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By R. T. Seaman

There are several hydrometallurgical alternative processing options under development for high enargite and arsenic containing copper concentrates ranging from biological, atmospheric, medium temperature oxidation to total oxidative leaching. The most developed of these options is the CESL process boasting pilot campaigns totaling more than 8760 hours of fully integrated continuous operation, as well as, over two thousand batch scale oxidation tests performed on dozens of concentrates for flowsheet development. This paper reports the observed deportment of arsenic under varying arsenic, iron and acid oxidation conditions; it also describes the impact of iron to arsenic ratios and residue recycle on overall arsenic behavior and its stability in residue. INTRODUCTION The CESL Hydrometallurgical Process (CESL) was originally developed to compete with smelting of clean chalcopyrite concentrates. High Treatment Charges and Refining Charges (TC/RCs) combined with premiums on London Metal Exchange (LME) grade copper from onsite refining made treatment of copper concentrates using CESL a viable option at the time. As world demand for copper increased and a subsidized Chinese refining market developed, smelting contracts became more favourable for the miner and focus was placed on modifying the CESL Hydrometallurgical Process to handle concentrates with elevated deleterious elements. Dozens of pilot campaigns processing concentrates containing elevated concentrations of uranium, fluoride, mercury and nickel all led to further developments of the CESL Hydrometallurgical Process. In 2016 a United States patent was granted for a novel modification of the CESL Hydrometallurgical Process for recovery of copper from arsenic-bearing and/or antimony-bearing copper sulphide concentrates, Henry Salomon de Friedberg (2016). To date, over 2000 bench scale tests along with five fully integrated closed loop pilot campaigns, totaling over a year of online operation time, have been conducted processing arsenic bearing copper concentrates. This paper summarizes the observed behavior of arsenic under varying autoclave and process conditions.

Jan 1, 2019

By M. S. Ünal

Creation of 3D model of coal seams is a tedious and time consuming operation. Computer aided 3D solid modelling of coal seams can be performed in a fast and detailed manner. However, in case of having tectonically disturbed coal seams where faults may be observed, expert opinion is necessary to decide the geometry of the coal seam. The aim of this study is detection of fault zones with computers by using drill hole data. Firstly, a digital database is generated by using the drill hole data. Surface models of the layers are produced by applying triangulation method on coal seam roof elevations. The generated surface is divided into small squares and consequently dip and dip direction values are calculated for each square. Variograms for dip and dip direction are determined and maps showing the variation of dip and dip direction are generated by using geostatistical methods such as kriging and co-kriging. Examination of disconformities observed on estimation maps created by kriging and co-kriging clearly reveals the extension of faults. The method used in this study is applied to detect fault lines of a known mine field. 3D solid modelling of the coal seam has also been performed by using conventional cross-section method. The results of both methods were in good agreement. Identification of major faults by using the method introduced in this study could certainly simplify 3D solid modelling of coal seams.

Aug 1, 2013

By J. B. Edwards

"The case is presented for the use of simulators for the computer-based training (CBT) of mining plant operators and for introducing them to automatically controlled systems. As well as their use in the classroom, the role of simulators is examined for ""on-plant"" use in trouble-shooting, fault-finding and maintenance of automatic systems. Case studies are presented showing how specific simulators are becoming established or have potential in the areas of automated materials handling, machine testing, setup and guidance. The evolution of scientific simulations into simulators of widespread practical use is discussed and present-day limitations of computer speed and graphics are considered. Related areas of research for the Canadian Centre for Automation and Robotics in Mining (CCARM) are identified.IntroductionCCARM's Commitment to Simulator DevelopmentAs automation is progressively developed and exploited in mining operations, there arises an urgent need to educate and train staff responsible for its introduction and operation in our mines and for its maintenance. For this purpose , an essential ingredient of an automation program is the development of appropriate mining system simulators for use by a wide variety of personnel. The author has been fortunate to have been closely involved with the development of automatic control systems for a variety of mining machines and mining systems in the United Kingdom. A key ingredient of the research phase in each case has been the use of simulation techniques. As projects have moved toward their commissioning and exploitation phase, the simulations have evolved into simulators tailored for use by machine operators and maintenance personnel. Illustrative case studies are presented later. The researach of the newly constituted Canadian Centre for Automation and Robotics in Mining (CCARM) will likewise involve extensive simulation, and the development of simulators (from the scientific programs) for use at the mine by operators and technicians will be given high priority in the Centre's over-all work program."

