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By Charles H. Hopkins, J. M. Lohr

A COMMERCIAL development requiring a suitable alloy or alloys for sealing into various grades of glass made it desirable to have a more exact knowledge' of the expansion characteristics of the nickel-iron alloys than appeared in the published literature. The expansion of the more common [ ] types of glass under consideration varies from 2.7 to 10.4 X 10-s per degree Centigrade, over the range 20° to 400° C. For reference, the thermal expansion curves of several types of glass used for sealing by the lamp and tube industries are given (Figs. 1 and 2). This paper covers a detailed investigation of the thermal expansion of a series of nickel-iron alloys in which the nickel content varies from 30 to 70 per cent. Particular stress is laid on the alloys that contain between 40 and 55 per cent Ni.

Jan 1, 1938

By Huntington Adams

The arrangement of a flow of cyanide-pulp through Pachuca tanks in agitation, so as to permit a continuous process, instead of alternate filling, agitation, and emptying, has been proposed by various writers within the last two years, and more particularly by A. T. Grothe, agent for the Brown patents on Pachuca tanks in Mexico. It was first put into practice, I believe, by M. H. Kuryla at the Esperanza mine in El Oro, Mexico. The starting of agitation in Pachuca tanks after filling may offer no serious difficulties with ores which do not settle rapidly in such tall tanks; and the adaptation of the tanks to continuous agitation under such conditions may give simply a somewhat more convenient method of treatment and greater agitation-capacity for a given number of tanks, because of the saving of time lost in filling and discharging. But in the treatment of pulp which tends to settle rapidly, as in the cyaniding of concentrates or of the whole pulp of ores containing heavy sulphides, the packing of the slime at the bottom may cause much trouble. The use of the radial air-pipe attachments near the top of the cone and of the air-valve outside of the air-lift tube at the bottom may obviate the difficulty to some extent; but the action of the radial air-pipes on the cone-sides is that of a sand-blast, and their continuous use cuts through the tanks. Moreover, even when these pipes are used, some pulps will pack tightly below them in the cones. Under such conditions the use of Pachuca tanks with intermittent filling and discharging becomes a troublesome process. Time is lost in starting agitation; large quantities of compressed air are wasted; pulp is blown over the tank-tops; and not infrequently it may be necessary to dig out the bottoms of tanks by hand. This trouble is the only important one occurring in the use of Pachuca tanks; and, since it is caused by intermittent filling, the arrangement of a continuous flow of pulp from tank to tank,

Jan 1, 1912

By Dennis V. D’Andrea, Robert C. Steckley, William C. Larson, Richard A. Dick

A fragmentation experiment was performed in cooperation with Duval Corporation in a porphyry copper molybdenum deposit near the Sierrita pit south of Tucson, Ariz. A 10-hole test blast was detonated to establish relationships between blasthole spacing and the resulting fragmentation. Blastholes were 9 in. in diameter and 110 ft deep. The 10 blastholes contained a total of 17,400 lb of aluminized slurry blasting agent in 50-ft columns with 60 ft of stemming. Blasthole spacings of 25, 20, and 15 ft were tested. Diamond drill core examination was the primary method used to determine the condition of the rock before and after blasting. Topographic surveys were used to measure the rock swell produced by the blast and a fragment size distribution was obtained for the rubblized material on the surface. The rubble zone at the surface was ideal for in situ leaching. Fragmentation to depths of 110 ft was excellent from the 15- to 20-ft blasthole spacing patterns. Good breakage was also produced by the 25-ft pattern although the effects of the blast were not as obvious. In situ leaching tests were not conducted. However, based on size consideration only, all three blasting patterns produced adequate breakage for successful leaching.

Jan 1, 1974

By S. P. Sharples

Having occasion a few weeks ago to investigate the subject of black band iron ore in West Virginia, I was surprised at being met at the outset with a denial of its existence. One gentleman went. so far as to offer one hundred dollars an acre for any land in West Virginia that contained a seam or vein of even a single foot in thickness, and when shown the ore he acknowledged that it was genuine, but declared it had been imported. That black band does occur in West Virginia is to-day well known to a number of persons. There is a seam on the Gauley River of about a foot in thickness of good ore, which I understand Mr. Lewis and others are making preparations to work. The great trouble with black band ores as heretofore found in this country has been their limited extent. At Fort Washington, for instance, they had a very fine show ing of ore, but it soon gave out. It has also been asserted that the black band ores of the Western Coal Measures were worthless in the furnace, and Fort Washington has been pointed out as an example of the fate of any one who should undertake to work them. But they have been successfully worked at Youngstown and in other parts of' Ohio, and I am assured by old furnace-men from Ohio that there is not the slightest difficulty in. working them if properly managed. The deposits to which I wish to call the attention of the Institute,

