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By James E. Lawver

The agriculture industry has made great strides during the past decade to increase agriculture yields through increased use of fertilizers. Increased use of fertilizers may prevent or at least delay mass starvation due to the alarming increase in world population. Phosphate was added to soil as a plant nutrient in the forms of calcined bones at least 2 000 years ago, (1) and man has used phosphate minerals as a source of fertilizers in one form or another for at least 100 years. During 1977 the world produced about 116 million metric tons of phosphate rock, with about 86% used for fertilizers and another 4% for animal feed supplements. More than three-fourths of the total production comes from the United States, Morocco, and the Soviet Union. From a mineral beneficiation point of view, the major sources of phosphate rock and the methods of beneficiation can be classified as follows. Marine deposits not containing appreciable carbonate minerals, marine deposits requiring a francolite carbonate mineral separation, igneous deposits not containing appreciable carbonate minerals, and igneous deposits, requiring an apatite carbonate mineral separation.

Jan 1, 1978

The traditional technological flow sheets for processing of ferrous quartzite (magnetite ores) al-low production of the iron concentrates with Fe content of 65%~68 % and recovery level about 55 %. The losses of iron with the tails of wet magnetic separation are related to hematite and quartz-magnetite particles, which are not extracted under low magnetic field employed. This work presents the results of the application of reverse cationic flotation for production of hematite concentrates with weak silica content from the tailings of wet magnetic separation of mag-netite. Fine particle size, complex mineralogy and presence of locked particles determine the impos-sibility of direct production of hematite concentrate by flotation or magnetic separation. The gravity concentration allows obtaining of iron concentrate from the well-prepared feed (size fraction -53+20 µm) but with very low recovery. Thus, hematite concentrates with weak silica content and satisfactory iron recovery were obtained by reverse cationic flotation, when it was fed with iron pre-concentrate produced by high gradient magnetic separation. The best flotation results were obtained by the use of formulations based on amines of different molecular structure that modulate the structure of adsorption layer, and favour a shifting of hydro-philic-hydrophobic balance on the surface of silicates with adsorbed starch and their preferential transfer into the froth product.

Jan 1, 2014

By B. R. Mohal, F. F. Aplan, S. Chander

"The wetting behavior of coal has been determined in the presence of nonyl and octyl series of nonionic surfactants containing polyethoxy groups of different sizes. The wetting behavior was determined by a modified Walker technique and contact angle measurements. The results show that the wetting rate of coal varies with coal rank, structure of the hydrocarbon chain and number of ethoxy groups in the hydrophilic group of the surfactant. A close relationship has been observed between the wetting rates and the short-time advancing contact angles.INTRODUCTIONNonionic surfactants are used in many applications to improve wettability of solids. They can be used as dispersing agents [ 1 ] or dust suppressants [ 2-5] and to control the flotation, flocculation, filtration and flowability of particulates. This study was undertaken to study the effect of a series of nonionic surfactants on the wetting behavior of coal. Two series of surfactants, namely, ethoxylated nonyl and octyl phenols were used. The nonyl phenol series contains a linear hydrocarbon chain containing nine carbon atoms ( CH3 ( CH2 ) 8-C6H4-( OC2H4 )""' where n is the number of ethoxy groups). The octyl phenol series contains a branched hydrocarbon chain containing eight carbon atoms ( ( CH3 ) 3CCH2C ( CH3 ) 2-C6H4-( OC2H4)"").Initial wetting rates - modified Walker techniqueWalker et al. [ 6] developed a sink test to determine the wettability of coal particles. In this technique, coal particles are dropped individually onto the surface of surfactant solutions of different concentrations, and the most dilute concentration in which coal would sink ""instantaneously"" is determined. This technique is a variation of a procedure initially developed by Draves and Clarkson [ 7] to determine the effect of surfactants on wettability of cotton fibers."

