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By Sanggono Adisasmito

"The quality of the higher education in Indonesia is being improved by implementing a program financed by the World Bank under a project named QUE (Quality for Undergraduate Education). The investments are provided to selected study programs through a competitive selection process. The grant finances staff development, the purchase of equipments, textbooks, consumables, technical assistance, and incentives for outstanding faculties such as teaching grants, project grants, lecture note awards, and educational policy studies. These additional investments are provided to produce chemical engineering graduates that will compete beyond the national market.Chemical Engineering Department of Institut Teknologi Bandung in Indonesia has been selected to receive the QUE grant beginning the year 2000 and ending the year 2004. The department is actively involved in the mineral processing issues, particularly in the aspects of energy supply and the environmental protection. The activities are distributed in different laboratories and areas of expertise, such as: thermodynamics and utility systems, process equipment, chemical reaction and catalysis, microbiology and bioprocess engineering, process control, ceramics, as well as polymer and membrane technology. The main objectives of the QUE project are to improve the undergraduate program in the following aspects: Relevance, Academic atmosphere, Institutional management and commitment, Sustainability, as well as Efficiency and productivity, or abbreviated as RAISE. At the end of every fiscal year, the progress of the program is evaluated to measure the effectiveness of the project.The achievement of the QUE project objectives were assessed using performance indicators developed during the program design. There are six indicators to measure the performance of the individual program of study, such as: (1) Admission Test score, (2) average students' Grade Point Average (GPA), (3) average graduates' length of study, (4) graduates' waiting time before getting first job, (5) Test of English as Foreign Language (TOEFL) score, (6) Graduate Record Examination (GRE) score. Essentially, the RAISE evaluation criteria will be used to perform three main functions, such as (1) to measure the achievement through the six quantitative performance indicators, (2) to support the progress of evaluation and reporting throughout the implementation of the program, (3) to provide a universal framework for qualitative evaluation."

Jan 1, 2003

By Buks Kruger

"After the milling and flotation of the platinum bearing ore, the flotation concentrate is electrically smelted in 6-in-line electric arc furnaces and the resulting furnace matte treated in Peirce Smith converters to remove the iron sulphide. The iron free (less than 1% Fe) converter matte is then granulated and sent to the Base Metals- and Precious Metals Refineries for further processing.During the smelting and converting processes two distinct gas streams are produced.The Peirce Smith converter off gas contains 4% - 9% SO2 which is treated in a conventional Sulphuric Acid Plant to produce sulphuric acid (H2SO4).The electric furnace off gas contains 0.9% SO2 and was (until September 2002) vented through a 91 meter high stack to atmosphere.Off gasses which contain less than 3% SO2 is difficult to handle and quite a few processes had been developed over the years to cope with this gas. A broad spectrum of process suppliers and technology approaches is available and the different technologies can be divided into a few main approaches i.e.Scrubbing of the off gas with an alkaline solution to produce an environmentally friendly and stable waste product which can be discharged onto a tailings dam or permanent landfill site.Physical absorption of the SO2 into a chemical solution to produce high quality chemically pure process chemicals.Catalytic reaction of SO2 with O2 to produce SO3 which is absorbed in water to produce sulphuric acid of less than 90% strength.In October 2002 Impala Platinum commissioned a Sulfacid Plant at its Smelter in Rustenburg which recovers the SO2 from the electric furnace off gasses into a weak sulphuric acid solution.The Sulfacid Plant technology is widely used in the paint pigment industry. This is, however, the first application of the technology on electric furnace off gas.The furnace off gasses contains flue dust which is removed in electrostatic precipitators. The gas exiting the precipitators normally still contains between 40 mg/Nm3 and 60 mg/Nm3 dust and passes through a quench-scrubber before entering the reactors. The quench-scrubber cools the electric furnace offgas down from ± 200 °C to 60 °C and act as a final dust removal stage."