Jan 1, 1882

By S. P. Sharples

HAVING occasion a few weeks ago to investigate the subject of black band iron ore in West Virginia, I was surprised at being met at the outset with a denial of its existence. One gentleman went so far as to offer one hundred dollars an acre for any land in West Virginia that contained a seam or vein of even a single foot in thickness, and when shown the ore he acknowledged that it was genuine, but declared it had been imported. That black band does occur in West Virginia is to-day well known to a number of persons. There is a seam on the Gauley River of about a foot in thickness of good ore, which I understand Mr. Lewis and others are making preparations to work. The great trouble with black band ores as heretofore found in this country has been their limited extent. At Fort Washington, for instance, they had a very fine show ing of ore, but it soon gave out. It has also been asserted that the black band ores of the Western Coal Measures were worthless in the furnace, and Fort Washington has been pointed out as an example of the fate of any one who should undertake to work them. But they have been successfully worked at Youngstown and in other parts of Ohio, and I am assured by old furnace-men from Ohio that there is not the slightest difficulty it working them if properly managed. The deposits to which I wish to call the attention of the Institute,

Jan 1, 1882

By J. A. Hren, C. M. Wayman

RECENT investigators have noted anomalous behavior in the electrical resistivity of vanadium below room temperature. Rostoker and Yamamoto1 in studying the vanadium-oxygen system hypothesized that the body-centered-tetragonal phase existing from 15 to 34 at. pet O at approximately 800°K was really a low-temperature allotrope of vanadium that was stabilized by oxygen. In measuring the electrical resistance of cold-swaged vanadium rod over a range of temperatures, a small discontinuity was observed at approximately 240°K, supporting their notion of allotropy. However, the magnitude of the observed discontinuity was extremely small. Loomis and Carlson2 in studying the ductile-brittle transition in vanadium also made resistance measurements and reported a discontinuity near 200°K. More recently, White and Woods3 showed that the electrical resistivity from room temperature to approximately 100 °K was not linear and at variance with the Bloch-Griineisen law. Instead of finding a discontinuity, they observed a deviation from linearity below 200°K. In discussing their results they pointed

Jan 1, 1961

By David Baker

In a paper presented to the American Institute of Mining Engineers, September, 1904, entitled uImprovements in the Mechanical Charging of the Modern Blast-Furnace,"' I showed the great fault of mechanical charging-devices to be that the materials charged by the dumping of the skip were separated, the coarse materials having high velocity, and the fine, low— thus giving paths of low resistance through the stock in the furnace, which resulted in unequal distribution of the furnace-gases, unequal reduction, slips, scaffolds, irregular cutting of the inwall, "of" iron, and increased fuel-consumption. I showed how this could be prevented by rotary distribution, through which the irregular distribution in one layer charged is compensated by charging the subsequent layers from succeesively varied positions of the charger, and becomes practically eliminated when the angle between two successive positions is a little more or less than an even fraction of a full circle. Of all the devices then on the market, the nearest approach to the ideal arrangement was found in the Brown distributor, a full description of which was given. The one defect pointed out, however, was the difficulty of maintaining so much mechanism on the top of a blast-furnace. Since the presentation of that paper, I have designed a very

