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By D J. Williams

The majority of surface tailings storage facilities continue to employ sub-aerial tailings slurry deposition. Surface TSFs are typically sized and operated in a way to minimise the initial capital cost of the facility, driven largely by the net present value approach to accounting. This generally leads to too small a storage, too fast a rate of rise of the tailings, and difficulties in managing supernatant water. In turn, this results in wet and soft tailings deposits of high moisture content and low density, and the need for frequent and costly tailings dam raises. Further, such tailings deposits often do not facilitate closure and rehabilitation of the facility. Globally, there are on average over two failures annually of such tailings dams, resulting in loss of life, damage to infrastructure and environmental impact downstream, and the loss of company shareholder value and reputation. Recent high profile tailings dam failures are threatening the mining industry’s financial and social licence to operate.Among the physical processes that tailings undergo on sub-aerial deposition are beaching, hydraulic sorting down the beach according to particle size and specific gravity, settling, consolidation, and desiccation on exposure to the sun and wind. Beaching and hydraulic sorting have proved difficult to test at laboratory scale and difficult to model, and are best assessed in the field. Settling, consolidation and desiccation may be assessed at laboratory scale, but to date there has been an absence of tests to form the basis for the design and management of tailings deposition, and ultimate closure and rehabilitation. The paper describes recent advances in tailings testing methods, including a purpose-built slurry consolidometer that tests the settling and consolidation of tailings from a slurry consistency, simulating increasing tailings depth to about 50 m; and a purpose-built instrumented column that tests the settling, self-weight consolidation and desiccation of a surface layer of tailings, also from a slurry consistency. Selected test results from these two apparatus are presented in the paper, together with brief descriptions of how they may be used to better design tailings slurry deposition. In addition, planned further advances in tailings testing methods are briefly described.CITATION:Williams, D J, 2018. Recent advances in tailings testing methods, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 8–37 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By C Armstrong, B Wentzinger

Upstream embankment raises often represent the lowest cost option for increasing the capacity of tailings storage facilities (TSF), but also pose the highest stability risk due to constructing on top of previously deposited tailings.This paper presents an overview of key aspects in the geotechnical investigation and design of upstream raises and some recent lessons learnt from experience across a number of TSFs in Australia. A summary of recommended field investigation and laboratory testing methods is provided with a focus on collecting quality information for design purposes. A strong focus is given in developing an accurate assessment of pore water pressures, which, if not correctly understood can have disastrous consequences on tailings strength parameter interpretation and wall stability assessment in static and post-seismic conditions.The assessment of the contractive or dilative shearing behaviour of the tailings material and rigorous interpretation of design characteristic values are presented. Some comments on stability analysis options and proposed methodology are also provided.CITATION:Wentzinger, B and Armstrong, C, 2018. Lessons learnt in geotechnical investigation and stability analysis for upstream tailings storage facility raise design, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 333–348 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By T Alexieva

Since the early 1900s the geotechnical community has investigated every significant failure of a tailings dam, improved our knowledge of the behaviour of the tailings storage facilities, developed analysis methods, compiled lessons learned, and committed to zero failures. The rate of occurrence of tailings dam failures has reduced since the 1980s, however, failures continue to occur and continue to surprise us. At BHP, we have decided to take an approach to the tailings management that is similar to the approach to safety. We are looking at ways to eliminate, substitute, separate or engineer around the hazard (tailings dam failure). As such, our ultimate long term goal would be to eliminate the need for new tailings facilities. Unfortunately, we have not developed yet technologies for extracting many of the common metals and minerals without producing tailings. Our shorter term goal is to substitute the current conventional slurry tailings facilities with less risky dryer facilities. We are working with vendors and research organizations to develop technologies that can be efficiently applied on a large scale. At the same time, we are committed to using the best available engineering to reduce the risks associated with our existing and new conventional tailings facilities. The best engineering can be achieved by people with the appropriate education, experience, attention to detail, discipline and authority. We have implemented a system of governance to make sure, we have the best engineering applied to all our facilities, considering the specific conditions at each site.This paper presents the current tailings governance process at BHP, and the initiatives that were undertook towards achieving a zero failure goal. CITATION:Alexieva, T, 2018. Tailings governance, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 2–7 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By M Barker, H Li