Jan 1, 2003

By Herman D. Mendoza

"The removal of finely dispersed mercury from the effluent of small-scale gold mining operations and the eventual recycling of the recovered mercury was investigated. The conventional method of amalgamation, or “ball milling”, involves the mixing of a substantial amount of mercury with ore to recover free gold during the grinding stage. During grinding, a portion of the mercury is transformed into minute droplets, which readily float and disperse in the effluent. A kilo of gold ore containing 20-30 g Au/t, when ground with 3 g of mercury, yields 0.005 to 0.050 mg/l of mercury in the effluent, exceeding the concentration of 0.002 mg/l allowed by law for surface water.A rapid recovery/ recycling process was introduced using the surface-chemical properties of finely dispersed mercury in aqueous suspension. It was observed that fine droplets of mercury in an aqueous environment readily attached onto a collector having positive surface potentials for pH 3 to 10. An example of a suitable collector is alumina (Al2O3), which has an iso-electric point of pH 9.8. When an effluent, coming from a settling procedure after an amalgamation-grinding stage, was passed through a column-bed packed with alumina fiber, removal and subsequent collection of finely dispersed mercury occurred under acidic conditions, pH 3-6. Recovery was around 99.5%, yielding an acceptable quality of water safe for disposal into the aquatic environment. The collected droplets of mercury, which are left in the column-bed of alumina fiber, were subsequently treated with a cleansing solution at alkaline conditions pH 10 -12. At these conditions, both mercury and alumina fiber carry negative surface potentials, which results in the eventual detachment of attached mercury from the alumina collector. The effective recovery of attached mercury from the alumina collector by the detachment procedure is only 30-35%. The collected mercury from the cleansing stage can be collected, cleaned and can be used for subsequent amalgamation processes. The attachment and detachment behaviour of finely dispersed mercury onto and from the microscopic collector alumina is shown in Figure 1. The result of attachment and detachment were analyzed using existing interaction energy theories like the Darguin-Landau- Verwey- Overbeek (DLVO) Theory."

Jan 1, 2003

By J. Shibata

The behavior in electric field of fine particles present in aqueous solution was measured in order to apply to the classification of fine particles. The sample particles used are spherical polystyrene particles with the average diameter of 0.03 µm, 0.1 µm, 1.0 µm, 4.3 µm and 9.6 µm. Electrophoretic mobility and zeta potential of various particles are measured by an instrument based on the principle of the laser Doppler effect. The influence of temperature, electrolyte concentration on the electro-phoretic mobility was investigated for various polystyrene particles. The electrophoretic mobility increases with increasing pH and temperature of suspensions. The measured electrophoretic mobilities are different from electrolyte concentration and particle size. The electrophoretic retardation effect and relaxation effect are considered to explain the behavior of fine particles in electric field by applying the electro kinetic theory of Wiersema et al. For all particle size, the electrophoretic mobility decreases rapidly in high concentration of KNO3 such as 0.1 mol/dm3due to the compression of electric double layer The forces acting the particles in electric field are considered to be electrical force, friction force and some other forces like relaxation effect and electrophoretic retardation effect which appear in ionic behavior. It is considered that the particle moving velocity depends on the particle size. When the particle size is less than 1µm, the velocity increases with increasing the particle size. On the oth-er hand, the velocity deceases with increasing in particle size, when the particle size is larger than 1µm. This phenomenon is considered to be interesting from the viewpoint of classification for fine particles. We found that the electrophoretic mobility of 1.0µm particles is larger than that of 0.1µm particles, and that it is possible to classify fine particles by using the difference of electrophoretic mobility by many experimental results. The phenomena can be explained by the forces acting the fine particles in the electric field. We can apply the behavior to classification of fine particles.

Jan 1, 2014

By A. V. Kozub, D. O. Sharkovsky, R. I. Ismagilov

"Due to complex mineral composition and fine ingrained nature concentration of iron ores deposited in Mikhailovskoye mine field requires application of wet magnetic separation to produce 65–66% Fetotal and 8.2–8.6 %SiO2, concentrate with 90–94% of material being –0.044micron grain size. Higher specific consumption of ROM, increase of production costs with concurrent reduction of output - those are inevitable side effects of desired concentrate grade improvement. Large-scale complex analysis and surveys have been carried out aimed at concentrate grade improvement with concurrent output increase. Classification of feed in hydraulic cyclones (hereinafter referred to as hydrocyclones) has been the bottleneck for improvement of processing throughput and concentrate output. Hydrocyclone classification efficiency is 50-60% and further improvement is practically impossible. Actual circulating load may achieve as much as 500-600% while the optimal rate is 200-250%. Application of wet fine screening has been considered to improve iron ore concentrate grade. Objective of this work is to design processing flow diagram for unoxidized ferruginous quartzites with implementation of wet fine screening. Large-scale tests have been run in Crushing and Concentrating Plant with application of wet fine screening stage. These tests included application of wet fine screening in 2 and 3 stages of classification to separate desired grain sized material; replacement of hydrocyclone classification with fine screening; application of fine screening as additional stages to concentration process and screening of final concentrate. Testing Methods. EXPERIMENTS AS WELL AS THEORETICAL RESEARCH HAVE BEEN APPLIED FOR THE PURPOSES OF THIS WORK; INCLUDING MAGNETIC, GRAIN-SIZE AND CHEMICAL ANALYSIS OF CONCENTRATION PRODUCTS. MODERN ANALYTICAL DATABASE HAS BEEN APPLIED TO STUDY WET FINE SCREENING FEATURES, MINERAL AND PHYSICAL COMPOSITION OF CONCENTRATION PRODUCTS. Work Results: - analysis of wet fine screening application for iron ore concentration. - technological solutions enabling to improve slurry classification of fine ingrained low magnetic iron ore have been developed. - effective process flow diagram including fine screening has been designed based on the feasible and reasonable arrangement solutions."