Jan 1, 1907

By Frederick H. Williams

THE object of this paper is to bring to the attention of those members of the Institute who are interested in the subject, a method for the estimation of manganese, which has been frequently used in the laboratory of the Vulcan Steel Works during the last eight months, and which is deemed worthy of more general use. It is simply an adaptation of well-known processes, for the purpose of determining this element in pig iron and steel. In general, the method consists in precipitating the manganese as binoxide, dissolving in dilute sulphuric acid in the presence of an excess of a standardized solution of oxalic acid, and titrating the remainder of the oxalic acid left unoxidized with permanganate of potash. For this method, therefore,. two standardized solutions are needed, viz., a permanganate solution and an oxalic acid solution. The permanganate solution is made so that 1 c.c. is equivalent to 1 mgr. of iron. By using so weak a solution and keeping the bulk of the solution to be titrated down to 75 c.c. or a little less, the accuracy of the process is greatly increased, since the final reaction is almost if not quite as sharp as if a stronger solution were used. The oxalic acid' may be of almost any strength, but if made so that 1 c.c. requires 3 c.c. of the permanganate to oxidize it, it will auswer well. The process is then, as follows : from 1 to 2 grams of pig iron or steel are dissolved in 40 to 50 c.c. of concentrated nitric acid with the aid of heat. As soon as solution is effected, in the case of steel, add gradually and cautiously, the solution being kept boiling, sufficient pulverized chlorate of potash to precipitate the manganese as binoxide. Two grams will be a great abundance. In the me of pig iron, first remove the carbon and silica by filtering the solution through asbestos and washing with concentrated nitric acid. Filter the strong acid solution in which the binoxide has been precipitated, through asbestos with the aid. of the filter pump. When it has entirely passed through wash well with water. Blow the contents: of the funnel into the beaker in which the precipitation was made and rinse the funnel with a little water.

Jan 1, 1882

By Frederick H. Williams

The object of this paper is to bring to the attention of those members of the Institute who are interested in the subject, a method for the estimation of manganese, which has been frequently used in the labratory of the Vulcan Steel Works during he last eight months, and which is deemed worthy of more general use. It is simply an adaptation of well-known processes, for the purpose of determining this element in pig iron and steel. In general, the method consists in precipitating the manganese as binoxide dissolving in dilute sulphuric acid in the presence of an excess of a standardized solution of oxalic acid, and titrating the remainder of the oxalic acid left unoxidized with permanganate of potash. For this method, therefore, two standardized solutions are needed, viz., a permanganate solution and an oxalic acid solution. The permanganate solution is made so that 1 C.C. is equivalent to 1 mgr. of iron. By using so weak a solution and keeping tile bulk of the solution to be titrated down to 75 C.C. or a little leas, the accuracy of the process is greatly increased, since the final reaction is almost if not quite as sharp as if a stronger solution were used. The oxalic acid may be of almost any strength, but if made so that 1 c.c. requires 3 O.C. of the permanganate to oxidize it, it will auswer well. The process is then, as follows: from 1 to 2 grams of. pig iron or steel ate dissolved in 40 to 50 C.C. of concentrated nitric acid with the aid of heat. As soon as solution is erected, in the awe of steel, add gradually and cautiously, the solution being kept boiling, sufficient pulverized chlorate of potash to precipitate the manganese as binoxide. Two grams will be a great abundance. In the case of pig iron, first remove the carbon and silica by filtering the solution through asbestos and washing with concentrated nitric acid. Filter the strong acid solution in which the binoxide has been precipitated, through asbestos with the aid of the filter pump. When it has entirely passed through wash well with water. Blow the contents of the funnel into the beaker in which the precipitation was made and rinse the funnel with a little water.

