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The Effect of Bulk Iron Concentration on the Copper Activation of Sphalerite at pH 9

Sep 13, 2010

By John F. Elliott

Six major trends that have had and are continuing to have major effects on the use and supplies of pig iron and scrap in the United States are (a) gradual replacement of the basic open hearth furnace (OH) by the basic oxygen furnace(BOF); (b) use of the electric furnaces for the production of plain-carbon steels, a trend which is closely related to the first; (c) United States changing from being a net exporter to a net importer of steel; (d) replacement of ingot casting by strand casting; (e) increased exportation of scrap; and (f) the lack of growth of the capacity of the U. S. steel industry to produce pig iron in the last 5 to 8 years. This report gives an analysis of the relationships between these trends and the use of processes for the production of raw steel in solidified form.

Jan 1, 1975

By William R. Wessels

This report describes a field survey and laboratory investigation into the causes of failure of resiliently clad screen decks applied to coal preparation plants. Blinding of screen deck perforations and delamination of the resilient cladding are studied and mechanisms responsible for these failure modes are hypothesized. A laboratory test program to simulate the mechanisms was begun and abandoned when it became apparent that meaningful test results would require a substantially redirected effort. No meaningful test data was obtained from the laboratory simulation.

Jan 1, 1982

To provide cooler air to miners working in hot areas of mines, particularly new deep hardrock mines. Approach Air supplied to hot working areas of mines is cooled by passing it through a series of water sprays. How It Works Water nozzles mounted inside a section of ventilation tubing release cooling sprays of water into the air being blown through the tube. The prototype of the water spray cooler consists of six evenly spaced water sprays located inside a 10-ft. long section of 16-inch-diameter fiberglass ventilation tubing. See diagram. This section of rigid tubing is installed into one of the positive pressure ventilation tubing lines that conduct fresh air into working stopes. The intake manifold to the six water sprays is connected to the mine?s cool water line, and the water valve on the manifold is opened. Warm ventilation air being supplied to the stope passes through the water sprays, and is cooled by the lower temperature water.

Jan 1, 1979

By S. S. Gross

A program was conducted to determine whether sufficient quantities of the flame retardant, ammonium phosphate, could be incorporated in a water-based foam solution to prevent or delay reignition (burnback) without. significant degradation of foam properties. Up to 20% of mono and diammonium phosphate was added .to d high expansion foam solution. This mixture was applied as a high expansion foam to burning wood and coal samples. The effect of this mixture on burnback was laboratory tested by placing the wood or coal sample in front of a radiant panel. It was found that diammonium phosphate levels of 20% by weight prevented reignition without degrading foam properties. A field test was then conducted using a 20%, diammonium phosphate mixture and a control with no phosphate on a wood crib fire. The experimental foam did extinguish the crib fire faster than the control as evidenced by the smoke from the crib. However neither crib reignited.

Jan 1, 1982

By J. D. T. Capocchi, M. B. Mourao

The rate of reaction between iron oxides and carbonaceous materials, agglomerated as pellets, was studied experimentally by measuring the weight loss as a function of time. The effects of temperature, carbon type, inert gas flow rate, pellet size and additions (sodium. carbonate and Portland cement) were determined. It was shown that the value of the apparent activation energy can display large deviations under different experimental conditions; in the present work it was found to be 226.6 kJ/mol. The reaction with coke is slower than with charcoal, and the rate increases as the flow of inert gas in the reaction vessel decreases. Comparison of the rates for pellets of different sizes has shown that for small pellets the initial rate is faster but that it slows down at high conversions owing to the penetration of inert gas into the pellet. Additions of sodium carbonate and Portland cement increase the rate; sodium. carbonate promotes the catalysis of the Boudouard reaction, which is the slowest of the partial reactions. The increase in the rate with Portland cement is attributed to the release of water vapour

Jun 18, 1905

By A. J. Farstad

Recent advances in microcomputer technology have opened the way for systems which can track the location of underground mining personnel from the surface. A computerized system has been designed which is capable of not only tracking the location of the miner but also of monitoring underground parameters, communicating between work stations and sounding alarms when underground conditions are judged to be unsafe. For the system described herein, the locations of the underground personnel are detected by a network of underground terminals which routinely emit RF pulses to interrogate miniature transponders worn by the miners. Each transponder is uniquely programmed to delay its response in such a way that the RF terminal can identify the individual transponders by the time slots in which the responding pulses are received. The underground terminals are then interrogated by the host computer on the surface which keeps a running account on underground mine conditions and personnel. The underground portion of the system is designed to operate even during mine emergencies, deriving its power from rechargeable battery supplies which are float charged during normal operation. Nine mines were visited on this program and the industry reaction to the system was generally favorable. By slanting the system design for daily use in the mine, the chance of its acceptance by the industry is enhanced. Furthermore its likelihood of being operational in the event of an emergency is significantly increased.

