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By R. Stach, S. Gola, P. Zgrzebski, K. Soroko

"The future of Polish copper mines KGHM Polish Miedz S.A. will be associated with mining at depth. At present, technologically advanced measures are being introduced to minimize the adverse influence of the environmental hazards on people working underground. Polkowice-Sieroszowice mine is the only mine in Poland where mining takes place in copper and salt deposits. On the basis of the current and anticipated methods of ventilation of a selected ore deposits the paper will analynze a number of solutions enabling planned mining of copper ore deposit, while minimizing the impact of natural aerological hazards in working areas. INTRODUCTION The future of copper ore mining, carried out by KGHM Polska Miedz S.A., will be based on mining from continuously greater depths (Butra, 2015). It is forecast that this will be accompanied by an increasing climatic hazard, resulting from an increase in the original temperature of rocks of more than 45°C as well as gas and geodynamic hazards (Soroko, 2015; Andrusikiewicz, 2015). Due to the safety of underground teams, a need arises to develop methods eliminating the adverse impact of the natural hazards, down to a level enabling the mining activity to be carried out on an industrial scale while maintaining favourable economic parameters. Current depths of the copper ore deposit being developed are effectively verifying the technical methods and measures employed to date for eliminating the natural aerological hazards. Amounts of air supplied to mining areas, with lengthy transport routes, are becoming insufficient for miners’ temperature safety, whereas increasing the power of cooling air-conditioning stations for cooling the air undermines the economic legitimacy. However, along with the temperature hazard, a significant problem at the current depths is an increase in gaseous occurrences in the headings’ areas. The concentrations of natural harmful gases found, even with the values below the permissible concentrations, in the case of limited amounts of air and/or low airflow rates, may pose a considerable danger to the workers. The hazards referred to are currently the major factors determining the advance of headings, above all in mining sections, being the outcome of geological structure and depth of lying of a deposit. However, at the current depths of mining minerals from deposits, room-and-pillar mining systems employed also have a decisive impact on the increase in natural aerological hazards."

Jan 1, 2019

By John B. Phillips

The mine is entered by a central vertical shaft, strongly timbered, and containing two compartments-one for the passenger cage, the other for the large skips bringing the ore to the surface. A man-way, for emergencies, is also provided, parallel to the shaft. The cage is a single-deck steel box, carrying about thirty persons; by means of arrangements above and below, it can also hoist and lower materials needed in the workings. Levels are run at intervals of 100 feet. In special cases, where the ore conditions warrant, sub-levels are operated, such as those at 1,113 feet and 1,123 feet (Fig. 7), which are connected by winzes with the 11 th level. One of these was pushed for 40 feet, and then abandoned because it was unprofitable to take up ore of the grade encountered. The ore between levels is removed by stoping. The drifts follow the course of the veins as much as possible, with numerous cross-cuts. Winzes, raises, connections, etc., are blasted out where needed. The main drifts are at least 8 ft. high by about 9 ft. wide. All former narrow drifts had to be widened some time ago, by ruling of the Ontario Department of Mines, to lessen the danger of accidents with cars in the small passages. Accurate plans of the under-ground workings are kept in the office, and extensive surveying is always being done underground to keep the maps up to date, measure the cubical contents of stopes, and so forth. Timber is extensively used in the construction of supports and chutes, and in the sinking of the shaft. Steel and concrete are too ex pensive to compete with timber, which 1s abundant in such sections as have escaped forest tires.