Jan 1, 1882

By W. G. Pfann

A simple method of obtaining multistage batch separations by crystallization was described recently. Known as zone-refining, it comprises passing short molten zones through a long solid charge. This technique can now be used on a continuous basis by means of the zone-void method described in this paper. Feed enters, at an intermediate point, a column down which molten zones travel, and waste and product leave at the ends. Materials move in the column through the agency of voids, which are introduced at the ends and travel toward the feed inlet. The voids and molten zones are moved by external heaters in a simple manner, and the principle of reflux is utilized. ANEW method of obtaining multistage separations by crystallization was described recently.' Named zone-refinina.,-, the method comwrises slowly passing a series of molten zones through a long solid charge. Solute becomes concentrated at one or the other end of the charge, depending on whether it raises or lowers the freezing point of the solvent. The separation increases with the number, P, of zone-passes, approaching a limit as P approaches infinity. Zone-refining has been highly effective in purifying germanium and other substances.2,3 and new applications are steadily increasing. Zone-refining is a batch method and as such it has certain limitations inherent in batch operation. If it could be made continuous, its scope and utility would be greatly broadened. This end has been achieved by the zone-void method described in this paper. In the zone-void method feed is introduced continuously at an intermediate point in a column down which molten zones travel, while impure waste and purified product leave at the ends. Both the flows of feed, waste and product, and also the travels of the zones, are actuated by external moving heaters in a simple manner; and the system utilizes the principle of reflux. The method provides, in the field of crystallization, the counterpart of the continuous fractiona-tion column in the field of distillation. The following will be discussed: apparatus and mode of operation, fundamental nature of the separation, design theory, and practical considerations. The method will be described in terms of a binary solute-solvent system in which the solute is an impurity to be removed and the solvent is the desired product. The distribution coefficient, k, defined as the ratio of solute concentration in the solid freezing out of a molten zone to that in the liquid in the zone, is assumed to be constant and less than one. The process is equally effective for k's greater than one and for ternary or higher order systems. Method and Apparatus The essential features of a continuous zone-refining process are represented in highly generalized form in Fig. 1. A series of molten zones, produced by moving heaters, travels slowly down the column or charge (to the left in Fig. 1). If there were no flows of feed, waste, or product, the process would simply be batch zone-refining, the action of the molten zones being to sweep solute down the column, solvent up the column. For the process to be con- tinuous, with stripping and enriching sections in the column, feed must enter, and waste and product must leave, as indicated. The zone-void process accomplishes both objectives, namely, the indicated movements of zones and the indicated flows of material. Zones are moved by moving heaters, just as in batch zone-refining. Materials are made to flow by creating voids at the waste and product exits and causing these voids to move to the feed inlet. Since there must be a net flow of material from the feed inlet to each of the outlets, the indicated movements of voids are in the desired directions, because movement of a void in a given direction corresponds to flow of material in an opposite direction. In order to produce the desired movements of voids, the column is folded into two vertical sections having the feed inlet in common at their upper ends. Voids are displaced upward by the liquids in the molten zones and their travel is actuated by the motions of the zones. Voids travel with the zones in the enriching section and move continuously. Voids travel opposite to the zones in the stripping section and move intermittently. Creation and travel of voids will now be examined in detail. The enriching section of a column in operation, with its void generator, is shown in Fig. 2. The column section is a vertical tube around which a series of closely fitting, regularly spaced heaters travel slowly upward. Each heater produces a molten region, the temperatures of the heaters and the cooling between heaters being controlled so as to maintain the molten zones approximately constant in size. A void is normally present atop the molten zone in each heater. As the heater rises, it continuously melts solid above it, which drips through the void into the molten zone and continuously freezes out solid below it, of concentration k times that of the liquid in the zone. When a molten zone and void reach the feed inlet, which is kept molten, the void is displaced by an equal volume of feed liquid. Generation of voids of controlled size in the enriching section is shown in Fig. 3. The void generator is a tube of small cross-section, provided with lateral heat-conducting fins which sense the position of the heater. Liquid can escape only when the entire outlet tube is within the heater. If any part of the outlet tube is outside the heater, liquid cannot escape,

Jan 1, 1956

By B. C. Scott, A. Baker

The Pitch mine of Pinnacle Exploration, Inc. is in the Marshall Pass district, thirty miles east of Gunnison, Colorado. This is a new mining district, having come into existence as recently as 1955, when uranium mineralization was discovered rather late in the days of the uranium boom. There have been three other mines in the district, all of them now inactive. Two of these produced a few hundred tons of very high-grade uranium ore, and the third, Pinnacle's Little Indian 36 mine, produced a few thou- sand tons of lower grade ore. Pinnacle was one of the first companies in the district, and was able to acquire a large acreage. The first two years of exploration were essentially wasted in looking for Plateau-type deposits in a mineralized sandstone bed, but this "wasted" work produced two specific items that paid off. One was an ore-grade outcrop that ultimately became the Little Indian 36 mine, and the other was a boulder of very high-grade uranium ore that eventually led to the discovery of the Pitch mine; however, the actual source of the boulder still has not been found.