The total number of tailings accidents has reduced from over 50/decade in the 1960s-1980s to less than 30/decade in the 2000s to 2010s. However, the rate of significant tailings dam failures has not been reduced. The significant tailings dam failures the mining industry experienced in the recent history include: Merriespruit, South Africa, 1994; Los Frails, Spain, 1998; Kolontár, Hungry, 2010; Mount Polley, Canada, 2014; and Samarco, Brazil, 2015. The conventional Factor of Safety approach itself may not be enough to further reduce the rate of significant tailings failures due to its limitations such as uncertainty. For example, the same factor of safety could have a vast range of annual probability of failure for different tailings dams, and insufficient consideration of failure consequence. This paper presents a risk based approach for design with the objective being to minimise tailings dam failures, especially those significant tailings failures with high consequence and low probability. This approach includes risk based design and risk management using bowtie tools. In the risk based design, quantitative analysis will be used to estimate the annual probability of failure and the tolerable failure criteria is linked to the consequence category. Bowtie analyses will be used to understand hazards and risks and identify and select independent controls that are effective in preventing and mitigating catastrophic failures. In this paper, examples of risk based design and bowtie analyses are presented and discussed. CITATION:Li, H and Barker, M, 2018. Risk-based approach for minimising tailings dam failures, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 397–414 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By A Li, H Jinto, M Laxman

The behaviour of tailings under cyclic loading has an impact on the stability and deformation of tailings dams and a good understanding of the cyclic behaviour of the tailings under earthquakes is important for tailings engineers and tailings operators for the design and safe operation of tailings dams. This paper presents an investigation into the cyclic behaviour of tailings using both laboratory cyclic direct simple shear (DSS) testing and numerical modelling. The laboratory testing involved cyclic DSS tests on gold tailings and zinc-copper tailings under different loadings and loading frequencies. The gold tailings specimen tested at a higher loading frequency and a higher cyclic stress ratio experienced spontaneous liquefaction during cyclic shearing and the zinc-copper tailings specimen tested at a lower loading frequency and a similar cyclic stress ratio exhibited ductile behaviour and liquefied due to cyclic mobility. The liquefaction behaviour of the tailings was modelled using an advanced constitutive model (UBCSAND), which was developed specifically to model soil liquefaction and strain softening under cyclic loading. The constitutive soil model presents the nonlinear soil behaviour under dynamic loading using a hyperbolic stress-strain relation. Dynamic analyses were carried out using a finite difference program FLAC. The cyclic stress-induced excess pore water pressures measured in the laboratory were modelled using numerical simulations of the laboratory tests under different loading conditions. The results of the non-linear dynamic analyses demonstrated the capability of numerical modelling of cyclic shearing induced excess pore water pressure and the onset of the spontaneous liquefaction. The laboratory investigation and numerical modelling technique provided the key properties and parameters for the dynamic analyses to assess the stability and deformation of tailings dams under design earthquake events. More importantly, the laboratory tests and numerical modelling provided some insights into liquefaction behaviour of the tailings during earthquakes. CITATION:Li, A, Laxman, M and Jinto, H, 2018. Liquefaction behaviour of tailings under cyclic simple shear testing, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 250–262 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By P Marianelli, J Theiler, B Beamish, A Spillman

The presence of reactive pyrite in waste rock contributes to the hazard of spontaneous combustion in emplacement facilities as it acts as an initiator of self-heating at low ambient temperatures. Organic carbon also present in the waste rocks acts as a fuel at elevated temperatures above 120°C and can lead to thermal runaway resulting in eventual ignition. A new laboratory test method (adiabatic incubation testing) is now available that can identify the presence of reactive pyrite and quantify the self-heating behaviour of the waste rock. McArthur River Mine has a waste rock profile that contains pyritic shale units, which have created spontaneous combustion events in the past. A systematic sampling and testing program is underway to characterise the spontaneous combustion hazard likelihood of the McArthur River Mine waste rocks to provide a sound database for future mine planning of the waste removal and emplacement. This paper presents some initial outcomes of this program and shows the leading practice in spontaneous combustion hazard assessment and management that has been adopted at McArthur River.CITATION:Beamish, B, Marianelli, P, Theiler, J and Spillman, A, 2018. Spontaneous combustion hazard assessment of McArthur River Mine waste rock, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 422–426 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By D A. Williams, P J. Chapman

