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By Saluja, Sunder S.

Man had to learn to break rocks as early as the Stone Age, when they formed his main source of raw material. He started with chipping and over the years has reached a stage where he can employ atomic blasts and break, with one blast, millions of tons of rock. In between these two extremes there have been several stages of development including fire setting, use of the expansion of water on freezing in chipped cracks in cold climates, the use of low or deflagrating explosive black powder in about the 17th century, the use of high explosives with the discovery of nitroglycerine in 1846 by Sobrero, followed by the monumental discoveries of the great Swedish scientist Alfred Nobel in the latter half of the nineteenth century.

Jan 1, 1968

By M. C. Fuerstenau, D. N. Collins, R. B. Bhappu, D. N. Moir

D. N. Moir (Senior Scientific Officer, Warren Spring Laboratory, D.S.I.R. Stevenage) and D. N. Collins (Scientific Officer, Warren Spring Laboratory, D.S.I.R., Stevenage, England) — During work on the petroleum sulphonate flotation of beryl in 1959 at Harwell, and subsequently at Warren Spring Laboratory, effects similar to those mentioned by the authors were noticed. Brief details of some of this work were given to the 6th International Mineral Processing Congress at Cannes.' It is interesting to note that the authors experienced strong activation effects with Fe+++ ions on beryl when using petroleum sulphonate collectors. This phenomenon was of interest in our work when

Jan 1, 1963

By Roland Kammel, Takeo Oki

A suspension electrolysis method has been developed which enabled a direct anodic extraction of zinc from zinc sulfide concentrate and simultaneously oxidized sulfide sulfur to elemental sulfur. The investigation was performed in a laboratory-scale electrolytic cell, where the zinc sulfide concentrate particles (chemical composition in weight percent: 61.1% Zn, 2.3% Fe, 30.6% S, 3.4% SiO2 were suspended with or without graphite powder in a dilute sulfuric acid electrolyte. The main parts of the cylindrical electrolytic cell are shown in [Fig. 1]. The cathode (1), a rod of aluminum, is set at the center of the cell. The anode (2), which consists of four plates, is mounted on the inner face of the cell wall. Both PbO2(Pb) and graphite anodes were used. The cathode compartment (3) is separated from

Jan 1, 1976

By H. J. Wogner

STORAGE of natural gas in underground reservoirs is one of the most important developments in the natural gas industry in recent years. However, it is only when we consider this development together with proved fuel reserves, the know-how of the fuel technologist, and the possibility of making manufactured gas available over large areas, that we begin to appreciate fully the impact that underground storage of gas may have on the future growth and development of large areas in the United States. During the past winter, shortages of natural gas in the industrial East were given wide publicity and domestic consumers were requested to reduce their requirements to a minimum, so that war plants might have sufficient gas to continue operations. Curtailments would have been more drastic except for the fact that large volumes of natural gas had previously been stored in underground reservoirs. Storage of natural gas in depleted or partly depleted gas or oil sands is not new, having originally been tried, as far as I know, about 1915. About five or ten years later an attempt was made to store manufactured gas in a depleted gas sand. This proved unsuccessful at first because the gas was not properly cleaned and the impurities plugged the pores in the sand.

Jan 1, 1945

By Charles H. Hopkins, J. M. Lohr

A commercial development requiring a suitable alloy or alloys for sealing into various grades of glass made it desirable to have a more exact knowledge of the expansion characteristics of the nickel-iron alloys than appeared in the published literature. The expansion of the more common types of glass under consideration varies from 2.7 to 10.4 X 10-6 per degree Centigrade, over the range 20" to 400' C. For reference, the t,hermal expansion curves of several types of glass used for sealing by the lamp and tube industries are given (Figs. 1 and 2). This paper covers a detailed investigation of the thermal expansion of a series of nickel-iron alloys in which the nickel content varies from 30 to 70 per cent. Particular stress is laid on the alloys that contain between 40 and 55 per cent Ni.