Jan 5, 1961

By H. E. Stauss

THE time-to-fracture test has been applied to pure platinum and to two alloys of platinum under the special conditions of small cross-sectional area of the specimens and of a test temperature above the annealing temperature. While the results are similar in character to those secured with large specimens of steel at temperatures below the annealing temperatures, two differences are noted: (I) an upward inflection in the curves for log stress vs. log time for the alloys, and (2) a sharp break in the curve for log stress vs. log time for pure platinum when single crystals filled the wire. The experiments showed that: (I) platinum and 10 per cent rhodium-platinum maintained their strengths at 1100°C. better than did 10 per cent iridium- platinum, and (2) the rhodium-platinum after a time exceeded the iridium-platinum in strength at 1100°C. Platinum alloys in their service at high temperatures encounter conditions some- what similar to those that exist in the usual form of the time-to-fracture "l test with steel. This paper is intended primarily to present results obtained by a "time-to- fracture" test under conditions approximating actual service for platinum (at the temperature 1100°C. under oxidizing conditions) with three materials, pure platinum (99.99 per cent), a platinum alloy with lo per cent iridium, and a platinum alloy with 10 per cent rhodium. The experimental procedure differed from that previously used in this type of measurement in that the samples were of small diameter (0.010 in.), were fully annealed, and were tested at a temperature definitely above their annealing points (600°C., 1000°C. and 1050°C., respectively, for 60 per cent cold reduction and 15 min. heating time2,3). The experimental arrangement was similar to that previously described,4 using as heating unit a small, horizontal, platinum- wound furnace, ½ by 12 in., maintained at constant temperature by an automatic controller. The samples were 0.010-in. wires, which had been annealed at 1200°C. by drawing them slowly through the furnace. The time-to-fracture was measured electrically. Elongation was not determined because of the difficulties inherent in the experimental arrangement. Life-that is, the time-to-fracture-was considered the important property in these first tests. No attempt was made to measure the reduction in area, but the types of fracture were noted qualitatively; in the text they are referred to as (I) the normal, plastic, or necked fracture, (2) the knife-edge fracture, and (3) the brittle or intercrystalline fracture with small reduction of area. Results for different constant applied stresses are plotted in Fig. I. In all cases at least two trials were made for each stress, although they cannot always be indicated separately on the curves. The breaking stresses drop very rapidly to a small frac-

Jan 1, 1943

By C. K. Leith

QUOTING from Dr. Richard T. Ely:1 "Conservation, narrowly and strictly considered, means the preservation in unimpaired efficiency of the resources of the earth; or in a condition so nearly unimpaired as the nature of the case, or Wise exhaustion, admits. And broadly considered, it means more than the word itself implies, for it naturally includes an examination of methods Whereby the natural inheritance of the human race may be improved; and still more broadly considered, and as used in popular discussion, it includes a treatment of the effects of productive conservation methods upon distribution. "Conservation means a sacrifice of the present generation to the future generations Whenever it is carried too far. There is a sharp limit to the economic sacrifice that we may reasonably ask the private person to make for even the present Welfare, and the limit is still sharper when we come to consider the interests of future generations." In a paper on the iron ores of America, presented to the Pan-American Scientific Congress at Washington, I have emphasized the fact that the reserves of iron ores in the two Americas are enormously in excess of the requirements of the present generation, in fact, so large that no shortage is to be anticipated for many generations in the future; that a large part of the value of iron ores is put into them by man's efforts to make them available. This fact is fundamental for the intelligent consideration of- policies of conservation as applied to iron ore. As I interpret it, this fact makes it practically unnecessary that the present generation should make any especial sacrifice for future generations in the way of conservation of its iron-ore resources. Even if we were disposed to look forward to a period of 100 or 200 years, with a view to insuring the welfare of the people living at that time, it is doubtful whether any procedure we could now formulate would materially help them in the matter of iron ores, so large are the reserves available. In order that an appeal for conservation may be effective it must obviously favor the welfare of the present or immediately following generations; it must promise benefits to general and individual welfare during a period within the range of comprehension of the average man.

Jan 2, 1916

By Henry Howe

(New York Meeting, October, 1913.) The Equilibrium. Position of A 1.-Some of the most important data on this subject are collected in Table I. Definition of Ae 1-Just as we call A 1 of rising temperature Ac 1, and that of falling temperature Ar 1, so we may give the symbol Ae 1 to the equilibrium position of A 1. Preliminary Assumptions.-In deciding what weight to assign the various data, and indeed what data are to count, three assumptions should be made. These are: 1. The corollary from the phase rule, that the temperature of Ae 1 is constant and independent of the carbon content, though, of course, it may be changed by the presence of other elements. 2. That because neither in heating nor in cooling can the transformation begin before the temperature reaches Ae 1, though it may be delayed by lag till after the temperature has passed beyond Ae 1, therefore Ae 1 should be at or below the observed beginning of Ac 1 and at or above the observed beginning of Ar 1, and, a fortiori, it should be at or below the observed maximum of Ac 1, and at or above the observed maximum of Ar 1. It may be necessary to take these maxima into consideration in view of the experimental difficulty of detecting these beginnings.