Jan 1, 1926

By L. Vu, V. Popov, J. Beland, R. Darling

"The Ferderber gold deposit is of Archean age. It consists of a series of gold-bearing quartz lenses within a shear zone that crosscuts the central part of the quartz dioritic Bourlamaque batholith. On average, this zone strikes N70E and dips 65SE. The Ferderber shear zone, which hosts the ore lenses, has been affected by a succession of tectonic events. A possible early period of brittle shear, accompanied by the formation of quartz lenses, resulted from strike slip movement along the zone. These early quartz veins were subsequently folded and boudinaged during reverse movement that accompanied a prolonged period of ductile shear. More quartz veins were emplaced in the shear zone at this time; these were also deformed by the thrusting. The latest tectonic event to affect the shear zone was a period of brittle fracture.Early dextral strike-slip movement on the shear zone is suggested by the local occurrence of Riedel shears, the preferred association of ore with east-northeast oriented segments of the zone, and by the apparent en echelon arrangement of some ore lenses. The most important event, a reverse movement, is indicatedby the attitudesoffoliation, folds, boudins, COS tectonites and slip planes. The late brittle fracturing formed narrow gouge filled faults, locally flanked by brecciazones, whichrun generally within and parallel to the shear zone, and also conjugate fractures that crosscut the zone.The Ferderber and six other adjacent gold deposits were formed in a structural regime dominated by a generally horizontal north-south regional compression. The Y axis of the strain ellipsoid is east-west and varies from horizontal to a plunge of 25 0 w."

Jan 1, 1987

By G. Mousavian, R. Bagheri, N. Dalili

Polypropylene (PP) and its composites have an increasing use in automobile and domestic industries. Since the published results on strain rate effect on yield behavior do not match, and there is a high attention paid for effect of nanometeric fillers on deformation behavior of composites, in this research the strain rate effect on yield behavior of PP and the effect of nanometeric fillers on deformation behavior of PP have been studied. Microscopic observations and tensile tests in different strain rates on neat PP samples and on samples filled with 5, 10 and 15 %wt have been used. A dramatic change in behavior for the modulus and post-yield slope curves when the strain rate is between 0.0433-0.05 s-1 has been observed. Microscopic observations on PP indicate a change in deformation mechanism from shear yield to crazing at the same strain rate that the change in behavior of curves occurs. It has been observed that in PP nanocomposites with higher amount of calcium carbonate, fracture in early stages of deformation occurs in lower strain rates. In other words for a fixed stain rate there is a critical filler percentage such that if the filler percentage is higher then early-stage fracture will occur. Similarly for a fixed filler percentage there is a critical strain rate and in higher strain rates early fracture will occur. The critical stain rate will decrease as the filler percentage increases and vice versa.

Jan 1, 2006

By F. Chiesa

Forty aluminium A356 castings were poured on a Low Pressure Permanent Mould industrial machine, 500x700mm in platen size. The 152mm wide casting comprised three steps, 25mm, 13mm, 6mm in thickness and a 2.5mm overflow which allowed to assess the thin wall capability of the process. The casting campaign, which produced 40 parts, allowed to test the influence of various production parameters including the time of application of the pressure in the crucible, artificial cooling of the mould and casting rate. The thermal history in the mould was recorded over the 40 cycles, which allowed to construct a reliable thermal model of the mould/casting assembly. The metallurgical quality of castings representative of the various conditions was assessed in the 25mm, 13mm and 6mm plates. This included measuring the level of microporosity, the dendrite fineness (DAS), along with the tensile properties in the T6 condition. The radiographic quality per ASTM E155 was also determined. Modelling filling and solidification allowed to verify the validity of the predictions based on available relationships relating microporosity, secondary dendrite arm spacing (DAS) and local tensile properties (Quality Index, Q) to the local thermal solidification parameters.