The acceptable rate of rise of the tailings beaches on upstream-raised tailings storage facilities (TSFs) is critical to life of mine planning. This is illustrated through a case study in Western Australia presented in this paper. Accurate estimates of expected beach slopes, the maximum rate of rise at which the tailings can be placed, and the dry density that the tailings solids will achieve after deposition (stored density) are required in order to design TSFs that will allow upstream raises to be constructed safely and economically. Where operations have been occurring for some time, these three parameters are able to be measured and can be well-defined. If process plant throughputs are proposed to increase through mine expansion, for example, increasing the rate of rise of the tailings can compromise the potential for upstream TSF raising, thus influencing the viability of such an expansion, the timing for its implementation, and significantly increase costs.This paper outlines how rate of rise can be a key constraint, and that ‘rules of thumb’ that are typically applied may not result in the outcomes they were meant to achieve. An example of an experimental method to justify an increase to the ‘rule of thumb’ ~2.5 m/year limit for gold tailings in a semi-arid climatic setting is discussed, followed by rate of rise modelling that ultimately framed the decision-making process for a mine expansion. The rate of rise modelling method was adopted to carefully distribute tailings deposition across four TSFs, comprising nine separate tailings cells, in order to maintain appropriate rates of rise. The implications resulting from various deposition splits are presented, including the need for expansion. In addition, this paper outlines the effect of rate of rise on the state (density) of the tailings after deposition, and provides commentary on how anecdotally acceptable rates of rise, based on the aforementioned ‘rule of thumb’ of 2.5 m/year may not provide assurance of geotechnical stability through the tailings achieving a dilative state, as has been thought in the past. An example of the influence of rate of rise on the state of the tailings, with respect to air-drying and the critical state line (CSL) for the material, is presented. The data indicate that reducing the rate of rise may allow a higher dry density to be achieved through air-drying (evaporative desiccation), sufficient to move the material from the contractive to the dilative zone (i.e. from above the CSL, to sufficiently below it).CITATION:Chapman, P J and Williams, D A, 2018. The importance of rate of rise in life-of-mine planning of an upstream raised tailings storage facility – a case study, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 350–360 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By D Liu, M Edraki, L Berry

The presence of clay minerals slows down the settling rate and mitigates compact consolidation efficiency in tailings dewatering. The increasing use of saline water in many plants, affects the dewatering performance and presents the mining industry with new concerns. Efficient tailings dewatering is a great challenge due to the complexity character of tailings, especially clay mineralogy, clay content, and water chemistry. In this study, existing studies of the effect of different affecting parameters, such as pH, ionic strength and polymer flocculants, on clay aggregation behaviours are reviewed. The settling behaviours of three types of commonly observed clay minerals in tailings, kaolinite, bentonite, and illite, are also investigated in saline water with different water salinity as a case study. The settling rates of clay minerals are found to be affected by water salinity, clay type, clay content and polymer dosage levels. High salinity water hinders the settling of kaolinite but assists the settling of bentonite and illite through formation of different aggregation structures.The current work has indicated that strategies to promote more rapid dewatering could include adjusting flocculant type or level, water salinity and salt balance, and tailings solid content levels. Implementing dewatering strategies may require a more detailed knowledge of the effect of surface chemistry on the nature and strength of the clay inter-particle forces. This study discusses the research gaps on how to better manage clay-rich tailings in saline water and identifies new research directions. The development of a water management model, supported through in-line monitoring data to predict and manipulate of the surface chemistry of the clay component of the tailings could be a new direction to manage the issues associated with clay minerals in the process of dewatering and tailings management. Mine planning (water use requirements, operating costs) could benefit from more detailed studies on dewatering of clay-rich tailings in saline water. CITATION:Liu, D, Edraki, M and Berry, L, 2018. Improving the dewatering efficiency of clay-rich tailings in saline water, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 476–484 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By Y Xu, J Hacker, D J. Williams

