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By Jarvis ST

Colliery spoil is the major constituent of colliery spoil 'rockpaste' which has been used to infill abandoned limestone mines in the West Midlands of England since the early-1980s. The other constituents of rockpasle are pulverised fuel ash, lime and water. A key property of the rockpaste is its ability to flow within the mine workings over considerable distances before setting. This paper describes the work carried out to identify suitable sites as sources of colliery spoil for making rockpaste and goes onto consider the flow properties of the material and the monitoring methods used on-site. A full-scale trial comprising mulling a 6600 nt' section of an abandoned mine was conducted prior to the mulling of the Littleton Street Mine which had a volume of about 500 000 m'. As well as describing the methods used for monitoring the movement of rockpaste material, a description is also given of a dip-meter developed specifically for the purpose of measuring the level of paste in the mine. This paper shows how a colliery spoil based paste has been successfully rued for infilling abandoned mine workings. The monitoring systems developed for use in the two case studies presented in this paper are now being used extensively for infilling other abandoned mine workings. To-date over I I mines with a total volume exceeding two million cubic metres have been backfilled.

Jan 1, 1998

By P Christen

The Ernest Henry Copper gold mine situated in North West Queensland, Australia, is owned and operated by Xstrata Copper. Currently the open pit produces 11 Mtpa of ore. With open pit mining ceasing in mid 2011 development has begun on an underground sublevel cave mine to extend the life of the operation by another 12 years. When completed the open pit will be 530 m deep and 1.5 km in diameter. The orebody dips at approximately 45° and has been outlined a further 450 m below the base of the pit. This provides some challenges for the Ernest Henry underground mine which is designed to initially truck development and production ore from the end of the pit until a hoisting shaft is commissioned in 2013. Production will then increase to 5.0 Mtpa on its way to an ultimate rate of 6.0 Mtpa in 2016.This paper will focus on the capital development and infrastructure requirements for the underground mine. Areas covered include mine accesses, ore handling system, accommodations for the dip of the orebody, primary ventilation design, dewatering systems and selection of an underground workshop over surface only maintenance.Discussions include the complications arising due to the mine being located directly below a large open pit and the combination of first principle cost analysis and risk assessment which has been used to safely optimise the feasibility study designs.

Mar 21, 2011

By D Capstick, M B. Ebell

This paper describes the test work, process design, commissioning and operation of a processing system at the Ergo gold operation that improves the extraction efficiency from gold tailings material. The improvement in recovery is derived from the separation of the gold contained within the sulfides of the tailings material and a dedicated process stream to recover that gold.The sulfides are separated by means of a flotation circuit and that resulting concentrate is subjected to a regrind of below 20 ¦m to enable a greater liberation of the gold. The ultra-fine material is then subjected to a dedicated leach circuit to recover the now exposed gold particles.The case study is an example of the challenges of introducing new technology and methodologies to a well-established operation and thereby attaining improved efficiencies and tangible business benefits.CITATION:Ebell, M B and Capstick, D, 2013. Improving extraction efficiency from Witwatersrand gold tailings using flotation and ultra-fine grinding of concentrates, in Proceedings World Gold 2013 , pp 301-306 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By G Morgan, C Kemp

In December 2010, a trial of borehole radar technology was conducted to test the usefulness of the technique in better refining the position and geometry of narrow vein orebodies away from the primary data sources of drilling and mapping of development excavations. This paper summarises the reasons why the technique was applied, describes the testing methods selected and summarises the outcomes of the trial.Poor reconciliations of recovered metal from a section of an orebody at Jundee mine site, Western Australia, led to an investigation that identified insufficient understanding of the geometry of a narrow vein orebody as a potential cause. This orebody was situated between mapped development excavations and away from surrounding drill holes. Borehole radar was identified as a possible technique that could supply information on vein location and continuity away from other data sources allowing more accurate orebody modelling and subsequent stope optimisation.A borehole radar instrument (10 - 100 MHz frequency) was inserted into pairs of purpose-drilled boreholes on either side of relatively well-constrained mineralisation and the radar reflection data was collected. This process was repeated in five locations across the mine to represent the most common geological settings, lithologies and orebody varieties encountered at Jundee to determine the suitability of applying the technique in each of these settings. Collected, processed and interpreted radar data was compared to other geology data collected independently for verification and interpretation.Conclusions drawn from the analysis were that the technique could effectively determine the following features of the mineralised veins in the majority of test environments: geometry of veins, magnitude of offsets where structures intersect and orientations of planar structures with short strike length. The technique was very useful in selecting the appropriate structural interpretation where available data could lead to multiple, equally likely, interpretations.CITATION:Kemp, C and Morgan, G, 2012. Using borehole radar to refine orebody interpretations in a narrow vein gold deposit, in Proceedings Narrow Vein Mining 2012 , pp 121-130 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Mar 26, 2012

