Search Documents

By Bernard H. Coyle, Robert N. Anderson, Judith A. Koperski

Between 6 and 8 million cars are shredded annually in the U.S. This shredded material is magnetically separated leaving a mixture of nonmetallics and nonferrous metals which can be further separated into its metallic and nonmetallic constituents. The metallic portion is a mixture of metalr; and alloys containing predominately zinc, and some aluminum, copper, and residual iron. Hydrometallurgical strategies are proposed for recovering the aluminum, copper, and zinc. The thermodynamic and kinetic behavior of the most promising alternatives to separation are discussed.

Jan 1, 1978

By Walter Nummela

INTRODUCTION By the end of 1979 pellet productive capacity from the processing of low grade iron ores in the Lake Superior-District will total 86 million tons per year. Of that tonnage, 72 million result from the processing of magnetic ores such as taconite, about 6 million tons from the flotation processing of relatively coarse grained specular hematite, and 8 million tons from the processing of fine grained non- magnetic ores at Tilden. The Tilden flowsheet represents a break- through in the processing of this type of crude ore and hence is unique in the Lake Superior District (1). Operations at Tilden started in late 1974 with Algoma Steel, J&L Steel Corp., The Cleve- land-Cliffs Iron Company, The Steel Company of Canada, Ltd., Wheeling- Pittsburgh Steel Corp., and Sharon Steel Corp. as participants. Cleveland-Cliffs operates and manages the operation. Other companies have conducted extensive pilot plant tests or are in commercial production in the processing of fine grained non-magnetic ore materials (2). Flowsheets and reagent schedules may be different for each particular application, but some of the problem areas in the processing of Tilden ores have also been experienced at operations such as the IOC Plant at Sept-Isles, at Lamco and at Bong in Liberia, and in pilot testing of Fabrica ores of Ferteco Mineracao in Brazil. With a grind of about 80-85% -500 mesh resulting in 50% of the particles in the concentrate being less than 15 microns, a discussion of the pro- cessing of Tilden type ores fits the topic of this workshop. There are very large tonnages of fine grained non-magnetic crude ores which exist throughout the Lake Superior District and other iron ore producing regions. These fine grained non-magnetic materials constitute an important source of iron minerals. Before going into specifics of the flowsheet, it is important to

Jan 1, 1979

By Magnus Troilius

SINCE the discussion on steel rails in America has forcibly drawn attention to the value of chemical analysis, if not as a necessary stipulation, at least as a guide to control the usual mechanical tests, some doubt has been thrown upon the accuracy of the analytical results obtained by different chemists. To any one having the least acquaintance with chemistry, it is quite clear that if exactly similar results are to be obtained from the same borings of steel, exactly the same methods must be used by the different analysts. Hence the necessity (if complications are to be avoided) of establishing what I may call standard or normal methods, to be used both by the inspectors and by the chemists at the works. Remembering that the application of chemistry to steelrail inspection is yet in its infancy, it is of great importance to possess a perfect acquaintance with the best methods in use. Being myself a grateful pupil of Professor Eggertz, of the School of Mines in Sweden, it occurred to me, two years ago, that I could not do better than start a laboratory of my own, and engage one of his pupils, Mr. Troilius, for the purpose of analyzing the steel borings from mechanically-tested rails, so that I might thus obtain without delay thoroughly accurate determinations. Moreover, in order to carry on the operations in perfect accordance with the methods used at the steel works in England and Germany, where I had to control the manufacture, I deemed it desirable to allow Mr. Troilius to go through a course of training at these works; and I gladly seize this opportunity of expressing my grateful acknowledgments to several works in England and in Germany for affording every facility for such an exchange of information as mas found necessary in arriving at the best analytical methods to be used.

