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By Q. Dong, S. A. Nightingale

An investigation has been carried out to assess the effects of an applied voltage on the dissolution rate of MgO refractory in a steelmaking like slag. In this study corrosion results obtained from dip tests using a dense direct bonded MgO refractory in a CaO-SiO2-Fe2O3-FeO-MgO slag are presented. These results demonstrate that the application of a voltage across a dense MgO refractory-slag interface can change the rate of refractory dissolution. For the slag composition used and the voltage range tested, it was found that a maximum corrosion rate was obtained at a voltage setting of -0.45V. The results of this investigation have been explained in terms of voltage affects on Marangoni (interfacial tension induced) stirring and its effect on the MgO dissolution reaction that is at least partly controlled by mass transfer in the slag.

Jan 1, 2004

By G. T. Fisher

A continuous process is used at Phelps Dodge Sierrita Inc. to produce copper sulfate pentahydrate via a solution extraction ? crystallization approach to supply the animal feed market. A review of the fundamental concepts of the process and unit operations is presented. Improvements in the process are aimed at achieving a controlled size distribution of product crystals (-40+80 mesh) with minimization of fines by primary nucleation and crystal breakage. An independent temperature control design was implemented for the heat transfer medium (water) in each crystallizer, albeit using common headers in and out of the chiller. This design was developed to maintain a controlled degree of supersaturation in each vessel while preventing localized spontaneous nucleation of fines and reducing encrustation of the heat transfer surfaces in each crystallizer. A model was developed to calculate the heat load and heat transfer coefficient of each crystallizer along with the saturation copper tenor as a function of temperature and free acid.

Jan 1, 2007

By K. Koyama

As a study to establish a new energy-saving copper recycling process, the copper deposition at a cathode and oxidation of copper(I) at an anode from ammoniacal alkaline solutions containing Cu(I) or Cu(II) were investigated in order to examine the feasibility of electrolysis in this solution.. The current efficiencies were greater than 95% in the current density range of 200 to 1000 A m-2. The current efficiency decreased with the increasing Cu(II) concentration and temperature. In the batch-type electrolysis at the anode, during the initial stage, the current efficiencies were 100%, and the anode potentials ranged from 0 to 0.15V vs. SHE at a current density of 100 A m-2. During the subsequent stage, the current efficiency decreased with time, and the anode potential was around 1.35V vs. SHE where oxygen evolution at the anode surface was observed. As a result, the present electrolytic method can be the core technology in the said copper recycling process.

Jan 1, 2007

By V. Pouyafar

Semi-Solid metal alloys, as used in SSM processing, have a special microstructure of globular solid particles suspended in a liquid matrix, which makes them behave differently in forming processes. The sensitivity of semi-solid slurries to temperature variations and their history and rate dependant behavior, make process design and control difficult. Precise selection of the process parameters is necessary in part production. Therefore, a numerical analysis and simulation of the process can be a valuable tool in process design. In this work we proposed a structural dependent model to account for the thixotropic behavior of semi-solid metals. The parameters of the model were then determined using rheometery tests. The results show a good agreement between the model and the experiments.

Oct 1, 2011

By R. A. Nemchek

Over the years, concentrator plant design has evolved from a large number of small grinding mills to a small number of large mills. In many cases, all of the tonnage runs through a single mill (typically a large SAG mill), so that the plant’s performance hinges on the productivity of this one machine. Industry specifications attempt to address the critical nature of today’s grinding mills in a manner that is often overly complex, neglects economics, and is not clearly focused on the end user’s goals. This paper surveys current industry practices, and proposes an improved approach to standards writing recognizing that product design, procurement, manufacturing, and quality are all inter-related in contributing to a project’s success. The lessons learned here can be extended to specifications for all types of machinery.