Shear strength parameters of compacted clay liners are needed to analyse the stability of mine waste dumps containing compacted clay liners as sealing layers for potentially acid forming waste rock. A representative clay sample was supplied by McArthur River Mine from the mine site in the Northern Territory, Australia, with an average as-supplied gravimetric moisture content of about 13.6%. The clay was compacted in a 100 mm by 100 mm direct shear box at the as-supplied moisture content to a dry density of 1.85 t/m3, representing the field compaction specification adopted by the mine. To determine the peak and ultimate shear strengths of the compacted clay, single-stage direct shear testing was carried out at nominal initial normal stresses of 50 kPa, 100 kPa and 200 kPa, representing shallow depths of burial in the North Overburden Emplacement Facility of about 2.8 m, 5.6 m and 11.1 m, respectively (assuming a waste rock wet unit weight of 18 kN/m3). Three shearing rates of 1 mm/min (rapid), 0.1 mm/min (intermediate) and 0.01 mm/min (slow) were applied to study the influence of shearing rate on shear strength. In addition, the development of a residual shear plane was tested by reversal and re-shearing in the direct shear box. In the first shearing, the peak and ultimate shear strengths are determined. The normal load was then removed and the box rewound to its starting position. The normal load was then re-applied and the specimen re-sheared. Two reversals were applied to each specimen, and it was found that there was no significant reduction in shear strength. Finally, based on a range of shear strengths obtained in the laboratory for McArthur River Mine clay and other materials by various laboratories over time, shear strength parameters for the compacted clay were recommended for use by the mine.CITATION:Xu, Y, Williams, D J and Hacker, J, 2018. Shear strength of compacted clay liner at McArthur River Mine, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 208–219 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By S M. Gover

Estimating the probability of failure for embankments is not intuitive. It requires not only an appreciation of the strength of the embankment, but an understanding of the variability and uncertainty in the strength parameters as well. These additional aspects are, in themselves, relatively new to most practicing engineers, and therefore require some discussion.This paper discusses the concepts of probability and uncertainty, and presents a reliability-based numerical experiment, together with a literary study and collation of some of the author’s historical slope stability analyses, to investigate whether a direct relationship between safety factors and probabilities of failure exists for certain levels of uncertainty in strength parameters. In doing so, a useful tool is presented whereby knowing the safety factor of a simple slope or embankment with a consistent level of uncertainty, one can infer an approximate probability of failure.CITATION:Gover, S M, 2018. Linking safety factor to probability of failure, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 384–396 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By W Ludlow, C Harrington

This paper presents an overview of the design and construction challenges to implement capping systems on Tailings Storage Facility’s (TSF) based on recent projects in Australia. Key aspects discussed include the cover design and barrier system to encapsulate the tailings, designing for a service life of 1,000 years, water management considerations. construction on tailings, vegetation selection and agronomy of the available capping soils plus the Health, Safety and Enivornmental challenges faced in working on tailings. Lessons learned from experience in capping TSFs are also presented. CITATION:Ludlow, W and Harrington, C, 2018. Experience with Capping of Tailings Storage Facilities for Decommissioning Projects in Australia, in Proceedings Mine Waste and Tailings Stewardship Conference 2018, pp 157–165 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 23, 2018