Jan 1, 1939

By Charles H. Hopkins, J. M. Lohr

A commercial development requiring a suitable alloy or alloys for sealing into various grades of glass made it desirable to have a more exact knowledge of the expansion characteristics of the nickel-iron alloys than appeared in the published literature. The expansion of the more common types of glass under consideration varies from 2.7 to 10.4 X 10-6 per degree Centigrade, over the range 20" to 400' C. For reference, the t,hermal expansion curves of several types of glass used for sealing by the lamp and tube industries are given (Figs. 1 and 2). This paper covers a detailed investigation of the thermal expansion of a series of nickel-iron alloys in which the nickel content varies from 30 to 70 per cent. Particular stress is laid on the alloys that contain between 40 and 55 per cent Ni.

Jan 1, 1939

By Iichiro Omori

THE Mabuki process, a Japanese hearth process for the treatment of matte, uses the same princi-ple as the Bessemer steel process. The only difference between the two is that in the Mabuki proc-ess a hearth furnace, not a converter, is used. Though the hearth is not as good as the converter, the first cost is very low and the capacity is compara-tively small; so the process is most suitable for smelters FIG. 1.-PLAN AND SECTION OF HEARTH. having a small production. To construct the hearth, an excavation, 6 ft. in each dimension, is made in the ground and a drainage channel is dug at the bottom. Then all side walls are faced with stone or slag brick and the cavity is filled with fireclay or brasque, except the hearth at the top.

Jan 9, 1922

By CARLE R. HAYWARDC

BEFORE discussing this subject it is necessary to define somewhat the meaning of the tern metallurgical.. When I was a student at M. I. T. ore-dressing was not thought of as metallurgy in any sense of the word, but it was considered as more closely allied to mining, enabling the miner to market an otherwise unmarketable product, or at least to market it to better advantage. Progress in ore-dressing has gradually allied it more closely with smelting, for at present the raw material received by the smelter is predominantly concentrates and smelting practice has been profoundly affected by the products of the concentrating mill. It is not surprising therefore that in many schools ore-dressing is frankly considered as metallurgy and although there may be some dissenting opinions it will be considered as such in this discussion. Twenty-five years ago at M. I. T. metallography was taught in a few optional lectures. This subject has developed rapidly and been expanded into the new and increasingly important field of physical metallurgy. To many metallurgists the -term metallurgy means only physical metallurgy. They know little or nothing about smelting and leaching and even less about ore-dressing. Having then broadened the scope of the term metal¬lurgy to cover ore-dressing, smelting, leaching and phys-

Jan 1, 1930

By L. O. Howard

THERE are three active mines in the Chewelah-Colville district, the United Silver Copper near Chewelah, and the Old Dominion and the Chloride Queen near Colville. The Admiral near Valley is also doing development work. The Chewelah district is in the south central part of Stevens County in the Colville Valley. Chewelah, a thriving town of 1600 people, and the scene of operations of the Northwest Magnesite Co., is about the center of the district. It is situated in a farming community on the Spokane-Nelson branch of the Great Northern railway, about 65 miles north of Spokane. Only two or three of the mines in the district have been extensively developed, although many have been prospected. The general elevation of the valley, is about 1600 or 1700 ft., that of the mountain ranges on each side about 3000 to 4000 ft., with gentle slopes and rounded glaciated tops. Prospecting is often difficult because of much glacial debris.

Jan 1, 1925

By R. T. ROLFE

IN this critical age, people are not content .with the judgments passed on men and things long ago, but must needs revise them. It is an excellent spirit, so long as we do not start out with the idea that old opinions must necessarily be wrong, and that all ancient malefactors must therefore be whitewashed. That interesting ogre, Gilles de Retz, to whom the process has recently been applied, is no longer with us, so no one will be the worse for it, but the old bugbear8 of the steelmaker, sulfur and phosphorus, still are, and now Mr. McIntosh, in a recent article in these pages, asks us to regard one of them in a new light.' This article is a most interesting one, with much of which one must agree. One of his -statements, how- ever, although correct, is somewhat' misleading, and he rather discounts the fundamental objection of the steelmaker to phosphorus, its dangerous propensity to segregate and the secondary effect on the carbon distribution and therefore on the homogeneity of the steel that is produced thereby. Further, the evidence on which he bases his claim that phosphorus does not lower the impact strength of steel is rather slight. The writer views with the utmost misgiving any proposal to increase the amount of phosphorus in steel, and cannot regard it in any other light than as a prejudicial impurity, to be kept down to as low a proportion as possible. It thus becomes necessary to examine the evidence upon which Mr. McIntosh's claims are based