Jan 1, 2012

By J. E. Gebhardt

Advances in computational modeling provide unprecedented process simulation tools for the process engineer to examine and explore options for optimizing heap leach operations. A phenomenological model developed within a computational fluid dynamic software framework provides a general heap leach modeling tool that describes reactive dissolution and fluid flow through the stockpile. A one-dimensional form of the model is used to parameterize the kinetic leach reactions for a mixture of copper sulfide and oxide minerals against data from operational leach tests. A two dimensional version of the model provides a means to investigate the effects of irrigation rate, lift height, air injection, bacteria limitations, and other factors on recovery and pregnant leach solution concentrations. The model was calibrated for the Nifty Copper operation and ore type in order to simulate heap performance. Model simulations are reported for the chalcocitetype ore and compared to process data. The application showed that the multidimensional nature of heap leaching causes heterogeneous effects that are not always adequately described by one-dimensional models. Irrigation flow rate and aeration effects were simulated for a multi-lift heap section, and model results indicated that air injection at the base of the second lift would be required to achieve expected copper recovery under these lift height and flow conditions.

Jan 1, 2007

By Robert D. Irvine

"Enhanced concern for protection of the environment and attendant actions by environ-mental regulatory authorities in support of this concern are influencing, to varying degrees, the demand and supply of a range of industrial minerals in a number of jurisdictions. These influences take a variety of forms.In this paper, the author seeks to delineate certain broad trends which are occurring relative to industrial minerals and the environment and then, through a series of examples, to outline opportunities, developments, and impacts respecting a number of industrial minerals produced and consumed in Canada and the United States."

Jan 1, 1996

By Anthony T. Eyton

Intelligent Systems: Advantages for Mining ? Increased safety (reduced risk to workers) ? Increased productivity (reduced downtime) ? Reduced maintenance costs ? Customized solutions for different mines ? Growing acceptance among mine managers A Typical Precarn Project ? Meets definition of intelligent systems ? Involves at least two Precarn members ? a technology developer partner and a user partner ? in a true collaboration ? Involves at least one university and may have various other players ? Leads to a demonstrated prototype ? Costs $2-4 million, and lasts 12-30 months ? Gets up to 40% of its funding from Precarn (max. $1 m) ? Produces new intellectual property -- owned by the project team

May 1, 2002

Everybody would agree that a good roadway leads to more efficient haulages by reducing haul times, smoother and safer operation for operator and less wear and tear on tires and equipment, thus improving availability and overall costs efficiency. There is a number of factors that come into play to achieve this especially when developing a mine. Excavations of Ramps and Headings: Operators should follow surveyors and layouts accurately while driving ramps. To maintain constant grades on ramps, which leads to better design control of water and easier grading of roadways. Dips and dives lead to needless over excavations and unnecessary cost and disposal of waste rock. When dressing a ramp some areas may require 2 to 3 feet of material to correct the dips and perfect to constant grade. You may ask yourself, is this all necessary? A small exercise is to follow a loaded haulage truck up ramp. At the first hump, grade change, notice the down shift and notice how far the truck travels to regain the up shift and his speed. The difference is remarkably noticeable when the grade is constant. All this leads to less driveline shock, less horsepower demand, better fuel efficiency and more productivity. Drill & Blast Patterns to control water for Ramp Headings: The drill pattern needs to allow for a ditch. A slight cross fall to form a ditch can easily be done with the lifters. The preferred side of the ditch is always the inside curve of the ramp as it has less tendency to erode roadbed material. On a level, the ditch is dictated by the sump location. A blasted ditch will eliminate water pounding and keep the roadbed dry. Water trapped in roadbed is the major cause of rollout and de-stability of roadbed. If the water is allowed to drain in the middle of the ramp it will cause erosion, movement and loss of fines and an increase in grading intervals.