Jan 1, 2007

By J. H. Crocket, J. Andy Fyon

"All gold deposits within the Tisdale Group are spatially associated with carbonate alteration zones; however, not all carbonate alteration zones are host to gold mineralization.Within the komatiitic and magnesium tholeiitic volcanic rocks at the base of the Tisdale Group, discordant and stratabound carbonate alteration zones occur throughout. The alteration zones consist of a ferroan dolomite - quartz inner assemblage which is enveloped by calcite-quartz and an outer chlorite-rich subzone. Factors which control the distribution of carbonate alteration include joint systems, flow contacts, synvolcanic faults and bulk composition of the host rock.Two environments of carbonate alteration can be recognized: 1) The subsea-floor alteration zones developed within the volcanic rock succession where hydrothermal fluids did not discharge directly onto the sea floor. Insignificant gold production has come from this alteration environment. 2) Seafloor zones, which represent points of hydrothermal fluid discharge into the hydrosphere, are spatially associated with felsic volcanic rock complexes and are host to syngenetic, auriferous cherty dolomite.Carbonatized, magnesium tholeiitic basalts, which are host to the auriferous, cherty dolomite, are enriched in antimony (>0.35 ppm), boron (>30 ppm), gold (>5 ppb) and lithium (> 35 ppm), but are depleted in copper ( < 70 ppm), with respect to carbonatized basalts not associated with gold. Orerelated, altered komatiitic flows can be screened using gold (>5 ppb), lead(> 10 ppm), arsenic(> 70 ppm) and antimony (>1 ppm).The habit, petrographic characteristics and certain geochemical characteristics of the altered volcanic rocks suggest that the hydrothermal fluid was of sea-water origin."

Jan 1, 1982

By W C. Shakespeare

The Ontario Committee on Taxation is making a comprehensive study of taxation in the Province of Ontario, and in this connection has received representations concerning mining taxation from a number of interested parties. Some of the more important recommendations on mining taxation are reviewed in this article. Introduction FOLLOWING the appointment of the Federal Royal Commission on Taxation, the Ontario Government, effective in November, 1962, appointed the Ontario Committee on Taxation to review taxes and revenues available to the Province of Ontario and its local governments, to co-operate with the Royal Commission on Taxation and with any other bodies of enquiry appointed by other provincial governments, and to make such recommendations as it sees fit to the Prime Minister of Ontario and the Executive Council. The members of the Committee are: MR. L. J. SMITH, F.C.A., Toronto, (Chairman) MR. ERIC HARDY, Toronto DR. R. CRAIG MCIVOR, F.R.S.C., Hamilton MR. CARL A. POLLOCK, Kitchener MR. R. BREDIN STAPELLS, Q.C., and Toronto. Like its Federal counterpart, the Royal Commission on Taxation, the Ontario Committee has held public hearings, has received written

Jan 1, 1965

By Frederik H. Kriel, John Ralston, Craig Priest

"Stream-based microfluidic solvent extraction offers a novel alternative to bulk-scale mixer-settler operations. However present maximum throughputs are restrictive and there are engineering challenges that need to be overcome before the technology is robust. This is especially the case for mineral processing, where circuits must be able to handle variable feed streams with long retention times and where maintenance should be minimized. This paper highlights research directed at investigating and evaluating these challenges for actual mineral leach solutions of metal ions. Molecular and particulate channel fouling is discussed. Most extraction systems studied to date show no effects that would preclude use of the technology. For rare earth elements (REE) with fast extraction rates, scale-up of volumetric throughput to 100 L/h using suitable arrays of channels, microfluidic chips and modules is shown to be achievable using a small contactor (approx. 2 m3) platform. This requires only 2–3 % of the typical aqueous phase inventory and residence time used in an equivalent mixer-settler. For a circuit with 100 contactors, the overall residence time would be less than 1 h, using an aqueous inventory of 40 L.INTRODUCTIONHydrometallurgy is of pivotal importance in many mineral processing circuits around the world, with liquid-liquid solvent extraction (SX) a key step in the separation of many base metals (e.g. Cu and Ni), radioisotopes, precious metals, and the ‘technology’ metals, such as rare earth elements (REEs) (Ritcey & Ashbrook, 1979). The standard equipment for SX in mineral processing is the mixer-settler, in which liquid dispersions are created, by agitation, to increase the surface-to-bulk ratio and, thus increase the mass transfer rate between the liquid phases. In stream-based microfluidic SX (microSX), these high surface-to-volume ratios are achieved by contacting microscopic streams (Ciceri, Perera, & Stevens, 2014), rather than forming small droplets, so that phase disengagement can be accelerated (essentially instantaneous via branching of the two streams of liquid at a channel junction). MicroSX is profoundly different from bulk mixer-settler SX operations and offers exciting opportunities for processing hydrometallurgy solutions (Kriel, Holzner, Grant, Ash, Woollam, Ralston, & Priest, 2015; Priest, Zhou, Klink, Sedev, & Ralston, 2012). Nonetheless, the advantages of using microfluidic environments are presently balanced by very significant challenges relating to throughput, process control, coupling of stages, flow stability, and fouling. If these challenges can be met using smart chip designs, process control and clever engineering, high-value/low-volume SX processes stand to benefit greatly."