By Julio Cesar Tremolada

La lixiviación con tiosulfato de amonio (ATS) puede ser considerada como una alternativa ecológica viable para lixiviar metales preciosos, por comparación con la alta toxicidad del proceso convencional de cianuración, especialmente en el caso de algunos minerales refractarios con presencia de impurezas que provocan baja recuperación de oro y altos consumos de cianuro. En este estudio se evaluó un mineral aurífero asociado a carbón para confirmar los óptimos resultados de la tecnología innovadora ATS, cuyos principales compuestos son amonio tiosulfato, sulfato de amonio, ion cúprico y metabisulfito. De acuerdo con el estudio reseñado en este artículo, la concentración cuprífera a un ratio de 0.5 Kg/Tm proporciona una óptima extracción de oro de 75.20% con 8.60 Kg/Tm de ratio de consumo de tiosulfato (escala de tratamiento: 10,000 Tm en pads de lixiviación a granulometría de 90% <2.5 pulgadas, en 45 días de lixiviación); y extracción de oro de 81.20% con 6.5 Kg/Tm de consumo de tiosulfato en mineral aurífero limpio y de características dóciles (escala de tratamiento: 20,000 Tm en pilas de lixiviación en similares tamaños granulométrico y tiempo de lixiviación). En tanques agitadores, las extracciones de oro son del orden de 90.75% en minerales refractarios (en 120 horas de lixiviación a granulometría de 80% <325 mallas), con ratio de tiosulfato de 7.4 Kg/Tm; y en minerales limpios/dóciles las extracciones de oro alcanzan 93.6% (en 120 horas de tratamiento a granulometría de 80% <325 mallas), con ratio de tiosulfato de 6.3 Kg /Tm. En cambio, la lixiviación convencional con cianuro en este tipo de minerales refractarios no supera al 10% de la recuperación metalúrgica del oro.

May 30, 2018

By Jorge Cangahuala

La neurociencia ha cobrado un papel muy importante en las organizaciones en las últimas décadas. En ese contexto, la neuroprevención busca determinar las potencialidades y limitaciones del cerebro al momento de enfrentar situaciones con potencial de algún incidente o accidente laboral. Identificando estos indicadores y conexiones neuro-centrales podemos tener mapeado cómo se comporta nuestro cerebro, cómo lo refleja en el comportamiento (acto seguro o inseguro) y cuáles técnicas implementar en cada proceso, para asegurar una cultura de seguridad preventiva y sostenible en el tiempo que se orienta primero al factor humano como generador de conductas que pueden ser remodeladas hacia acciones seguras.

Apr 30, 2018

By Gustavo De la Torre

Más allá de contar con las certificaciones ISO 9001, ISO 14001, Y OHSAS 18001, la planta concentradora de Cerro Lindo busca ser catalogada como un desempeño de categoría mundial, lo que implica usar la capacidad total del área (procesos, tecnología y talento humano) basado en un equipo de alta performance-EAR, y gestionar de forma sistemática seguridad, salud ocupacional, medio ambiente, costos, productividad, calidad y confiabilidad, además del proceso productivo. En el presente artículo se analiza información recopilada durante la fase de crecimiento, se presentan diferentes etapas en desarrollo y se describen los estudios realizados en la planta de beneficio, a nivel técnico y de gestión, con óptimos resultados de producción, eficiencia e indicadores metalúrgicos.

Apr 30, 2018

By Xueqin Li, Xuewei Lv, Yu Zhang, Wenchao He

In order to make full use of the chromium-bearing vanadium titanium magnetite with chromium, a new process of “direct reduction-electric furnace smelting separation” has been developed for recovering the iron, vanadium, titanium and chromium in recent years. In this paper, FactSage, one of the most frequently-used thermodynamic calculation software, was used to calculate the reduction degree of Fe, V and Cr with different n C/nO (mole ratio of carbon and oxygen). It was found that the suitable operating conditions of direct reduction process were n C/nO > 1.07 and T > 1473 K. In addition, the direct reduction experiment of Hongge vanadium titanium magnetite was carried out and the obtained samples after direct reduction were analyzed by XRD and chemical composition. The result shows that the metallization rate of carbon-containing pellet is nearly 90%.