Feb 1, 2008

By Michel Ruel, Ali Soltanzadeh

This paper describes how to make advanced control choices when difficult processes need improvement. The decision-making process involves choosing between a rules-based approach and a model-based approach as well as weighing benefits and drawbacks, complexity and simplicity, investment and results. This paper will present briefly each solution: basic control, advanced regulatory control, model predictive control and expert systems such as fuzzy logic controllers and neural networks. Three examples are presented: ARC (Advanced Regulatory Control) on pH in a comminution circuit, MPC (Model Predictive Control) for combustible management and FLC (Fuzzy Logic Control) on a Semi Autogenous Mill. The article then proposes a decision tree for selecting the most appropriate approach. A table will compare usage, development, commissioning, maintenance and lifecycle costs for each approach. Finally, conclusions and suggestions will summarize the methodology.

Jan 1, 2014

By E. P. Cadwell

"Throughout the years Cyanamid has been a supplier of cyanide and a supplier of information to the mining industry. In general, the knowledge of mineralogy is greatly overlooked. Mineral deposits in the Western hemisphere have been exceedingly rich in the past but now they are becoming poorer. In other words, we will have to use our talents to the utmost to extract the precious metals and base metals from these ores. Modifications of some of the mineralogical equipment displayed here belong in the mill.Cyanidation of copper has been one of the main projects in our labs in recent years. De-rimming or de-filming of copper in order to upgrade copper concentrate was the main aspect investigated. A study was made as to how wide spread was the filming of secondary copper on pyrite, and to what extent it affected the copper industry. It was very wide.Often there is no conception as to what the minerals are. One open pit copper producer with a chalcopyrite ore was producing a copper concentrate with a 5% copper value whereas chalcopyrite contains 35% copper. They used primary and secondary grinding and a regrinding section. The ore contained about 8 parts chalcopyrite to one part of other copper minerals. In tests, a 3 1/ 2% copper rougher concentrate, cleaned without regrinding but conditioned with cyanide for a low contact time of 30 seconds produced a 30% copper concentrate with 90% recovery by removal of the film. It was of utmost importance that some quantitative mineralogical analysis be made before flow sheet changes were made. Every man should be trained to do his own microscopic examination in order to get quick answers. The fundamental thing in all mineral dressing is to first of all know the minerals and the mineral associations."

Jan 1, 1964

By R. F. Favreau

"After a blast, the volume of the blasted rock normally occupies more space that it did before the explosion. The degree of such swell significantly affects the efficiency of digging the muck with a shovel or dragline. This paper explains why swell occurs, and describes the new subroutine SWELL of the blast simulator BLASP A which can simulate blast-induced swell. Results are also presented which display the effect of various blasting parameters on the degree and distribution of the swell within the muck pile of a bench blast. IntroductionIt is a common opinion that fragmentation is the most important of the various aspects which affect the efficiency of excavating rock with explosives. This paper proposes that, in fact, displacement and swell of the blasted rock are as important as fragmentation if the excavation process is to be rapid and efficient. It must ""a priori"" be recognized that a minimum degree of fragmentation is indeed necessary. For a given shovel or dragline, this minimum degree of fragmentation may be defined as follows: even the largest fragment of rock must be easily contained within the bucket. Once this criterion is met, however, there are good reasons to believe that displacement and swell take over as the key criteria which influence the rate of mucking, in cubic metres/hour. If the muck pile is not well displaced and swelled, the teeth of the bucket have difficulty penetrating between the rock fragments even if fragmentation is good and, as a result, the mucking is slow and inefficient. The purpose of this paper is to use computer simulations on the model BLASP A to demonstrate the effect of the blast design parameters on the displacement and swell of the blasted rock."

