Search Documents

By JOHN R. SUMAN

COMMENCEMENT exercises this year have a peculiar significance because the graduating students are entering upon their life's work at the most critical time in the history of the United States. We are engaged in a great struggle the outcome of which is none too clear even to the best informed students of international affairs. We are starting late in a vicious world conflict where it is generally recognized that our adversaries have distinct superiority over us in armament on the land, on the sea, and in the air. We have the gigantic task of building up our armed forces and armament and at the same time supplying our allies with equipment which they must have. We can do this job if we are given sufficient time, but there is a possibility that the war will be over before we are ready. Few realize the seriousness of this situation. If this fight is to be won-and we dare not try to visualize the future of this country if it is lost-all dissension and bickering between Congress, capital, labor, and agriculture must cease. When and where voluntary co-operation proves inadequate for the successful conduct of the war effort, laws must be enacted or strengthened to achieve our purpose.

Jan 1, 1942

By R. Sprycha, J. Szczypa, W. Janusz, J. Neczaj-Hruzewicz

INTRODUCTION Because large aqueous suspensions of various fine solids originate during the beneficiation of ores, the Mining Industry constantly requires efficient and feasible dewatering methods. Among the techniques currently in use (1,2), filtration (vacuum, press) and centrifugation are fairly expensive and thus are limited to use with more valuable materials. Furthermore, installations of reasonable size produce only moderate outputs. Therefore, tailings from ore dressing plants are usually treated by sedimentation or settling techniques with a tailings dam as the ultimate sedimentation basin (3). Apart from growing environmental and economic questions, the solid product obtained from the tailings dam basin has in most cases, a rather high moisture content and a persistent semi-fluid consistency. Thus, it is difficult to transport and use further. On the other hand, the solids may be utilized as a filling material, fertilizer, etc. providing they are dry enough and properly granulated. Demands for an improved technique are met to a great extent, by the technique presented in this paper. AGGLOMERATION OF FLOCCIJLATED SLIMES Origin and Qualitative Description of the Process Phenomena of consolidation and pellet formation in flocculated fines were first observed by Yusa and Gaudin (4) while studying rheological properties of flocculated kaolinite. On this basis, methods of separating liquid from solids have been worked out (5-7) and many possibilities for application have been suggested (5,6). Yusa termed the technique "wet pelletization''.

Jan 1, 1980

By James J. Halbouty

The restraining effects of war conditions on oil-field development are well illustrated by statistics on South Texas † fields for the year 1942. Statistics also show a decline in wildcatting, but this decrease is much smaller than that shown by field activity. In comparison with results in 1941, there was a reduction of about 44 per cent in the total number of wells drilled in the area (802 in 1942 against 1452 in 1941) This 44 per cent drop represents declines of 50.4 per cent in field wells and of 17.4 per cent in rank wildcats. Field wells (exclusive of 18 wildcats that discovered fields) totaled 598; also, 204 rank wildcats were drilled (see Tables 3 and 4). The corresponding figures for 1941 are 1205 field and extension wells and 247 rank wildcats. In this connection, it should be noted that whereas in 1941 the rank wildcats made up only 17 per cent of all wells drilled in the area, their percentage of the 1942 total was 25.4 per cent. In spite of the decrease of 43 in the number of rank wildcatst drilled, there were 18 new productive areas discavered, one more than the 17 new fields found in 1941. Thus the field-discovery rate for 1942, one new field for every 11.3 wildcats drilled, compares favorably with the I to 14.5 rate of 1941. Thirteen new producing levels were opened in fields; this includes the finding of 44' gravity crude on the west flank of the Sejita field in a 5700-ft. sand, which produccs distillate higher on the structure. Interesting, and showing the general scarcity of sand discoveries, is the fact that of the 13 new sands discovered, 7 were found in Jim Wells County. The year's sand-discovery rate of one new level for every 46 field wells compares very unfavorably with the I to 19.7 rate of 1941, during which 61 new producing horizons were found. Developmeilt of new fields was on a small scale. In several instances activity in these areas was not carried beyond the drilling of the discovery well. The field discoveries of 1942, together with the type of production obtained from the discovery wells and the total number of wells (productive and dry) drilled in them, are given below: Discovery Num- Field.I County Well her Produced Wells I. Cadena....... Duval Oil 2 a. Garza......... Duval Oil I 3. Dinn......... Duval Gas I 4. Keller......... Duval Gas I 5. East.......... Tim 0 11 I 6. Green Branch . McMullen Gas 3 7. Frost. .GreenBranch........ Starr Oil I 8. Garcia........ Starr Oil 6 9. Ulrich........ Starr Oil 4 10. Lykes......... Webb Oil 2 11. McLean....... Webb Oil 9 Iz. Alamo........ Hidalgo Distillate 2 and gas 13. Penitas....... Hidalgo Distillate 2 and gas 14. Xmpnan..... Jim wells i a 15. South Premont Jim Wells Distillate i and gas 16. Quinto Creek.. Jim Wells Gas 4 17. Roth.. . :..... Jim Wells Gas I I 18. South Sinton.. San Distillate I Patricio and gas . • See Table 2 for data on discovery wells and Table I for information on these fields. • See Table 4.