Jan 1, 1989

By Thiago Pinto Silva

Este estudo teve como objetivo investigar o efeito da substituição da dolomita por magnesita como fonte de MgO no processo de sinterização. Em testes realizados em escala piloto, observou-se que a utilização de magnesita eleva a resistência mecânica do sínter. A diferença de resistência foi decorrente da formação de uma solução sólida entre magnésio e ferro durante a sinterização. No caso da dolomita, que é fonte tanto de cálcio quanto de magnésio, a solução sólida Mg-Fe promove o encapsulamento do cálcio no seu interior, o que dificulta a formação das fases mineralógicas que promovem o endurecimento do sínter. Assim, a participação do cálcio na formação das fases ligantes é inibida, limitando a resistência mecânica obtida. A magnesita, por sua vez, não apresenta cálcio em sua constituição, sendo esse elemento adicionado via calcário. Dessa forma, o efeito do encapsulamento do cálcio não ocorre, havendo grande disponibilidade desse elemento para a formação de fases ligantes, permitindo a obtenção de níveis mais elevados de resistência mecânica do sínter. Portanto, a substituição da dolomita pela magnesita mostrou-se viável, desde que a granulometria seja similar à da dolomita, com grande potencial de melhora produtiva da sinterização industrial.

Oct 30, 2017

By Egnalda Pereira da Silva Pimenta

Visando a redução de custos e peso dos veículos, uma grande variedade de materiais, metálicos ou não, tem sido utilizada na produção de carrocerias. Cada um desses materiais possui uma tensão crítica de aplicação da tinta cataforética (tensão de ruptura) e, como a carroceria é pintada integralmente, a homogeneidade da pintura final em todas as partes representa um fator de grande relevância. Geralmente a tensão de aplicação da tinta é determinada em função do tempo disponível e não considera o tipo de tinta empregada, o que, em muitos casos, restringe o emprego de certos substratos metálicos. Por isso, o estabelecimento de janelas de processamento para a pintura dos materiais permite uma maior flexibilidade operacional. Assim, para esse estudo, foram pintados, em linha de pintura piloto, corpos de prova de aços, com e sem revestimento de zinco, utilizando-se três tipos de tintas e variando-se as tensões e os tempos para sua deposição, de modo a estabelecer uma “janela de processamento” para cada aço em função do tipo de tinta empregada. As “janelas de processamento” conferem maior flexibilidade aos processos de pintura, além de ser uma maneira conveniente de selecionar a tinta de melhor desempenho para uma determinada linha.

Aug 8, 2018

By B Mohanty, D Zwaan

Systematic near-field vibration monitoring of stope blasts was carried out in a large, deep underground mine. A total of 31 production blasts were studied in order to investigate the effectiveness of existing blast designs. This involved the vertical retreat mining method, which requires drilling a raise bore or blasting a slot raise (typically 1.22 m in diameter) using large diameter boreholes (165 mm). The diagnostic technique employed multistation near-field monitoring of blasts with high-g (100 g) and high-frequency (>10 kHz) triaxial accelerometers. The amplitude of the vibrations is correlated with the strain energy transmitted from each explosive deck. The results showed that more than 30 per cent of the explosive decks contributed little energy to the rock breakage process in these blasts, and an equal number contributed only inadequately. These findings are indicative of serious blast malfunctions. The problems can be traced to inadequate deck blast design and possibly to drill hole deviation. The various causes for such malfunctions are discussed and remedial measures suggested.CITATION:Mohanty, B and Zwaan, D, 2015. Assessment of underground production blast designs and blasting performance, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 607–616 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By A. G. Loomis

Although secondary-recovery methods have not been applied widely in California, it is apparent that increasing attention and effort must be given to this phase of recovery if the State is to maintain its high rank as a petroleum producer. Steadily increasing demands for petroleum products and decreasing rates of discovery of new oil fields and rapid depletion of existing reserves emphasize the prospect of an adverse situation of supply and demand in the not-far-distant future. If the trend of discoveries becomes more favorable or if more complete economic recovery of the oil in place can be obtained by secondary recovery, this situation can be averted. Not only are these reserves of economic importance to the petroleum industry to meet increasing market demands, but economic reclamation of such reserves is an important conservation measure, which will prolong the productive life of many fields" Accordingly, progressive operators in California are alert to the possibilities of secondary recovery and have done much to implement such operations wherever feasible. Most of the operations are of the pressure-maintenance type} in which the reservoir pressure is maintained or partly maintained by injecting natural gas to increase oil recovery. The possibilities of recovering additional oil from stripper fields by gas drive and water flooding (including water disposal) also are being tested in experimental field projects. Table 1 summarizes gas and water-injection projects in California.