Jan 1, 2018

By Aubrey Mainza, Malcolm S. Powell

"A hydrocyclone with two vortex finders, named the three-product cyclone (3PC), has been successfully tested in the Platinum industry for dealing with the dense Chromite found in UG2 ores. This dense component preferentially reports to the cyclone underflow, resulting in an over-ground fine Chromite component in the final product. The dense media effect caused by a high concentration of this in the cyclone feed produces a coarsening of the cyclone overflow, which results in loss of recovery through over-size silica in the PGM carrying component material in the float feed. The fine barren particles of Chromite that report to the overflow are recovered through entrainment in the flotation process, resulting in detrimental contamination of the slag produced from the concentrate.Data from many industrial scale tests of the 3PC have shown that three distinct products are obtained when the inner vortex finder length (LIVF) is extended to the region either above (normal classification) or below (reverse classification) the transition zone (a region were the inner and outer overflow streams are identical). Due to wear problems arising from extending the IVF deep into the cone of the cyclone, it is advantageous to use the shorter IVF. Only the normal classification results are reported here, but similar outcomes (to opposite overflow streams) were obtained for the reverse classification. The results showed notable differences in the percentage split of the plus 100µm material in the product streams, confirming that three distinct products are discharged from the 3PC. About 12% of the plus 100µm material in the feed reports to the middlings stream, 1% reports to the final product, and the remainder to the cyclone underflow.Results of silica and chrome splits to the three distinct products namely, the inner overflow (INO), the outer overflow (OUO) and the underflow (U/F) are given in Table 1. These show that the 3PC can be used to recover coarse silica through screening the middlings product - which has a high silica content. When the vortex finder ratios (ratio’s of cross-sectional areas) are carefully selected, the split of plus 100µm silica to the middlings product ranged from 2.9 to 9.6%. Large amounts of oversize silica and chrome report to cyclone underflow, explaining their high percentages in the underflow stream."

Jan 1, 2003

By C. H. Veloso

"Starch is the most widely used depressant in the reverse cationic flotation of iron ores. There is however, an indication from recent studies, that other polysaccharides may successfully replace them. When starches are used in the flotation of iron ores in the presence of quartz as gangue mineral, their strong adsorption on the surface of iron oxides can be explained by the molecular conformation between the available sites on the mineral surface and two hydroxyls of starches. However, when the gangue minerals are iron-bearing silicates, the strong interaction with starch can occur on these minerals since they have the same surface behaviour as iron oxide. In this work bench scale tests were conducted in order to generate scientific knowledge about other alternatives depressants for the flotation of iron ores. A magnetic pre-concentrate from a skarn iron ore processing plant was used as feed material for flotation tests. The reverse flotation approach was used to upgrade the iron content by removing complex ironbearing silicates. The depressants used in this study were: corn starch, dextrin, carboxymethyl cellulose (CMC) and humic acid. The tests were performed under different pH conditions in order to try to relate the efficiency of depression to the pH used during flotation. The results show the important role of pH as each depressant reached its best performance at different pH values. At alkaline pH the corn starch showed best depression performance while the humic acid is more efficient at pH close to neutrality.INTRODUCTIONIron corresponds to approximately 6% of earth’s crust composition (McDonough and Sun, 1995). It is the most used metal in our lives, some of its properties as resistance and facility to be shaped makes is replacement very difficult. The primary sources of iron on our planet are minerals. The iron-bearing minerals most commonly found in nature and economically exploited are magnetite [Fe3O4], hematite [Fe2O3], goethite [FeO(OH)] and siderite [FeCO3] (L O Filippov et al., 2014). These minerals are commonly associated with other minerals (most of the time not economically exploited) forming the so-called iron ore. Iron ore is the source of primary iron for the world’s iron and steel industries."