Jan 1, 1943

By James J. Halbouty

The restraining effects of war conditions on oil-field development are well illustrated by statistics on South Texas † fields for the year 1942. Statistics also show a decline in wildcatting, but this decrease is much smaller than that shown by field activity. In comparison with results in 1941, there was a reduction of about 44 per cent in the total number of wells drilled in the area (802 in 1942 against 1452 in 1941) This 44 per cent drop represents declines of 50.4 per cent in field wells and of 17.4 per cent in rank wildcats. Field wells (exclusive of 18 wildcats that discovered fields) totaled 598; also, 204 rank wildcats were drilled (see Tables 3 and 4). The corresponding figures for 1941 are 1205 field and extension wells and 247 rank wildcats. In this connection, it should be noted that whereas in 1941 the rank wildcats made up only 17 per cent of all wells drilled in the area, their percentage of the 1942 total was 25.4 per cent. In spite of the decrease of 43 in the number of rank wildcatst drilled, there were 18 new productive areas discavered, one more than the 17 new fields found in 1941. Thus the field-discovery rate for 1942, one new field for every 11.3 wildcats drilled, compares favorably with the I to 14.5 rate of 1941. Thirteen new producing levels were opened in fields; this includes the finding of 44' gravity crude on the west flank of the Sejita field in a 5700-ft. sand, which produccs distillate higher on the structure. Interesting, and showing the general scarcity of sand discoveries, is the fact that of the 13 new sands discovered, 7 were found in Jim Wells County. The year's sand-discovery rate of one new level for every 46 field wells compares very unfavorably with the I to 19.7 rate of 1941, during which 61 new producing horizons were found. Developmeilt of new fields was on a small scale. In several instances activity in these areas was not carried beyond the drilling of the discovery well. The field discoveries of 1942, together with the type of production obtained from the discovery wells and the total number of wells (productive and dry) drilled in them, are given below: Discovery Num- Field.I County Well her Produced Wells I. Cadena....... Duval Oil 2 a. Garza......... Duval Oil I 3. Dinn......... Duval Gas I 4. Keller......... Duval Gas I 5. East.......... Tim 0 11 I 6. Green Branch . McMullen Gas 3 7. Frost. .GreenBranch........ Starr Oil I 8. Garcia........ Starr Oil 6 9. Ulrich........ Starr Oil 4 10. Lykes......... Webb Oil 2 11. McLean....... Webb Oil 9 Iz. Alamo........ Hidalgo Distillate 2 and gas 13. Penitas....... Hidalgo Distillate 2 and gas 14. Xmpnan..... Jim wells i a 15. South Premont Jim Wells Distillate i and gas 16. Quinto Creek.. Jim Wells Gas 4 17. Roth.. . :..... Jim Wells Gas I I 18. South Sinton.. San Distillate I Patricio and gas . • See Table 2 for data on discovery wells and Table I for information on these fields. • See Table 4.