Jan 6, 1913

By E. E. Russell Tratman

The use of dynamite in cold weather is attended with some difficulty, owing to the freezing of the material and its consequeut liability to fail to explode when the fuse is fired. With proper methods and care the dynamite can be thawed with reasonable safety, but numerous accidents occur (more than get reported in the public press), due to carelessness in the operation and to the treacherous nature of the material, or a combination of both conditions. Dynamite will stand treatment at one time which at another time will result in explosion. An expert on explosives says that the most dangerous means of thawing cartridges are ingeniously devised by ignorant laborers; baking, boiling and toasting being favorite methods, while at a stone-quarry, in one instance, an apparatus was arranged for steaming the cartridges over a pot of boiling water. In this latter case the nitro-glycerine leaked through the canvas cover and settled on the bottom of the pot, with the result that an explosion occurred, the water acting as a tamping to the charge. The fact that small quantities of explosives containing nitroglycerine will burn quietly and without explosion if ignited by direct contact with a flame, has led to the dangerously mistaken reasoning that merely heating the explosive can produce no ill effect. If . a dynamite cartridge is ignited or placed in a fire it will probably burn harmlessly away, but if placed on a stove or in an oven and

Jan 1, 1893

Howland Bancroft (A Modern Approach To Foreign Mineral Development, P 666) was born in Denver, Colo and attended the University of Colorado, University of Michigan and received a B S and B A degree From 1907 to 1912 he was with U S Geological Survey In 1911 he was involved in study of mining resources of Peru Mr Bancroft resigned from Federal Survey and opened offices as consulting mining geologist in Denver in 1912 From 1919 to 1920 he was a consulting engineer in San Francisco He was manager of Sinclair Panama Oil Corp in Panama City in 1920 From 1921 to 1923 he was vice president and managing director of same corporation He did independent examinations in Western states and an exploration trip through Turkey in Asia from 1924 to 1925 Mr Bancroft was vice president and general manager of Lago Petroleum Corp in charge of operations in Venezuela Mr Bancroft has spent time in 34 different countries in the world and in a number of different Latin American States, Europe, Asia Minor and Africa

Jan 1, 1952

By T. B. Crowe

MucH has been written upon the precipitation of metals from cyanide Solution by zinc. We often read of the many factors that influence precipitation, such as zinc surface, purity of zinc, percentage of lead, temperature of solutions, strength of solutions in cyanide or alkali, etc. -Little do, we hear, however, of the part that oxygen plays in precipitation. Caldecottl says: "As the dissolving of gold is essentially an oxidation process, so its precipitation is one of reduction." All who have studied or worked with cyanide solutions will agree that Caldecott's statement is true.' . In the cyanide work in the mills of the Portland Gold Mining Co., we have always found oxygen to be the greatest enemy to precipitation. Oxygen Antagonistic to Good Precipitation A few years ago, while making some experiments on the effect of pressure upon the dissolving rate of gold from our ores, to prove a point, I made some bottle tests under vacuum. The results were surprising, and showed that under vacuum practically no gold dissolved, which confirmed my belief that Elsner's equation was true and also led me to investigate the amount of dissolved air carried by solutions at atmospheric pressure. The experiment consisted in partly filling an acid-bottle with mill-solution and connecting it by a rubber hose to a vacuum pump. When the vacuum was suddenly applied, a cloud composed of thousands of small air bubbles rose out of the solution, showing qualitatvcily' the amount of dissolved air that was contained in the solution, and also proving that the relief of atmospheric pressure on the solution permitted this dissolved air to escape. In studying literature on the subject, we find Henry's law—"The amount of gas dissolved by a liquid is proportional to the pressure to which the gas is subjected."