Jan 1, 1993

By S. A. J. Hopper

"The Golden Manitou mine is in the northeast quarter of Bourlamaque township, Abitibi county, Quebec. During the summer of 1937 a body of gold-silver-zinc ore was outlined in a series of diamond drill holes located to the west of an old copper-zinc showing in the property of Quebec Manitou Mines, Limited. In 1938, a shaft was sunk and the orebody further explored from levels at depths of 210 and 360 feet.In 1941 the western half of the Quebec Manitou property was acquired by a new company, Golden Manitou Mines, Limited, and the installation of a mining and milling plant was at once undertaken. Milling started in August 1942. The following is a summary of production to December 31, 1946:The orebodies are sulphide replacements in a sericite schist shear zone. They vary in width from 8 feet to 65 feet and range in length up to 850 feet . Much of the ore is of the 'massive sulphides' type . The sulphide minerals in the ore are pyrite and sphalerite with minor quantities of .galena, tennantite, chalcopyrite, and arsenopyrite. Native silver (as wire and leaf silver) has been found in vugs and as coatings along fractures. In one section of the mine a few specks of gold were observed. Spectrographic analysis of ore samples has indicated the presence of zinc silicate."

Jan 1, 1954

By U. Troncoso

Mantoverde is a heap leach-SX-EW operation that was commissioned in December 1995 at a production rate of 42,130 ton of copper per year and 5.4 million ton of ore per year. Copper production has been steadily increased to reach 62,000 ton in 2005. The forecast copper production for 2006 is 60,300 ton for an ore treatment rate of 9.5 million ton. A first dump leach operation was started in 1999 at a production rate of 1,922 ton of copper. A second dump leach operation was started in early 2002 at a production rate of 2,805 ton of copper. Dump leach production will be increased over time to as much as 24,000 ton of copper. Several improvements in the heap leach process have been implemented to cope with the higher ore throughput and copper production. However, the solvent extraction plant has remained unchanged which has resulted in a lower availability of raffinate solution and, as a consequence, in longer leach cycles. Different studies have been undertaken in order to optimize the solution management system at Mantoverde, including column test work aimed to reduce the leach cycle and solvent extraction plant modifications aimed to increase the raffinate solution availability. The test work program and the economical evaluations carried out, as well as the conclusions and recommendations obtained, are discussed in this paper.

Jan 1, 2007

By Donald A. Cranstone

Donald Cranstone holds B.Sc. (Honours) and M.Sc. degrees in Geology from the University of Manitoba and a Ph.D. in Economic Geology from Harvard University. He has worked as a mine geologist, a provincial geological survey geologist and as a senior exploration geologist. He joined what is now the Minerals and Metals Sector of Natural Resources Canada in 1971, where he has been a commodity specialist for gold, for copper and another 28 metals. He is a senior mineral economist, currently engaged in analysis of mineral exploration and discovery success in Canada and of the future of the Canadian mining industry. Abstract This paper examines the history of Canadian non-petroleum mineral production. The outlook over the next 25 years, for mining in Canada and in each province and territory, is reviewed. The outlook for mining in Canada and in most provinces/territories is favourable, but problems seem likely in a few jurisdictions unless new orebodies are brought into production. In terms of exploration potential, Canada consistently ranks among the top three countries in the world. Over the last eight years, Canada has consistently been second only to Australia as a destination for exploration investment. For the first time, Canada is ranked in terms of total mineral production, including coal and construction materials, relative to all the countries of the world including countries of the former communist bloc.

May 1, 2001

By T. Hartmann

The presence of crud represents a permanent challenge for solvent extraction in the hydro-metal industry. The crud is a stable emulsion which slowly spreads along the phase boundary between the aqueous and organic phase. The crud can significantly impair the efficiency of hydro-metal extraction because the phase boundary between the aqueous and organic phases assumes substantial proportions, and the settlers cannot react flexibly. In a chain reaction, all settlers connected in series become infected with crud. The transfer of organic phase to the electrowining (EW) cell can cause 'cathode burn'. Continuous treatment of the crud is extremely effective and reliable with a 3-phase separating solid bowl centrifuge. All three phases are separated distinctly from one another. All associated process steps exhibit a steady uniform efficiency. First and foremost, they ensure a reliable, continuous extraction process and, second, they recover valuable re-usable organics from the crud.