By Egan J. R

Changes have recently been applied to the Sullivan Concentrator lead and zinc circuits to treat fine-grained ores which make-up the majority of ore reserves in the mine. Pilot plant testwork conducted in 1990 - 91 indicated that concentrate grades would be substantially improved by reducing the particle size (Pao) of the lead from 38 to 15 ¦m and the zinc from 45 to 24 ¦m. Circuit revisions involved installation of major new equipment including: two 600-kilowatt Vertimills for regrinding, a four metre diametre column flotation cell and a four metre diameter hyperbaric pressure filter for dewatering. Duties of the existing regrind mills were Reassigned.

Jan 1, 1993

A recoverable uranium resource, shown to be suitable for in situ leaching, was discovered at Honeymoon in South Australia in 1971. Exploration of the deposit was carried out during the period from 1973 to 1979. Uranium mineralisation occurs in a coarse-grained unconsolidated sand aquifer located in the Yarramba Palaeochannel at a depth of approximately 110 m. Following initial development during 1979 to 1983 and the construction of demonstration leach facilities, the Project was put on hold. Southern Cross Resources purchased the Project in 1997. Government approval was received in March 1998 for the operation of on-site demonstration leach and recovery facilities while an Environmental Impact Statement was prepared and a 1000 tpa commercial production plant was designed. The Environmental Impact Statement (EIS) was released in June 2000 and operation of the test facility was completed in August 2000. Acceptance of the EIS by Commonwealth and South Australian state governments was announced on 20 November 2001. A Mining Lease was granted over the area of the proposed ISL operation on 8 February 2002. Operation of the Project is entirely dependent on using highly saline underground water resources to supply process and human needs. The management of discharge streams from the plant by re-injection was approved. The Honeymoon demonstration plant was the first adaptation of the solvent extraction process to highly saline in situ leach solutions. As such, it incorporated a number of unique operating and installation features. The trial period enabled optimisation of the process chemistry, additives and management and serves as an invaluable base for the proposed plant design and future operation. This paper discusses the nature of the uranium occurrence, the effect of saline water on the leach process and equipment, project design and environmental considerations, the requirements for disposal of discharge streams to minimise the impact on the arid environment and the requirements for rehabilitation following project completion.

Jan 1, 2002

In practice a sampling solution is a compromise of many requirements: the sample should be representative; the sampling system should also be reliable, less than 95 per cent availability restricts the use of the assayed sample for process control purposes; no sample is the worst sample, and investment costs and installation space/layout are frequently a restriction. For instance, online X-ray analysers for process control introduce a delimitation error by the nature of X-ray physics. Thus only in special cases a relative accuracy better than three per cent relative, as one standard deviation, is achieved. A sampling system for process control needs not to be, as representative, for so many sample properties, as one for composite laboratory analysis samples. Sampling system maintenance is also an important issue. There are many sampling systems in the industry which have been difficult to maintain and are in disuse for lack of resources or incentives to keep them running. Pierre Gy developed the most generally accepted sampling theory. One of the main principles is that all particles in a one-dimensional process stream should have equal chances of being included into the sample. A correctly designed and operated transversing cutter comes close to this goal but has limitations in temporal representativity. For slurries an acceptable solution in many cases is to use a fixed vertical cutter(s) in a position where the slurry is well-mixed by turbulence and other means. For online analysis, reliability problems are mostly related to faulty design or installation of the piping system to the analyser. Properties of material processed, process flow sheet and piping details before and after the sampler have to be taken into account when deciding on which sampling arrangement is appropriate. Guidelines and some solutions to these issues are presented in this paper.