Jan 1, 1943

By J. F. Gallie

From the standpoint of exploration and new discoveries, South Arkansas had a discouraging year in 1944. In January there were 73 untested drilling blocks, and 60 additions were made during the year. Of the total, 65 were condemned by dry holes on or adjacent to them, while 5 proved productive. The latter resulted in the discovery of the Salem Church, Calhoun Wilks, and Strong fields, and the extension of the Village field to the southeast. The year ended with 63 untested blocks, 41 of which were scheduled for tests to the Smackover lime, the state's deepest oil-producing formation. Geophysical activity in 1944 totaled 164 crew weeks, of which 110 were seismic, 43 gravity, and 11 radioactive (Fig. I), in contrast with 674 crew weeks reported for 1943, of, which 563 were seismic and in gravity, Five seismograph and two gravity crews were engaged in exploration in South Arkansas during January 1944. but only two seismograph crews were working there at the end of the year. In addition, exploratory core drills were used for a total of 38 weeks during the year. The year's few discoveries, none of which is considered as having added appreciably to state reserves, were the meager results obtained in the drilling of 62 wildcat wells 2000 ft. or deeper. Of this total (a detail of which appears in Table 2), 42 were drilled to the Smack-over lime or below, The average depth of the 62 wells was 5384 ft., as compared with 4992 ft. in the preceding year, while the average depth of the 42 wildcats in the lime was 5913 ft. in 1944. Fig. 2 has been prepared to show all , wells penetrating to the Reynolds oölitic lime. The 1944 dry holes are circled lightly, while discoveries are heavily circled and shown as producers. Smackover lime fields, producing from the Reynolds oolitic lime member, are indicated in black, and the locations of dry wildcat wells drilled prior to 1944 are also shown. Table 3 provides a listing of all Smackover lime wells drilled through the end of 1944. Production for the year was slightly more than in 1943, totaling 29,282,747 bbl., as compared with 27,521,943 bbl. for the preceding year. The increase was 1,760,804 bbl., or 6.4 per cent, bringing production to a peak exceeded only in the 1923 to 1928 period of flush production from the older shallow fields, principally Smackover. The increase was largely attributable to additional development in the Dorcheat-Macedonia, Atlanta, Fouke, Stephens-Smart, Haynesville, and Village fields, little production deriving from 1944 discoveries. These six fields accounted for loo of the 122 field wells drilled during the year. Annual and cumulative production for the producing life of the state are presented graphically in Fig. 3. Fig. 6 has been prepared by the author to show the producing ages and present known productive limits of all fields in South Arkansas. Production data, as usual, are assembled in Table 2, and provide a further breakdown of producing formations in the individual fields.

Jan 1, 1945

(Under this heading will be published notes sent to the Secretary of the Institute by members or other persons introduced by members.) Member, mining engineer, technical education, married, 15 years' experience as foreman, superintendent, manager of examination and exploration work. Prefers Pacific Coast or Alaska, but will go anywhere. Available Nov. 25. No. 422. Mine manager or mill superintendent. U. S. A., Canada or Mexico preferred. Age, 33. Member. Five years mill superintendent, mills up to 2500 tons a day-gold, silver and lead; 6 years mining from bottom up to manager. No. 423. Member, mining engineer, technical graduate, age 40, 17 years' experience, having filled every position at a mine; superintendent of large mine at present. Familiar with all kinds of mining machinery. 'Best of reference. Available after Jan. 1, 1918. No. 424. Member, age 41, with 20 years' experience in design construction and operation of mining and smelting works and steam, electric and water-power plants, etc., who has held positions of responsibility in important concerns, desires a position requiring executive or engineering ability, or both. No. 425. Member, age 37, graduate mining engineer, with 29 years' experience in all phases of anthracite and bituminous mining, at present engaged as manager of one bituminous mine and consulting engineer for others, desires position as manager of a coal mine or consulting engineer for banking interests. No. 426.