Jan 1, 1990

By PAULL. BROUGHTON

Commercial deposits of sodium sulphate are harvested from alkaline lakes that are widespread throughout semi-arid southern Saskatchewan and adjacent southeastern A lberta. Concentration of sodium sulphate occurs in undrained basins under semi-arid conditions. Precipitation runoff from land adjacen1 to 1hese basins leaches 1he mineral from the soils and carries it in solu1ion 10 the basins. The process may be largely subsurface, wherein spring seeps feed basins associated with buried (preg/acial) river valleys. Evapora1ion during summer concentrates salts in the brines, and chilling of water below sa/Uration poin1 during win1er resu//s in deposi1ion of sodium sulpha1e (mirabili1e) crystals on lake bo//oms. Sodium su/pha1e, commercially known as sa/1 cake, ranks second only 10 po1ash in cen1ral-wes1ern Canada's nonme1allic mineral production. // is recovered from su,face brines, directly from intermittenl salt beds, and, until recently, by solution mining of shallow subswface deposits. Sodium sulphate is extrac1ed from seven alkaline lakes and sail f/a1s in Saska1chewan and one in Alberta. Annual produc1ion is approxima1e/y a halfmillion tonnes. Manufacture of kraft paper is the mos1 significanl marke1 for salt cake, but addi1ional quantifies are used in the glass and detergent manufac1uring indus1ries.

Jan 1, 1984

The introduction consists of back-ground information, of an historical and statistical nature, relating to the Thompson mine. The geological presentation is based on illustrations that are intended to provide a progressively closer look at the ore occurrence. The illustrations consist of an index map, a geological map of a 15-by 85-mile area including the Thompson mine, a series of four maps dealing with the geophysics and geology of a 6-by 4\f.j-mile area at Thompson, a mine level plan and corresponding section, two sto11e 11lans and corresponding sections, and photo-graphs and photomicrogra11hs of the various one types. T HE Thompson mine is located about 400 miles due north of Winnipeg. The ore deposit was dis-covered in February, 1956. Five years later on March 25, 1961, the Thompson production facilities were officially dedicated with the shearing of the first nickel produced at the Thompson refinery. Full production, at an annual rate of more than 75,000,000 lbs. of refined nickel, was attained later in the year.