Mar 1, 2010

By R E. McIvor, K M. Bartholomew

Classification system efficiency (CSE) is a simple, powerful metric that provides a comprehensive measure of classification system performance. CSE directly quantifies the amount of coarse solids in the mill, and as a result, also directly quantifies the percentage of mill power being used effectively. In this manner, it is an effective, practical grinding energy efficiency metric.Three independent variables drive CSE: circulating load ratio, sharpness of classification, and classifier bypass. Due to practical downstream constrains on per cent solids, improvements realised by increasing circulating load reach diminishing returns as sharpness of classification and bypass deteriorate in the most commonly used classification device, the hydrocyclone. This combination of effects leads to the use of CSE, and its relationship to operational economics, as an objective circuit optimisation criterion.Its simplicity in measurement makes CSE a useful tool for the plant metallurgist, and it is not subject to a great amount of experimental error. CSE provides the plant operator a fast, simple, and effective means to evaluate the performance of the plant classification system. Improvements in CSE relate directly to circuit throughput and energy efficiency. This paper, through description and plant case studies demonstrates the power and utility of this emerging grinding system optimisation metric.CITATION:Bartholomew, K M and McIvor, R E, 2013. Classification system efficiency - a comprehensive closed-circuit grinding optimisation metric, in Proceedings World Gold 2013 , pp 389-394 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By F Cesnik

The past few years has seen a concerted effort to improve the recovery of gold along with its co-product copper from the æhigh-gradeÆ Ridgeway concentrator at Newcrest Mining LtdÆs Cadia Valley Operations. A number of initiatives were identified and implemented, culminating in a sustained improvement in recovery of approximately three to four per cent for both metals. The key projects that contributed to this improvement included the installation of a 355 kW Metso stirred media detritor (SMD) to create a regrind circuit, installation of froth crowders on the scavenger circuit, installation of a Falcon SB2500SE gravity concentrator as part of the regrind circuit to improve gold recovered to bullion on-site and the optimisation of the grinding circuit to reduce the 80 per cent passing size (P80) of the primary grind from 160 to 121 ¦m for the same throughput via process control, cyclone and ball charge optimisation. This paper will focus on the supporting test work, where applicable, that was used as the design basis for the project, but more importantly the plant data before and after the changes to clearly identify the improvements to plant recovery.

Jan 1, 2007

Central to any business is its Asset Management Plan which encapsulates the business context and key organisational objectives such as profitability, safety and environmental standards. Life Cycle Planning (LCP) is a key component of an overall Asset Management Plan. A comprehensive approach to Life Cycle Planning forecasts the financial expenditure required to support the performance of the asset over the business life. It incorporates capital, maintenance and operational expenditure along with an estimation of economic life. Within its body the LCP provides the detail of the maintenance plan and method of its execution. Once optimised the LCP becomes the overarching plan executed through the application of several elements of the Asset Management Plan to ensure the return on investment from the assets is optimal. Each of the elements of the LCP is bound by a set of loops that provide information based on the analysis of outcomes. These loops drive the continuous improvement of performance and cost over the life of the asset. In this way we ensure that the LCP is a dynamic plan responsive to the changing business environment. The paper being presented today will describe the process undertaken and the outcomes derived when this approach was applied to a $600 M+ coal handling and preparation plant in QueenslandÆs Bowen Basin. It will also delve into the difficulties encountered from both technical and cultural aspects; the latter proving to be the most difficult to manage. It will describe the hurdles and barriers that hampered progress including the human influences and the natural desire to revert to what has been done in the past when things became a bit difficult. In the end the results are there to show that the upfront expenditure and investment in time was time and money well spent and the outcome has the operation well placed to manage the assets in a manner designed to deliver the optimal business outcome.

Jan 1, 2007

By Bradford NL

The Isa Mine of Mount Isa Mines Limited produces 5.1 million tonnes of copper ore and 2.2 million tonnes of silver-lead-zinc ore from sublevel open stopes annually. Extraction of the narrow, steeply dipping silver-lead-zinc orebodies requires a strategy quite different to that used in the massive copper orebodies. A range of blasthole diameters, explosive types and initiation systems gives the flexibility needed to adapt open stoping to a variety of situations. Hole diameters from 70 mm to 200 mm are being used, with lengths of up to 100 m common for the latter.

Jan 1, 1982

The issues which are the subject of this paper cover an extremely broad field. In themselves the components of the topic could be the theme, in considerably greater detail, of a two day seminar. Indeed a full course in an academic year would probably not do justice to the topic. I have therefore experienced considerable difficulty in condensing such a broad subject range down to a 30 minutes address and in doing so have tried to, hopefully, provide a little bit of everything for the wide range of professional interests and different levels of commercial, professional and legal expertise represented at this conference. Perhaps my address could best be described as a "bird's eye" view rather than a "worm's eye" view of the subject.