Jan 1, 1926

By G. D. TRANT

HOT metal is commonly transported from the blast furnace to the open hearth by one or the other of two general methods: (1) by hot-metal ladles, usually in conjunction with a stationary mixer, or; (2) by means of mixer-type ladle cars, taking the place of both the hot-metal ladles and the stationary mixer. In both cases, the use of transfer ladles for charging the metal into the open-hearth furnaces is necessary. The American Rolling Mill Co. at its Middletown division, adopted hot metal practice on. June 2, 1928. The pig iron is produced' in a .blast furnace about 11 miles from the open-hearth furnaces, and is trans- ported in Pugh-type mixer cars having a capacity of 150 gross tons each. Three cars are in service and handle the delivery of hot metal to the pig machine and the open-hearth furnaces. The capacity of the blast furnace is 550 tons and casts are made every four hours.

Jan 1, 1929

By W. A. Tiller

SEVERAL authors1-6 have shown that, during solidification from the melt, the direction of formation of substructure boundaries depends upon the direction of heat flow and the rate of solidification of the metal. The most prominent of these observations was that a preferred orientation developed during the solidification of the columnar zone of an ingot which for face-centered-cubic metals was the <100> direction. Previous explanations1-&apos; given to account for this preferred orientation and the other boundary phenomena are all based on the premise that the phenomena are characteristics of the pure element. However, recent experiments by Rosenberg and Tiller7 have demonstrated that the preferred orientation in pure lead is the <111> orientation, and that the heretofore observed <100> orientation is due to the effect of solute on the mode of solidification of the metal. Teghtsoonian and Chalmers,4 studying striation boundaries in tin, and Chalmers and Rutter,5 studying corrugation boundaries in tin, showed that these substructure boundaries were aligned parallel to the axis of heat flow for slow rates of growth, and that the alignment varied from this direction as a function of the rate of growth. to approach the den-drite direction at high rates. Chalmers,6 studying the direction of formation of a grain boundary separating two crystals of different orientation, showed that at slow growth rates the boundary is parallel to the axis of heat flow, while at higher speeds it will deviate from this direction, sloping into the crystal whose dendrite orientation departs the most from the axis of heat flow. It is this phenomenon that allows certain crystallites in the chill zone region of an ingot to encroach on their neighbors and ultimately produce the preferred orientation of the columnar zone of the ingot. Since the previous explanations of this preferred orientation are unable to account for the recent observations,&apos; a new mechanism will be considered. This will lead to an explanation of the other substructure boundary phenomena as well. Investigations by Graf,8 Billig,9 Rsenberg,10 and others have demonstrated in a striking fashion that crystal growth takes place by the deposition of individual layers oriented along the close-packed planes of the material considered. This lamellar or

Jan 1, 1958

By Henry Seltz, Cyril Wells, Hugh J. MacDonald

Several investigators have measured the heat capacity of cementite, using different methods of attack, but the agreement between the values obtained cannot be considered good. Naeserl has made measurements of "average heat capacities" of iron carbide between 1026" and 85" K., using a water calorimeter. His computed true specific heat at 78.1" K. is 11.22 cal. per gram-formula mass, which, if correct, is much too high for any reasonably accurate extrapolation to 0" K. The cementitc used by Naeser was obtained from a steel containing 0.9 per cent carbon, by electrolytically dissolving out the iron in a neutral bath of ferrous chloride. The cementite remained as a coarse, crystalline, gray powder. Andes2 has measured the specific heat of iron carbide, from 102" to 323" K., as it exists in steel. The specific heats of several slugs of steel of known iron carbide content were determined, and the specific heat of the iron carbide (Fe3C) calculated by plotting specific heat versus percentage of carbon, and extrapolating to pure Fe3C (6.7 per cent C). The heat-capacity values for temperatures below 100" K. were obtained by comparing the temperature-specific heat curve for Fe3C to that of Fe. Since the two were very similar in the range examined experimentally and approach more closely at low temperatures, it was assumed that near the absolute zero the form of the curve for Fe3C would be similar to that of Fe. Andes calculates for the entropy of Fe3 C,S298 = 23.55 e.u. The heat of formation of Fe3C has been studied by several workers. Kelley3 has reviewed these measurements and calculations, and selects those of Roth* and Naeser6 as worthy of most consideration. Roth has given AH = 5400 cal. + 30 per cent as a result of his own and other work. Naeser has determined the heat of formation from Fe and different forms of carbon, and for graphite (0) he finds AH = 5600 cal. Kelley accepts the rounded figure AH = 5500 as the heat of formation at 298.1" K., but this value is quite uncertain.