Jan 1, 2018

By S. M. Bradshaw, C. Dorfling, F. Ngandu

"Selenium removal and platinum group metal (PGM) recovery from copper sulfate leach solutions form an integral part of platinum producers’ base metal refinery operations. Recent studies found that substantially higher PGM recoveries can be achieved if excess thiourea instead of sulfurous acid is used as precipitation reagent; however, the impact of the proposed process on downstream processes was unknown. The objective of the current study was therefore to investigate the effects that excess thiourea and residual selenium present in the rich copper sulfate electrolyte have on copper electrowinning. This was achieved by performing cyclic voltammetry tests using a platinum rotating disk as working electrode, a graphite auxiliary electrode and a saturated calomel reference electrode. A synthetic copper sulfate electrolyte containing 0.01 M Cu2+, 1 M H2SO4 and varying amounts of selenium (20 – 150 mg/L) and thiourea (10 mg/L and 100 – 300 % excess) was used. The results obtained have shown that both thiourea and selenium interact with the cupric ion cathodic reduction reaction. Thiourea polarized the working electrode and lowered the efficiency of the cupric reduction reaction. Tests on the solutions with high selenium concentration showed simultaneous reduction of copper and selenium, which led to copper selenide formation. Nodule formation on the deposit surface also became significant at higher selenium concentrations. Based on these results, it was concluded that precipitation of PGMs from the copper sulfate solution with excess thiourea is not feasible due to the detrimental effect on downstream electrowinning operations.INTRODUCTION During the high pressure oxidative leaching stage in a typical base metal refinery (BMR) circuit, selenium, tellurium and some platinum group metals (PGMs) are dissolved along with the desired copper ions. The impurities (selenium and tellurium) may pass to the copper electrowinning circuit where it can result in the formation of nodular copper electrodeposits or reduced current efficiency. The presence of PGMs in solution, on the other hand, increases the precious metal inventory and potential losses of the operation. Currently, sulfurous acid is widely used for selenium and tellurium precipitation from copper sulfate leach solutions. Sulfurous acid is capable of reducing cupric ions to cuprous ions; the generated cuprous ions then react with Se4+ and Se6+ to precipitate selenium as a copper selenide (Bello, Dorfling, 2014). Recent studies have, however, proposed the use of excess thiourea as a precipitating agent for the removal of selenium and tellurium; it has the advantage of improved PGM recovery in the Se/Te precipitation step (Lottering, Eksteen et al., 2012; Mulwanda, Dorfling, 2015)."

Jan 1, 2018

By R. ?. Sherembayeva, ?. ?. ?uktybayeva, ?. B. Rakhimbekova, N. ?. ?m?rova

"Studying the interaction of the phosphorus-containing flotation reagent with the components of the flotation system ""liquid-gas-solid"" during flotation of non-ferrous metal ores allows regulating the enrichment process. The phosphorus-containing reagent-collector anabasinium-O,O-dimethyl-thiophosphate has beensynthesized under laboratory conditions and the concentrated aqueous solution of anabasin hydrochloride and the 40% solution of sodium hydroxide have been used as the raw material. The phosphorus-containing reagent has been obtained by interaction of the anabasine base, sulfur and dimethyl phosphite, due to sulfur and nitrogen atoms it can form complex compounds with heavy metal ions.Studying flotation of copper-sulfide ore of the Sayak field with the use of the phosphorus-containing reagent-collector anabasinium has been performed in the open and closed cycles. The degree of ore grinding was 60- 62% of the class -0.074 mm. There has been established the dependence of the ore flotation parameters on: a) pH of the pulp; b) the consumption of the reagent-collector anabasinium.The effect of the pulp pH on the technological parameters of copper ore flotation has been carried out with a reagent regulator that increases the difference in the surface properties of the minerals to be separated.There has been used lime as the regulator of the medium, the consumption of which varied from 750 to 1500 g/t; the consumption of the reagent-collector anabasinium was 10, 15, 20 and 25 g/t.It has been found that when flotation of copper ore without the use of lime at pH equal to 7.8 and at the reagent consumption, g/t: anabasinium - 25, T-92 - 55, copper recovery in the concentrate is 92.72%, the quality of concentrate is 7, 1%.In flotation according to the factory mode (the consumption of xanthate is 44 g/t, T-92 is 55 g/t, pH = 7.8 (without lime)) of copper ore, copper recovery in the concentrate is 87.38%, the concentrate quality is 7, 97%, with reducing the xanthate consumption to 25 g/t copper recovery is reduced to 83.39%, the quality of the concentrate is up to 6.69%.In the experiments using the factory reagent mode in the closed cycle, with the xanthate mass consumption of 44 g/t, T-92 blowing agent of 55 g/t, the third recleaning concentrate contained 19.13% copper with recovery of 86.89%.Using a phosphorus-containing reagent instead of xanthate with the same flow rate, the third recleaning concentrate with the mass fraction of copper of 19.82% has beenobtained with recovery of 87.77%."