Jan 1, 1952

By Carlos Magno de Lima Leonel

O presente trabalho teve como objetivo comparar o desempenho de processo entre espirais convencionais e espirais de grande diâmetro, na concentração de minérios de ferro. Foram realizadas campanhas de testes para levantar os dados necessários para comparar os dois modelos de espirais em estudo. Os resultados mostraram que as principais variáveis que afetaram a eficiência de separação nas espirais foram a abertura dos lemes e a concentração de sólidos na alimentação. A espiral de grande diâmetro obteve resultados melhores, mesmo sem a utilização de água de lavagem, porém mais testes serão necessários para uma conclusão definitiva.

Aug 16, 2017

By Charles Vaught, Warren G. Lacefield, Ronald D. Wasielewski, Philip K. Berger, Henry P. Cole, John V. Haley, Shannon L. Price

A comprehensive review of published research was carried out to identify methods for teaching and assessing critical but nonroutine skills needed for coping with emergency situations. Computerized searches of the relevant data bases were carried out, along with identification of relevant articles and materials by personal contact with experts in many fields. The citations listed in this bibliography resulted from this systematic literature search and review. The computer searches and an analysis of this literature are described in technical report 1. Specific methods for assessing critical skills proficiency in aviation, medicine, organization management, the military, and other industrial/ technical workplaces were described. The potential application of these methods for teaching and assessing (1) critical first aid and (2) self-rescue and escape skills to underground coal miners in annual refresher training was explored. Research and development activities that may improve mine health and safety training were suggested. Most of the entries in this bibliography were assembled in 1984 through 1985. Study of these materials contributed to the completion of the project research that followed. This later work is reported in the project technical report 2 and the final report. This bibliography is most useful when combined with examination of technical reports 1 and 2 and the final project report.

Jan 7, 1988

By M. A. Elliott, F. W. Brown

"INTRODUCTION During the recent war the Bureau of Mines, at the request of one of the armed services, investigated the hazards that night be encountered 5n handling perchloric acid, particularly if spilled on certain materials. The hazardous nature of perchloric acid when mixed with reducing agents had been known qualitatively, but it was desired to obtain quantitative data on the explosion hazards of such materials. Accordingly, tests were made to determine the sensitivity of mixtures of perchloric acid and oxidizable materials to initiation by heat, impact, sparks, flame, and explosive impulses. This report summarizes the results of those tests.PROPERTIES OF PERCELORIC ACIDAnhydrous perchloric acid is a colorless,hygroscopic, volatile, mobile liquid that fumes in the air. The anhydrous acid is unstable at ordinary temperatures, and therefore the commercial acid is a water solution containing either 60 percent or 70 percent by weight of the anhydrous acid. The commercial acid is widely used in chemical analysis, frequently to oxidize organic material. If proper precautions are not observed, such an oxidixation may become exceedingly rapid and result in an explosion. Several such explosions involving the acid are mentioned in the literature. 4, 5, 6/"

Jan 1, 1948

By R. F. Tenney

The performances of four anthracite-burning stokers have been observed under identical 74-hp. steam boilers. Fifty runs of 12 and 24 hours' duration were made in accordance with the test code of the American Society of Mechanical Engineers (ASME). The capacity of each stoker for burning anthracite has been determined, the heat efficiency at each fuel rate has been computed, and the various significant items of hear loss have been estimated. The operating data and results from each run are tabulated in this report in the form used in the test code. The heat efficiencies and most significant operating data for each run are also presented graphically for each stoker to establish the trends with increasing boiler outputs, The tests show that rice anthracite can be burned on stokers adapted to its use at heat-conversion efficiencies of 82 percent or more under continuous firing. These high efficiencies are maintained with fuel inputs 30 percent higher and lower than the peak efficiency rate. Moreover, a heat efficiency of 70 percent or more is obtained at 50 percent of the optimum fuel rate, even though the excess air into the furnace cannot be held below 150 percent.