Jan 1, 1981

By J. A. Finch, Zhenghe Xu

The competitive adsorption of xanthates on sulphide minerals in a binary mineral system (pentlandite and pyrrhotite) was studied using the pseudo-in-situ technique of attenuated total-reflectance FTIR spectroscopy. The minerals were placed in the same collector solutions, either separated by a glass wall or in direct contact with each other before magnetic separation and separate analysis. The effect of mineral interaction on xanthate adsorption was clearly demonstrated spectroscopically for the first time. At low concentrations of xanthate, its adsorption on pentlandite was activated by physical contact with pyrrhotite; the effect may be attributed to the enhancement of electron transfer through electrical contact between the two minerals. The results emphasise the need for caution in extrapolating results obtained from single-mineral studies to flotation practice

Jun 18, 1905

By L. B. Phelps

A method is presented for the burial of potentially toxic spoil in high density zones or packages within spoil piles. Such burial could reduce the outflow of pollutants and thus minimize contamination of groundwater flows. Laboratory model studies using ammonium bromide tracer were performed to quantify the expected outflow mixing that could be achieved through package construction in spoils. Field drilling and geophysical density logging of spoils was carried out at three sites in Pennsylvania and Ohio to obtain a range of field spoil bulk density measurements and spoil samples. These data are analyzed to determine the relationships between spoil density and the controlling factors of lithology, depth, age, particle size distribution and mining method. A separate series of spoil permeability tests were performed in the laboratory to investigate the relationship between permeability and its related parameters. Research results are applied to the toxic package method to suggest guidelines for pack-age size, shape, density and placement for future field prototype development.

Jan 1, 1981

By G. D. Schena, M Zanin

A numerical approach is presented for predicting the liberation of phases during comminution, with direct calculation of a liberation spectrum giving the fraction of the particulate system in each narrow size-composition class. The numerical model uses a Poisson flat process for stochastic generation of the non-convex three-dimensional Poisson polyhedral textures and the system of fractures that give rise to convex fragments. With this numerical approach, there is no need to assume random uniform isotopic fracture (lack of selective liberation); only computational geometry primitives are exploited for the derivation. The agreement with relationships obtained previously under the random uniform isotopic fracture hypothesis demonstrates that the approach is capable of deriving full liberation spectra directly. Both volumetric and superficial composition can be calculated

Jun 21, 1905

By Jon H. Gould

This paper describes the following at the new Advanced Solid Rocket Motor (ASRM) nozzle manufacturing facility, which is being constructed inside an existing manufacturing facility: 1) generalized subsurface conditions, 2) pile load test program and evaluation, 3) pile selection, 4) problems associated with pile driving operations, and 5) production pile installation. The poor subsurface conditions, known and unknown underground obstructions, and work environment inside the existing building, used to manufacture the Space Shuttle external fuel tanks, required special pile installation equipment, procedures, and work schedules to install the economical pile foundation system ahead of schedule and without a lost time accident. GEOTECHNICAL STUDIES In April and May 1990, 16 soil test borings were drilled inside the existing building with a truck-mounted drill rig. The borings extended to depths ranging from 60 to 65 ft (18.3 to 19.8 m) below the floor slab. Typically, the silty and clayey soils were sampled by pushing "undisturbed" Shelby tubes, and the more sandy soils were sampled by driving a Standard Penetration Test (SPT) split-spoon sampler. The unconfined compressive strength, water content, and unit weight of the Shelby tube samples were measured in the laboratory. A geotechnical report was issued in May 1990 presenting the results of the field and laboratory testing and foundation recommendations (Gilbert, 1990).