Jan 1, 2018

By P. Hatefi, O. Rahmani, M. Noor-Mohammadi, A. Tohry

"Depressants play an important role in the selective separation of impurities from iron minerals by direct or inverse flotation. In this paper, sodium co-silicate (SCS) with chemical formula of Na4SiCO6, as a depressant with pH modifier features, has been synthesized and used for phosphorus bearing iron ore in anionic reverse flotation. In this process, phosphorus is floated while the iron oxides are depressed, using fatty acids as collector in an alkaline medium. Batch and pilot flotation tests were carried out to investigate the influence of SCS on the separation selectivity of phosphorus from iron oxides. Also the depression mechanism of SCS on hematite surface was investigated by microflotation tests and FTIR spectroscopy measurements. The flotation results indicated that without using a pH modifier, the pH of pulp could reach up to 10, when SCS was used as depressant. In this condition, a better depression performance was observed compared to sodium silicate (SS). Using the SCS, phosphorus and total iron content in iron concentrate was 0.046% and 66.29%, respectively, compared to SS where these values were 0.06% and 65.75%, respectively. As a result the weight recovery of iron concentrate was increase by around 4%, compare to SS. It was also found that 238 g/t of SCS could be used instead of 3 types of reagents collectively, including 32 g/t of NaOH, 151 g/t of Na2CO3 and 400 g/t of SS gel.INTRODUCTIONThe phosphorous presents in iron ore minerals is mainly in the form apatite mineral. The apatite is separated from iron ore minerals by magnetic and flotation methods (Ma, 2012). The reverse anionic flotation of iron is one of the most common method for removing phosphorus from iron concentrate (Araujo et al., 2005).Usually apatite minerals are readily floated using anionic collectors such as fatty acids (Ma, 2012). In this conditions the iron minerals are depressed and by modifying the pH in alkaline conditions, selective separation of phosphorus from iron concentrate can be achieved. Depressants including; sodium silicate (SS), starch, dextrin, guar gum and humic acids play an important role in the reverse flotation of iron ore (Kar et al., 2013; Ma, 2012; Turrer and Peres, 2010; Araujo et al., 2005). Studies have shown that SS has a better effect on iron recovery and phosphorous reduction, compared with other depressants (Tohry and Dehghani, 2016; Qi et al., 1992, Dho and Iwasaki, 1990). In most flotation processes, modifiers are used to adjust the pH. To achieve alkaline conditions, mainly pH modifiers such as carbon dioxide and sodium carbonate are used."

Jan 1, 2018

By Jia Muxin

The adsorption behaviors of metal ions on a silicate mineral and the flotability of a metalized silicate mineral with sodium oleate as collector are closely related to the structure of the silicate mineral. The adsorption isothermals of the metal ions on different silicate minerals are studied, the parameters of the isothermal give the information how many surface oxygen anions a metal ions is attached to, from this information and the structure of the mineral the site where a metal ion is attached can be guessed (The adsorption isothermals and adsorption behaviors with pH are fitted with Temkin, Frenudlich and Kurbatov equations respectively). Metal ions as Cu2+, Ni2+, Zn2+ are attached to the oxygen anions of surface species –Si-O– on the quartz surface, most of them coordinate to only one surface oxygen, their adsorption ability on quartz is low, but this metal ions on quartz surface protrude out of the surface perfectly, so their ability to combine with oleate acid radical is excellent. Quartz can be activated well by such metal ions. The isothermal of Fe3+ on quartz indicates these cations coordinates with more than two surface oxygen anions. This means the Fe3+ nucleates on quartz surface in the form of Fe(OH)3 colloid particles. The isothermals of Cu2+, Ni2+, Zn2+ Fe3+ on spodumene shows such ions coordinate with more than two surface oxygen anions, it indicate these ions may attach to the position where Li+ is formerly exists, such metal ions stay in a cave on the mineral surface, their adsorption abilities on spodumene are quite well, but they are affect by the oxygen anions of the two Si tetrahedron chains, the can almost not activate this mineral. These cations may attach on the site where Al3+ exists on the muscovite surface, just like spodumene, muscovite can not be activated well by such cations. Pt2+ has a large ion radius, as Pauling’s rules depicts polyhedron can not attach to Si tetrahedron well, the adsorption ability of Pt2+ on quartz is low and quartz is activated badly by Pt2+. On the other Pt2+ can adsorb well on spodumene and muscovite well and activated them well because it is not affected so bad by the tetrahedron oxygen anions of the minerals for their its large radius. The isothermal of Ca2+ on quartz indicates a Ca2+ coordinates with less than one surface oxygen anion, this means Ca2+ attaches on quartz mainly by physical adsorption. The adsorption abilities on mineral surface and the interaction abilities with oleate acid radical of the transition metal ions with the same valence are guessed to be determined by their d electron number, the rules should be d1<d2<d3<d4>d5<d6<d7<d8<d9>d10. Hydrogen bond may play an important rule in the activation of the mineral by HF and the interaction of the HF activated silicate mineral with collectors. The general rule is high bond valence and small metal ion radius surface species –Me-O can be activated well by HF with sodium oleate as collector. For example – SiIV-OH is neutral while –SiIV-FH+ and –SiVI-FH+0.33 are positively charged, the positively charged surface species are more likely to connect oleate acid radical via hydrogen bonds.