Jan 1, 1960

By G. B. Gait

This report is the fourth in a series concerning the Bureau of Mines program for microfilming maps of abandoned mines in the Pennsylvania anthracite region; a catalog of the microfilmed maps of 70 mines in the Western Middle field is presented. Previous reports were catalogs of microfilmed maps of mines in the Eastern Middle field and in the Wyoming and Lackawanna Basins of the Northern anthracite field. Additional catalogs will be published as the microfilming of significant mining areas is completed.

Jan 1, 1971

By Marcos Meyer

A pelotização é um processo de aglomeração com objetivo de agregar valor aos finos de minérios de ferro (pellet feed). A partir de 2010, a mina de Brucutu situada no Quadrilátero Ferriferro (QF) passa a ser a maior fornecedora de matéria prima para as plantas de Tubarão / Vitória-ES. O estudo avaliou a performance industrial de duas misturas com alta participação de minério de Brucutu, acima do padrão utilizado na usina de pelotização. Os minérios compostos nas misturas foram caracterizados por análise química, física, mineralógica e microestrutural. O desempenho operacional mostrou superior à mistura padrão utilizada para a produção de pelotas para redução direta, permanecendo com os parâmetros de qualidade consoantes com as especificações do produto final. O conhecimento das características geometalúrgicas destas misturas com minério de Brucutu em maior escala foi de suma importância para adequar o processo e custo das principais operações unitárias da planta envolvida (moagem e forno).

Aug 1, 2018

By Ltd. (CYMCO) Technology Center Yunnan Metallurgical Group Co., S. Jian, T. Song, J. D. Miller

"As sulfide zinc ore deposits become exhausted, nonsulfide zinc ore deposits become the other resource for zinc production. However, flotation for zinc recovery from nonsulfide deposits is much more difficult than the flotation of sphalerite from sulfide deposits and may become an option for zinc production only if a suitable processing technology is developed. In this regard, research efforts are being devoted to the flotation of nonsulfide zinc oxide minerals. Some common methods which have been used for the flotation of zinc oxide minerals include sulfidization-flotation, activation, and direct flotation with anionic and cationic collectors. The traditional flotation techniques have low efficiency and difficulty in separation and recovery of the zinc minerals from gangue minerals, for example, smithsonite (ZnCO3) from other carbonate gangue minerals and hemimorphite (Zn4Si2O7 (OH)2·H2O) from silicate gangue minerals. In this study potassium lauryl phosphate was evaluated as a collector for the flotation of nonsulfide zinc minerals. Results from contact angle and microflotation experiments at pH 6–9 show that hemimorphite (Zn4Si2O7 (OH)2·H2O) can be floated from quartz and that smithsonite (ZnCO3) can be floated from calcite. However, when dodecylamine, which is a common collector reported in literature for the flotation of nonsulfide zinc minerals, was used as collector, no significant difference between nonsulfide zinc minerals and gangue minerals was observed at any pH value. Initial evaluation suggests that potassium lauryl phosphate is effective at low concentration and may be a promising collector for zinc oxide mineral flotation.INTRODUCTIONBefore the twentieth century, zinc was mainly produced from nonsulfide ores (Large, 2001; Gilg, Boni, & Cook, 2008). With the development of differential flotation processes in the late 19th century major production switched from nonsulfide zinc sources to sulfide zinc ores (Hitzman, Reynolds, Sangster, Allen, & Carman, 2003; Gilg et al., 2008). However, as it is becoming more difficult to find new sulfide ores, recovery from nonsulfide deposits is being considered. Nonsulfide flotation for zinc recovery is much more difficult than the flotation recovery of sphalerite from sulfide deposits and may become an option for zinc production if a suitable technology is developed. Zinc and lead oxide ores are difficult to beneficiate ores due to their similar floatability with gangue, high solubility in water, and the influence of slimes (Fa, Miller, Tao, & Li, 2005). In order to improve the performance of oxidized minerals, lots of effort is being devoted to this field of study (Ejtemaei & Mahdi, 2014)."