Jan 1, 2016

By Greg Baiden

Telerobotics focused on mining is currently being introduced into production systems around the world. Mining companies in Canada, Sweden, South Africa and Australia have tended to lead the international charge to this form of technology for mining. While this introduction is taking place a few basic questions have yet to be answered. How many machines can a single operator run? How many types of machines can a single operator run? A new Canadian Research Chair in Robotics and Mine Automation has been established at Laurentian University. This chair will investigate these questions and many more through a series of experiments in a newly established telerobotics laboratory that connects Laurentian teleoperation workstations to model mining machines at Cambrian college?s eDome. The laboratory will support many experiments allowing researchers to physically run multiple robot scenarios differing the numbers and types of machines at one/quarter scale. Further experiments are being designed to investigate the potential for managing time delays in telerobotics. This paper describes the laboratory, experiments and some preliminary results.

May 1, 2003

By N. A. Jabit

The dissolution behaviour of ilmenite in acid solutions has been studied by many researchers to improve the leaching efficiency. Most studies which utilized natural ilmenite from different origins resulted in different reactivity due to the alteration caused by the weathering process. Previous researchers have suggested that the greater reactivity shown by some ilmenite samples towards sulphuric acid may be a result of the mineral being relatively unaltered. In the present study a rotating synthetic ilmenite disc of 2.2 cm diameter was subjected to leaching studies in hydrochloric acid. The dissolution rates of iron and titanium from synthetic ilmenite were determined in hydrochloric acid solutions (4 M to 9 M) over a temperature range of 50 to 80°C. Results show that the rate of dissolution of both iron and titanium increased with the increase in acid concentration. However, the rates decreased with time and obeyed a parabolic rate law indicating the blockage of the surface by an insoluble product. The rates of dissolution of both iron and titanium were higher in the presence of SnCl2 and remained unaffected with time indicating the reductive role of SnCl2 which inhibits the formation of surface blocking solids. Application to natural ilmenite is also discussed.

Jan 1, 2014

By J. P. Harrison, N. Bozorgzadeh, M. Dolowy-Busch

"It is common in rock engineering practice to characterize the triaxial strength of intact rock by using only data samples of small size. Practical guidelines such as ASTM support such sample sizes. In this paper, we investigate the reliability of the Hoek-Brown strength criterion estimated from such samples. For this purpose, we use an unusually large published set of triaxial strength data to randomly select a large number of data samples of small size to simulate the situation that frequently encounters in practice. The samples are generated with different arrangements with regards to the confining pressure. We fit the Hoek-Brown criterion to each of these samples, obtain estimates of strength parameters and compare them to those obtained from the complete data set. Our analysis suggests that estimates based on small samples are not reliable and can lead to both over- and under-estimation of strength.Additionally, we use these small samples to investigate the statistical methods for obtaining design values of strength as suggested by limit state design standards such as Eurocode 7. We show that, if used in conjunction with small samples, these methods do not guarantee a safe estimate of strength and in many cases lead to highly over-conservative estimates.We present a potential solution to this problem by augmenting the small data sets with Bayesian informative priors to give much more reliable estimates of strength. We conclude with suggestions for the development of informative prior distributions."