Jan 1, 1992

By S. K. Oraee

Most management decisions at all levels of the organization are as directly or indirectly depends on the circumstance of future. With regard to predict the future events in the process of decision-making plays a main role, therefore, forecasting is very important for every organizations and institutions. There is a variety of methods to predict time series. In general, these techniques can be divided as following: statistical, artificial intelligence and analytical techniques. Two of the most common methods for time series prediction is autoregressive integrated moving average (ARIMA) and artificial neural network (ANN) methods, these methods are the subset of statistical and artificial intelligence techniques respectively. In this paper, a hybrid model of ARIMA and ANN models are employed to predict the number of fatal injuries in the USA underground coal mines. This research showed the result of hybrid model is better than split model.

Jan 1, 2011

By J. R. L. Read, A. N. Ogden

This paper describes mining industry funded research that is being undertaken to address the critical gaps and uncertainties in our knowledge so that we can develop new approaches and create more effective ways for predicting the reliability of rock slopes in large open pit mines. It is envisaged that this research will not only lead to more effective pit slope design but further reduce the potential for unforseen geotechnical risks by enabling the geotechnician to communicate the risks more effectively with management and to optimise site specific control measures. To achieve this, several research tasks are in hand. The first is to accurately represent the structured rock mass with a 3D computer model (Siromodel) that creates polyhedral blocks from structural distribution data characterised by position, orientation and persistence. Siromodel is being coupled with particle flow and other numerical codes to evaluate how the structured rock mass deforms in the stress environment of an open pit and how a candidate failure surface may propagate through the dilating rock mass along the path of the least shear and/or tension resistance. A beta version of the Siromodel software has been distributed to 20 Sponsor mine sites for technical evaluation. The end state is to develop methods of analysis that characterise the reliability of a described candidate surface, and the probability of the candidate surface propagating to failure, recognising that the rock mass strength may well be defined in a different way than before.

Jan 1, 2006

By G. F. Kuncir

The analysis summarized herein evaluates the Bureau of Mines Program for Advancing Mining Technology Oil Shale in terms of the economic benefits which may be derived for the Nation as a result of its successful research and development efforts. On the basis of postulated oil shale production scenarios, benefit-cost ratio indicators are computed for the program elements as they apply to surface, underground, and modified in situ oil shale mining systems. Eight value indicators are used to measure the Program's beneficial impact on the future oil shale industry in relation to planned research and development costs. These are: capital cost savings, operating cost savings, labor savings, environmental quality maintenance cost reduction, reduction in production costs, byproduct production benefits, total production benefits, and additions to recoverable reserves. Program costs are aggregated from 1974 through 1987 and major benefits are accrued from 1982 through 2040. Both cost and benefit streams are discounted to mid-1975 present value.

Jan 1, 1977

By Osama El-Fiky

There are many types of deep foundations currently being used in the San Francisco Bay Area, one of the most common being driven precast, prestressed concrete (PC/PS) piles. PC/PS piles are frequently selected for use due to of ease of installation, availability, and relatively low cost. Disadvantages of using PC/PS piles are noise, vibrations, pollution, front-end delays due to indicator pile programs, and reduced flexibility. An acceptable alternative to driven PC/PS piles was selected for construction of foundations for the heavy housing and administrative buildings at the San Francisco County Jail #3 replacement project in San Bruno, California. The pile type selected, the Auger Pressure Grouted Displacement (APGD) pile, was chosen to reduce noise, vibrations, installation time, and cost, and to allow for greater flexibility of installed pile lengths. This paper presents a case history of the use of APGD piles that were substituted for driven PC/PS concrete piles for the subject project. Standard and quick loading pile load tests were performed to confirm adherence with the design criteria originally used for the driven PC/PS concrete piles. The APGD piles were found to increase shear strength around the piles similarly to driven displacement piles. In addition, this paper presents the methodology used in monitoring APGD pile installation.