Jan 1, 1963

By Y. Rama Murthy, Amit Ranjan, Pankaj Satija, Sunil K. Tripathy

"Chromite ore is one of the essential raw materials for ferroalloy and steel industry. Boula-Nuasahi belt of Sukinda region, Odisha, is the only resource of chrome ore in India. The Indian deposits are typically characterized as ferruginous and siliceous type ores. Chrome ore is generally mined by open cast mechanized mining method in these areas. The run-off-mine (ROM) ore from the various mines is sent to beneficiation plant via stack yard for further up gradation. The chrome ore beneficiation plant (COB) has two major circuits: comminution (feed preparation) circuit and beneficiation circuit. In the comminution circuit, the ore is reduced to <1 mm size ( for complete liberation of chromite) from -220 mm size in stage wise crushing (primary and secondary crusher) followed by screening and single stage grinding in a ball mill. Fraction having size <1 mm is further upgraded in the beneficiation circuit to produce three different concentrates having specific chemical composition and Cr: Fe ratio. The beneficiation plant is a complex circuit comprising of combination of unit operations (spiral concentrator, Floatex density separator, hydrocyclone, wet shaking tables). In the recent years the overall performance efficiency (grade and recovery) of the beneficiation circuit got affected with numerous changes in the run-off-mine ore quality (physical and chemical), mineralogical composition, etc.In this article, attempts made for improving the performance of chrome ore beneficiation circuit is discussed. The approach adopted and practical problems encountered while the process were also highlighted. The results of the trials has shown an improvement in the performance of the cyclone (d50 : 56 µm – 40 µm) and chromite losses into tailing to <12%.INTRODUCTIONChromite has a wide range of application, from refractories to metallurgical industries, and from chemical to non-ferrous alloy industries. Chromium ore (Fe2+, Mg) [Cr, Al, Fe3+]2O4) occurs exclusively in rocks formed by the intrusion and solidification of molten lava or magma which is very rich in the heavy, iron containing minerals such as pyroxene and olivine. With the richness of silica and iron, the chrome ores are broadly classified as siliceous type and ferruginous type. Pure chromite with composition FeCr2O4 is rare because magnesium usually substitutes for ferrous ion and aluminum and ferrous ion substitutes for chromium. Generally the associated gangue minerals are talc, quartz, hematite, goethite, limonite, gabro, serpentine, anorthosite, dunite, pyroxinite, etc. Around 96% of the chromite ore production is consumed for metallurgical applications of which 94% is converted into different grades of ferrochrome i.e., high carbon ferrochrome and charge chrome as shown in Figure 1. Stainless steel being the leading consumer of ferrochrome, any change in the dynamics of the stainless steel industry impacts overall chrome ore demands significantly."

Jan 1, 2016

By C. Prévost, V. Leclerc, R. Pinto, M. Ruel

"A buffer’s ability to dampen production variations is directly related to its size. Small buffers cannot handle large variations in production, resulting in production losses when their inventory is depleted or saturated. This paper presents a predictive control algorithm used to regulate the inventory in a buffer of limited size, subject to large production variations caused by an upstream batch process. The algorithm was designed to manage the acid flow rates in an acid regeneration process, servicing batch leach reactors at Rio Tinto Fer et Titane, in Sorel-Tracy, Québec. The objective was to increase production by reducing equipment downtime caused by imbalances in the acid tanks servicing the leach reactors. The controller attempts to maintain acceptable acid tank volumes by optimizing the leach reactors acid/slag ratio and reaction time as a function of anticipated acid needs, all while maintaining product quality.INTRODUCTION Some beneficiation processes in extractive metallurgy require processing bulk material in batches. Typical examples of metallurgical beneficiation batch processes are smelting, leaching, electrowinning, elution and carbon-in-pulp. These processes are often situated midstream in an ore beneficiation flow sheet and either receive or transfer ore to continuous processes. Batch processes, by their very nature, introduce large variability in the flow sheet, because they process large finite quantities of material at nearly periodic time intervals. In order to dampen variations in production, various buffers–tanks and stockpiles–are utilized to accumulate ore upstream and downstream of batch processes. A buffer’s ability to dampen production variations is directly related to its size (Phillis & Gumede, 2011). Small buffers cannot handle large production variations, resulting in equipment downtime when their inventory is depleted or saturated (Everett, 2010, Berton et al., 2013). Consequently, the batch equipment production rates must be adequately managed to minimize production losses, attributed to depleted or saturated inventories, while maintaining product quality. Algorithms that anticipate or predict future production variations are often utilized to regulate buffer inventories, subject to large flow rate variations (Salvo et al., 2002; Bonvin, 2013). This paper presents a predictive control algorithm used to maintain an acceptable volume in a spent acid tank servicing several batch leach reactors. The algorithm is implemented at the acid leach plant of Rio Tinto Fer et Titane, in Sorel-Tracy, Québec."