Jan 1, 1940

By Henry Seltz, Hugh J. MacDonald, Cyril Wells

Several investigators have measured the heat capacity of cementite, using different methods of attack, but the agreement between the values obtained cannot be considered good. Naeserl has made measurements of "average heat capacities" of iron carbide between 1026" and 85" K., using a water calorimeter. His computed true specific heat at 78.1" K. is 11.22 cal. per gram-formula mass, which, if correct, is much too high for any reasonably accurate extrapolation to 0" K. The cementitc used by Naeser was obtained from a steel containing 0.9 per cent carbon, by electrolytically dissolving out the iron in a neutral bath of ferrous chloride. The cementite remained as a coarse, crystalline, gray powder. Andes2 has measured the specific heat of iron carbide, from 102" to 323" K., as it exists in steel. The specific heats of several slugs of steel of known iron carbide content were determined, and the specific heat of the iron carbide (Fe3C) calculated by plotting specific heat versus percentage of carbon, and extrapolating to pure Fe3C (6.7 per cent C). The heat-capacity values for temperatures below 100" K. were obtained by comparing the temperature-specific heat curve for Fe3C to that of Fe. Since the two were very similar in the range examined experimentally and approach more closely at low temperatures, it was assumed that near the absolute zero the form of the curve for Fe3C would be similar to that of Fe. Andes calculates for the entropy of Fe3 C,S298 = 23.55 e.u. The heat of formation of Fe3C has been studied by several workers. Kelley3 has reviewed these measurements and calculations, and selects those of Roth* and Naeser6 as worthy of most consideration. Roth has given AH = 5400 cal. + 30 per cent as a result of his own and other work. Naeser has determined the heat of formation from Fe and different forms of carbon, and for graphite (0) he finds AH = 5600 cal. Kelley accepts the rounded figure AH = 5500 as the heat of formation at 298.1" K., but this value is quite uncertain.

Jan 1, 1940

By R. Maddin, S. K. Tung

SUCCESS of the dislocation theory in formulating the transitional lattice theory proposed by Har-greaves and Hill in 1929&apos; is well established for low angle grain boundaries. The theoretical work of Burgersa and Read and Shockley,3 together with the experimental observations of Aust and Chalmers4 and Parker and colleagues,6 leaves little doubt as to the structure of grain boundaries with differences of orientations up to between 15" and 20". Beyond these angles, the structure of the boundary is not so clear, and is still a matter for conjecture. There have been notable experiments devised from which the data could be used to calculate energetics for possible arrangements of atoms in forming a large angle boundary.6 Most of these experiments deal with diffusion through and along the grain boundary. The recent work of Rhines and Cochart7 and Rhines, Bond, and Kissel18 was concerned with the relative movement of grains in aluminum bicrystals under constant tensile loads with their boundaries aligned at 45 " to the tension axis. The gliding along the grain boundary was cyclic and began after an incubation period. The velocity of gliding increased with the sum of the angular difference, 8, between the operative slip direction in the conjugate crystals and the angular difference between the active slip planes as measured between their traces upon the grain boundary. The initial gliding rate varied with temperature, and the logarithm of the average gliding taken over a considerable period was a linear function of the reciprocal of the absolute temperature: the slope gave an activation energy of 11,000 ±1,000 cal per mole. Since the rate of grain boundary shear is sensitive to the misorientation of the grains themselves, as shown by several workers,7,8 it is suggested that further work of this type might be fruitful in adding information regarding the behavior of boundaries under stress. The techniques devised by Chalmers" added impetus to the facility for observing grain boundary behavior, in that they provided a simple means for producing bicrystals of predetermined orientation so that the angle of the boundary could be controlled,