Jan 1, 2002

By T. G. Carnahan

In-place leaching is being actively utilized to extract uranium, copper, and evaporites from low-grade and difficult-to-mine ores. The purpose of this report is to discuss in-place leaching technology, its advantages and disadvantages, and to give an overview of past, current, and envisioned in-place leaching operations in the U.S.A. Application of in-place leaching to uranium ores has been particularly successful because the conditions for leaching are nearly ideal. The ores are generally in highly permeable sandstone aquifers bounded above and below by impermeable shales. The uranium ore minerals are easily leached with oxidizing acid or base solution and the pregnant solutions are amenable to ion exchange concentration and purification prior to conventional solution neutralization for recovery of yellow cake. Copper is routinely recovered from sub-grade rock by dump leaching at most major copper mines. Acidified ferric sulfate is either sprayed on the surface of the dumps or is ponded on top of the dumps. The leaching solution migrates down through the rock and dissolves copper. The solution is collected from the base of the dumps and copper is recovered by solvent extraction-electrowinning or by cementation on detinned steel cans. True in-place copper leaching is being practiced in the caved stopes of an exhausted underground copper mine. Other innovative in-place copper leaching techniques have been tested commercially and laboratory- and pilot-scale experiments have been conducted to investigate proposed in-place leaching techniques for extracting copper from difficult-to-treat chalcopyrite ores. Solution mining of evaporites is being conducted commercially for the extraction of sodium chloride and potassium chloride. A large-scale experimental project for solution mining of trona has been undertaken.

Jan 1, 1982

By Juan J. Campo

The Freeport-McMoRan Main Pass Mine development in the Gulf of Mexico is a complex designed to extract up to 67 million long tons of sulphur over a 40 year period. The initial development includes 15 platforms and 13 bridges located in water depths ranging from 208 to 214 feet, approximately 15 miles east of the Mississippi River Delta. Three additional platforms were designed and installed for the oil and gas development in the complex. Over 110, 000 short tons of steel were required to fabricate the structures. As the sulphur is extracted significant subsidence is predicted over a major portion of complex in the shape of a very large bowl. Vertical elevations are predicted to change as much as 65 feet. Horizontal movements and mudline slope changes cause adjacent platform decks to move as much as 30 feet relative to each other. Differential soil movement is predicted between piling of individual platforms causing the piling to spread, resulting in significant lateral loading on the piling. Relative vertical soil movements are predicted along the lengths of the piles which causes "up drag" or "down drag" forces on individual piles. This paper addresses the design of the piling for the structures in the complex. Design criteria will be discussed explaining how the more traditional offshore environmental and gravity loadings were combined with the unique loading caused by subsidence. Design and analysis procedures will be explained and analysis results presented. These results include the incorporation of 100 ksi steel in thicknesses up to 5 inches in some of the tubular piles. Comparisons will be made between conventional offshore structures and these structures designed to accommodate the subsidence.

Jan 1, 1992

By Clyde L. Holmberg, Paul Zinner

"INTRODUCTION In view of the large tonnage of low-grade iron ore and iron-bearing material known to exist at the western limits of the Gogebic range, the Bureau of Mines undertook an investigation of the area for the purpose of evaluating the iron-bearing formations as sources of iron for possible future utilization.After 6o years of exploration an, development on the Gogebic range, the area investigated by the Bureau represents the known western limit of direct-shipping ore mined from operations on the Gogebic range.An area about 2 miles in length between the villages of Pence and Iron Bolt in Iron County, Vic., was selected for investigation, and trenches wore excavated through the overburden and fully across the iron-bearing formation to obtain 108 bulk samples for beneficiation tests. Exhaustive tests involving gravity and flotation methods, magnetic separation, and magnetizing roasts followed by magnetic separation were conducted on the samples to determine the ammability of the individual formations and the entire iron-bearing zone to beneficiation.Empirical data on the character and mineral content of the formations arc tabulated herein, as well as the results of the beneficiation tests."

Dec 1, 1947

By Guangyi Sun

Wall rock classification method for coal mine support is the main factor affecting mine support. It is greatly affected by the combined effect of randomness, fuzziness and human being's incomplete knowledge. There are several coal rock classification methods. Using different rock classification methods the same engineering rock mass can be classified into different classification leading to different construction practices.

Jan 1, 2005

By V. Krupa, E. Lazarova

A method is proposed for the continuous calulation of a rock mass in real time while tunnelling with a TBM. Rock properties are investigated through models of the fracture stress under the disc cutters, the quasi-shear stress between the disc cutters and the specific energy of cutting under the disc cutters. Comparison of theoretical and monitored data of cutting specific energy can be used to determine theoretically the prevailing shape and size of the bulk debris. The shape and size of the chips from a given rock vary with the boring parameters. Introducing shape and volume corrections into the models of the evaluated stresses suppresses the influence of the boring regime and allows the rock properties to become dominant

Dec 1, 1996