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By G. Akdogan, S. M. Bradshaw, A. P. Van Wyk, T. Punt

Recycling has become an important part of the lithium-ion battery (LIB) life cycle due to the growing demand for energy storage in applications like electric vehicles and renewable energy. Recycling spent LIBs provides a secondary source for strategically scarce metals, like lithium and cobalt, helping to reduce the environmental impact of LIBs. Organic acids have been proven to be effective lixiviants with the benefit of reduced environmental impacts, amongst which citric acid has shown to exhibit similar extraction performance when compared to mineral acids. Leaching LCO and NMC batteries with 1.5M citric acid and 2 vol.% H2O2 at 95°C, 20 g/L for 20 minutes achieved 93% Al, 90% Co, 96% Li, 94% Mn and 94% Ni dissolution. The strong chelating property of citric acid affects the separation of the metals, providing unique extraction opportunities. The first extraction uses 12 vol.% D2EHPA at a pH of 2.5 and O/A ratio of 2 to separate 96.4% Mn and 100% Al from the PLS in two counter-current stages. Stripping the loaded organic with 1.25M citric acid at an A/O ratio of 3 allows for up to 91% stripping of the manganese in a single stage. The second extraction then separates 96.5% Li from the PLS in three counter-current stages using 20 vol.% D2EHPA at a pH 5.5 and O/A ratio of 5. The raffinate remaining after the second separation contains 48.4 wt.% Co and 50.3 wt.% Ni. Keywords: Hydrometallurgy, lithium-ion batteries, metal recycling, citric acid, solvent extraction

Jan 1, 2020

By B. P. Atkin, D. W. Brown

The handleability monitor has been specifically designed to provide a simple, rapid and on-site assessment of the whole or part consignment of a coal blend in its ‘as-received’ condition. Evaluation has been carried out at a number of coal-handling plants, on both metallurgical and power station coals from a variety of sources world-wide. The results which are used to predict which coals could routinely pass through a handling plant at line capacity, without causing blockage or delay, have also been correlated with moisture, ash and size analyses of the coal to develop a predictive model of handleability.

Jan 1, 2000

By Sandeep Kumar Jeripotula, Govinda Raj Mandela, Aruna Manglapady

Dumper operators are frequently exposed to whole body vibration (WBV) in surface mines. Surface mining activities involve the amalgamation of comparatively high intensity of vibration and extended exposure durations. Efficient risk reduction mandates knowing of important phases of a task that poses a threat to health of dumper operators. So far in India very limited studies have been reported on WBV exposure with regard to surface mines. This paper evaluates WBV of dumper operators based on ISO 2631-1:1997 Standards and European Union (EU) Directive 2002 for different phases of job cycle. Six dumpers were considered for this study and the vibration measurements were made for all the four phases of the job cycle by placing the triaxial accelerometer on the operator’s seat-surface and at the seat-back, independently. The findings of the study revealed that the haulage task (loaded travel and empty travel) remains the chief contributor to vibration exposure according to seat-surface and seat-back measurements. Maximum frequency weighted root mean square (RMS) of 1.12 m/s2 and 1.09 m/s2 were reported for empty travel task for seat-surface and seat-back measurements, respectively. For seat-surface measurements based on RMS, Z axis remains as the dominant axis of vibration for all the dumpers during haulage task, whereas for seat-back measurements, the dominant axis varies between X and Y. Exposure action value (EAV) based on RMS has exceeded the threshold value of 0.5 m/s2 for all the dumpers during loaded travel and empty travel for seat-surface as well as for seat-back measurements.