Jan 1, 1882

By Magnus Troilius

INTRODUCTION BY C. P. SANDBERG. SINCE the discussion On steel rails in America has forcibly drawn attention to the value of chemical analysis, if not as a necessary stipulation, at least as a guide to control the usual mechanical tests, some doubt has been thrown upon the accuracy of the analytical results Obtained by different chemists. To any One having the least acquaintance with chemistry., it is quite clear that if exactly similar results are to be obtained from the same borings of steel, exactly the same methods must be used by the different analysts. Hence the necessity (if complications are to be avoided) of establishing what I may call standard or normal methods, to be used both by the inspectors and by the chemists at the works. Remembering that the application' of chemistry to steel-rail inspection is yet in its infancy, it is of great importance to possess a perfect acquaintance with the best methods in use. Being myself a grateful pupil of Professor Eggertz, of the School of Mines in Sweden, it Occurred to me, two. years ago, that I could not do better than start a laboratory of my. own, and engage One of his pupils, Mr. Troilius, for the purpose of analyzing the steel borings from mechanically-tested rails, so that I might thus Obtain without delay thoroughly accurate determinations. Moreover, in Order to carry on the, operations in perfect accordance with the methods used at the steel works in England and Germany, where I had to control the manufacture, I deemed it desirable to allow Mr. Troilius to go through a course of training at these works; and I gladly seize this opportunity of expressing my grateful acknowledgments to several works in England and in Germany for affording every facility for such an exchange of information as was found necessary in arriving at the best analytical methods to be used.

Jan 1, 1882

Note Any member who desires to be designated as being "Available for Consulting Work" can arrange it simply by sending a written request to the office of the Secretary of the Institute The following list of members is primarily arranged geographically, with secondary consideration to political subdivisions arranged alphabetically First, the states of the United States , then other North America, in order Alaska, Canada, Mexico, the West Indies, and Central America Then cones South America, Europe, Africa, and Asia, each including the near by islands associated with those continents Australia, the islands to the north, and the Pacific islands except Japan are grouped together under Oceania The various countries are indexed on the preceding page NORTH AMERICA UNITED STATES ALABAMA America -Dyar, G C Anniston -DePriest, S H Klugh, B G Lefforge, J W Auburn Poor, R S Bankhead -Armstrong, W D Bessemer -Beck, A IV, Jr Carnes, D Chabot, L S , Jr Creveling, J C

Jan 1, 1952

By W. P. Sykes

SINCE Honda and Murakami1 in 1918 proposed their constitutional diagram of the carbon-free iron-tungsten system, considerable effort has been expended by several investigators in attempts to define more positively the structural features of the alloys. The existence of an intermediate phase corresponding to the formula Fe3W2 (68.7 per cent W) was proposed from evidence of a purely metallographic nature by one of the present authors2 in 1926. Since that time the identity of this phase has been confirmed by Arnfelt3 and by Takeda,4 both of whom employed X-ray methods as well as the microscope and the chemical analysis of isolated microconstituents. According to Arnfelt, Fe3W2, as crystallized from the iron-rich melts at a temperature above 1450'C., contains by analysis 68.7 per cent W. The lattice of this phase is characterized by trigonal symmetry. Arnfelt, moreover, proposed a second intermediate phase formed at some temperature between 1450° and 1000° C. by a peritectoid reaction involving Fe3W2 and the iron-rich solid solution. A melt containing 25 per cent W was cooled to 1000° C. and heated for. 100 hr. The precipitated tungsten-rich constituent was separated and found by analysis to contain 62.6 per cent W. This composition agrees closely with that represented by the formula Fe2W (62.2 per cent W). Diffraction patterns from the concentrated precipitate showed a hexagonal unit cell. Takeda confirmed the data of Arnfelt regarding Fe3W2 but was unable to detect Arnfelt's second intermediate phase. While Takeda. failed to describe in detail the treatments employed, he stated that in alloys containing 40 per cent W which were quenched after heating at various temperatures between 1200° and 1450° C., no evidence of the second phase (Fe2W) was observed either in the microstructure or in the diffraction patterns of isolated residues. He therefore considered the existence of this low-temperature hexagonal compound as disproved.

Jan 1, 1932

By A. L. Holmes

Significant technologic advances were made in open pit mining during 1973. The industry faced mounting problems on one front where expansion of stripping activities encountered enlarged public resistance and on another where manpower and materials were in short supply. These challenges, along with the challenge and opportunity to meet the increased demand for mining products including materials for energy production, placed a premium on technical developments and their application. The demands on technology also included the providing of facilities and methods to economically extract minerals from deposits of lower grade, lesser accessibility, and where other uses of land approached the value of its minerals. Detection of Failures in Slope Walls The Bureau of Mines has undertaken research directed towards providing a mine operator with the opportunity to take corrective action before a potential slide becomes a problem.