Jan 1, 2003

By H. Araneda

Throughout Chile?s history, mining has consistently been a leading industry in the country. The 1990s marked the beginning of a boom in Chile?s mining industry, especially in copper mining, due to both foreign and local direct investment in the sector. Mining?s contribution to the GDP was 15.6% at current prices in 2009, and it accounts for 56% of the country?s exports. Chile?s copper market share reached 35% in 2009. The investment portfolio in mining in Chile for the coming decade has been estimated at 90 billion US dollars. The acute scarcity of human resources currently experienced by the mining sector in Chile will be accentuated in the coming decade as a result of this scenario of investments. The situation is, additionally, similar to the one confronted by other countries involved in the mining industry such as Australia, South Africa, Canada, and in Latin America includes, Peru, Colombia and Brazil. A study carried out by Fundacion Chile, ¨Labor Force in the Chile Mining Industry, Diagnostic and Recommendations, 2011-2020? shows the projected labor shortage for the operation of projects in the development stage, considering only the requirements of the process of extraction, processing, and maintenance. The demand, accumulated incrementally, will be around 115,000 technically skilled workers, professionals, and qualified workers. This figure refers to the operational work force, and does not include the human resources that will be required for the prior stage of the engineering and construction of the projects (brownfield and greenfield). The demand for technically skilled workers and professions for the stages of engineering and construction of the projects that have already received investments is estimated to be 190,000 people for the period 2012-2020. The peak of the demand for engineering is 2012, with a figure that surpasses the 12,000 professionals for all of the engineering specialties. The analysis of the formation of human resources at the tertiary level (where tertiary includes technical/vocational and academic degrees at the undergraduate level) for mining and related majors demonstrates that the programs are scarce with a bias toward theoretical contents and that they are excessively long (40% longer than comparable programs in Australia, Canada, and in OECD countries). The completion rates are low, especially in the technical-vocational programs, which have a completion rate of only around 30%. Finally, the rates of attraction of technically skilled labor and professionals towards careers in mining are insufficient to reduce the identified skill gaps. In the case of university professionals such as geologists, mining engineers and engineers in metallurgy, 80-90% will work in mining. In the case of graduates of relevant majors, that cover skills also utilized by other industries, not only mining?such as maintenance workers, operators of fixed and mobile equipment, etc.?the mining sector appears to be unattractive for reasons such as shift schedules, geographical location of work sites, and other factors. On the basis of the available diagnosis a strategy for the sector has been developed (Workforce Development and Skills Strategy) whose objective is (i) to define a Mining Qualifications Framework to identify the critical roles to be filled (ii) to start, with public resources, a ¨fast-track? training program to assure the availability of at least 28,000 operators (machinery operators, truck drivers, etc.) and maintenance specialists in 2015 (iii) to promote the development of training hubs for mining with learning technologies to train technical labor and professionals on the basis of world class standards (iv) to design and implement a campaign oriented toward the perception of mining as an attractive field of employment opportunity (v) to develop curricular innovations for tertiary education programs, on the basis of international benchmarks. Keynotes: Chile, mining, copper mining, skilled human resources

Sep 1, 2012

By Masakazu Niinae, Kenji Aoki

"Electrokinetic soil remediation by electroosmosis and ionic migration is restricted to soluble substances. At a higher pH, the soil particles sorb more heavy metals than at a lower pH and the precipitation of heavy metals are promoted. Both mechanisms make heavy metals immobile, rendering cleanup more difficult and electrokinetic extraction inefficient.In this study, the effectiveness of introducing a complexing agent to enhance the removal of cadmium from kaolinite in the region of neutral pH by ionic migration is examined. The complexing agent selected was ethylenediaminetetraacetic acid (EDTA). The investigation was carried out in a laboratory-scale column containing kaolinite contaminated with cadmium. As the results of the study, cadmium migrates toward the anode without accumulation of cadmium and is successfully removed at the anode reservoir."

Jan 1, 2003

By J. Yianatos

The cleaning circuit operation and its effect on the plant metallurgical performance, was characterized at Los Pelambres concentrator, Chile. Experimental data from columns, scavenger and regrinding stages was evaluated. Each stage was characterized by size fractions, and the interaction between stages (columns, scavenger, regrinding) as well as the effect that circulating loads had. The approach for describing the flotation equipment operation (cells and columns) considered the collection and froth zones separately. This methodology allows for the identification of the impact that particle size distribution has on the actual collection and froth transport processes, independently. In this way the effect of regrinding on flotation recovery and grade can be related to the corresponding operating variables, e.g. pulp flowrate, air flowrate, pulp level and pulp density, among others. The effect of gangue entrainment was considered using an empirical dimensionless correlation. The interaction between the circulating load and the overall performance of cleaning circuit was evaluated. The circulating load was defined as the ratio between the solid flowrate of scavenger concentrate over rougher concentrate. It was found that the overall cleaning flotation circuit (column-scavenger) can operate at a relatively high and constant recovery for a wide range of mineral treatment. This is possible when the scavenger has the capacity for compensating the decrease in column recovery at larger circulating loads. Under the condition of high overall cleaning recovery, the rougher stage closely represents the plant recovery. However, at large mineral treatment conditions, the design characteristics (e.g. concentrate transport channel capacity and transfer boxes) as well as instrumentation, control facilities and operation, became bottle-necked. A simulator was developed using empirical models for each stage (column, scavenger and regrinding) in order to evaluate proper operational strategies for cleaning flotation circuits Keywords: flotation, cleaning, regrinding, Vertimill, simulation.