Jan 1, 2017

The principles and utility of in-situ coal gasification are discussed, and a first field test conducted by the Alberta Research Council in 1976 near Forestburg, Alberta, is described. The test was carried out in a 12-ft subbituminous coal seam under 60 feet of cover. Within this seam, a 30 by 60-foot block , containing approximately 650 tons of coal, was delineated by four injection/production holes which were oriented to take advantage of the natural fracture system in the coal. Linkage between holes was established by reverse combustion and gasification was accomplished by injecting air into the ignited coal. No steam was injected but operating pressures were adjusted to utilize formation waters for partial carbon -steam gasification. The coal gasification runs lasted six weeks and gasified an estimated 900 tons of coal ,&apos; during sustained periods of gasification, a fuel gas with heating values of between 110 and 150 Btu/scf was obtained. Plans are now being developed for excavating the test site and inspecting the subsurface cavities created by gasification.

Jan 1, 1977

By P. E. Davidson

The management of solid waste is known to be a large and increasing problem in high-population areas throughout the world. It is not necessary here to add further definition to the nature and magnitude of the problem. Instead, it is the purpose of this paper to describe a new process, called the Andco-Torrax System, which will be of use in converting municipal solid waste into useful energy forms and a granulated slag by-product. The paper includes a description of the first commercial plant for the process.

Jan 1, 1977

By R. L. Stanton

"The present contribution is complementary with a preceding one on the field association of the conform-able ""pyritic"" deposits. It considers the more important features of their mineralogical constitution and their microtextures, re-examines the present interpretations of these, and of-fer-some alternative explanations. The term ""pyritic"" for these de-posits is m many cases a misnomer, as two quite distinct ore types are inuolve. One is a banded pyritic sphalerite-galena-chalcopyrite ore (for which the term '•pyritic"" is in-deed quite suitable), while the other is non-banded and is composed essentially of pyrrhotite and chalcopyrite. In addition to these constitutional differences, each is distinctive in general appearance and texture. The occurrence of two such consistent but clearly distinguishable ore types is attributed -rather than to difference in source material and pressure-temperature conditions of deposition -to the contribution of similar source material to dissimilarly oxygenated environments of sedimentation. Textures in the banded ores generally thought to be indicative of replacement or of high-temperature exsolution are explained by slow, law-temperature segregation in situ during compaction, folding, and regional metamorphism."

Jan 1, 1960

By Jacek Paraszczak, Stefan Planeta

"RésuméDans la première partie de cet article on discute Ie contexte technico-économique de l&apos;usage des foreuses à l&apos;eau sur béquille dans des mines sud-africaines. Par la suite on présente les résultats d&apos;une étude comparative du forage avec les foreuses à l&apos;huile et à l&apos;eau par rapport aux foreuses pneumatiques. La performance des foreuses est discutée sous les deux aspects: l&apos;aspect technique concernant Ie taux de pénetration et la quantité d&apos;eau rejetee dans les galeries et l&apos;aspect de fa santé et sécurité au travail, et plus particuliérement, les niveaux de bruit et de vibrations ainsi que Ie brouillard de l&apos;huile. On conclut par l&apos;évaluation du potentiel de forage à I&apos;aide des foreuses hydrauliques dans Ie contexte canadien.AbstractIn the first part of this paper the technical and economical aspects of water-powered drilling are discussed. This technology, originally employed in South Africa, received some interest from Canadian mine operators. In this context a comparative experimental study of pneumatic and hydraulic (oil- and water-powered) jackleg drills has been realized. The performance of the drills is compared and the results reviewed with regards to technical aspects (penetration rate, amount of water spilled) as well as health and safety considerations (noise and vibration level, presence of oil mist). The potential for application of hydraulic jackleg drill is discussed."

Jan 1, 1995

By M. P. Tixier

Abstract In a review of the application of electrical logging in Canada, examples are .given of long and short distance correlations by means of the electrical logs. The use of MicroLogging for the determination of permeable and porous formations is explained. The question of log analysis for the quantitative determination of fluid saturation and porosity is .discussed. An example is provided to illustrate the significance of the resistivity gradient. The advantages of the new method of the Laterolog are shown, chiefly for the case of wells filled with high-salinity mud. Introduction Electrical logging techniques developed rapidly in Canada at the time an intensive drilling activity started for the exploitation of the Devonian series in Alberta, namely, at the beginning of 1947. The conventional service was soon thereafter supplemented with the latest technica1 improvements. Canada has been among the first regions to take advantage of MicroLogging*, which has proved a most powerful .tool for the investigation of permeable and porous formations; also, the more recent development known as the Laterolog has ?been introduced in Canada. The Laterolog provides a better determination of .the formations, particularly in the case of salty mud where the conventional logging is greatly handicapped. The various methods of electrical logging are now commonly known in oil industry and have been described in numerous publications ( 1) ( 2) (3).