By Karl Dufresne

Blasting in geothermally high temperature ground and/or extremely reactive ground is an increasing common challenge for surface and underground mines. Many current PETN based non-electric and electronic detonators have manufacturer published in-hole temperature limits ranging from 55°C to 65°C (131°F to 150°F). When confronting blasthole temperatures above the manufacturer published limits, operations may request site-specific guidance and qualification for use. The advised safe loading window for in-hole PETN based detonators is often too short to be practicable for production blasting. To overcome limitations of PETN based initiation systems, surface mines with high temperature ground and/or reactive ground are known to load blastholes with a qualified high temperature bulk emulsion that are top primed with a cartridge of temperature qualified detonator sensitive emulsion plus an RDX detonating cord downline. As there is no in-hole delay detonator in this system, blasthole timing is accomplished with surface delays. Although this system is safe, top priming and surface delaying does influence floor quality and top size fragmentation, and safe loading windows times reduce blast block size and increase blasting frequency. A mining company with a site characterized by geothermally high temperature ground plus highly reactive ground employed a blasting system like the one described above. The site desires to improve blasting performance by moving to an in-hole delay initiation system that can withstand the site ground conditions. At the request of the mining house, DynaEnergetics developed an electronic initiation system for application in geothermally high temperature ground and/or extremely reactive ground conditions. The DynaEnergetics IGNEO high temperature electronic initiation system is rated for in-hole use in ground up to 150C (302°F) for 48 hours. The detonator consists of a high strength detonator with an HMX base charge and thermally resistant downline. To make up a primer, the detonator is inserted into a booster charge assembly that is fitted with a small HMX shape charge. This high energy primer is designed to be compatible and reliable for firing bulk emulsions, including those with high percentages of urea inhibition to combat reactive ground. Up to 1000 detonators may be programmed in 1ms increments up to 1500ms. The system is controlled by a digital firing panel that can be used with either a wired or wireless trigger.  The system enables high temperature and/or reactive ground sites to utilize in-hole delay initiation and realize the associated performance benefits. Conclusions and Future Work 1] The HMX based electronic initiation system permits bottom in-hole delaying in ground temperatures above 80°C (175°F). As compared to top priming and surface delaying, in-hole bottom delaying is known to improve floor quality, muckpile fragmentation uniformity and reduce oversize. 2] Field evaluation of the HMX initiation system at the Lihir Mine is continuing. 3] Work on the next generation of the HMX initiation system is underway and will bring with it expanded application range and flexibility. 

Oct 1, 2024

By R. V. Higgins

Tarner (1),3/ Muskat (2), and Schilthuis (1) have presented methods of calculating oil recovery by the expansion of dissolved gas with and without return of gas to the reservoir. Although electronic computers have eliminated the tedious and time-consuming calculations (4) required by each of these methods, many petroleum engineers do not have access to electronic computers. For these engineers a short method is presented that uses the Tarner method as a base. Moreover, for engineers who have access to computers and have not as yet prepared a program, the short Tamer method requires less computer time than the long iterative methods. In the proposed short method, no plotting of the calculated data is required to determine a point of intersection described in the original Tarner presentation, as only one calculation is needed to determine the value sought, or two calculations if greater accuracy is desired.

Jan 1, 1960

By Paulo César Pontelo

Buscando atender seus clientes com soluções inovadoras no campo do tratamento de metais líquidos, a Sidertec efetuou a atualização tecnológica do sistema de dessulfuração primária de uma grande usina integrada brasileira trazendo o seu sistema antes obsoleto para o estado da arte em dessulfuração e ainda substituindo o dessulfurante a base de CaC2 anteriormente utilizado por PureSteel®; tendo como benefícios a otimização do processo, redução de custo de 61% e melhora na condição de segurança operacional pela retirada de produto perigoso do processo da usina. Esta implementação utilizou o Know How Sidertec e se baseou na metodologia de estudo do problema, aprofundamento de engenharia das possíveis soluções e realização do revamping proposto.

Aug 17, 2017

By C. H. Tiernon

"This paper was' prepared to emphasize the part that coal washing tables can play in the development of many of the reserves of coking coals in Western Canada_ It covers a brief history of the development of the coal washing table through the present third-generation unit, which suspends from overhead steel beams and is driven by a counter-rotating gear mechanism. The design and operation of this unique table are covered in detail.An analysis of actual operating data is included, with explicit statistical breakdowns of the table products. The data used were actually produced by operating coal companies, and also produced by the United States Bureau of Mines while gathering data for a research investigation. Table feed capacity is discussed, as well as performance criteria and the parameters of relative table performance. Several typical table flowsheets are described, emphasizing the specific reasons for their use. The paper covers the past and present value of the table to the United States coal industry, and makes mention of the newest addition to the family of suspended, multiple-deck, counter-rotating, gear-driven, coal washing tables, the CONCENCO ""88"" Deister table."