Jan 1, 1958

By R. H. Marshall, J. Welchner, E. S. Rowland

THIS paper presents results on an exten¬sion into the realm of high-carbon steels of some work recently published&apos; on the effects -of time at temperature, quenching temperature and prior structure on the hardenability of one 0.20 and four 0.40 per cent carbon alloy steels. It was shown at that time that unless the conditions of time, temperature and prior structure are substantially the same in performing the hardenability test as in conducting harden¬ing of parts in production, the correlation of hardenability information with the [ ] hardness and properties of production parts is often not of satisfactory accuracy. The general effects of these variables on the austenitic grain size, distribution of excess carbides and critical cooling rate have been known for many years and one or more have been investigated by Shepherd ,2 3 Davenport and Bain,4 Digges,5,6 Digges and Jordan,7 Post and associates&apos; and Roberts and Mehl,9 to mention only a few. There has been no systematic investigation, however,&apos; into the quantitative variations produced on the hardenability of commercial high¬carbon steels by changes in these factors of time, temperature and prior structure. PROCEDURE A plain carbon hypereutectoid steel, S.A.E. 52100 and Graph-Mo, a molyb¬denum-bearing high-carbon steel contain¬ing some graphite, were chosen for this investigation. The chemical analyses of these electric-furnace steels are given in Table I. [ ] The procedure used was exactly that reported previously,&apos; hence the details will not be repeated here. Normalized (1650°F.) and spheroidized prior structures were utilized on all steels with hot-rolled and quenched (1600°F. oil) prior conditions added for the plain carbon steel. The end-quench test developed by Jominy10 was selected for use in this investigation and, with the noted exceptions, the American Society for Testing Materials standard. procedure was followed. The effect of time at temperature was examined at intervals of 0, 10 and 40 min. and 4 hr., and a few i6-hr. tests were run. Salt-bath heating of the specimens was employed to control and minimize the

Jan 1, 1944

By L. E. Young

THE purpose of this paper is to start a discussion on: (1) methods of supporting the immediate roof, particularly of local areas of poor roof, during the mechanical loading of coal; (2) methods of increasing the rapidity of the movement of the mining faces so that, without the use of cribs, jacks, pack walls, and filling, there will be no danger to men, equipment,, and working places from the subsidence of the overlying strata. In the Pittsburgh district the application of mechanical loading devices in mines working in the Pittsburgh seam, has been retarded by the difficulties of holding and handling the draw slate. Normally the thickness of this slate averages about 8 in. but the hardness varies, and a cut of coal cannot always be loaded without placing posts or crossbars to support the slate. Locally, the slate may be thicker and special methods of support may be required. If crossbars are placed to hold the slate when the coal averages 5 ft. in thickness, the standard methods of transporting the coal cannot be followed, and the use of conveyors may be desirable. Very little information is available on the effect of increasing the rate of movement of advancing or retreating break lines or longwall faces. A few British publications have presented some data but all such data relate to longwall faces that have moved not more than 6 ft. a day. The most rapid rate of movement of longwall faces in Germany is 6 ft. per day. In the ordinary hand-loading mine in western Pennsylvania break lines on full retreat will move about 2 ft. per day. If loading machines are used under similar conditions the, rate of retreat may reach 4 ft. per day. In a mine where coal is loaded by hand on conveyors three shifts per day, the rate of retreat has ranged from 11 to 16 ft. per day, with an average of 13 ft. If mobile loading machines could be used to load on con-veyors on break lines, the rate of retreat should be increased substantially.