Jan 1, 1951

By L. A. Jameson, J. Awmack, P. J. Lind

"Peñasquito is a polymetallic deposit containing gold, silver, lead, and zinc. The operation is currently the largest producer of gold in Mexico. Over the next few years, the process flowsheet will be expanded beyond the flotation of lead and zinc to include flotation of pyrite from zinc tails and subsequent leaching of the pyrite concentrate. This paper outlines mineralogical leach characterization that has been carried out to improve the understanding of the complex hosting of gold and silver minerals in the ore. Organic carbon that is present in the ore can have an impact on flotation and leaching. Mineralogical techniques used to characterize this deleterious component of the ore are introduced.INTRODUCTION Goldcorp’s Peñasquito operation is located in the Mexican state of Zacatecas, approximately 200 km from the city of Zacatecas as shown in Figure 1. Peñasquito has been in operation since 2009 and is currently Mexico’s largest gold mine. Mining is carried out by open-pit methods, with oxide ore proceeding to a heap leach facility and sulfide ore treated in the sulfide processing plant.The processing capacity of the sulfide plant is 130,000 tonnes of ore per day and in 2016 production amounted to 450,000 ounces of gold, 17.6 million ounces of silver, 109 million lb of contained lead, and 263 million lb of contained zinc in lead and zinc concentrates. GEOLOGY The Peñasquito deposit is hosted in and adjacent to two breccia pipes; Peñasco and Breccia Azul. The two breccia pipes are branches of a larger intrusive-related complex, which is hosted in the sedimentary Caracol formation as illustrated in Figure 2. The regional geology is dominated by Mesozoic sedimentary rocks which comprise a thick series of marine sediments deposited during the Jurassic and Cretaceous periods. A 2 km thick sequence of carbonaceous and calcareous siltstones and interbedded sandstones is underlain by a 1.5 to 2 km thick limestone sequence (Goldcorp Inc., 2015)."

Jan 1, 2017

By G. Diaz

Técnicas Reunidas (TR) has been involved for over 30 years in the development of process technologies for the recovery of zinc from different primary and secondary feed materials, such as the ZINCEXTM process. Because of the complexity of the feed mineral resources, solvent extraction (SX) is an invaluable technique to concentrate and purify zinc solutions. When applied to a pregnant leach solution, solvent extraction can produce an extremely high quality zinc electrolyte, suitable for obtaining SHG zinc ingots, after electrowinning and melting and casting processes. However, the high affinity of most organic extractants for Fe(III) poses a serious problem, which may adversely affect the zinc extraction process. Different methods may be applied to deal with the negative effect caused by Fe(III). An acid regeneration step and electro-reduction stripping have been considered as the most viable techniques to remove the iron from the organic phase. This paper describes some findings of Técnicas Reunidas in the area of zinc solvent extraction, especially on removing Fe(III) from the organic phase.