Jan 1, 1973

By Grażyna Dzik, Adam Mirek, Krzysztof Król

The Upper Silesian Coal Basin is located in the area of the Upper Silesian Syncline and belongs to one of the most complex tectonic units in Europe. It occupies 5,650 km2. In 2020, there were 20 hard coal mines operating in the area. Seismological research in this area consists of observation of precursors/symptoms of shock generation and understanding of their effects. Studies (Teisseyre R. 1972, Mutke G. & Stec K. 1997, Stec K. 2007, Dubiński J. & other 2010, Idziak A. 2010) of complex impacts of rock mass provided a background for determining the conditions for the formation of exploitation and regional seismic shocks. Issues related to tectonic and exploitation stresses, successive extraction of coal seams at higher depths, operation in the vicinity of fault zones, often complex geological and organic conditions result in the activation of a discontinuity surface due to stress caused by deformation of rock layers, which, as a result, causes the emergence of strong shocks above 107 J. The article was based on analyses of extraction value, high-energy shocks, both of mining and tectonic-mining (so-called regional shocks) origin, against the background of changing operating conditions, which, as a result, creates an image of periodically changing seismic activity and location of strong shocks. Observation results show that, with an increase in exploitation depth and declining extraction, the number of strong shocks caused by tectonic stress (107 - 109 J) and exploitation stress (≥105 J) has been steadily increasing over the last 25 years.

Apr 26, 2022

By L. B. Phelps

The nation is confronted with thousands of acres of abandoned coal lands. In Pennsylvania alone, these lands have been estimated to cost $15 billion to reclaim (Pennsylvania Bulletin, 1985). One way to deal with this problem is to provide a mechanism by which the active mining industry can undertake to remine certain of these abandoned mine areas. Remining is classified as reaffecting previously mined areas in order td extract the remaining coal reserves while improving the environmental quality of these lands through land restogation and abatement of pollutional discharges. However, there currently is a disincentive for operators to plan to extract reserves on these abandoned mine lands which have preexisting pollutional discharges. Therefore, they presently avoid them. This is because of the "potentially unlimited liability of post- mining treatment for any discharges that would remain after mining? (Pennsylvania Bulletin, 1985).

Jan 1, 1987

By L. Li

Chemical composition, mineral composition, and iron occurrence state of main mineral are studied, Research of mineral processing technology is carried out according to ore features. The test results indicate, that through staged grinding-staged concentration process, the better separation index is up to 65.54%, iron preparation concentrate grade and 85.66% recovery with the fineness (-200 mesh) 45.88% in the primary grinding ore and the fineness (-200 mesh) 75.50%, in secondary grinding ore in the situation of best magnetic field intensity (roughing 0.2T and cleaning 0.15T).

Sep 1, 2012

By S. K. Kawatra, H. J. Haselhuhn

"Fine-grained hematite ore can be concentrated by the process of selective flocculation and dispersion, which relies on proper reagent selection and control of water chemistry. While many previous studies have been performed analyzing the effects of different reagents on this process in a laboratory environment, this paper focuses on investigating the water chemistry within the process in a pilot-scale continuous deslime thickener.The pH, sodium concentration, calcium concentration and magnesium concentration were varied to determine their effects on the iron concentrate grade and recovery, and the phosphorus concentrate grade and rejection in the pilotscale selective deslime thickener. The ideal pH for the iron grade and recovery of the process using a starch selective flocculant was found to be 10.5. Phosphorus rejection, however, was increased at lower pH values. Minimization of sodium concentration was shown to improve iron grade, iron recovery and phosphorus rejection. Calcium acted as a nonselective flocculant showing higher iron recovery, lower iron grade and lower phosphorus rejection with increasing concentration. Conclusions could not be drawn from the experiments that varied magnesium concentration.The zeta potential of the solid-liquid interface of particles in each sample taken was also analyzed to show relationships between zeta potential and process performance. In all cases, a maximization of the magnitude of zeta potential correlated with increased iron grade and recovery. This supports the hypothesis that a higher level of dispersion enhances the selective flocculation and separation process.IntroductionThe United States produced 53.2 million metric tons out of the 3,000 million metric tons of concentrated iron ore produced worldwide in 2012 (Tuck, 2013). With this in mind, there has been a large increase in iron ore processing research (Bolen, 2014; Carlson and Kawatra, 2008, 2013; Halt and Kawatra, 2014; Halt et al., 2014; Haselhuhn et al., 2012a,b, 2013a,b; Liu et al., 2014; Manouchehri, 2014; Sandvik and Larsen, 2014; Semberg et al., 2014). Of the 53.2 million metric tons produced, roughly 8 million metric tons of hematite (Fe2O3) concentrate were produced using a process known as selective flocculation and dispersion (Cliffs Natural Resources, 2011). This process is the only economically viable method for concentrating low grade (< 40% Fe) fine grain (< 25µm liberation size) hematite ores. It is scarcely used due to difficulty in controlling the surface chemistry of the ore and high reagent costs (Department of Energy, 2001; Haselhuhn et al., 2013a). The process is highly dependent upon both reagent selection and precise control of the water chemistry during separation. This study shows the dependence of the process performance of a pilot-scale deslime thickener on the water chemistry in the feed slurry."