Jan 1, 1938

By Raymond O. Ladoo

FUSED quartz is a glass made by the fusion of nearly pure silica. Some confusion in terminology exists but in the trade today "fused quartz" generally refers to the perfectly transparent colorless product made from rock crystal whereas "fused silica" is a white, translucent product made from silica sand. Vitrified silica is the term preferred by purists for all quartz glass, but it lacks the definiteness of -the trade terms. Since the raw materials, methods of production, and properties of the finished products arc different for the two types, the trade terms are preferred. As fused quartz is amorphous, it-physical properties differ greatly from those of quartz crystal. Lacking crystallographic directions and having no piezo-electric properties, fused quartz. of course, has no value for the making of radio oscillator plates; but it does have other valuable and unique properties. Perhaps the &apos;best known and most useful properties are its extremely low coefficient of expansion and its ability to transmit short-wave ultraviolet radiant energy. Crystal quartz not only has an aver-

Jan 1, 1947

By R. E. Collins, Paul B. Crawford

Mathematical equations have been derived to show the effect of the slippage phenomomenon (Klinkenberg effect) on unsteady-state gas flow through porous media. The assumption is made that the slippage may be represented by an equation of the type It is pointed out that most of the existing data on unsteady gas flow may be corrected for slippage by a simple change in definition of the dimen-sionless groups. INTRODUCTION Several solutions to the various problems associated with the unsteady-state flow of gas through porous media have been recently presented in the literature.&apos;,&apos;" The cited publications have resented solutions for flow under ideal conditjons. The principal assumptions involved include: (a) the density of the gas obeys the perfect gas law; (b) the viscosity of the gas is constant; and (c) the gas permeability is constant. Few, if any, actual gases under reservoir conditions are believed to conform with the above, but the ideal solutions do provide the basis for making improved estimates on the performance of gas reservoirs. The purpose of this paper is to show the performance characteristics when assumption (c) is corrected for the slippage phenomenon or the Klinkenberg effect. This is believed to be a step nearer to reality. MATHEMATICAL DEVELOPMENT Case 1. Gas Flow — Ideal Conditions The equations describing the flow of gas under ideal conditions have been clearly presented in the cited literature; however, for completeness of this work they are repeated here. The basic differential equation describing the flow of gas is Equation (6). It may be derived as follows: The continuity equation, the perfect gas law and Darcy&apos;s law are combined to give: Manuscript received in the Petroleum Branch office Aug. 3, 1963 or If — is constant, Equation (5) is rewritten to form the basic Equation (6). or for the linear case A dimensionless equation is obtained by dividing through by (pl)z and making the substitutions shown below: The resulting equation is A similar procedure for the radial case leads to the following equations: where and Equations (11), (12), and (13) are those used by Bruce, et al., and Jenkins and Aronofsky for their computational work.

Jan 1, 1953

By Gilbert Cady

EXTENSIVE Sampling of coal in Illinois during the past 10 or 12 years by the State Geological Survey, in cooperation with various organizations, such as the U. S. Bureau of Mines, the University of Illinois, and the Illinois Cooperative Mining Investigations, has made possible the delineation of two areas of low-sulfur coal in the southern part of Illinois. The sulfur content is less than 1.25 per cent., so that, if otherwise suitable, these coals can be employed for metallurgical uses and for the manufacture of water-gas and retort gas. One of these areas is small and lies in Jack-son County, near Murphysboro, the other is much larger and includes a large part of the famous Franklin County field. A small area of No. 2, or Murphysboro, coal has been worked for many years near the town of Murphysboro, Jackson County, Ill. In two mines, at least, the coal has a sulfur content of less than 1.25 per cent. It is doubtful, however, whether this field will ever be a source of large tonnage as the total area underlain by low-sulfur coal in workable thickness is probably less than 15 sq. mi. (24.14 sq. km.), and a large part of it has already been worked out. The location of the area of low-sulfur coal in the Franklin County field is shown in the accompanying map. The small area underlain by the Murphysboro low-sulfur coal is shown near the town of that name in the central part of Jackson County. The larger area lies in the west side of Franklin County, extending also about 6 mi. (9.65 km.) south into Williamson County, about 4 mi. (6.43 km.) west into northern Jackson and western Perry County, and northward an undetermined distance into Jefferson County. All but the northern limit of the area is fairly well defined by sampling in numerous mines. The inner cross-lined area is underlain by coal having less than 1 per cent. sulfur, the outer boundary surrounding the area Underlain by coal having less than 1.25 per cent, sulfur.

Jan 7, 1919