Jan 1, 2006

By J. D. Bateman

Introduction The lifting of restrictions on the development of radioactive mineral deposits by private individuals has re-opened the search for uranium in Canada to a large body of professionally trained prospectors. The entry of private capital and experienced prospecting techniques into the search for radioactive minerals has been enormously stimulated by the atomic developments of the past several years; and we can now look forward to the discovery of new productive sources of uranium. The rate of new discoveries will, how ?ever, depend on the effectiveness of the methods used. The large number of new pitchblende occurrences reported within the past several months is largely a measure of the energy with which the portable Geiger-Müller counter has been applied in the field. The counter is simply a &apos;radio&apos; receiver tuned to one of the products of spontaneous atomic disintegration that is characteristic of all radioactive materials. Its effective use depends largely on how it is applied under the various geological and topographical conditions that ma y be encountered, and also on an understanding of its limitations. Extensive geological information relating to the occurrence of radioactive minerals in Canada has been accumulated during the past several years, and it is now possible to define in a general way many of the geological formations in which pitchblende and related minerals are likely to occur. Furthermore, prospecting can be localized in those parts of the favourable formations that offer the greater promise of containing commercial deposits. In this selection, the Geiger counter is the most useful tool available to the prospector for the actual detection of radioactive materials. As an example, an area of two square miles in the Northwest Territories, within which about a dozen pitchblende occurrences had been found over a several year period by conventional prospecting methods, yielded more than forty-five additional discoveries by application of the Geiger counter. Yet earlier attempts at prospecting this area with the counter had failed, due largely to faulty instruments and lack of experience in field application. The limitations of the counter are very considerable; but, when they are recognized, there is no more useful tool for the discovery of radioactive ores. It was not until 1944 that a practicable portable counter was developed, and then only by co-operation in the field by geologists and physicists. Officers of the Geological Survey of Canada working with physicists of the National Research Council brought about the development of the modern counter.

Jan 1, 1949

By Aaro E. Aho

Yukon, one of the most potentially accessible, relatively undeveloped, regions of Canada, has major mineral possibilities. The Klondike placer gold fields and the Mayo silver-lead ?district are the sole major producers but large base-metal re-serves have been discovered in re-cent years and important asbestos deposits are now being explored. Several major exploration companies are active in this region despite short seasons, permafrost overburden, remoteness, lack of transportation, and resultant high costs. Pro-posed new roads can be expected to accelerate development. At ?present the major future mineral possibilities are considered to be lead-zinc, copper, aslbestos, silver-lead, gold, and mineral fuels. These and other mineral possibilities are outlined for various geological subdivisions of Yukon. Major favourable metallogenic features of Yukon include complexity of rock types and structures, widening of the Cordillera with cross-trends, and variety and quantity of mineralization found even with limited prospecting. Comparisons with southern &apos;British Columbia and the U.S. Cordillera suggest that further exploration will result in discovery and development of more major ore deposits and reserves which will eventually revolutionize economy of mining in Yukon. Such mineral resources, with interior petroleum and natural gas possibilities, and ?huge coastal hydroelectric power potential, are the foundations of a much larger future mining industry in Yukon.

Jan 1, 1958

By J. W. Meier, J. O. Edwards, R. C. Bell

"IntroductionTHE DIE CASTING industry .as we know it today is the direct result of the invention and development of die casting machines during the nineteenth century and of reliable alloys in the twentieth. The early machines were designed to cast low melting point metals such as lead .and tin, and their alloys.It was inevitable that, as these die castings were put into service, the demand should arise for stronger materials. Zinc alloys, often containing lead, tin, copper, and aluminum as major constituents, were relatively easy to cast and stronger than the lead and tin alloys. However, it became apparent after a number of years that these zinc alloys tended to become brittle, distort, and corrode, particularly if kept in warm, humid atmospheres. Thus, considerable quantities of zinc-base .alloys were in use before the trouble was realized and effective measures could .be taken to determine the cause of the instability.The deleterious effect of certain metallic impurities on the properties of zinc •die casting .alloys has now been known for about thirty years. Brauer .and Peirce, and, later, other research workers of the New Jersey Zinc Company such as Anderson and Werley, discovered the pronouned effect of lead, cadmium, and tin on the stability of zinc-alloys."