Jan 1, 1918

By AIME

AS the Petroleum Division rounds off the first quarter century since its evolution from technical committee status, there steps to the long line of notable men who have presided over its activities a young man, currently of Tulsa, one Herbert F. Beardmore by name. For one year, as Chairman for 1946, the Division will be his oyster. hi; baby, his responsibility. "Herb" Beardmore was born at Columbus, Ohio, Feb. 6, 1904, and lived there until he was thirteen. Then his family moved to Oklahoma City, and later sent him to the University of Oklahoma, where he graduated in 1925 with a B.S. in engineering geology. His final year in college was the first year in which a petroleum engineering course was taught at the school. Since his course of study so closely paralleled that of a petroleum engineer, he has frequently been spoken of as the first petroleum engineering graduate from the University of Oklahoma. Out of college he went to work as an oil-field roustabout in the Ranger, Texas, field for Jake L. Hamon. This work consisted of all manual labor phases of cable-tool operation and beam-pumping of oil wells. He moved in 1926 to Bartlesville, to become a gas engineer for the Indian Territory Illuminating Oil Co., where he was employed in gas-well drilling, gas production, and transportation, mostly in Osage County, Oklahoma.

Jan 1, 1946

By K. D. Jacob

ALL types of commercial phosphate rock produced throughout the world contain fluorine in quantities ranging from approximately 0.4 to 1.3 per cent in the Curacao and Christmas Island phosphates to 3.1 to 4.2 per cent in the phosphates of the United States and North Africa1. For a given type of rock, the fluorine content is usually roughly propor-tional to the phosphorus content. SIGNIFICANCE OF FLUORINE IN PHOSPHATE ROCK On the basis of chemical and X-ray diffraction studies, Hendricks and co-workers2 concluded that fluorapatite, Ca10F2(P04)6, is the essential phosphatic constituent of the commercial types of domestic phosphate rock. On the other hand, Bredig and co-workers3 have recently advanced the opinion, also based on X-ray diffraction studies, that the mineral phosphates usually contain carbon dioxide in the apatite lattice, and that the phosphate rocks of. the United States are really fluorcarbonate apatites. However, the domestic types of phosphate rock do not seem to differ greatly from coarsely crystalline fluorapatite in their behavior toward chemical reagents in general, and for the purpose of this paper it will suffice to consider fluorapatite as being the essential phosphatic constituent of these types of rock.

Jan 1, 1936

By Charles Mitke

(San Francisco Meeting, September, 1915) INTRODUCTION THE Copper Queen mine is composed of seven divisions which are operated through the following shafts: Division Shaft Depth, Air Current No. Feet Uncle Sam 600 Downcast (shut clown April, 1914, to 1 curtail production) Southwest 600 Downcast 2 Czar 400 Downcast 3 Holbrook 600 Downcast 4 Spray S00 Downcast (shut clown April, 1914, to curtail production) 5 Gardner 1,000 Downcast 6 1 Dallas 1,400 Downcast 1 Lowell 1,600 Upcast 7 Sacramento 1,700 Downcast " I I The workings of the different shafts are connected by motor-haulage drifts on the even numbered levels. The general location of the orebodies and workings is illustrated by the vertical projection of orebodies of the district as shown in Fig. 1. The Uncle Sam, Southwest, and Czar workings have many connections to the surface through raises and extensive cracks that were caused by moving ground. These divisions are cool and are ventilated entirely by natural means. The Holbrook is ventilated partly by natural and partly by artificial ventilation, while the Spray, Gardner, Lowell; and Sacramento are ventilated entirely by mechanical means. In some of the divisions mentioned above a considerable quantity of air exhausts through shafts of adjoining properties.

Jan 9, 1915

By N. M. Raju, B. Singh

The paper seeks to present the results of experimentation in room and pillar stopes with different ground conditions to determine the safe working span. In the experimental stopes, ground movement was monitored with gradual widening of the room span. The field measurements included closure between the stope walls and the extent of ground movement in the hangwall using borehole extensometers. hock bolting was used as an exclusive support system which enabled introduction of scrapers for improving productivity. In one nine, phosphate bed, 3 to 3.5 m thick dipping at 45O and overlaid by weak laminated shale, was worked at shallow depth of cover. h the experimental panel, five s topes were worked with spans varying from 5.5 to 7 m. In the second mine, the chalcopyrite orebody up to 6 m in thickness dipping at 25 - 30" was worked at a depth of 1100 m. The hangwall consisted of fairly competent schistose rocks and therefore 10 to 15 m wide spans could be experimented. The field measurements confirmed that in the phosphate mine with weak shale roof, 7 m span could be safely worked with subsequent caving of the bolted roof. In the copper mine, 15 m span could be worked and the stopes required subsequent backfilling for better ground control.

