Concentration Operation in the flotation of apatite staffelite ore. The apatite staffelite ores (ASO) of Kovdor deposit are dominated by fine-grained aggregates containing both phosphate minerals and silicates — vermiculite, smectites, zeolites. These minerals exhibit ion-exchange properties. These minerals have certain properties requiring a more detailed examination for a better understanding of the flotation properties of apatite staffelite ores."

Jan 1, 2018

By K. H. Luo, J. Y. Liu

An experimental study on interparticle breakage of three iron ores was carried out by compressive stressing of particle-bed in a piston-die device. The feeds to the particle-bed stressing were five narrow size fractions in the size range of 0.2~3.2 mm respectively and a wide size fraction of 0/4.0 mm. The pressures applied were in the range between 30 and 360 MPa. The results show that the energy absorption of the particle bed increases linearly with the pressure; the increase of the product fineness with the pressure declines as the pressure goes up; and the product size distributions resulting from interparticle breakage of different narrow size fractions have no self-similarity. Using data obtained from the piston-die compressive stressing test, the suitability of a previously-developed material-characterization model for interparticle breakage was verified for these ores. It is shown that the particle-bed compression test conducted with piston-die device in lab-scale may provide a cost-effective way of studying and modelling size-reduction of ore materials by interparticle breakage.

Jan 1, 2014

By Xuliang Yang, Yuemin Zhao, Bo Zhang, Liang Dong, Cheng Sheng, Gongmin Li, Zhenfu Luo, Yaqun He, Chenlong Duan

Coal plays an important role in the primary energy consumption of all over the world. In 2012, coal reached the highest share (29.9%) of global primary energy consumption since 1970. Coal burning mainly contributes to the emission of SO2, NOX, Hg and other impurities that jeopardize the future of environment. . Beneficiation before coal utilization is the most economical and effective technology for removing the hazardous material and gangue. In this paper, a novel process of dry beneficiation based on gas-solid two-phase flow composed of the compound dry cleaning separator (FGX), the air dense medium fluidized bed separator (ADMFB) and the vibrated fluidized bed with autogenous medium (VFB) is proposed. The main equipment and the flowsheet of the united system are described in detail. Separating principle of the FGX, ADMFB and VFB devices are all based on gas-solid two-phase flow. In FGX, gassolid suspension is composed of continuous gas flow and coal powder in feed coal. Large size coal (+6- 80mm) can be pre-separated effectively, and large size gangue can be removed effectively. Moreover, - 6mm particles fed serve as autogenous medium in FGX. The probable E value is 0.13 for -80 mm raw coal. In ADMFB, magnetic powder with -0.3 + 0.045 mm size fraction and coal powder in feed coal are compound medium solids. The separation density can be adjusted and controlled according to properties of raw coal. -50 + 6 mm raw coal can be cleaned efficiently, the probable E value is 0.05. In VFB, -6 + 1 mm coal can be separated. Generally, -80 mm raw coal can be cleaned efficiently in the united system based on gas-solid two-phase flow.

Jan 1, 2014

By Markus A. Reuter, Albert Scholte, Ewoud V. Verhoef, Gerard P. J. Dijkema

A dynamic, interactive map has been developed of the life cycle of a number of metals, from mining through to minerals processing, metal production, product manufacturing, recovery and waste management. Whilst the existing metal process network and waste management infrastructure provide substantial scope for (product) design, these also limit change due to the complex interdependence of metals, both in production and recovery, and the strong path dependency of industry and infrastructure development. Therefore, models for dynamic simulation were constructed that allow the specification and evaluation of the metal process network and waste management infrastructure ‘products’ over a longer time span. The model has been constructed using a bottom-up approach, to enable assessment of the environmental aspects of metallurgy and to simulate changes in the system structure and technology, i.e. from reactor or individual process step up to integrated material cycles. The model comprises hierarchical mass balances and linear models of individual processes and sub-processes. Thus, at lower system aggregate levels an increasing level of technical detail is represented. Data reconciliation has been used literature data on process feed, products and residue composition to calculate representative and reliable split factors around each (sub-)process. World production figures on process capacity and recovery rates are be used to calculate the relative contribution of processes. The dynamic map is illustrated with a case on the introduction of lead-free solder.

Jan 1, 2003