Jan 2, 1974

By Bernard MacDonald

Of the treatment of the slime-pulp of gold- and silver-ores by cyanidation, agitation is an essential part. When prepared for treatment, this pulp, consisting of ore reduced to such fineness that approximately 80 per cent. of it will pass through a 200-mesh screen, is mixed with a certain proportion of water, carrying in solution the cluantity of cyanide (KCN) and other chemicals required. The water-constituent of the pulp thus prepared usually ranges from 1 to 2 parts by weight to 1 of the dry ore. Thus constituted, the pulp is charged into treatment-tanks, the shape and capacity of which vary, according to the quantity of pulp to be treated daily and the method of agitation to be employed. Tanks have no other function in a cyanide,plant than that of being economical and corlvellient containers or receptacles for holding the pulp, solutiou, or water used in the operations. It is by agitation that the solids in the pulp charged into the tanks are kept in suspension in, and mixed with, the solution in the proper proportions required for the treatment. If the proper mixture of solution to dolids be determined to be 2 to 1 by weight (which is, approximately, 5 to 1 by volume), this proportion should be maintained in every part of the charge; that is, each solid particle of the pulp, whether it be of' 180- or 400-mesh size, should be surrounded by five times its own volume of solution throughout the whole period of treatment. The reason is, that the amount of chemicals ascertaiued to be necessary for dissolving the gold and silver contained in the solids, is held in uniform solution in the water-constituent of the pulp, and, therefore, the determined proportions of solution and solids must be maintained at all times during treat-

Jan 1, 1912

By Charles B. Dudley

DEAR SIR: It is now nearly three years since my first report to you on the subject of steel rails was written. That report, as you will remember, dealt principally with the question of the relation between the chemical composition and physical properties of steel rails end their power to resist crushing and fracture in actual service. Other matters were referred to or touched upon in that report, but the main question was, Why do some rails crush or break in service while others do not? Yon will doubtless remember that the principal conclusion arrived at was, that the softer rails are less liable to Crush or break in service than the hard ones. Or, in other words, so far as conclusions could be drawn from the chemical analysis and physical test of 25 samples of steel rails which had actually been in service, these conclusions were that those rails which have the smaller amounts of carbon, phosphorus, silicon, and manganese are less liable to crush or break in service than those which have larger amounts of these elements. Or, again, looked at in the light

Jan 1, 1881

By Francis C. Krauskopf, Carl E. Swartz

Metallurgists differ considerably in their opinions regarding the effect, if any, of small amounts of iron pyrites, or other iron compounds on zinc sulfide ores during the roasting operation. As a result, the literature on this subject expresses many conflicting ideas. The ore, previously crushed to pass through a 1-mm. screen, dries in the roasting kiln, losing water up to 200° to 300° C. At 150° C. iron pyrites begin to lose sulfur. As the temperature increases, while the ore is passing to the hotter part of the furnace, the sulfur burns to sulfur dioxide, leaving the metals as zinc oxide and ferric oxide. These two substances then interact to form zinc ferrite, a compound, yellow brown in color, having the general characteristics of a spinel. Like magnetite, another spinel, zinc ferrite is insoluble in alkalis and dilute acids. As a result, when leached with 10 per cent. sulfuric acid solution, zinc values tied up in this compound remain behind History In the electrolytic recovery of zinc from its ores, the roasted ores are usually leached with a 10 per cent. sulfuric acid solution. When the zinc ore contains iron pyrites as an impurity in an appreciable amount, the actual yield of metallic zinc is much lower than a theoretical calculation would indicate. Further, losses of zinc are, in a rough way, directly proportional to the amount of iron pyrites or other iron compounds present. When the iron is present in the ore in an isomorphous relation to the zinc, as in the case of a marmatite, a greater amount of zinc remains insoluble than when present as a true pyrite or marcasite. Work on the insoluble residues obtained from leaching of the calcines shows that the zinc lost is intimately tied up in this residue. Some investigators have suggested a definite compound, such as zinc ferrite; others merely a mixture of zinc and iron compounds. As early as 1851, Pelouze(')' prepared calcium ferrite by fusion of calcium oxide and ferric oxide. Ebelman, 2) about the same time, prepared