Jan 1, 1983

By James Gardner

IN 1923, Oklahoma took second place as an oil-producing state; whereas in 1922 it was the leader. California surpassed it, in 1923, by nearly 100,000,000 bbl. In 1923, Oklahoma produced, according to statistics of The Oil & Gas Journal, 165,013,685 bbl., or an increase of approximately 10 per cent. over the preceding year; the increase in California was approximately 90 per cent. The number of wells drilled in Oklahoma and the results of the two years are contrasted in the following table from data published in a preliminary bulletin by the U. S. Geological Survey. 1922 1923 Oil wells 4,149,68%. 3,515, 60% Gas wells 571, 9 %u 587, 11% Dry holes 1,428,23% 1,731,29% Total wells 6,148 5,833 The initial production from wells drilled in Oklahoma in 1923, according to The Oil & Gas Journal, was the largest in the history of the state, being 1,277,936 bbl. It has been 32 years since oil development began in the state, last year being the largest in the amount of production. The production of the past year would have been considerably greater were it not for the shutdown order in the Burbank field and curtailment of production in the Hewitt and Tonkawa pools.

Jan 3, 1924

By the courtesy of Sir Robert Hadfield, we have received the fol¬lowing communication relating to the development and encouragement of science and research in Germany at present. These statements have been translated by Sir Robert from various German sources, and are presented here as an indication of what Germany is doing not only to further her military power, but also to prepare for the period of trade rehabilitation to which she is looking forward after the close of, the war. KAISER WILHELM TRUST FOR PROMOTION OF WAR SCIENCE The Kaiser has approved the foundation of a Trust with the name given above. The aim of the Trust is to further the development of scientific and technical aids to warfare, by uniting the scientific and the military forces of the country for work together. The scientific Work is to be carried on by the following technical committees (or commissions) (1) Committee for the chemical raw materials, for the production of munitions-manufacturing materials. (2) Committee for chemical war materials (powder, explosives, gas, and the like). (3) Committee for physics, including ballistics, telephony, telegraphy, determination of targets and distances, measurements, and the like. (4) Committee for engineering and communication. (5) Committee for aeronautics. (6) Committee for obtaining and preparation of metals.

Jan 8, 1918

By Frederick Forscher

Frederick Forscher (Nuclear Materials and Equipment Gorp.)—It is gratifying to see another series of experimental results that essentially reconfirms our reported observations of "Strain-Induced Hydrogen Embrittlement in Zirconium" (F. Forscher: AIME Trans., 1956, vol. 206, p. 536, noted as Ref. 3 of paper). However, several important considerations may have been overlooked, or—at least—have not been specifically pointed out. It is the purpose of this discussion to present some of these considerations. The statement is made that "the equilibrium concentration of hydrogen in solution at 20°C in zirconium is approximately 10 ppm; i.e., no zirconium hydride precipitates are formed at or below this hydrogen content." This is perhaps the case in the unstressed condition. In the presence of triaxial (plastic) strain however, even as little as 1.4 ppm H2 (Forscher's Figs. 6 and 11) will cause porosity near fracture in 20°C tests. The necked-down region that develops during a tensile test provides the triaxiality necessary for these pores to open. Both Beevers' and Forscher's micrographs show that porosity is concentrated in the necked region. So-called "pure zirconium" containing about 10 ppm H2 also shows pronounced porosity near fracture (Beevers' Fig. 3). Since it is generally agreed that such porosity is