Mar 1, 2018

By Kun Wang, Weipeng Luan, Qingbo Yu, Qin Qin

The oxygen uncoupling property of the oxygen carrier is essential for the chemical looping gasification process. In this paper,the combined Cu-based oxygen carrier were prepared by mechanical mixing method. XRD and SEM were used to characterize the oxygen carrier prepared. TG experiments were performed in a thermal analyzer to investigate the oxygen uncoupling property. The XRD pattern of the fresh oxygen carriers showed that the phases of the oxygen carriers were stable.The active phase of oxygen carrier was CuMnO. With the increasing of x 3-x 4 heating rate, the starting and ending temperatures of the reduction reaction increased. However, the reaction time decreased and the reduction rate increased. With the increasing of oxygen concentration, the starting temperatures of the reduction reaction shifted to high level. Temperature had great effect on the reduction rate and the reduction rate increased with increasing of the reduction temperatures.

Mar 1, 2018

By Ahmad Ghahreman, James McNeice

Separation of rare earth elements (REE) is often achieved by acid leaching of mineral concentrates followed by subsequent solvent extraction (SX), to purify individual rare earth metals (REM). Cerium, the most abundant REE, is usually the largest component of these ores. Demand for less prevalent REE, such as praseodymium and dysprosium; have led to a market saturation and price collapse of cerium. One method of improving the economics of REE separation is to remove cerium from solution prior to SX. This is accomplished via the oxidation of cerium (III) to cerium (IV), which precipitates as cerium hydroxides. This study probes the efficacy of four oxidants; hydrogen peroxide, sodium hypochlorite, potassium permanganate, and Caro’s Acid with the goal of improving cerium removal whilst minimizing REE and reagent losses. The effect of oxidant type and dosage, pH, cerium concentration, and temperature on the kinetics of the process will be discussed.

Mar 1, 2018

By Pamela Bogust, York R. Smith

Photovoltaic (PV) modules are becoming an ever increasingly larger part of our energy portfolio. As more and more PV modules are installed and come on-line, management of end-of-life (EOL) modules becomes an important issue. Currently, management of overburden EOL PV modules is not an issue, but is anticipated to be by 2030. Recovery and recycling of valuable metals in PV modules presents several environmental and economic advantages. In this brief review, we will describe processes for refurbishing and recycling of PV silicon. These processes involve some combination of mechanical, thermal, and chemical processing, all of which all have their oPV) modules have become wn respective challenges. Also, projections of PV module material streams are also highlighted.

Mar 1, 2018

By Mairyanne S. S. Souza, Sergio Neves Monteiro, Victor Tomazinho Bartolazzi, Dienifer Daiana Konzen

Clay is used in the production and manufacture of materials for the construction of buildings from remote periods. Advances and improvements of its properties have allowed several applications to this raw material. In this work the quality of four types of ceramic tiles manufactured or used in the northwest of the state of Rio de Janeiro and in the southeastern state of Minas Gerais was evaluated. Geometric, physical and mechanical aspects were evaluated according to the Brazilian standard NBR 15310:2009. The results indicate numerous nonconfor- mities with highlights for geometric parameters, surface flatness and yield tests. The nonconformities found in the samples indicate that there was a failure in the production control of the product and in the approval of the control of the lots.

Mar 1, 2018

By Ozgul Keles, Dila Sivlin

Lithium ion batteries are potential energy source of next generation electric vehicles (EVs). However, some problems such as safety, durability, low capacity, cycle life etc. restrict their use in EVs. These problems mostly related with cathode materials, an improvement in cathode materials may cause significant changes in battery performance. In this work, to overcome cycle life problem Al2O3 coating on LiNi0.5Mn0.3Co0.2O2 cathode material produced by sol-gel method. The surface modification of LiNi0.5Mn0.3Co0,2O2 was started by adding LiNi0.5Mn0.3Co0.2O2 powders into alumina sol. Then, sonication was started and two different sonication powers were tested (45, 100%). After the second gel is obtained, last heat treatment for Al2O3 crystallization was done at 600 °C for 4 h. X-ray diffraction (XRD) measurements showed that the material had a well-ordered layered structure and Al was not in the LiNi0.5Mn0.3Co0.2O2. Al2O3 coated materials show better cycling performance compared to the pristine material. It is believed that, this improvement is caused by the fact that Al2O3 layer prevents direct contact between active material and electrolyte and reducing decomposition reactions.

Mar 1, 2018