Sep 1, 2012

By Rod Hocking, Nenad Djordjevic, Randolph Pax

"Semi Autogenous (SAG) mills exhibit complex interactions between the competing processes occurring inside them. Traditional practice is to measure the operation of the SAG mill at an operating point in terms of its load, power draw, steel load, ore throughput rate, water addition rate and more recently the feed size distribution. However significant departures of operating conditions can occur due to changes, for example, in ore hardness, the quest for higher throughputs and mill internal geometry.Fundamental to SAG mill operation are the internal processes that ensure that a given ore throughput and discharge grind size are obtained and maintained. These processes can be measured using non-contact acoustic emissions from the SAG mills which utilise the information rich noise that is generated by the grinding, flow and charge movement inside a mill.Non-contact acoustic in-mill measurements can be used for the validation of discrete element modelling (DEM). The approach being reported in this paper is to model the individual physical processes and then to simulated the assemblage of a physical mill."

Jan 1, 2003

By G. Granata, C. Tokoro, T. Kato

The rare earth elements (REE) are composed of 17 elements that are 15 elements of lanthanide added scandium and yttrium. REE are divided into light rare earth elements (LREE) and heavy rare earth elements (HREE). Although the supply source of LREE is distributed around the world, the supply sources are unevenly distributed. Thus, the development of a new HREE supply source is required. In this study, we focused on the weathered residual rare earth ore as a new HREE supply source. Since so far this weathered residual rare earth ore could not be treated neither by flotation nor by wet high intensity magnetic separation, it was not considered as HREE resource before. In this study, we investigated the leaching of HREE from the weathered residual rare earth ore and elucidated the effectiveness of planetary milling with sodium hydroxide as a method to enhance their recovery. For this purpose, the weathered residual rare earth ore was first grinded by planetary mill in the presence of sodium hydroxide and then leached by sulfuric acid. The influence of planetary milling on HREE recovery was investigated by assisting the leaching experiments with X-ray absorption fine structure (XAFS) in cerium and yttrium K-edge. Since yttrium was the most contained HREE in the weathered residual rare earth ore used in this study, we focused on yttrium in XAFS analysis. Results clearly showed that the recovery of HREE increased by planetary milling with sodium hydroxide. XAFS analysis revealed that a part of the yttrium in the weathered residual rare earth ore was changed to yttrium hydroxide by planetary milling with sodium hydroxide. It is supposed that all HREE were affected like yttrium due to a similar behavior observed in leaching.

Jan 1, 2018

By Erico Tabosa, Kym Runge, Peter Holtham

"The distribution of turbulence in an industrial scale mechanical flotation cell and its effect on flotation kinetics was studied using a fully instrumented 3m³ cell. The cell was operated at a copper concentrator in Australia with different combinations of airflow rates, impeller speeds and sizes and cell aspect ratio providing a wide range of hydrodynamic conditions. An analysis of the overall flotation cell performance showed that the overall copper recoveries were very similar for the conditions tested. However, by decoupling pulp effects from froth effects it was possible to evaluate whether the changes made affected the pulp zone and/or froth zone responses. The analysis showed that the overall recovery has the potential to be up to 7% higher, if not limited by froth recovery. The cell hydrodynamics were characterised by the overall energy dissipation rate and, to understand the distribution of turbulence within the cell, localised measurements were made using a piezoelectric vibration sensor. By comparing the metallurgical performance of the cell with the different hydrodynamic conditions it was found that the collection zone flotation rate constant was not directly related to overall energy dissipation, as is commonly observed at laboratory scale, where energy is usually only changed by varying impeller speed. In this study, energy dissipation rate was varied using not only impeller speed, but also the size of the impeller and the cell aspect ratio. In these circumstances, the best correlation was found to be between the collection zone flotation rate constant and the distribution of turbulence, i.e. the size of the turbulent zone."