Jan 1, 1965

By Cyril Stanley Smith

Although alloys of copper and silicon were examined several years ago,' and their excellent mechanical properties were shown, it was not until C. B. Jacobs 2 introduced manganese in small quantities to the alloys that they became of commercial importance. A few years ago The American Brass Company took over the patents and commenced to manufacture the alloy under the name "Everdur." The present study of the constitution of the ternary system was undertaken in order to reach a fuller understanding of the behavior of the alloy. Review of Previous WORK on the BinaRy Systems There have been no papers published dealing with the constitution of the ternary system, although some tests of the mechanical properties have been described," which indicate that there is a change in solubility with temperature. Copper-silicon System The copper-silicon system has been studied in detail by the author and is described in two papers published in 1928.V he portion of the diagram up to 8 per cent. silicon, as determined by this research, is reproduced in Fig. 1. The author's previous papers include a complete review of the work of other investigators and it is not necessary to deal further with this system here. Copper-manganese System The copper-manganese system has been investigated by several workers, notably Lewis,5 Wologdine,6 Sahmen7 and Schemtschuschny,

Jan 1, 1930

By E. M. Wise

THE properties required of gold alloys for jewelry are not well standardized, due in part to problems peculiar to certain branches of the jewelry industry, in part to the individual preference of the fabricator and to his willingness to cope with certain difficulties in manufacture, which arise with the use of certain alloys. GENERAL REQUIREMENTS In general, the properties desired may be classed as follows: 1. Color should conform to the dictates of good taste and smart style. 2. Corrosion resistance and tarnish resistance should be good. This is to a considerable extent determined by the carat. Resistance to such corrosive agents as mercuric chloride as well as certain depilatories is unreasonable to expect and difficult to meet. 3. Strength and hardness must be adequate to maintain the delicate contours of finely modeled jewelry. 4. Wear resistance must be great enough to resist abnormal wear, such as is encountered by a wedding ring in a lifetime of wear. 5. Ductility must be sufficient to permit the fabrication of drawn shells, tubes and difficult shapes. Material having a yield point of not less than 60,000 lb. per sq. in., an ultimate strength of 100,000 lb. per sq. in., and an elongation of 40 per cent. is desirable. 6. Melting point should be between 800° and 1200° C.

Jan 1, 1928

The 128th meeting of the American Institute of Mining and Metallurgical Engineers constituted a two weeks trip through the Great Northland of Ontario and Quebec and was a most memorable occasion. The last visit of the Institute to Canada was made in 1907 when the mines, which now have brought world wide fame to some of the camps, were not yet dis-covered. The party reached its greatest numbers at Porcupine where 167 visitors and nearly one hundred local members participated. Five members of the party from the States were on the previous trip in 1907. They were Mr. and Mrs. L. D. Huntoon, John Stevenson and son and E. F. Eurich. The Minister of Mines for the Province of Ontario attached his private car to the "Mining Engineers' Special" and made the complete trip through Ontario. This was a happy incident in many ways and gave the visitors an opportunity to discover a spirit of mutual accord between the Minister and mining industry that might well be emulated elsewhere. Two compartment cars and one standard Pullman with the Institute members from New York and the metropolitan district were attached special to the 6.15 p.m. Lehigh Valley train from New York, Sunday, Aug. 19, en route to Toronto, where was held the first session of the Institute's 128th Meeting.

Jan 9, 1923

By Werner Goldsmith, Akihiko Kumano

An experimental investigation was conducted to study the response of soft, porous rock, green shale, under dry and liquid-filled conditions to normal impact of hemispherically-tipped cylindrical steel projectiles with diameter and mass of 6.35 mm and 31 g, respectively. Disk-shaped green shale specimens with nominal thickness and diameter of 32 mm and 127 mm, respectively, were tested in the initial projectile velocity range of 18 to 42 m/s. For the liquid-filled tests, the green shale specimens were saturated with kerosene. A total of eight impact tests were conducted. Information on the extent and pattern of the damage in the rock and velocity histories of the projectiles were collected. It was found that while the penetration depth was quadratically related to the initial projectile kinetic energy for the dry case, the penetration depth for the liquid-filled case was directly proportional to the initial projectile kinetic energy. The results of the impact tests under dry and liquid-filled conditions conformed well to a linearly viscous model and a Coulomb frictional model, respectively. The major deformation processes in the dry specimens were found to be compaction and equivolumnial distortion of the material. In the liquid-filled case, however, formation of cracks and equivolumnial distortion with less material compaction were observed. Furthermore, craters were formed as a result of the crack formation in the liquid-filled specimens.