Jan 1, 1990

By M Grigorescu, J H. Hodgkinson, H Alehossein

A new framework that collates and interprets pre-existing data to assess vulnerability and ultimately plan to avoid or minimise flood-related risk to infrastructure, people, downtime, environment and revenue has been developed. The æClimate Related Adaptation from Terrain Evaluation ResultsÆ (CRATER) method tested at a coal mine in Queensland, provides semi-quantitative information to assist decision makers when designating investment for minimising vulnerability of mining operations to climate. Here we present the processes involved in this three-step approach that uses pre-existing spatial data of the mine site and local knowledge to build a set of visual tools to assist decision-making. The first step of the process is performing multi-criteria evaluation (MCE) within a geographic information system (GIS) on ranked natural conditions at the mine, such as elevation, slope, drainage, soil and vegetation, which is performed to identify critical flood areas. Secondly, a fault-tree analysis identifies how impact can occur and what options there are for impact reduction. Finally, a resource assessment of the mineÆs capacity to adapt reduces the adaptation options to those most suited to the mine. The results are confidential, but for the purpose of introducing the methodology, we present simplified results, particularly of steps 2 and 3. CRATER can also be used for future æwhat-ifÆ flooding scenarios to identify the most suitable locations for roads, buildings or other critical infrastructure. The methodology is transferable to any mine, series of mines or locations along the mining value chain that have sufficient data, providing a practical decision-making tool to identify æno-regretsÆ actions that not only could reduce downtime after or during an event, but in some cases may enhance production between extreme events. We now plan to test this method at a broader scale, to encompass more than one mine in the analysis.CITATION:Hodgkinson, J H, Grigorescu, M and Alehossein, H, 2013. Climate Related Adaptation from Terrain Evaluation Results (CRATER) - interpretation of pre-existing data for mine site flood vulnerability and management, in Proceedings Water in Mining 2013 , pp 259-266 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

By I D. Gregson, A Gandhe, A S. Garcia, K M. MacAndrew

"Falls of ground still cause around one-third of all underground mining fatalities. The recent introduction of mechanised room and pillar working into Indian coalmines is an example of the application of new design by measurement and safety monitoring strategies, which can be used to reduce falls of ground risks in mines.Rock Mechanics Technology, now part of Golder Associates UK Ltd (Golder), is providing rock bolt support and pillar design services to the mines using a design by measurement approach. This involves in situ monitoring to confirm support and pillar designs and pillar extraction sequences.Site examples are given of the support designs determined and the monitoring programs undertaken for both design and safety.Routine safety monitoring of roof movement using telltales is also described. A new auto warning telltale has been developed specifically to warn of imminent caving as pillars are extracted.The approach used by Golder has played a major role in ensuring the success of these projects. As a consequence, mechanised room and pillar working is now firmly established in India, and wider application is planned to help meet future demand for coal.The experience confirms that the design by measurement method for this application has important advantages over conventional design approaches using analytical or empirical methods. Firstly, it measures the design performance or outcome rather than trying to calculate or predict it. Secondly, it provides the opportunity for the design to be adjusted to obtain the optimum outcome. Thirdly, it can do this at a local level, so that the support design can be matched to changing conditions to give the most cost-effective design. Finally, it incorporates long-term monitoring of support performance, again at a local level, so that subsequent change can be identified to enable corrective measures to be implemented in a timely manner and to ensure that ground control safety is maintained.CITATION:MacAndrew, K M, Garcia, A S, Gregson, I D and Gandhe, A, 2014. Application of design by measurement for support and pillar design in mechanised room and pillar coal mining in India, in Proceedings AusRock 2014: Third Australasian Ground Control in Mining Conference, pp 65–76 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 5, 2014

By P Waters, P Hollings, M Baker, D R. Cooke

Over the last three million years, porphyry and epithermal mineralisation in the Baguio Mineral District has been driven by calc-alkaline magmatism associated with the subduction of the South China Sea plate and the Scarborough seamounts beneath northern Luzon, Philippines. Coupled with extreme uplift and exhumation rates, mineralisation in the Baguio District has been responsible for the emplacement of over 922 million grams of gold. As one of the oldest intrusive bodies associated with the Baguio District, the Black Mountain Cu-Au deposit consists of at least five intrusive phases overprinted by potassic and propylitic alteration and sulfide mineralisation. Gold ore grades are low and molybdenum grades high with respect to other porphyry Cu-Au deposits in the Baguio Mineral District. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