Jan 1, 2015

By J. Grignon, C. Fleming

It is possible to reproduce the performance of an operating CIP or CIL plant in the laboratory, in small scale batch kinetic tests, coupled with mathematical models that translate kinetic data into predicted steady state gold profiles across multi-stage adsorption circuits. Once the performance of the commercial plant has been mimicked by the model, the plant operating parameters can be varied systematically in the model, and the likely response of the plant to the step wise change can be determined. In this way it is possible to inexpensively optimize the operating conditions of an existing plant, with no disruption to plant operations and no economic risk to the mining company. This approach had been adopted by IAMGOLD to optimize the performance of their Rosebel CIL plant following several major expansions in mill capacity since 2004.

Jan 1, 2011

By P. Lind, A. Gagnon

"Goldcorp has embarked upon an ambitious, industry-leading, multi-year water use reduction effort. This is a proactive, voluntary effort that reflects our commitment to truly sustainable mining. This effort will focus on increasing water re-use and recycling, and reducing water inputs ultimately towards zero. All of our operating mines are expected to contribute to this effort and are currently in the process of developing plans to meet short and long term objectives. One of the largest needle movers to increase water re-use and recycling is in the area of tailings management. Within five to ten years at Goldcorp, it is envisioned that the need for wet tailings dams will be eliminated and that all new tailings facilities will consist of only filtered or dewatered tailings. Filtered tailings is developing into a mature technology with wide application in mine waste management. This paper describes a conceptual level evaluation on the transition from a slurry to a filtered tailings operation at the Cerro Negro mine in southern Argentina. Key benefits and challenges are highlighted.INTRODUCTION Goldcorp’s Cerro Negro operation is located in the Santa Cruz province in the Patagonian region of Argentina. Cerro Negro has been in operation since 2014 and commercial production was achieved on January 1, 2015. The processing capacity of the plant is 4,000 tonnes of ore per day and in 2016 produced 363,000 ounces of gold and 3.1 million ounces of silver (Goldcorp Inc., 2017). As the mine is located in a semi-arid area, it is important to evaluate technologies that could reduce freshwater consumption and maximize water re-use and recycle rates. The current tailings operation at Cerro Negro incorporates pumping of tailings slurry into a conventionally lined Tailings Storage Facility (TSF). Water is reclaimed from the tailings supernatant pond to the process plant via pumps, however, water losses occur due to evaporation and solution retention within the slurry tailings voids. Converting to a filtered or dewatered tailings operation would allow for increased water recovery prior to tailings disposal, and decreased water losses from evaporation and from retention in the tailings solids void space. This paper describes a conceptual level evaluation on the transition to filtered or dewatered tailings with the primary objective of moving closer Towards Zero Water."

Jan 1, 2017

By Hang Zhao, Xinping Li, Pingan Wu, Yi Luo

"The deep-buried rock surrounding the Jinping II Hydro-power Station was taken as the engineering background. Using model specimens of classified rock materials to simulate fractured rock mass under high in-situ stress conditions, the test about acoustic propagation law on single fracture model of specimen under different pressures and different angles were carried out. The variation of p-wave velocity in fractured rock mass and axial stress-strain relationship in the whole test procedure was also studied. Based on damage mechanics principle and the acoustic wave propagation in cracked rock mass, comparative study on damage constitutive relation of fractured rock mass under high in-situ stress in consideration of equivalent strain and equivalent energy was performed. As the results showed, with the change of axial stress level under constant confining pressure, the change in wave velocity can be divided into three stages: slow increase (small variation in amplitude), rapid reduce (large variation in amplitude ) and accelerate reduction. When the confining pressure is constant, the maximum p-wave velocity and the peak strength of specimens increases with the decrease of the crack angle.When the crack angle is constant, the maximum p-wave velocity and the peak strength of specimens increases with the increase of confining pressure.It is identified that the theoretical calculation results of constitutive relation about elasto-plastic damage model containing variable wave velocity in the fractured rock mass is consistent with the model test results.Therefore,the constitutive relation can provide reasonable suggestions for engineering practice. INTRODUCTIONThere are a lot of joints and fractures in surrounding rock mass of deep-lying in the Jinping-II hydropower station, which has a great influence on the physical and mechanical properties of rocks and effects the acoustic wave propagation and attenuation law in rock. Many previous research and project examples has proved that sound propagation parameters are closely related to crack and stress condition. Thus, it has certain theoretical significance and practical application value to carry out researches on sound propagation characteristics and establish damage constitutive model of fractured rock mass which is related to sound propagation parameters."