Jan 1, 2007

By E. Roman E.

A novel anode slime purification process was developed and tested at pilot scale in the Chuquicamata Refinery. The process consists of three main stages: First, an atmospheric alkaline leaching at 90°C, under controlled pH and ORP operation parameters where metalloid impurities are preferentially removed from the anode slimes with high efficiency. In a second stage, alkaline washing of the mud leached with addition of reducing agent, with the intention of reducing the silver of the AgCl to metallic silver releasing the chloride, and finally, copper and other remaining impurities are leached out in mild conditions (60°C, one hour in sulphuric acid). In a side process Se, Te, and Sb are recovery with high efficiency from the alkaline liquor as chemical grade products. The global balance shows a high mass loss yielding a final product with high precious metal and low impurities content showing advantages in both a technical and economic point of view with a clear environmental sustainability. This treatment allows either the direct sale of the purified anode slimes or its pyrometallurgical treatment to obtain metal doré without emissions of Se, Sb and As. Chemical mechanisms for this novel process are also described.

Jan 1, 2007

By Bish Chanda

In the minerals business, like any other commodity-based business, management faces the daily challenge of holding down costs while the real prices of products are continually falling on an inflation-adjusted basis. Since the marketplace sets the prices, often without any premium attached for product quality, being one of the lowest-cost producers is the most viable competitive strategy. Continuous improvement is the mantra that can make the difference in terms of long-term survival of a mining company. Yet, this message has not always been followed, especially during periods of prosperity ushered by high commodity prices. More often than not, the need for improvement is only triggered by a crisis. This may be caused by events such as the onset of a severe economic recession, a prolonged oversupply situation due to an optimistic expansion of capacity during the period of prosperity, or simply falling profits alerting management to bring costs under control. At that time, there would be a need to implement a new cost-saving program, bring in a consultant to find ways to reduce costs, or re-activate an old program that had been shelved for some time.

May 1, 2003

By N. Hiroyoshi

In the leaching of chalcopyrite with sulfuric acid solutions, the copper extraction rate reaches a maximum at a given redox potential. This article reviews our studies on the determination of the optimum redox potential for chalcopyrite leaching. Shaking flask and column leaching experiments for a chalcopyrite concentrate were performed under various conditions, and the results were analyzed using a normalized redox potential defined from a reaction model assuming the formation of an intermediate CU2S from chalcopyrite. Factors, such as metal ion concentrations, solid/liquid ratio, and presence of iron-oxidizing bacteria, caused significant variations in the copper extraction versus time plots. However the copper extraction rate versus normalized redox potential plots were independent of the above factors and the copper extraction rate reached a maximum at the normalized redox potentials around 0.43. Converting the normalized redox potential to the solution redox potential gives the optimum redox potential for chalcopyrite leaching as a function of cupric and ferrous ion concentrations. This semi-empirical equation can be used to predict the optimum redox potential during leaching operation, and is useful to design the redox-controlled heap leaching for chalcopyrite.

Jan 1, 2007

By George McIsaac

This paper discusses the formulation of a linear program with the objective of maximizing the cash flow of the long-term plan of an underground operation. A mine is split into eleven independent ore zones, each characterized by its reserves, required development and mining method. Based on practical considerations, maximum rates are set for each zone?s development and production capacity. As for the total mine plan, a minimum daily production rate is set along with a minimum feed grade to the mill. A maximum number of development metres per day is set based on the equipment and labour available. Proven and probable ore is mined preferentially over possible ore in the early years of the plan. Furthermore, the fixed cost of operating the mine is taken into consideration whenever mining activities take place. Once the linear program is solved, it can be critically reviewed, and unrealistic results can be identified. Some resource allocations constraints can then be changed in certain sectors, and new results can be analysed. What-if scenarios can also be examined, such as determining the impact of hiring a contractor to develop a given sector, or dropping an ore zone completely from the plan.

May 1, 2003