Jan 1, 1919

By Vernon F. Swanson

An equation has been developed which will permit the direct determination of free settling velocity of any sized particle encountered in mineral benefici-ation. The equation is based on Newton's Law with the friction factor defined as a function of the laminar boundary layer. Development of the equation is described first from an empirical trial-and-error approach. Examples are given of actual settling data from the literature versus calculated data to prove the validity of the new equation. Newton's law of resistance of a fluid to flow around a sphere is expressed in Eq. 1. Free settling velocities can be determined by setting Eq. 1 equal to the gravitational force on a particle and solving for V. Experience has shown that when the solids are greater than 1 mm in diam, or when Reynold's number for the system is greater than 800-1000, the friction factor term, fD, essentially becomes a constant, and Eq. 2-b becomes Newton's equation for free-settling and is applicable under the conditions stated. Another special condition exists for particles smaller than 0.05 mm or when Reynold's number for the system is less than three. In this case fD=24/NRor24µ/pL,dV,. Eq. 2-b can then be rewritten as

Jan 1, 1968

By A. D. Hoagland

The Flat Gap mine is located on Copper Ridge in the Appalachian Valley of East Tennessee. Large zinc orebodies occupy zones of solution and collapse breccias in Lower Ordovician Kingsport limestone and dolomite. The principal ore mineral is sphalerite and the principal gangue is dolomite. The ore-bearing horizons are considerably more than 95% covered by thick residual clay. Geochemical prospecting under these conditions is an effective exploration technique which played an important role in the discovery and exploration of the Flat Gap mine. The Flat Gap mine, an important zinc deposit of the Appalachian type, is located in the Copper Ridge Belt in the Valley of Tennessee approximately 30 miles northeast of the Mascot-Jefferson City zinc district (Fig. 1). The ore is found in large stratigraphically linked deposits in solution and collapse breccias of the Kingsport, Longview and, to a minor extent, Mascot formations of Lower Ordovician age. The principal ore mineral is sphalerite and the principal gangue minerals are dolcrmite and accessory pyrite. There is local minor galena and very rare barite and fluorite. The ore-bearing horizons are covered by about 20 to 100 ft or more of residual clay except where active streams have exposed bedrock. Considerably less than 5% of the favorable host rocks are exposed in outcrop, and this nearly complete soil cover creates a serious obstacle to exploration. Comprehensive surveys of the base metal content of soils furnish a useful substitute for outcrop geology, and under favorable conditions, this technique is a very valuable prospecting tool. The analysis is carried out by a titrametric dithizone method modified after the procedure described by E. B. Sandell.' This method detects

Jan 1, 1962

ON JUNE 7 the German Government handed to the French and Belgians a new proposal for reparations, which offered 1,200,000,000 gold marks annually, to be guaranteed as to 500,000,000 by a mortgage on the national railways, as to another 500,000,000 by a mortgage on industry, commerce, land and factories, and as to 200,000,000 by a luxury tax. The number of years for which this payment should run to be left to settlement by an international conference. This offer was taken under consideration by the French and Belgians, who instituted conversa-tions with the British in the hope of arriving, at some joint action with respect to the Germans. Up to the end of June nothing had been determined. In the meanwhile, the continued French and Belgian occupation of the Ruhr seemed to develop a condition of guerilla warfare, considerable bloodshed occurring throughout the region. The second Lausanne Conference dragged on, the Allies being apparently unable to take any firm, joint stand, while the Turks increased their importunities and managed to get concession after concession. Early in June a revolution occurred in Bulgaria, the previous Government under Premier Stambulisky, based on the agrarian party, being forcibly thrown out by a bourgeois and military combination. This pro-duced considerable disorder in Bulgaria, outside of which country the nature and purpose of the revolution does not appear to be well understood. Stambulisky's partisans offered feeble, isolated resistance to the revolu-tion; in connection with which there was some blood-shed and Stambulisky himself was reported killed, although this was later contradicted. Professor Zan-kof, the new Premier, issued a statement, that the change of the Government was the result of discontent, that the foreign policy of the new Government would be peaceful, and that Bulgaria would continue to fulfill her international obligations, particularly the treaty of Neuilly. It was the opinion of London that the immu-nity from taxation enjoyed by the farmers under the agrarian regime is likely to he superseded by more equi-table taxation, and in general that the bourgeoisie will be better administrators of the public affairs In domestic affairs industrial activity continued at a high rate, but there was distinct relaxation in the demand for raw materials, and also in some manufac-tured goods. During June there were reductions of prices by many of the automobile tire manufacturers. There seemed to be also further contraction in the demand for automobiles.

Jan 6, 1923