Jan 1, 2015

By Hani S. Mitri

Overhand cut-and-fill mining of narrow vein orebodies inevitably leads to the creation of horizontal pillars. As the thickness of the overlying crown pillar diminishes, stresses build up in the pillar. More often than not, this situation causes an increased level of seismicity and possible pillar burst. One well-known strategy to reduce the hazard of crown and sill pillar burst in cut-and-fill vein mining is that of destress blasting. The paper first reviews the methods used for the monitoring and assessment of potential pillar burst in narrow vein cut-and-fill mining. The influence of horizontal stress, mine depth and pillar thickness on stress build-up in the crown pillar is examined through a characteristic narrow vein numerical model. The paper then presents, with reference to three mine case studies, the benefits of destress blasting and the factors affecting its success as a ground control technique.

Oct 1, 2001

By Arthur L. de Carle

"IntroductionThe Key Lake uranium-nickel deposits are located within a Mineral Lease centred at latitude 57 ° 12' north and longitude 105 °39' west along the southeastern rim of the Athabasca sedimentary basin in northern Saskatchewan, approximately 240 km north of La Ronge (Fig. 1). Access is provided by an allweather provincial highway from Pinchousc, situated about 200 km to the south, and a private airstrip maintained at the mincsitc.These deposits have been developed by Key Lake Mining Corporation on behalf of the Saskatchewan Uranium Joint Venture. Participants in the joint venture include Saskatchewan Mining Development Corporation (50%), Urancrz Exploration and Mining Limited (33 1/3 %) and Eldor Resources Limited (16 2/3 %).Considerable geological work has been conducted on the Key Lake orebodies and reported in summary papers published by Dahlkamp and Thn, (1977), Dahlkamp, (1978), Gatzweiler eta/., (1979) and Kirchner el a/. , (1980). However, intensive geological research is ongoing, particularly since many problems regarding ore genesis and controls remain unresolved . Exploration History and DevelopmentThe events (Gatzweiler eta/., 1980) which led to the discovery of the Key Lake ore bodies began in the summer of 1971 by following up on the reports of airborne radiometric anomalies and anomalous radon values in the Zimmer Lake water situated approximately 5 km to 6 km to the southwest. This work succeeded in locating a few high-grade uranium and nickel-bearing boulders associated with esker material. An integrated program, consisting of various geochemical and geophysical surveys along with diamond drilling, culminated in the discovery of the Gaertner orebody during July 1975. Subsequent fence drilling across the strike extensions of this ore structure located the Deilmann deposit, approximately I km to the northeast, in June 1976"

Jan 1, 1986

By E. Hardwick, K. C. Sole, Y. Jurrius

"The Luilu cobalt plant at Kolwezi, Democratic Republic of Congo, has been operating since the late 1950s, using a conventional precipitation flowsheet for removal of impurities from the cobalt process stream. Most impurities are, however, incompletely removed using this technology. Copper and zinc, both of which quantitatively deposit at the cathode in the cobalt electrowinning process, are two of the main impurities contaminating the cobalt metal product. Ion exchange offers a modern approach to removing these impurities from the cobalt advance electrolyte.Following a laboratory testwork programme to identify a suitable ion-exchange system, an on-site pilot-plant trial, treating 1500 to 3000 L/d of electrolyte, was operated for a period of six weeks to optimise the operating conditions and to determine full-scale design criteria. Copper removal was carried out using a fixed-bed lead-polish configuration with the Lanxess iminodiacetic acid resin, TP 207. Zinc removal was subsequently carried out in a similar configuration using the Lanxess aminophosphonic acid resin, TP 260. The optimised system proved capable of removing both copper and zinc from 20 to 30 mg/L to <1 mg/L from plant electrolyte containing ~20 g/L Co. Selective elution allows co-loaded cobalt to be returned to the main circuit and value to be obtained for the copper impurity. The process shows operational and economic advantages over the traditional flowsheet. Full-scale implementation of the developed process is in progress and some design considerations are discussed."