Jan 1, 2015

By W. R. Hardwick

This Information Circular describes the development of block-caving methods and practices by the Miami Copper Co. at the Miami mine in Gila County, Arizona. It is one of a series published by the Bureau of Mines on mining methods, practices, and costs in various mining districts of the United States. This report gives a history of the district and outlines early prospecting and exploration including methods of sampling and estimation of ore tonnage and value at the Miami mine. Early mining methods are described, particularly those that influenced developments in the caving method. Mine exploration, development, and operating methods for block caving are described with particular attention to those factors, physical, economic, engineering, and managerial that have improved efficiency in the mining operations over a long productive period. Extraction, ventilation, wage system, safety, water supply, power plant, and shop facilities are discussed. The last section gives a brief sumary of such costs as are available for publication.

Dec 1, 1964

By Rayane Sonda Cassel Bielefeldt

As TRC (tensões residuais compressivas) induzidas por shot-peening (SP) podem ser relaxadas e redistribuídas sob cargas cíclicas mecânicas, térmicas e termomecânicas. O objetivo desta pesquisa é avaliar a redução da TRC por SP através da difração de raios-X fast in-situ (DRXin-situ) na superfície do aço SAE 4140 durante tempo (t) de patamar de t [s] = 54000 em três diferentes temperaturas (T) de T [K] = 423,16; 523,16 e 623,16. É investigada a relaxação de TRC por cargas térmicas, mantendo as amostras, previamente tratadas por SP, em um forno com diferentes temperaturas de patamar, enquanto são medidos os valores de TR ao longo do t. Foi construída uma câmara de vácuo acoplada a um difratômetro de raios-X. Obteve-se 100 % cobertura por SP, as TRC aliviaram com o aumento da temperatura de patamar e o tempo. A maior variação de TRC ocorreu nos primeiros minutos de ensaio, no restante do tempo a TR permaneceu constante. A macrodureza superficial e FWHM das amostras diminuíram com o aumento da temperatura de patamar ao longo do tempo. A macrodureza superficial das amostras e FWHM são maiores após o tratamento de SP, antes do aquecimento. O FWHM reduziu ao longo do tempo com mesmo comportamento da queda da TRC, correspondente e proporcional à redução da TRC. A energia de ativação do processo, calculado pela função Zener-Wert-Avrami não foi coerente com a autodifusão do Fe-a. Logo, é recomendada a repetição para verificar o resultado. Com base nos dados obtidos, se pode concluir que esta pesquisa possui relevância industrial.