Jan 1, 1928

Jan 1, 1953

Discussion of the paper of W. A. Forbes, presented at the New York Meeting, October, 1913, and printed in Bulletin No. 82, October, 1913, pp. 2477 to 2514.. SAMUEL K. VARNES,* Steelton, Pa.:-We have a gas-cleaning plant consisting of a, centrifugal dry dust catcher, and two rain-type wet scrubbing towers, 25 by 60 ft. each, for rough cleaning of blast-furnace gas. This plant was put in early in 1910, with the intention of cleaning gas for use in hot blast stoves and under boilers, and was so used for several months. Soon after it went into service, the blast-furnace men complained that they could not get as high blast temperatures as they had obtained when using dirty gas. It was decided to run a series of careful tests to determine if this were true and to what degree the apparent results might be affected by other conditions. About 60 tests were run, covering a period of five months, and at the end we came to the conclusion that it did not pay us to scrub the gas for stoves and boilers. The tests were all run upon a single stove, no boiler tests being made, but the conclusions of the stove tests being applied to the boilers. The furnace burden was practically the same for all the tests and averaged: Per Cent. Daquari and other hard ores 57 Nodules 13 Raw Mayari ore 25 Mill cinder and scale 5

Jan 12, 1913

THE developments in construction and operation of the basic open-hearth furnace that have taken place in recent years have placed new emphasis on the vital influence played by regulation and control of the combustion system in both furnace production and furnace life. The several factors influencing flame development, such as regulation of fuel supply, air supply, air preheat, furnace draft, and furnace reversal, must be controlled closely if successful furnace performance is to be accomplished. Rugged instrumentation of distinctive design is required to sup- ply dependable information concerning operating conditions, which is requisite to proper regulation of combustion. This chapter attempts to give a practical discussion of the various features of open-hearth practice and instrumentation related to the efficient heating of the furnace, control of temperature, and protection of the furnace structure from accidental overheating. The appended references will be helpful to readers wanting a more detailed treatment of individual topics. OPEN-HEARTH FUELS The most important open-hearth fuels are listed in Table 4-1 together with their compositions and other data useful for combustion calculations. A detailed discussion of open-hearth fuels is not attempted here, but certain factors peculiar to their application to this type of process are briefly indicated on the following pages. Very often an open-hearth shop is forced by economic factors to use a fuel to which its furnaces are not very well adapted, because the general fuel-allocation scheme for the works as a whole seems to demand it. Often a variable marginal supply of coke-oven gas or tar must be consumed by the open hearth, together with another fuel such as producer gas, natural gas, or oil, to fill out total requirements. Most furnaces employ more than one kind of fuel during their useful life; however, the partial redesign

Jan 1, 1964

By J. J. Crowe, G. K. Burgess

PAGE, Theories of Allotropy of Iron........... 667 Previous Determinations of A2 and A3 in Iron........ 668 Critical Ranges as Determined by Expansion........ 669 Critical Ranges by Thermoelectric Observations........ Critical Ranges in Terms of Crystalline Structure....... 670 Critical Ranges as Detected by Mechanical Methods...... 670 Critical Ranges as Given by Electrical Resistance....... 670 Critical Ranges as Determined Magnetically........ 671 Critical Ranges as Determined Calorimetrically....... 673 Critical Ranges from Heating and Cooling Curves....... 673 Summary of Previous Determinations of A3 and A2 in Pure Iron.... 675 The Present Investigation............ 678 The Experimental Method........... 678 Arrangement of the Apparatus.......... 679 The Measurements of Temperaturc.......... 679 The Measurement of Time........... 679 The Thermocouples............ 681 Temperature Scale and Calibration of Thermocouples...... 681 Mounting of Thermocouples........... 682 The Differential Measurements.......... 682 The Furnace and Accessories........... 682 The Vacuum Pump............ 683 The Energy Supply............683 The Rheostat.............. 683 The Materials Investigated............ 685 Sources of Iron............. 685 Preparation and Description of Samples......... 685 Chemical Analyses............. 687 The Experimental Data............. 688 The Preliminary Observations.......... 688 The Definite Series............691 Description of the Plotted Curves........... 694 The Effect of Plotting at Different Intervals........ 694 The Curves of the Definite Series.......... 695 . The Curves of the Preliminary Series......... The Existence of Other Critical Ranges......... 696 The Microscopical Examination........... 697 Summary and Conclusions............ 698 Bibliography............... 701 Plates................ 704

Jan 1, 1914

A1 in carbon steel, equilibrium temperature, XLVII, 740-747. A2 and A3 in pure iron, critical ranges, XLVII, 665-739. Abbott, Ai Arthur: [biog. notice, Bulletin No. 27, Mar., 1909, xxvii]; death, XXXIX, . [xl]. Abbott, Arthur Vaughan: [biog. notice, Bulletin No. 16, July, 1907, 6581; death, XXXVII, [xxxix]. [ ]