Jan 1, 1952

By J. S. Stewart

THIS paper was prompted by a persistent demand for what information we have that will throw light on the oil and gas possibilities of the Maritime Provinces. The problems involved were made familiar to the writer during three seasons of field work in New Brunswick and Nova Scotia. The reasons for renewed interest are: (1) In many parts of that region, the surface is underlain by a thick series of unaltered sedimentary rocks. (2) Oil seepages occur, and oil in commercial quantity has been exploited&apos; near Moncton, New Brunswick, for many years. (3) In recent years, a new method of attack has been developed toward the finding of stratigraphic traps. This method is based on a detailed study of the geological history of the region, as revealed in surface outcrops and samples from deep wells. The well samples show the lateral variation of strata, far from any possible surface outcrop of the same beds. Sufficient work has now been done in the Maritime Provinces to reveal the broad features of the geological history and the character and distribution of the various rock formations. Comparatively little deep drilling has been done in this region, but the holes are widely scattered and the samples from them have added much to the information obtained from the numerous outcrops of bed-rock. The following discussion gives a summary of available information that has a bearing on the subject.

Jan 1, 1943

By G. E. Peacock

SIGMA MINES is situated in the township of Bourlamaque, Abitibi County, Quebec. It is a gold producer, and presently treats an average of 1,200 tons of ore per day, at a grade of approximately 0.18 oz. per ton recovered. The mill started operations in March, I937, at a rate of 300 tons per day. This was increased to 800 tons in I940, and to 1,000 tons by I943. The rate was cut back during the war years, but was brought back up to capacity by I948. The mill tonnage was in-creased to the present 1,200 tons per day in I960. The underground workings are serviced through No. 2 Shaft (Figure 1), which, with 24 operating levels, extends from surface to a depth of 3,317 feet. When depth exploration was decided upon, two possibilities were considered: (a) deepen the main shaft by1,000 feet; (b) put down a winze for the same distance.

Jan 1, 1962

By K. Horikawa, S. Kitahata, H. Kobayashi

"It has been clarified that the Al-5%Mg alloys containing 200 mass ppm of sodium showed grain boundary (GB) fracture, even when tested at room temperature, as well as at high temperatures (~500°C). SEM/EDX study revealed that the GB fracture was associated with the segregation of sodium on grain boundaries of the Al-Mg base alloys. Differential scanning calorimetry (DSC) revealed that the GB fracture at room temperature of Al-Mg alloys was caused by sodium segregation in the solid state. It was also shown that the tendency of the GB fracture strongly depended on the heat treatment; the alloys after the solution heat treatment showed severe GB fracture compared with the alloys after the homogenizing treatment. Moreover, it was shown that the GB fracture at room temperature by sodium segregation was suppressed by the addition of bismuth or indium. The suppression of the GB fracture by the additional elements was believed to be the scavenging effects by forming the sodium bearing compounds in grains.INTRODUCTIONIt is widely known that Al-Mg base alloys containing high amount of magnesium(~5 mass%)show better workability at room temperature, while that the alloys show grain boundary (GB) embrittlement at higher temperatures ranging from 200 to 500°C, depending on grain size(Otsuka, 1984), sodium impurity level(Ransley, 1959, Okada, 1997, Horikawa, 2001)and testing strain rate(Yamada, 2012). In the case of coarse-grained Al-5%Mg alloys (~300 ?m), 2 mass ppm of sodium causes severe GB fracture around 300°C, however, the Al-5%Mg-2ppm alloy does not show GB fracture at room temperature. It has also been shown that the GB embrittlement caused by 2ppm of sodium was suppressed by the additional elements, such as bismuth (Talbot, 1995), antimony (Ueda, 1997) and indium (Horikawa, 2012). Basedon these facts, we have concluded that the GB embrittlement at higher temperatures of Al-Mg alloys is attributed to the synergy effects of GB segregation of atomic sodium and GB sliding. For the GB embrittlement mechanism of Al-Mg alloys, involvement of low melting point metallic phases has been pointed out (Lynch, 2002),since the GB embrittlement appeared only at high temperatures. Up to date, the effects of high amount of sodium addition more than 2 ppm on GB fracture were not fully investigated in Al-Mg alloys. In the present study, the effect of 100 ppm ordered sodium impurity on GB fracture of Al-5%Mg alloys was examined, together with the effect of another additional elements."

Jan 1, 2017