Jan 1, 2014

By J. Bouchard, Ali Vazirizadeh, R. del Villar

"The amount of water reporting to the concentrate correlates well with the solid entrainment. It is well known that the frother and collector dosage as well as the froth depth and gas rate influence the amount of water reporting to the concentrate. This is also true for gas dispersion properties such as gas holdup and bubble surface area flux. On the other hand, a positive bias rate, required to reduce hydraulic entrainment, also affects water recovery and thus the particle recovered by entrainment (depending on the their size). Up until now, the effect of the gas rate on the water recovery has been studied, but no comprehensive investigation on the gas holdup, bubble size and bubble surface area flux has yet been reported. This research precisely aims at addressing this issue. The experimental work was carried out under a constant gas flow rate to eliminate the gas volume effect, while other gas dispersion properties have been varied by modifying the frother concentration and the shearing water introduced to the frit-and-sleeve sparger. A constant froth depth and no wash water were used, in order to be able to evaluate the exclusive correlation between the water recovery and the bubble surface area flux and/or the bubble size. It is worth mentioning, that the particle size of the hydrophobic particles did not show a significant effect on the amount of water going to the concentrate. Not surprisingly, experimental results demonstrate that water recovery increases with the bubble surface area flux and with the gas hold-up."

Jan 1, 2014

By M. L. Torem, R. H. Rojas, A. G. Merma

"Fine particle recovery by conventional flotation processes is very low mainly due to the low probability of bubble/particle collision and adhesion. In order to solve the problem of low particle recovery, several flotation technologies have been developed to increase bubble/particle collision efficiency. Among these technologies, the electroflotation process stands out. This process has advantages in the generation of microbubbles (<100 µm) and in the production of different amounts of hydrogen and oxygen microbubbles. These advantages favorably influence the fine particle floatability, due to the greater probability of particle/bubble collision and adhesion. The electroflotation tests were conducted for a hematite/sodium oleate system in a Partridge-Smith modified electroflotation binary cell of 0.38 L usable volume. The sodium oleate concentration, particle size, pH and current density were evaluated. Satisfactory results in the recovery of hematite were found at pH values of 7, reaching hematite floatability of 99% and 90% with hydrogen and oxygen bubbles, respectively.INTRODUCTIONThe flotation recovery of fine and ultrafine particles is normally very low and is caused by several factors, among them, the low probability of collision and adhesion bubble-particle, the difficulty to overcome the energy barrier (entrainment and entrapment), low selectivity, surface oxidation and mineralogical changes (Schulze et al., 1989; Waters et al., 2008; Shahbazi et al., 2010). This problem can be overcome by decreasing the bubble size or by increasing the apparent particle size. However, it is worth noting that the use of small bubbles or micro bubbles also involves some disadvantages such as their low momentum resulting in a slower process comparing with conventional flotation. Electroflotation is an attractive alternative for treating fine particles with small bubbles less than 100 µm, generated by the electrolysis of water. Electroflotation is one of the variants of the flotation process, where the gaseous phase is produced by electrolysis of an aqueous solution, generating oxygen and hydrogen bubbles (Sarkar, 2010; Gupta and Ali, 2012). These smaller size bubbles allow the recovery of fine particles by increasing the collision efficiency. This process is versatile and competitive in relation to other techniques such as dissolved air flotation and dispersed air flotation because the electroflotation units are smaller, more compact and require less maintenance and less operating cost than other flotation units (Zouboulis and Matis, 1995,). In addition, the electroflotation process is a clean technique and provides results in a short time, requiring only the investment in the electroflotation cell construction stage and the choice of the electrodes (Ketkar et al., 1991; Sarkar et al., 2010; Sun et al., 2011). In this sense, this study assesses the effect of pH, particle size and sodium oleate concentration on electroflotation of hematite fines."

Jan 1, 2018

By H. Gallardo, J. Yianatos

Flotation is a separation process in which mineral recovery depends on the particle surface properties. The selective collection of particles by air bubbles requires hydrophobic mineral surfaces. Hydrophobicity can be selectively induced on a valuable mineral surface by means of reagents. For this purpose, it is required that mineral grains in the ore become physically liberated or exposed in the particle surface after grinding. The grinding process generates three types of particles according their exposed surface in the floatable mineral: locked particles (0-10%), associated particles (10-90%) and liberated particles (90-100%). Locked particles have low floatability, and they typically show low recovery (<20%), while liberated particles have a high floatability and can be easily recovered (98-100%) at different particle sizes (10-150 µm). The main challenge in the flotation process is the recovery of associated particles. These particles typically have recoveries of 20-80%, but strongly depend on the particle size, particle surface liberation and collector dosage. Recent studies on particle floatability by size-liberation have significantly contributed to improving the characterization of flotation processes. In this work, a study of flotation recovery of associated particles of 10-90% liberation is presented for particle sizes (10-150 µm) and collector dosages (5-40 g/ton). In this work historical data on galena recovery based on particle cross-section composition of galena was used, assuming they represent an acceptable estimate of particle surface composition, as shown by some previous researchers. The results showed that galena recovery can be well represented by a model consisting of the interaction of a linear function and a Gamma distribution function to account for the liberation and the particle size effects. Consequently, an alternative approach for modelling the recovery of associated mineral (10-90% liberation), with a reduced number of parameters, was developed and validated.

Jan 1, 2018