The Douglas mineral sands deposit is located 75 km north of Hamilton in western Victoria, Australia. The deposit was discovered in the late 1990s by Basin Minerals Limited and purchased by Iluka Resources Ltd in 2002. Prestrip mining commenced in December 2004, with ore mining commencing in August 2005. Douglas is the first of several projects being implemented by Iluka Resources Ltd in the Murray Basin, with all heavy mineral concentrate planned to be treated at the companyÆs mineral separation plant in Hamilton. The mineralisation at Douglas lies along the south-eastern margin of the Murray Basin. It is hosted by marine Pliocene Loxton-Parilla Sands and consists of three discrete deposits; Bondi Main, Bondi West and Bondi East. The mineralised sediments dip at a low angle to the west and lie unconformably beneath a veneer of top soil (50 - 100 mm) and subsoil (up to 600 mm) and between three to 12 m of overburden. The barren overburden, characterised by high clay content (<53 ¦m material) generally provides a stark contrast to the sandy ore, which is between 1 m (parts of Bondi East) and 15 m (Bondi Main) thick. Both overburden and ore are removed utilising standard dry mining techniques using both scraper-bulldozer and truck-excavator combinations. All ore is delivered to run-of-mine (ROM) stockpiles before being reclaimed by front end loader into the processing plant. Grade control at Douglas is based around visual dig control aided by high precision survey, which enables accurate reference to the resource drilling and block model data. Vertical excavator faces, inclined scraper faces plus regular test pits and trenches provide opportunities for in pit mapping and sampling. This data is used to refine not only the resource estimate for Douglas but also the drilling, interpretation and resource modelling methods used for similar deposits across the basin. The foundations of the geological reconciliation process at Douglas are the in pit surveys undertaken each time the mining fleet has completed building a ROM stockpile. These surveys and the subsequent interrogation of resource models enable robust estimations of the heavy mineral content of the stockpiles, which are subsequently used to predict the daily input grades into the plant during their reclamation. Reconciliation of this daily data is then undertaken at the end of each month against metallurgical production data and plant balances. Learnings and results from the reconciliation process are used to further refine subsequent resource models and modelling methods.

Jan 1, 2009

By W L. Daniels, C Stilson, C Zimmerman

Mineral sands mining for ilmenite, rutile and zircon has disturbed over 1000 ha of prime farmland in Virginia (USA) since 1997 and additional areas are likely to be disturbed in Virginia and North Carolina (USA) over the next 15 years. Full-scale mining operations at the Old Hickory Project in Virginia were initiated in 1997 by Iluka Resources Inc. and restoration protocols have continued to evolve in response to a variety of economic, technical and social issues. Early on, the return of these lands to agricultural row-crop production was complicated by vertical stratification of tails + slimes and lateral variability in soil physical conditions in the reclaimed pits and by limited topsoil return. Virginia Tech and Iluka have worked cooperatively with all stakeholders for over 20 years to review the pre-existing research base, conduct new and innovative site-specific research and thereby provide reasonable expectations of post-mining soil productivity levels. In 2004, Virginia Tech, Iluka Resources and a local leaseholder (Carraway-Winn family) agreed to jointly manage a 45 ha research demonstration farm where the long-term effects of alternative soil reconstruction practices are being rigorously monitored for both row crops (corn and wheat) and forage production. All mined land crop yields are also compared to an adjacent undisturbed exceptional quality prime farmland soil. Row crop yields between 2005 and 2010 were significantly above county average yields (regulatory target level) and approximately 75 - 80 per cent of undisturbed adjacent prime farmlands. The state regulatory authority has recently relaxed its position on the necessity of topsoil return versus use of topsoil substitutes based on appropriate on-site research results and the ability of the reclaimed soils to meet comparative local county crop yield targets. This cooperative effort allows all clientele groups to objectively assess the post-mining productivity of these mined lands while providing an invaluable educational opportunity for the mining industry. CITATION:Daniels, W L, Stilson, C and Zimmerman, C, 2012. Development of effective rehabilitation protocols for mineral sands mining in Virginia, USA, in Proceedings Life-of-Mine 2012 , pp 97-104 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By D A. Bowman, S Schafrik