Oct 30, 2017

By B. Konda, R. Lauer, D. Camilucci, D. Gladwin

"Income based taxes are significant cost elements to be considered in evaluating investment in new mine development. This paper presents the results of comparative analysis of effective income-based tax rates for mining in the Northwest Territories (NWT), selected Canadian provinces and international jurisdictions. The study was done as background to a review of royalty regulations for the NWT. ObjectiveThis paper presents results of comparative analysis of effective mining royalty1 rates, and combined effective mining royalty and income tax rates on selected mine models for the Northwest Territories (NWT), with those for several other jurisdictions in Canada and abroad which compete with the NWT for mining investment.BackgroundThe February 27, 1995 federal budget directed the Department of Indian Affairs and Northern Development (DIAND) to proceed with a comprehensive review and amendments to northern natural resource management legislation in order “to increase revenues and ensure a fair return to the Crown.” DIAND is responsible for the administration of the Territorial Lands Act, and its regulations.The Territorial Lands Act gives the Governor-in-Council the authority to “… make regulations for the leasing of mining rights in, under or on territorial lands and the payment of royalties therefor,…”. In the NWT, the Canada Mining Regulations (CMR) provide for the disposition of mineral rights for most minerals, other than coal, petroleum and related hydrocarbons, in return for the payment of a royalty to the Crown.As part of this review of the NWT mining royalty regime, several computer mine models were developed and tax regimes in a number of jurisdictions were analyzed. Effective mining royalty rates, and the combined effective mining royalty and income tax rates were compared across the jurisdictions. The results presented in this paper are a part of the background work done in preparing a discussion paper on proposed changes to the NWT mining royalty that is expected to be released for public consultation in the very near future."

Jan 1, 1997

By KNona C. Liddell

Goethite is an important naturally occurring sorbent for divalent heavy metals and has often been used as a model compound in studies of adsorption on oxide mineral surfaces. Surface complexation modeling, surface spectroscopy, and electrochemical techniques have all been applied to goethite adsorption. Modeling studies have shown that usually several different sets of fitted parameters are equally successful in representing surface charging and adsorption data. Surface spectroscopic data are proving valuable in determining the nature of the surface sites, and refined models now incorporate structural information on interatomic distances and coordination numbers. Multisite surface complexation models can give very good fits to surface charging and adsorption data, but further improvements are needed to better represent surface reactions involving exchange of protons and divalent cations. Recent experimental and modeling studies on adsorption of divalent transition metals on goethite are described and the present status of the field is assessed.

Jan 1, 1999

By S. Fahland, P. Vogel

"The Gorleben salt dome has been investigated since 1979 for its suitability as a repository for the disposal of high-level radioactive wastes. The geoscientific surface exploration was followed by underground exploration of the site beginning in 1983: underground excavation work included the sinking of two shafts from 1986 to 1994, the excavation of the infrastructure area and of drifts located in the first exploration area EB1 within the following years. The exploration was interrupted for ten years from 2000 to 2010 as part of a moratorium. After the expiry of the moratorium in March 2010, the geoscientific underground exploration at the Gorleben site was resumed. The investigations were interrupted again in autumn 2012 due to a political decision. The exploration programme included extensive geoscientific investigations: geological exploration, geophysical investigations, mining exploration and mining observation, laboratory tests, in-situ geotechnical measurements, geological modelling and numerical model calculations. To analyse and interpret the results of the in-situ measurements and mining observation geomechanical, thermal and thermo-mechanical model calculations were carried out. One of the main elements of the in-situ geotechnical investigations were high-resolution geothermal measurements performed in boreholes used for geological exploration and geotechnical tests.The geothermal measurements are used to evaluate several geotechnical findings, e. g. drift closure, rock deformation, stress change, and are completed by thermal model calculations to analyse and interpret the results of in-situ measurements and mining observation. The model calculations have been carried out using the special purpose JIFE code. To consider the whole exploration mine with the adjoining host rock as well as the successive excavation of drifts and boreholes in detail a three-dimensional finite-element model was developed. The model calculations are used to analyse the cooling-off of the surrounding rock of the drifts caused by ventilation. The cooling-off of the surrounding rock is an ongoing process affecting the results of further geotechnical measurements in the near field of the drifts. To predict a realistic time and space dependent distribution of the temperature field of the host rock within the exploration area which is influenced by ventilation thermal model calculations are necessary. Comparing the calculated temperature field with the in-situ determined rock mass temperature field within the exploration area EB 1 the results show a sufficient agreement. Furthermore there is very good correspondence, both qualitatively and quantitatively, between the experimental and the calculated findings regarding the temperature profiles including the effects of excavation and ventilation of the drifts."