Jan 1, 1982

By J. E. Coyne, L. E. Tanner, J. E. Boyd

In recent investigations of the isothermal transformations of the retained 0 phase in a titanium alloy having 13 pct V, 11 pct Cr, and 3 to 4 pct Al, there have been indications that the w transition phase is the initial decomposition product at temperatures below about 950°C (510 c).' This metastable phase, found in a number of titanium-base alloys rich in stabilizing elements and known to have an adverse effect on their ductility and toughness, is not easily observed by the usual experimental techniques. Since wis coherent with the /3 matrix,495 distinct interphase boundaries are not revealed metallographically. However, in some cases, an etching effect (i-e., a "mottled" /3 surface) poorly resolved by light microscopy has been found to correspond with the presence of w.6 X-ray diffraction examination has generally been the most suc- cessful means for identifying this phase and crys-tallographic determinations have been made.4'5 Dynamic elastic modulus7 and electrical resistivity measurementse have also aided in the identification of w. In the current study, the electron microscope was utilized to examine microstructures in aged Ti-13V-11Cr-3A1 that were unresolvable by light microscopy techniques. Using negative parlodion replicas (shadowed with chromium at 27 1/2 deg) examination was made of various transformation

Jan 1, 1962

By W. L. Zeigler

The mill is a departure from gravity concentration and has gained a reputation for the low initial cost of erection, extreme simplicity and the low cost of milling on the refractory character of the ore which is treated. The structure is of heavy timbers with board walls and corrugated roofing. The floors are concrete and the general layout is of the ground floor only. All the machines are driven by individual motors and the transmission usually found in such a plant is entirely absent. (Fig. 2.) ORE The ore from the Galena mine is sheared Wallace quartzite replaced with quartz, siderite, pyrite, sphalerite, gray copper (tetrahedrite) and very fine-grained argentiferous galena. Much of the silver is undoubtedly associated with the gray copper, the amount, however, apparently varies with different localities in the vein. An average assay of the ore is 6.0 per cent. lead, 1.3 per cent. zinc, 0.3 per cent. copper, 17.5 per cent. iron and 4.5 oz. silver. The concentrates produced are of an average 53 per cent. lead, 40 oz. silver, 8 per cent. zinc and 11 per cent. iron, while the tailings are 0.5 per cent. lead, 0.4 oz. silver. With the present market for zinc no attempt is made to produce a zinc concentrate.

Jan 1, 1927

By A. P. Herring, S. F. Ravitz

Manganese dioxide reacts with sulfur dioxide solution in the absence of oxygen to form manganous ion and dithionate ion, together with a small amount of sulfate ion. The effects of SO, concentration, hydrogen ion concentration, stirring speed, and temperature on the rate of the reaction were studied. If it is assumed that undissociated SO2 molecules react rapidly with MnO, at active surface sites and that bisulfite ions react slowly, an equation can be derived that satisfactorily represents the observed reaction rates. For solutions in which the reaction with undissociated SO2 predominates, reaction rates and activation energies estimated from diffusion theory agree well with those found experimentally. Manganese dioxide dissolves readily in aqueous solutions of sulfur dioxide. The nature of the dissolution reaction was first investigated by Gay-Lussac and welter1 in 1819; they identified a new oxysulfur radical, the dithionate ion, S2O6, as one of the reaction products. Since then, the reaction has become a standard method of preparing dithionates in the laboratory and one of the more promising methods of leaching manganese from low-grade ores. In the "dithionate process" developed by the U.S. Bureau of Mines2,3, manganese-dioxide ore is suspended in a solution of calcium dithionate and leached with gas containing sulfur dioxide. The manganese is dissolved and the sulfur dioxide is oxidized according to the reactions:

Jan 1, 1965