With the goal of reducing injuries and fatalities related to haul truck accidents, this research investigates technologies and intervention strategies for improving worker training using a virtual environment (VE). Funded by the National Institute for Occupational Safety and Health (NIOSH), this research specifically focuses on training workers in preshift inspections of haul trucks to avoid preventable defects from causing worker injuries and expensive equipment damage. Improved training in these inspections is expected to increase uptime. The VE developed to train workers for preshift inspections consists of three phases: the virtual tour, the virtual inspection and the shift simulation. The virtual tour introduces information necessary to conduct a preshift inspection by guiding the worker around a haul truck, identifying parts to be inspected and explaining defects to look for. The virtual inspection assesses retention as the worker navigates around a haul truck and identifies defects. During the shift simulation, the worker is shown a simulation of the work shift, which animates severe consequences of any overlooked defects to emphasise the importance of preshift inspections. To provide multiple training platforms, desktop and CAVEÖ versions of the training VE were created. Flux Studio was used to model the environment and to produce Virtual Reality Modelling Language (VRML) files for the desktop version. DIVERSE, an application programming interface, was then used to implement a more realistic version of the VE in a CAVEÖ, a room-sized visualisation system. Initial feedback from mining colleagues indicates that the training VE may replace normal classroom training for preshift inspections in the future. As opposed to PowerPoint presentations and instructional videos, the training VE provides better spatial understanding of the location of parts and incorporates interactive features to actively engage drivers in the learning process, which may result in better retention. Initial feedback also indicates that minor improvements can be made to the virtual tour and virtual inspection phases.

Jan 1, 2008

By D Howe

The Athena gold deposit was discovered in 2007 by Gold Fields Australia Ltd, at the St Ives Gold Mine, 35 km southeast of Kambalda, Western Australia. Gold anomalism was identified in sheared Paringa Basalt as a result of a regional scale aircore drilling program, in association with geophysics. In the 18 months following discovery, the deposit was intensely drilled and by June 2009, it was announced that the Athena deposit contained an ore reserve of 1.7 Mt @ 5.6 g/t for 316 koz. This was followed by a feasibility study, and as a result mine development commenced in November 2009.The Athena mineralisation is hosted in a discrete, north-south striking, steep to moderately dipping shear zone within the southwest dipping Paringa Basalt. Vein intensity has a strong correlation to grade and vein type varies from early thin quartz-albite-sulfide (pyrite and/or pyrrhotite) shear parallel veins to strong brecciation and irregular veining with quartz-albite-actinolite-biotite-pyrrhotite infill. The geology preproduction process developed at the Argo mine was refined and improved following a business improvement project. The aim of the process is to construct detailed geological interpretations prior to development allowing informed mining decisions to be made. The process delivers significant cost savings and revenue enhancements.The development of macroscopic classification scheme was critical to determine ore or waste in the early phases of mining. The Style of Deformation, Alteration and Veining (SAV) Code was the result, and has been enhanced as greater geological knowledge is gained over time.

Aug 22, 2011

By H Y. Niu

The coal left in the goaf is easily submerged by groundwater damage. During the mining process of the underlying coal seam, it is necessary to drain the water in the overlying goaf. The coal sample is prone to spontaneous combustion after being soaked in water and air-dried. To explore the effect of micro-functional group transformation of water-immersed coal samples on the spontaneous combustion characteristics of coal samples during the low-temperature oxidation process. Using the experimental method of infrared spectroscopy, the migration law of special functional groups under different oxygen concentrations of water-soaked coal samples was analysed. By means of thermal analysis, the endothermic and exothermic properties of the functional groups in the water-soaked coal samples were studied. The results show that: the higher the oxygen concentration, the more oxygen-containing functional groups in the water-soaked coal sample, compared with the 18 per cent oxygen concentration, the 14 per cent oxygen concentration has a small increase, and the chain length is shortened. The temperature increase together with the oxygen concentration content determines the functional group content, the pyrolysis process produces some functional groups. The lower the oxygen concentration, endothermic rate decreases and endothermic temperature increases, the higher the ignition temperature of coal oxy-combustion, the lower the total heat release, the higher the burnout temperature, and the faster the oxygen-absorbing weight gain and the conversion of functional groups. Below 14 per cent oxygen concentration, the oxidative combustion process will be greatly reduced. The results provide a theoretical basis for preventing long-term water-soaked coal body oxidative spontaneous combustion in shallow buried coal seams.

Oct 12, 2022