Jan 1, 1918

By William E. Ford, Edward Salisbury Dana

This section includes one distinct group, the Stibnite Group, to which orpiment is related; the other species included stand alone. Pyr., etc. - In the closed tube melts and gives a dark red liquid when hot and a red- dish yellow solid when cold; in the open tube (if heated ver slow? ) sulphurous fumes, and a white crystalline sublimate of arsenic trioxide. B.B. on ciarcoaTburm with a blue Hame, emitting arsenical and sulphurous odors. Soluble in caustic alkalies. Artif. - Realgar is frequently noted as a sublimation product from furnaces roasting ores of arsenic. Crystals are produced when arsenic sulphide is heated in a sealed tube with a solution of sodium bicarbonate. Obs. - Realgar occurs usually in veins associated with silver and lead ores. It has been found in volcanic regions as a sublimation~duct. It has also been noted as a deposit from hot spring waters. It is often rtasociate wlth orplment. It occurs at Felsi5bBnya, Kapnik and NagyAg, Hungary; Allchar, Macedonia. Binnental, Switzerland, in dolomite. In the United States, at Mercur, Utah; in the Norris Geyser Basin, Yellowstone Park, as a deposition from the hot waters. Found at the Monte Cristo millin district, Snohomish Co., Washington: the namerealga7 is from the Arabic, Rahj af gh&r,powder of the mine. Use. - Was used in fireworks to give a brilliant white light when mixed with saltpeter and ignited. The artificial material is now used for this purpose.

Jan 1, 1922

By Oliver Smalley

Except for the work of Guillet, who conducted a systematic investigation on the zinc-replacing value of nickel in brass, and extended his investigation with a view to developing commercial high zinc content nickel brasses, the author does not know of any other systematic research on the subject. The most promising commercial alloys and their physical properties obtained by Guillet are given below: These test results scarcely justify the use of such quantities of so expensive a metal, and could have been obtained from ordinary commercial brass. For purposes of comparison, the physical properties of ordinary brasses, ranging from 70 per cent. to 50.1 per cent. Cu in both the cast and normalized1 conditions are included in 'Table 1. These incidentally furnish a useful standard of the properties of castings and of rolled, extruded and forged brass when correctly annealed. A close study of some of the well-known special brasses containing nickel reveals a series of alloys which bewilder by their complexity, and me can only hazard a guess at the function and commercial value of each of the many elements used.

Jan 1, 1926

By Thomas Harris

This paper. was written in conjunction with the work being undertaken by the Technical Committees on Classification of Coal, and an effort has been made to compile information relative to the use of coal for stationary steam generation in order to use this information to assist the Committee on Classification of Coal for the ultimate purpose of elimination of losses both by the' reduction of indivi-dual effort and waste in the consumption of material. Under the auspices of the National Association of Purchasing Agents, a questionnaire was drawn up to develop this information from stationary steam plants throughout the United States. in order to consolidate the information de-veloped from the many hundreds of boiler tests on coals consumed by various coal¬burning equipment. These questionnaires covered: 1. The company reporting, location and method of delivery to the plant. 2. Complete coal date, including description of coals used (with. sufficient space to- include first, second and third, preference) on--source of coal used,- complete-analysis and factors affecting choice of, coal used. 3. Plant data, divided into - A. Hand fired, B. Overfeed stokers,. . C. Underfeed stokers, D. Traveling grate stokers, E. Pulverized coal, and included complete description of furnace data, draft data, coal-burning rate, type of stoker, type of pulverizer, efficiency date and remarks.

Jan 1, 1933

GENERAL COMMITTEE GERALD F. G. SHERMAN, Chairman. ARTHUR NOTMAN, Secretary. NORMAN CARMICHAEL, JOHN C. GREENWAY, W. L. CLARK, W. G. McBRIDE, B. BRITTON GOTTSBERGER, FOREST RUTHERFORD. General Committee on Transportation WALTER DOUGLAS, Chairman. CLEVELAND E. DODGE, Secretary. ARTHUR S. DWIGHT, JOHN C. GREENWAY, JULIUS KRUTTSCHNITT, JR. Committee at El Paso W. D. GORDON, ROBERT McCART, JR., W. W. ROSE. Committee at Santa Rita JOHN M. SULLY, Chairman.

Jan 12, 1916

By R. Hadfield

Last year this institute was good enough to accept some remarks by the writer regarding sound steel, entitle Plant for Hadfield Method of Producing Sound Steel Ingots…

Jan 1, 1915