Jan 1, 2015

By Qian Liu

Mining in highly stressed ground conditions has been an increasing challenge at the Brunswick Mine. Two large regional pillars were established on the 1000 m Level to support the ground for safe extraction of the surrounding ore. The South Regional Pillar contains about 5 million tonnes of ore and the North Regional Pillar has about 3 million tonnes of ore. In the fall of 2000, mining activities were suspended following a series of ground movements around the South Regional Pillar along weak geological structures. After extensive geotechnical investigations, a decision was made to carry out a mass destress blast in the West Ore Zone (WOZ) to cut the principal stress across an area of 135 m along strike and 86 m high. At the end of July 2001, the WOZ mass blast was successfully initiated. Following this success the mine decided to take a similar approach to destressing the North Regional Pillar (NRP). The final mass blast was taken in early February 2003. Advanced blasting technologies, including state of the art electronic detonators and blast simulation, played an important role in achieving the successful blasts. The high precision of delay timing and long delay duration of the electronic detonators ensured accurate and reliable initiations of over 800 blastholes in the WOZ mass blast. Orica?s DMC_Blast (Distinct Motion Code) simulation code was used to study different blasting blocks for the desired timing in the initiation sequence. This paper describes the process of applying electronic detonators in complex blasts, and discusses how blast simulation results were interpreted to guide engineering design of the mass blasts.

May 1, 2003

By M. G. Stamatakis, C. Zagouroglou, C. Helvaci, J. Kanaris

"Abstract -Borate minerals, such as colemanite, ulexite and borax, have been reported in Tertiary continental basins of West Anatolia, Turkey, and Samos Island, Greece.Tuffaceous rocks interbedded with the borates are rich in authigenic silicate minerals such as zeolites, potassium feldspar and opal-CT, all of which have a genetic association with the borates. Chemical analyses of the tuffaceous rocks show variation in major elements due to the varying percentage of carbonaceous, detrital, and volcanic derived material.The volcanic activity in the vicinity of each particular lacustrine basin created ion-rich fluids from which a series of borates were precipitated under arid climate. Additionally, the saline-alkaline character of these fluids was responsible for the diagenesis of the silicic glass of the tuffaceous rocks, altering them to silicates and silica polymorphs."

Jan 1, 1993

By Ben E. Lusk

First of all let me say what a genuine pleasure it is to be here. Acapulco certainly is a beautiful change. I&apos;m going to spend sometime talking about change, because frankly I&apos;m astounded at the rate of change in our world today. One good example of this, reminds me that the first time I spoke before the AIME two years ago, we were at the Ramada Inn in Beckley, West Virginia. Today we&apos;re at the Princess Hotel in Acapulco, Mexico. Now that&apos;s what I call a change. Seriously though, I&apos;m sure you&apos;ve all heard it said that the most consistent thing about our society is its constant change. Five years ago, no one could have predicted the changes we experienced in the United States during the first half of the 1970&apos;s. In the past twenty-four months alone, we have seen two presidents, three vice-presidents and hundreds of administration and government personnel changes. We have stumbled from one social crisis to another, while suffering through rising inflation, major energy shortages and labor unrest that could plunge us into a full scale economic depression. In view of these constant and unpredictable changes around us, it&apos;s obvious that we must learn to deal with change and "roll with the punches" if we are to survive. A controversial book published recently, explores in detail the various aspects of change and its impact on man.

Jan 1, 1974

By Arthur W. Ruff

Estimated reserves of high-grade iron ore at Serra dos Carajás total 16 billion metric tons and have an average grade of 66.7 percent iron, 2.2 percent combined silica and alumina, and 0.05 percent phosphorous on a dry basis. Hematite is predominant and no significant sulfur or other deleterious elements are present. Figure 1 illustrates the comparative magnitude of the Carajás reserves. Serra dos Carajás is located in northern Brazil, about 550 kilometers southwest of Belém, Pará. It is six degrees south of the equator between the Xingu and Tocantins Rivers. Both rivers flow northward toward the Amazon River. The greater part of the area is covered by thick jungle, and the most practical means of access is by air. Figures 2 and 3 show the location of Serra dos Carajás. Figure 4 shows the distribution of the major iron-ore deposits.

Jan 1, 1973