Jan 1, 2016

By Gustavo Ribeiro de Carvalho

O presente trabalho apresenta o projeto que propiciou melhores formas de controles internos possibilitando a redução do itinerário utilizado para o transporte de escória entre os Altos Fornos da Usina Presidente Vargas - UPV e a CSN Cimentos através da implantação de sistemas de controles de viagens por Validadores de Acesso, com a finalidade de viabilizar a utilização da melhor rota correspondente à menor distância entre as unidades operacionais e por consequência menor custo e impactos ambientais. A otimização do trajeto de escória possibilitou sinergia entre economia, meio ambiente e sociedade proporcionando ganhos financeiros e de produtividade. O projeto trouxe melhorias significativas, refletidas nos principais aspectos: Benefício financeiro com a redução dos custos contratuais com transporte interno de Escória; Inovação tecnológica que possibilitou controlar o registro de viagens por caminhão para melhor apuração da quantidade de viagens e maior confiabilidade dos desvios de estoques; Aumento da produtividade através da otimização do trajeto e aumento na performance de abastecimento da Cimentos; Redução mensal de 18 tCO2 eq. de gases do efeito estufa associado a economia média de 6600 litros do aspecto ambiental “consumo de recursos naturais” (Óleo diesel) com a otimização de 13.000 km.

Aug 17, 2017

By D. W. Mitchell

Planning today for what hopefully will never happen is one of the surest ways to decrease the chance of it happening. As Napoleon proved and Ian Mitroff wrote, "The heat and stress of battle is the worst time to make decisions of strategic importance." Mitroff also wrote, "The value of a plan is not that it will ever perfectly match reality, but going through the process of planning speeds the process of recovery. It allows the organization to emotionally work through the worst before it actually happens." This paper concentrates on things miners must consider; on the need for plans to be like a belt conveyor strong enough to carry the load, flexible enough to stretch a little; on the criticality of throwing away fax machines and telephones, and having certain officials at the scene rather than back in head-quarters; on the training of fire brigades and mine-rescue teams; on having company-controlled chromatographs; on having people who can look at trends rather than numbers. Some of the things in this paper might anger some readers; for that, I can only ask them to consider first the problem not their position.

Jan 1, 1993

By Norimasa Yamasaki, Masao Kurosaki

"The effects of plating conditions on the crystal orientation of electrodeposited zinc were investigated by varying elecyrolyte flow rate and current density. Precipitation of the Zn (00 • 2) basal plane is promoted at lower current density and higher flow velocity. Effect of the flow velocity on the mass transport was evaluated based on the polarization measurement in which Cu was used as the tracer. As a result, it has been clarified that the crystal orientation of electrodeposited zinc can be uniquely arranged by the overvoltage (iU0.5) that can be simply calculated by considering -the current density and boundary layer thickness. At the same time, the electrode potential during electrodeposition that can be calculated by using a model based on the competitive reactions of hydrogen reduction 'and zinc reduction exhibits an extremely good correlation with the crystal orientation of electrodeposited zinc.Introduction Electrogalvanized steel sheet has better surface properties than hot-dip galvanized steel sheet, and is used in home electric appliance and automobile applications. Factors such as crystal morphology, crystal orientation and surface roughness have a large influence on its appliance, formability and corrosion resistance [1-3].Electrolysis, condition, bath composition and alloying elements are reported as factors that affect the crystal orientation of the electrogalvanized coating. Factors that can be controlled on time in the production site are electrolysis condition that-is current density and plating solution flow velocity.Some studies[4-6] report that the crystal- orientation of the Zn(00 • 2) plane is increased by promoting, the mass transfer of zinc ions in the plating solution or decreasing the concentration overvoltage, but did not investigate in detail the plating solution flow conditions in the plating cell nor quantitatively determine the effects of both current density and plating solution flow conditions on the crystal orientation of ' electrodeposited zinc."