Jan 1, 2014

By Junior Santos

Kinross Paracatu started the operation of the new gold processing plant in the end of 2008, being composed by one SAG mill and two ball mills. During the first year of operation the plant had several problems related to stability and throughput capacity, mainly due to low grinding efficiency of the ball mills. In this period many actions were taken to maximize the throughput rate. Among the actions are reducing the size of balls in the mills, increasing the ball charge in the SAG mill, changing cyclone configuration and return of circulating load to SAG mill. With better stability of the circuit, the second stage of improvements has begun with the objective of increasing throughput rate and also reducing operation costs. Among the actions are the optimization of ball charge in the mills and a better operational control of cyclone parts. After two years of operation was obtained a significant increase in plant capacity, but still requires the addition of a third ball mill in order to maximize the use of SAG mill, which has spare capacity.

Jan 1, 2012

By K. S. Raja, F. Battick, B. Pesic

"CeO2 doped with lower valence cations, such as Y3+, Sm3+, Gd3+ etc. is considered as electrolyte material for low temperature SOFC. Doping introduces additional oxygen vacancies and improves ionic conductivity. This work describes the preparation of yttria-calcia doped-ceria precursor material, its sintering in DC and AC field methods, and characterization of sintered electrolytes with respect to the ionic conductivity. Doped precursor materials were prepared by a controlled co-precipitation process. Sintering of prepared, pelletized particulates was carried out using three different methods such as: 1) conventional; 2) spark plasma sintering; and 3) an alternating current field at 1125°C (AC assisted sintering). The mechanism involved in the conductivity improvement as a function of defect density, grain boundary area and phase stability will be discussed. INTRODUCTIONThe performance of SOFCs depends highly on the properties of materials. Subtle variations in the composition, microstructure, or density of SOFC components can considerably alter the power output capabilities of fuel cells. Early SOFCs utilized zirconia based electrolytes but efforts in lowering the operating temperatures of SOFCs have prompted investigations into several other oxygen ion conductors – often modified with dopants to either promote the formation of oxygen vacancies or to stabilize a vacancy rich high temperature phase – such as bismuth oxide, lanthanum gallate, and ceria.The transport of oxygen ions through the electrolyte first begins with diffusion into the material. While this is generally a surface kinetics phenomenon, it is safe to say that it is highly dependent on oxygen pressure and vacancy gradients. The role of the cathode in SOFCs is to reduce oxygen at the electrolyte surface creating an O2– ion gradient which induces permeation into the material. Once inside and under the influence of a potential field, O2– ions migrate by a vacancy hopping mechanism, Catlow, C.R.A. (1990), effectively exchanging positions throughout the matrix until they reach the anode and react, thus leaving the matrix."

Jan 1, 2012

By F. L. Wu

Based on the analysis of a sealed coal mine resulting from a fire-triggered explosion, limitations were discovered in the re-entry procedures used to reduce the size of the sealed area that were being applied during the process of re-opening the mine. The analysis of two re-opening plans in a mine using mechanical ventilation showed that the estimation of the degree of damage of two air doors close to the working face with the fire was key to the identification of the optimum mine recovery plan. The operation points of airflow and air pressure of the main fan under either the doors? damaged or intact conditions can be estimated through the use of a ventilation network simulation program. Starting the main fan for a short time period and measuring its operation points of airflow and air pressure allowed their comparison with the simulated values. This procedure provided a reasonable estimation of the degree of damage of the ventilation structures and more confidence in choosing a recovery plan. Through this process, it was possible to conclude that the two doors were still intact. Consequently, the final plan of installing a new main fan in the main decline, sealing the initial upcast shaft and unsealing the auxiliary downcast shaft, was proven to be reasonable at the mine site.

Aug 1, 2013