Jan 1, 2000

By A. G. Loomis

METHODS for measuring relative permeability as a valid function of saturation were compared by the. Bureau of Mines, using core samples from representative oil-productive California formations, from the Bartlesville sand in Oklahoma, and from synthetic samples. Measurements for gas-oil systems were made by steady-state dynamic, unsteady-state displacement and two stationary-phase methods. Measurements for water-oil systems were made by the unsteady-state displacement method. As the ratio rather than individual relative permeabilities is measured by the last method, three methods for calculating individual relative permeabilites from their measured ratio were compared for gas-oil systems and two methods for water-oil systems. Errors arising from capillary discontinuities, such as the end effect and stabilized-zone flow, are discussed and evaluated; possible errors rocs arising from turbulant flow are also examined. The inapplicability of non-steady-state methods for water-oil systems that are not definitely oil-wet is discussed in detail. Measurements of relative permeability to both gas and oil can be made quickly and accurately by the steady-state dynamic method when rates of flow of the two phases are sufficient to minimize the capillary discontinuity at the outflow end of the sample. At such rates relative permeability-saturation measurements are essentially independent of the rate of flow. The steady-state method wits modified by a dispersion section at the inflow end of the sample acid designated tie dispersed-feed method.

Jan 1, 1962

By Joseph Moses Botbol

Two methods are developed whereby; (1) mineralogic data can be arranged in order of typicality, and (2) mineralogic data external to a model can be compared with the model and the degrees of association computed. Thirty arbitrarily selected base metal mining districts in the conterminous United States were classified as copper, lead, or zinc districts on the basis of tonnage of the major base metal produced. For each of the copper, lead, and zinc districts binary-occurrence distributions were compiled for primary (unoxidized) and secondary (oxidized) minerals. Primary and secondary minerals were then arranged in order of decreasing typicality. Model copper districts are most typified by primary chalcopyrite, pyrite, and secondary malachite. Model lead districts are most typified by primary galena, quartz, pyrite, sphalerite, and secondary anglesite and cerargyrite. Model zinc districts are most typified by primary sphalerite, galena, pyrite, quartz, and secondary smithsonite and cerus-site. The Park City district was removed from the model and its primary and secondary mineralogy was compared with the model copper, lead, and zinc districts. The primary mineralogy of the Park City district is about equally associated with the model copper and lead districts, but the secondary mineralogy is much more akin to the model copper districts. Thus, with respect to the model data, the geochemical target presented by the Park City district resembles a copper district more closely than a lead district.

Jan 1, 1969

By G. A. Smyres

The Bureau of Mines investigated a HCI-02 leaching procedure to recover Cu, Ni, and Co from a low-grade bulk sulfide flotation concentrate prepared from the Duluth gabbro complex. Since the Duluth gabbro complex is the largest known and unexploited Ni resource in the United States, the development of options for extracting the metal values from the flotation concentrate of this domestic resource is necessary. Conditions were determined for producing a pregnant solution low in Fe to facilitate recovery of the metal values. Leaching experiments were conducted at 15 pct solids, 1000 to 1200 C, 0.2 to 0.3 g HCI per gram concentrate in a 50-gal reactor pressurized to 50 pSig with 02. Base metal extractions from the concentrate were, in percent, 90 to 92 Cu, 99 Ni, 97 to 99 Co, and 0.1 .Fe. Precious metals extractions were erratic and unpredictable; at best their extractions were, in percent, 55 Au, 90 Ag, 40 Pt, and 45 Pd. The reaction time at 1200 C was 0.5 h. The use of compressed air instead of 02 as the oxidant was also investigated. Solvent extraction using LIX 622 was used to remove Cu from the pregnant solution. Cementation on Cu was tested for precious metals recovery, while sulfide precipitation was used to produce a Ni-Co product. A conceptual flowsheet for treating the Duluth gabbro concentrate is proposed.

Jan 1, 1985